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Praseodymium Oxide Nanopowder
Pr6O11 Nanoparticles (nm)
12037-29-5

Product
Product Code
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99.9% Praseodymium Oxide (powder)
PR-MITE-AP
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99.9% Praseodymium Oxide (dispersion)
PR-MITE-AD
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99.9% Praseodymium Oxide
PR-MITE-O
Contact American Elements

PR-MITE powders and dispersions are inorganic praseodymium-oxide nanoparticles. PR-MITE-A products are uncoated and hydrophilic. PR-MITE-O products are coated with an organic silane (1-4%) and are hydrophobic. Particles are available in the size range of 10-200 nm. They are also available as a nanofluid through the AE Nanofluid production group. Nanofluids are generally defined as suspended nanoparticles in solution either using surfactant or surface charge technology. Nanofluid dispersion and coating selection technical guidance is also available. Other nanostructures include nanorods, nanowhiskers, nanohorns, nanopyramids and other nanocomposites. Surface functionalized nanoparticles allow for the particles to be preferentially adsorbed at the surface interface using chemically bound polymers. Development research is underway in Nano Electronics and Photonics materials, such as MEMS and NEMS, Bio Nano Materials, such as Biomarkers, Bio Diagnostics & Bio Sensors, and Related Nano Materials, for use in Polymers, Textiles, Fuel Cell Layers, Composites and Solar Energy materials. Nanopowders are analyzed for chemical composition by ICP, particle size distribution (PSD) by laser diffraction, and for Specific Surface Area (SSA) by BET multi-point correlation techniques. Novel nanotechnology applications also include Quantum Dots. High surface areas can also be achieved using solutions and using thin film by sputtering targets and evaporation technology using pellets, rod and foil. For technical, research and safety information for PR-MITE or for more information on nanotechnology, please contact our customer service department.

Praseodymium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f36s2. In its elemental form praseodymium's CAS number is 7440-10-0. The praseodymium atom has a radius of 182.pm and it's Van der Waals radius is is unknown. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Praseodymium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. The element is found in most all light rare earth derivatives. It is highly valued in glass and ceramic production as a bright yellow pigment because of its optimum reflectance at 560 nm. Much research is being done on its optical properties for use in amplification of telecommunication systems, including as a doping agent in fluoride fibers. .

Formula CAS No. Appearance Molecular Weight Density Melting Point Boiling Point Solubility Stability
Pr6O11 12037-29-5 Brown powder 1021.43       Insoluble in water, moderately soluble in strong mineral acids Slightly hygroscopic
PRODUCT CATALOG Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc.
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Recent Research & Development for Praseodymium

  • Ethanol electrooxidation on Pt/C catalysts promoted with praseodymium oxide nanorods. Wang Y, Nguyen TS, Wang C, Wang X. Dalton Trans. 2009 Oct 7;(37):7606-9. Epub 2009 Jul 27. PMID: 19759930 [PubMed - in process]

  • Triggered Instability of Liposomes Bound to Hydrophobically Modified Core-Shell PNIPAM Hydrogel Beads. Mackinnon N, GueŽrin G, Liu B, Gradinaru CC, Rubinstein JL, Macdonald PM. Langmuir. 2009 Sep 15. [Epub ahead of print] PMID: 19754070 [PubMed - as supplied by publisher]

  • Carboxymethylated cyclodextrins and their complexes with Pr(III) and Yb(III) as water-soluble chiral NMR solvating agents for cationic compounds. Provencher KA, Weber MA, Randall LA, Cunningham PR, Dignam CF, Wenzel TJ. Chirality. 2009 Jun 18. [Epub ahead of print] PMID: 19544350 [PubMed - as supplied by publisher]

  • Breaking of the selection rules for optical transitions in the dielectric PrFe3(BO3)4 crystal by a praseodymium-iron exchange interaction. Popova MN, Stanislavchuk TN, Malkin BZ, Bezmaternykh LN. Phys Rev Lett. 2009 May 8;102(18):187403. Epub 2009 May 8. PMID: 19518913 [PubMed]

  • Praseodymium doped NaYF4 nanocrystals in oxyfluoride glass-ceramics; morphological and spectroscopic studies. Dominiak-Dzik G. J Nanosci Nanotechnol. 2009 Apr;9(4):2525-31. PMID: 19437997 [PubMed]

  • An investigation of the interaction of iminosulfurane transdermal penetration enhancers with model skin preparations using NMR spectroscopy. Burch CP, Chandrasekaran S, Henary MM, Spring A, Strekowski L, Smith JC. Int J Pharm. 2009 May 21;373(1-2):48-54. Epub 2009 Feb 12. PMID: 19429287 [PubMed - indexed for MEDLINE]

  • Syntheses, crystal structures, and gas storage studies in new three-dimensional 5-aminoisophthalate praseodymium polymeric complexes. Qiu Y, Deng H, Yang S, Mou J, Daiguebonne C, Kerbellec N, Guillou O, Batten SR. Inorg Chem. 2009 May 4;48(9):3976-81. PMID: 19351164 [PubMed]

  • Structural and sensing properties of high-k PrTiO3 sensing membranes for pH-ISFET applications. Pan TM, Liao KM. IEEE Trans Biomed Eng. 2009 Feb;56(2):471-6. Epub 2008 Oct 21. PMID: 19272929 [PubMed - indexed for MEDLINE]

  • High-resolution hard x-ray spectroscopy of high-temperature plasmas using an array of quantum microcalorimeters. Thorn DB, Gu MF, Brown GV, Beiersdorfer P, Porter FS, Kilbourne CA, Kelley RL. Rev Sci Instrum. 2008 Oct;79(10):10E323. PMID: 19044485 [PubMed]

  • 3-Hydroxypyridin-2-one complexes of near-infrared (NIR) emitting lanthanides: sensitization of holmium(III) and praseodymium(III) in aqueous solution. Moore EG, Szigethy G, Xu J, Pålsson LO, Beeby A, Raymond KN. Angew Chem Int Ed Engl. 2008;47(49):9500-3. No abstract available. PMID: 18972461 [PubMed - indexed for MEDLINE]

  • Derivative spectrophotometric determination of praseodymium in rare earth mixtures with lomefloxacin. Wang N, Ren X, Si Z, Jiang W, Liu C, Liu X. Talanta. 2000 Mar 6;51(3):595-8. PMID: 18967892 [PubMed - in process]

  • Pre-concentration of rare earths using silica gel loaded with 1-(2-pyridylazo)-2-naphthol (PAN) and determination by energy dispersive X-ray fluorescence. Cornejo-Ponce L, Peralta-Zamora P, Bueno MI. Talanta. 1998 Aug;46(6):1371-8. PMID: 18967266 [PubMed - in process]

  • Determination of formation constants of hydroxo and carbonate complexes of Pr(3+) in 2 M NaCl at 303 K. López-González H, Jiménez-Reyes M, Rojas-Hernández A, Solache-RiŽos M. Talanta. 1997 Oct;44(10):1891-1899. PMID: 18966931 [PubMed - as supplied by publisher]

  • Efficient visible laser emission of GaN laser diode pumped Pr-doped fluoride scheelite crystals. Cornacchia F, Di Lieto A, Tonelli M, Richter A, Heumann E, Huber G. Opt Express. 2008 Sep 29;16(20):15932-41. PMID: 18825230 [PubMed - indexed for MEDLINE]

  • Seven-coordinate ruthenium atoms sequestered in praseodymium clusters in the chloride {RuPr3}Cl3. Herzmann N, Mudring AV, Meyer G. Inorg Chem. 2008 Sep 15;47(18):7954-6. Epub 2008 Aug 15. PMID: 18702484 [PubMed]

  • Insight into substrate binding in Shibasaki's Li3(THF)n(BINOLate)3Ln complexes and implications in catalysis. Wooten AJ, Carroll PJ, Walsh PJ. J Am Chem Soc. 2008 Jun 11;130(23):7407-19. Epub 2008 May 15. PMID: 18479140 [PubMed - indexed for MEDLINE]

  • New M(3)N@C(2n) endohedral metallofullerene families (M=Nd, Pr, Ce; n=40-53): expanding the preferential templating of the C(88) cage and approaching the C(96) cage. Chaur MN, Melin F, Elliott B, Kumbhar A, Athans AJ, Echegoyen L. Chemistry. 2008;14(15):4594-9. PMID: 18399530 [PubMed]

  • Strong blue emission from Pr3+ ions through energy transfer process from Nd3+ to Pr3+ via Yb3+ in tellurite glass. Kumar K, Rai SB, Rai A. Spectrochim Acta A Mol Biomol Spectrosc. 2008 Nov 15;71(2):508-12. Epub 2008 Jan 16. PMID: 18304862 [PubMed - indexed for MEDLINE]

  • Tuning the self-assembly of lanthanide triple stranded heterobimetallic helicates by ligand design. Jensen TB, Scopelliti R, Bünzli JC. Dalton Trans. 2008 Feb 28;(8):1027-36. Epub 2007 Dec 4. PMID: 18274683 [PubMed - indexed for MEDLINE]

  • Luminescence properties of praseodymium- and erbium-doped silver bromide crystals. Bunimovich D, Nagli L, Katzir A. Appl Opt. 1997 Oct 20;36(30):7708-11. PMID: 18264289 [PubMed - in process]

 

 

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