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99% 2N 99.9% 3N     99.99% 4N   99.999% 5N     99.9999% 6N 

Thin Film Using Sputtering Targets
AE Thin Film™

With the advancement of microelectronics beginning in the 1960s, the need for thin film products for electronic and semiconductor layers lead to the development of the "sputtering" on of layers using physical vapor deposition (PVD) on to a selected substrate from a "target" bearing the layer material. As advancements in sputtering technology were made; particularly in the type of sputtering equipment offered, sputtering of thin film layers found application in numerous other scientific and industrial fields, including optical and architectural glass, memory storage devises, tool coatings and, most recently, fuel cells and solar energy panels.

32.4 (A)/00.022


Hydrogen                                 Helium
Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                   
    Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
    Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium      

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American Elements specializes in producing high density ultra high purity (99.9% to 99.9999%) sputtering targets for all of these applications using both vacuum melt/casting and hot isostatic pressing (HIP) technology. Sputtering targets are available monoblock or bonded with dimensions and configurations up to 820 mm with hole drill locations and threading, beveling, grooves and backing designed to work with both older sputtering devises as well as the latest process equipment, such as large area coating and flip-chip applications. Research sized targets are also produced as well as custom sizes and alloys. All targets are analyzed using best demonstrated techniques including X-Ray Fluorescence (XRF), Glow Discharge Mass Spectrometry (GDMS), and Induction Plasma Spectrometry (ICP).

Applications for sputtering targets have continued to expand. The most recent uses are described below. When relevant, properties and latest research are also covered.

Sputtering Targets for Electronics and Semiconductors. The first commercial use for the sputtering target was in semiconductors and electronics for front end and back end packaging, diffusion barriers, compounds, phase change memory, IC interconnects, micro contacts, and in sensors, MEMs and LEDs. Sputtering targets of copper and copper alloys including copper-nickel, copper-chrome are manufactured for packaging and other applications, as well as, nickel and many nickel alloys including nickel-aluminum, nickel-vanadium, nickel-platinum, nickel-copper and nickel-chrome. Aluminum is available in its elemental form and alloyed with copper and silicon as aluminum-copper, aluminum-silicon and aluminum-copper-silicon. Elemental titanium is available up to 99.999% purity and alloyed in titanium-tungsten. The conductive and solder wetting properties of gold make it an important deposition material, including gold alloys such as gold-tin, gold-antimony, gold-silicon, gold-copper, and gold-germanium. Recent materials include Phase Change Alloys such as germanium-antimony alloyed with tellurium, silver, indium and platinum and transparent conductive oxides (TCO) for light emitting applications such as sensors and light emitting diodes (LED). These include indium-tin oxide (ITO) and zinc oxide doped with aluminum and other elements (ZnO). American Elements also produces ultra high purity sputtering targets for electronic applications including hafnium, molybdenum, silver, iridium, rhodium and ruthenium.

Anti-abrasive coatings for Wear Protection. Electroplating of tool, die, drilling and cutting tool active surfaces to protect against wear and extend life has given way in recent years to the deposition of these coating materials as a more cost effective alternative. Typical protective materials using sputtering targets include titanium, titanium-carbide, silicon carbide, boron carbide, aluminum, nickel, chromium and tungsten-carbide.

Magnetic Materials. The use of high strength magnets have found application is numerous industries including automotive, aerospace, biomedical imaging and auditory engineering. Sputtering targets of these advanced magnetic materials are manufactured by American Elements from samarium-cobalt and neodymium-iron-boron alloy.

Optical and Architectural Glass. The ability of certain elements to selectively absorb and emit highly specific wave length ranges and also reduce glare due to their high refractive index when deposited on a glass substrate resulted in the development of sputtering and evaporation materials of elemental rare earths, such as neodymium and dysprosium and many other optically active and anti-reflective (AR) materials. More recently, architectural glass for residential, commercial and office building applications has benefited from the availability of these same coatings.

Photovoltaic Solar Energy Panels. The three primary solar energy technologies, silicon based, Copper Indium Selenide (CIS) and Copper Indium Gallium Selenide (CIGS) are layered structures that require sputtering targets at several stages including certain transparent conductive oxides (TCO) such as indium tin oxide (ITO) and doped zinc oxide as the top electrode, molybdenum as the back plate, and antimony-telluride and zinc-telluride in CIS and CIG photovoltaic cells.

Solid Oxide Fuel Cells. Typical solid oxide fuel cell (SOFC) designs contain an electronically conductive low density cathode, a high density, ionically conductive electrolyte and an electronically conductive open air electrode. New technology is being developed for the deposition of these layers. Sputtering targets are produced by American Elements to meet the needs of each of these layers including Perovskite cathode materials including Lanthanum Strontium Manganite (LSM), Lanthanum Strontium Ferrite (LSF), Lanthanum Strontium Cobaltite Ferrite (LSCF), Lanthanum Strontium Chromite (LSC), and Lanthanum Strontium Gallate Magnesite (LSGM) with doping levels and other parameters to customer specifications and ionically conductive electrolytes including YSZ, SCZ (Scandium doped Zirconia), Samarium doped Ceria, Gadolinium doped Ceria and Yttrium doped Ceria. These fuel cells materials are marketed under the trademark AE Fuel CellsT.

Data Storage. Sputtering targets are now essential to the coating and manufacturing of optical storage devices such as CDs and DVDs to provide both wear protection and reflectivity.





Chloride, Nitrate, etc. Submicron & Nanopowder Tolling Foil Sputtering Target Crystal Growth Advanced Materials Information Center

 

Recent Research & Development for Thin Film

  • Effect of thin carbonate-containing apatite (CA) coating of titanium fiber mesh on trabecular bone response. J Mater Sci Mater Med. 2008 May;19(5):2087-96. Epub 2007 Oct 30.

  • Thin films of SiO(2) and hydroxyapatite on titanium deposited by spray pyrolysis. J Mater Sci Mater Med. 2008 May;19(5):1871-9. Epub 2007 Oct 4.

  • Fabrication of CdS films with superhydrophobicity by the microwave assisted chemical bath deposition. J Colloid Interface Sci. 2008 Apr 15;320(2):540-7. Epub 2007 Nov 24.

  • Effect of introduced charge in cellulose gels on surface interactions and the adsorption of highly charged cationic polyelectrolytes. Phys Chem Chem Phys. 2008 Apr 7;10(13):1819-25. Epub 2008 Feb 14.

  • Higher mass loadability in comprehensive two-dimensional gas chromatography-mass spectrometry for improved analytical performance in metabolomics analysis. J Chromatogr A. 2008 Apr 4;1186(1-2):420-9. Epub 2007 Dec 7.

  • Reversible on-demand cell alignment using reconfigurable microtopography. Biomaterials. 2008 Apr;29(11):1705-12. Epub 2008 Jan 14.

  • A lithographically-patterned, elastic multi-electrode array for surface stimulation of the spinal cord. Biomed Microdevices. 2008 Apr;10(2):259-69.

  • Peri-implant tissue response to TiO(2) surface modified implants. Clin Oral Implants Res. 2008 Apr;19(4):348-55. Epub 2008 Feb 5.

  • Development of phase plates for electron microscopes and their biological application. Eur Biophys J. 2008 Apr;37(4):345-58. Epub 2008 Feb 8.

  • Endothelial cell growth on silicon modified hydrogenated amorphous carbon thin films. J Biomed Mater Res B Appl Biomater. 2008 Apr;85(1):105-13.

  • Preparation and characterization of nanostructured Ni(OH)(2) and NiO thin films by a simple solution growth process. J Colloid Interface Sci. 2008 Apr 1;320(1):254-8. Epub 2007 Nov 13.

  • Back-etch method for plan view transmission electron microscopy sample preparation of optically opaque films. J Electron Microsc (Tokyo). 2008 Apr;57(2):47-52. Epub 2008 Jan 28.

  • Interfacial tension and spreading coefficient for thin films. Langmuir. 2008 Apr 1;24(7):3185-90. Epub 2008 Mar 5.

  • Interfacial mobility and bonding strength in nanocomposite thin film membranes. Langmuir. 2008 Apr 1;24(7):3446-51. Epub 2008 Feb 15.

  • Gated proton transport in aligned mesoporous silica films. Nat Mater. 2008 Apr;7(4):303-7. Epub 2008 Feb 24.

  • Growth, structural, optical and thermal properties of gamma-glycine crystal. Spectrochim Acta A Mol Biomol Spectrosc. 2008 Apr;69(4):1114-8. Epub 2007 Jun 28.

  • Size Dependence of Transition Temperature in Polymer Nanowires. J Phys Chem B. 2008 Mar 27;112(12):3586-3589. Epub 2008 Mar 5.

  • Quantitative Methods Based on Twisted Nematic Liquid Crystals for Mapping Surfaces Patterned with Bio/Chemical Functionality Relevant to Bioanalytical Assays. Anal Chem. 2008 Mar 21; [Epub ahead of print]

  • Depth Profiling of Organic Films with X-ray Photoelectron Spectroscopy Using C(60)(+) and Ar(+) Co-Sputtering. Anal Chem. 2008 Mar 21; [Epub ahead of print]

  • Boron removal from aqueous solutions by activated carbon impregnated with salicylic acid. J Hazard Mater. 2008 Mar 21;152(1):415-22. Epub 2007 Jul 7.

 


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