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(2-Allylphenoxy)trimethylsilane
C12H18OSi
18042-43-8
Product Product Code Order or Specifications
(2N) 99% (2-Allylphenoxy)trimethylsilane SI-OM-02 Contact American Elements
(3N) 99.9% (2-Allylphenoxy)trimethylsilane SI-OM-03 Contact American Elements
(4N) 99.99% (2-Allylphenoxy)trimethylsilane SI-OM-04 Contact American Elements
(5N) 99.999% (2-Allylphenoxy)trimethylsilane SI-OM--05 Contact American Elements
(2-Allylphenoxy)trimethylsilane also known as 3-(Trimethylsiloxy)propene, is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Hydride compounds are used often used as portable sources of hydrogen gas. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Silicon is a Block P, Group 14, Period 3 element. The number of electrons in each of Silicon's shells is 2, 8, 4 and its electronic configuration is [Ne] 3s2 3p2. In its elemental form silicon's CAS number is 7440-21-3. The silicon atom has a radius of 117.6.pm and it's Van der Waals radius is 210.pm. Silicon is not toxic but can cause chronic respiratory problems if inhaled as a fine silica or silicate dust. Asbestos silicates are carcinogenic. Silicon isElemental Silicon one of man's most useful elements. It makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, being exceeded only by oxygen. The Czochralski process is commonly used to produce single crystals of silicon used for solid-state or semiconductor devices. Silica, as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Silicon is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Ultra high purity silicon can be doped with boron, gallium, phosphorus , or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics and space-age industries. Hydrogenated amorphous silicon has shown promise in producing economical cells for converting solar energy into electricity. Silcones are important products of silicon. They range from liquids to hard, glasslike solids with many useful properties. Silicon was first discovered by Jons Berzelius in 1823. The name Silicon originates from the Latin word "silex" which means flint or hard stone. See Silicon research below.

Hydrogen is a Block S, Group 1, Period 1 element. The electronic configuration is 1s1. In its elemental form hydrogen's CAS number is 1333-74-0. The hydrogen atom has a radius of 37.3.pm and it's Van der Waals radius is 120.pm. Hydrogen is highly flammable. Hydrogen was discovered by Sir Henry Cavendish in 1766.
Formula CAS No. Appearance Molecular Weight
C12H18OSi 18042-43-8   206.36
 
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Recent Research & Development for Silicon

  • RECONSTRUCTION OF THE THUMB WITH A MODIFIED WRAP-AROUND FLAP IN A PATIENT SUFFERING FROM ?-THALASSEMIA MINOR. Galeano M, Checcucci G, Ceruso M. Hand Surg. 2011;16(3):361-5. PMID: 22072476 [PubMed - in process]

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  • Structures of medium sized tin cluster anions. Wiesel A, Drebov N, Rapps T, Ahlrichs R, Schwarz U, Kelting R, Weis P, Kappes MM, Schooss D. Phys Chem Chem Phys. 2011 Nov 9. [Epub ahead of print] PMID: 22071636 [PubMed - as supplied by publisher]

  • Discrimination task reveals differences in neural bases of tinnitus and hearing impairment. Husain FT, Pajor NM, Smith JF, Kim HJ, Rudy S, Zalewski C, Brewer C, Horwitz B. PLoS One. 2011;6(10):e26639. Epub 2011 Oct 31. PMID: 22066003 [PubMed - in process]

  • A suggested technique for the application of the cone beam computed tomography periapical index. Esposito S, Cardaropoli M, Cotti E. Dentomaxillofac Radiol. 2011 Dec;40(8):506-12. PMID: 22065800 [PubMed - in process]

  • (4-Chloro-3-nitro-benzoato)triphenyl-tin(IV). Win YF, Choong CS, Teoh SG, Quah CK, Fun HK. Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1270-1. Epub 2011 Aug 27. PMID: 22065496 [PubMed]

  • Bis{2-[(E)-(5-tert-butyl-2-hy-droxy-phen-yl)diazen-yl]benzoato}dimethyl-tin(IV). Basu Baul TS, Paul A, Tiekink ER. Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1383-4. Epub 2011 Sep 14. PMID: 22065466 [PubMed]

  • Chloridodiphen-yl{[1-(1,3-thia-zol-2-yl-?N)ethyl-idene]-4-phenyl-thio-semicarbazidato-?N,S}tin(IV) methanol monosolvate. Arumugam SR, Dasary SS, Venkatraman R, Yu H, Fronczek FR. Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1409-10. Epub 2011 Sep 30. PMID: 22065366 [PubMed]

  • catena-Poly[[triphenyl-tin(IV)]-?-5-amino-2-nitro-benzoato-?O:O]. Win YF, Choong CS, Teoh SG, Quah CK, Fun HK. Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1276-7. Epub 2011 Aug 27. PMID: 22064934 [PubMed]

  • Dual detection strategy for electrochemical analysis of glucose and nitrite using a partitionally modified electrode. Wang J, Diao P, Zhang Q. Analyst. 2011 Nov 7. [Epub ahead of print] PMID: 22064849 [PubMed - as supplied by publisher]

  • fac-(2-Amido-ethyl-?C,O)trichlorido(urea-?O)tin(IV). Howie RA, de Lima GM, Tiekink ER, Wardell JL, Wardell SM. Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1420-1. Epub 2011 Sep 30. PMID: 22064619 [PubMed]

  • Highly sensitive nonenzymatic glucose sensor based on electrospun copper oxide-doped nickel oxide composite microfibers. Cao F, Guo S, Ma H, Yang G, Yang S, Gong J. Talanta. 2011 Oct 30;86:214-20. Epub 2011 Sep 8. PMID: 22063533 [PubMed - in process]

  • Cross-Linked Perylene Diimide-Based n-Type Interfacial Layer for Inverted Organic Photovoltaic Devices. Hains AW, Chen HY, Reilly TH, Gregg BA. ACS Appl Mater Interfaces. 2011 Nov 7. [Epub ahead of print] PMID: 22059439 [PubMed - as supplied by publisher]

  • Bis-(chloro-acetato-?O)bis(trimethyl-silylmethyl)tin(IV). Ding RF, Wang QB. Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1190. Epub 2011 Aug 2. PMID: 22058841 [PubMed]

  • A new langbeinite-type phosphate: K(2)AlSn(PO(4))(3). Li HY, Zhao D. Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):i56. Epub 2011 Sep 20. PMID: 22058680 [PubMed]

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  • Allylsilanes in "Tin-free" Oximation, Alkenylation, and Allylation of Alkyl Halides. Rouquet G, Robert F, Méreau R, Castet F, Landais Y. Chemistry. 2011 Nov 3. doi: 10.1002/chem.201101842. [Epub ahead of print] PMID: 22052660 [PubMed - as supplied by publisher]

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Recent Research & Development for Hydride

  • Diazaphospholenes: N-Heterocyclic Phosphines between Molecules and Lewis Pairs. Gudat D. Acc Chem Res. 2010 Jun 24. [Epub ahead of print] PubMed PMID: 20572668.

  • Thymidylate Synthase Catalyzed H-Transfers: Two Chapters in One Tale. Wang Z, Kohen A. J Am Chem Soc. 2010 Jun 24. [Epub ahead of print] PubMed PMID: 20575541.

  • Cobalt-Mediated Linear 2:1 Co-oligomerization of Alkynes with Enol Ethers to Give 1-Alkoxy-1,3,5-Trienes: A Missing Mode of Reactivity. Lebœuf D, Iannazzo L, Geny A, Malacria M, Vollhardt KP, Aubert C, Gandon V. Chemistry. 2010 Jun 23. [Epub ahead of print] PubMed PMID: 20575116.

  • Synthesis and evaluation of silica hydride-based fluorinated stationary phases. Pesek JJ, Matyska MT, Prajapati KV. J Sep Sci. 2010 Jun 22. [Epub ahead of print] PubMed PMID: 20572267.

  • Kinetics of substituted silylene addition and elimination in silicon nanocluster growth captured by group additivity. Adamczyk AJ, Reyniers MF, Marin GB, Broadbelt LJ. Chemphyschem. 2010 Jun 21;11(9):1978-94. PubMed PMID: 20549662.

  • Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides. Tobisu M, Fujihara H, Koh K, Chatani N. J Org Chem. 2010 Jun 17. [Epub ahead of print] PubMed PMID: 20557065.

  • Thermal Decomposition of Mono- and Bimetallic Magnesium Amidoborane Complexes. Spielmann J, Piesik DF, Harder S. Chemistry. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20564288.

  • Versatile New C(3)-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize Cu(I) and Rh(I) Species and Tune Their Reactivity. Wassenaar J, Siegler MA, Spek AL, de Bruin B, Reek JN, van der Vlugt JI. Inorg Chem. 2010 Jun 16. [Epub ahead of print] PubMed PMID: 20552965.

  • Iron-Catalyzed Hydrogen Production from Formic Acid. Boddien A, Loges B, Ga¨rtner F, Torborg C, Fumino K, Junge H, Ludwig R, Beller M. J Am Chem Soc. 2010 Jun 15. [Epub ahead of print] PubMed PMID: 20550131.

  • Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation. Yi CS, Lee DW. Organometallics. 2010 Mar 19;29(8):1883-1885. PubMed PMID: 20567607; PubMed Central PMCID: PMC2887707.

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