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PHOSPHIDE INFORMATION CENTER
AE Phosphides ™

32.4 (A)/00.022


Hydrogen                                Helium  
Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Ununquadium Ununpentium Ununhexium Ununseptium Ununoctium
                                   
    Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
    Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawerencium      

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Phosphide Ion

A phosphide is an ion, and phosphides of almost every metal in the periodic table are known. They exhibit a wide variety of chemical and physical properties. Although there are a number of ways to prepare phosphides, the most general method is to heat stoichiometric amounts of the metal and red phosphorus to high temperature in an inert atmosphere or a vacuum. Alkali and alkaline earth metals transition-metal phosphides are inert metallic-looking solids with high melting points and electrical conductivities.

Metal phosphides have been used as rodenticides, primarily calcium phosphide, zinc phosphide, and aluminum phosphide. Zinc phosphide baits have strong, pungent garlic-like odor characteristic for phosphine liberated by hydrolysis. The odor attracts rodents, but has a repulsive effect on other animals which are not sensitive to the smell. Aluminium phosphide is also wide band gap semiconductor. Calcium phosphide has uses in incendiary bombs. On contact with acids or water, calcium phosphide releases phosphine, which ignites spontaneously. Calcium phosphide is also used in fireworks, torpedoes, self-igniting naval pyrotechnic flares, and various water-activated ammunition.

Copper phosphide does not react with water. When subjected to ultraviolet light, copper phosphide shows fluorescence.

Titanium phosphide is normally encountered as a grey powder , it is high melting and a metallic conductor. It is not attacked by common acids or water.

Boron phosphide is a semiconductor. Iron phosphide is Insoluble in water and is a semiconductor used in high power, high frequency applications and in laser diodes. Gallium phosphide is used in the manufacture of low-cost red, orange, and green light-emitting diodes (LEDs) with low to medium brightness since the 1960s. It has a relatively short life at higher current and its lifetime is sensitive to temperature. Pure gallium phosphide LEDs emit green light at a wavelength of 555 nm. Nitrogen-doped gallium phosphide emits yellow-green (565 nm) light, zinc oxide doped gallium phosphide emits red (700 nm). Indium phosphide is a semiconductor and is used in high-power and high-frequency electronics because of its superior electron velocity with respect to the more common semiconductors such as gallium arsenide. Indium phosphide also has one of the longest-lived optical phonons of any compound with the zincblende crystal structure.

Sodium phosphide is a source of the highly reactive phosphide anion. The material is insoluble in all solvents but reacts as a slurry with acids and related. Sodium phosphide is also employed commercially as a catalyst in conjunction with zinc phosphide and aluminum phosphide for polymer production. Sodium phosphide is highly dangerous releasing toxic phosphine upon hydrolysis, a process that is so exothermic that fires result.

Purities include 99%, 99.9%, 99.99%, 99.999% and 99.9999% which are sometimes referred to as 2N, 3N, 4N, 5N and 6N.

Physical properties may include nanopowder, nano particle, submicron, - 325 mesh, rod, foil, and high surface area bromide with particle distribution and particle size controlled and certified. We produce larger - 40 mesh, - 100 mesh, -200 mesh range sizes and < 0.5 mm, 2 mm, 5 mm and other mm size shot, granules, lump, flake and pieces, too.

American Elements maintains industrial scale production for all its phosphide products.

American Elements will execute Non-Disclosure or Confidentiality Agreements to protect customer know-how.

Please select from the table a Phosphide Material:

Aluminum Phosphide
Antimony Phosphide
Arsenic Phosphide
Barium Phosphide
Beryllium Phosphide
Boron Phosphide
Cadmium Phosphide
Calcium Phosphide
Cerium Phosphide
Chromium Phosphide
Cobalt Phosphide
Copper Phosphide
Dysprosium Phosphide

Erbium Phosphide
Europium Phosphide
Gadolinium Phosphide
Gallium Phosphide
Gold Phosphide
Hafnium Phosphide
Holmium Phosphide
Indium Phosphide
Iodine Phosphide
Iron Phosphide
Lanthanum Phosphide
Lithium Phosphide
Lutetium Phosphide

Magnesium Phosphide
Manganese Phosphide
Molybdenum Phosphide
Neodymium Phosphide
Nickel Phosphide
Niobium Phosphide
Potassium Phosphide
Praseodymium Phosphide
Samarium Phosphide
Scandium Phosphide
Silver Phosphide
Sodium Phosphide
Strontium Phosphide

Tantalum Phosphide
Terbium Phosphide
Thorium Phosphide
Thulium Phosphide
Tin Phosphide
Titanium Phosphide
Vanadium Phosphide
Ytterbium Phosphide
Yttrium Phosphide
Zinc Phosphide
Zirconium Phosphide


French Phosphure German Phosphid Italian Fosfuro Portuguese Fosforeto Spanish Fosfuro 磷化 リン化物 Swedish Fosfid

 



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Recent Research & Development for Phosphide

  • Phosphido pincer complexes of platinum: synthesis, structure and reactivity. Mazzeo M, Strianese M, Kühl O, Peters JC. Dalton Trans. 2011 Aug 9. [Epub ahead of print] PMID: 21826355 [PubMed - as supplied by publisher]

  • Unusual complication of aluminum phosphide poisoning: Development of hemolysis and methemoglobinemia and its successful treatment. Soltaninejad K, Nelson LS, Khodakarim N, Dadvar Z, Shadnia S. Indian J Crit Care Med. 2011 Apr;15(2):117-9. PMID: 21814377 [PubMed - in process] Free PMC Article

  • Surface basicity on bulk modified phosphorus alumina through different synthesis methods. Wang X, Shen M, Song L, Su Y, Wang J. Phys Chem Chem Phys. 2011 Jul 27. [Epub ahead of print] PMID: 21796296 [PubMed - as supplied by publisher]

  • Aluminium phosphide (tank pill) poisoning in the Transkei region of South Africa: a case report. Meel BL. Med Sci Law. 2011 Apr;51(2):116-8. PMID: 21793477 [PubMed - in process]

  • Phosphide poisoning: A review of literature. Bumbrah GS, Krishan K, Kanchan T, Sharma M, Sodhi GS. Forensic Sci Int. 2011 Jul 13. [Epub ahead of print] PMID: 21763089 [PubMed - as supplied by publisher]

  • Label swapper device for spectral amplitude coded optical packet networks monolithically integrated on InP. Muñoz P, García-Olcina R, Habib C, Chen LR, Leijtens XJ, de Vries T, Robbins D, Capmany J. Opt Express. 2011 Jul 4;19(14):13540-50. doi: 10.1364/OE.19.013540. PMID: 21747509 [PubMed - in process]

  • Approved quarantine treatment for Hessian fly (Diptera: Cecidomyiidae) in large-size hay bales and Hessian fly and cereal leaf beetle (Coleoptera: Chrysomelidae) control by bale compression. Yokoyama VY. J Econ Entomol. 2011 Jun;104(3):792-8. PMID: 21735895 [PubMed - indexed for MEDLINE]

  • Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals. Gresback R, Hue R, Gladfelter WL, Kortshagen UR. Nanoscale Res Lett. 2011 Jan 12;6(1):68. PMID: 21711589 [PubMed - in process] Free Article

  • Palladium nanoparticles on InP for hydrogen detection. Cernohorsky O, Zdansky K, Zavadil J, Kacerovsky P, Piksova K. Nanoscale Res Lett. 2011 Jun 2;6:410. PMID: 21711487 [PubMed] Free Article

  • Scattering lens resolves sub-100 nm structures with visible light. van Putten EG, Akbulut D, Bertolotti J, Vos WL, Lagendijk A, Mosk AP. Phys Rev Lett. 2011 May 13;106(19):193905. Epub 2011 May 13. PMID: 21668161 [PubMed - in process]

  • NMR and NQR parameters of the SiC-doped on the (4,4) armchair single-walled BPNT: a computational study. Baei MT, Sayyad-Alangi SZ, Moradi AV, Torabi P. J Mol Model. 2011 May 28. [Epub ahead of print] PMID: 21625895 [PubMed - as supplied by publisher]

  • Aluminum phosphide poisoning: an unsolved riddle. Anand R, Binukumar BK, Gill KD. J Appl Toxicol. 2011 May 24. doi: 10.1002/jat.1692. [Epub ahead of print] PMID: 21607993 [PubMed - as supplied by publisher]

  • Terahertz generation based on parametric conversion: from saturation of conversion efficiency to back conversion. Jiang Y, Li D, Ding YJ, Zotova IB. Opt Lett. 2011 May 1;36(9):1608-10. doi: 10.1364/OL.36.001608. PMID: 21540943 [PubMed - in process]

  • Cytotoxicity of InP/ZnS quantum dots related to reactive oxygen species generation. Chibli H, Carlini L, Park S, Dimitrijevic NM, Nadeau JL. Nanoscale. 2011 Jun;3(6):2552-9. Epub 2011 Apr 21. PMID: 21509403 [PubMed - in process] Free Article Related citations 15. Effect of sweet almond oil on survival rate and plasma cholinesterase activity of aluminum phosphide-intoxicated rats. Saidi H, Shojaie S. Hum Exp Toxicol. 2011 Apr 20. [Epub ahead of print] PMID: 21508069 [PubMed - as supplied by publisher]

  • Ternary cobalt-iron phosphide nanocrystals with controlled compositions, properties, and morphologies from nanorods and nanorice to split nanostructures. Ye E, Zhang SY, Lim SH, Bosman M, Zhang Z, Win KY, Han MY. Chemistry. 2011 May 16;17(21):5982-8. doi: 10.1002/chem.201002698. Epub 2011 Apr 13. PMID: 21491516 [PubMed - in process]

  • Terahertz-wave spectroscopy for precise histopathological imaging of tumor and non-tumor lesions in paraffin sections. Miura Y, Kamataki A, Uzuki M, Sasaki T, Nishizawa J, Sawai T. Tohoku J Exp Med. 2011;223(4):291-6. PMID: 21467828 [PubMed - in process] Free Article

  • Time domain switching/demultiplexing using four wave mixing in GaInP photonic crystal waveguides. Cestier I, Willinger A, Eckhouse V, Eisenstein G, Combrié S, Colman P, Lehoucq G, De Rossi A. Opt Express. 2011 Mar 28;19(7):6093-9. doi: 10.1364/OE.19.006093. PMID: 21451632 [PubMed - indexed for MEDLINE]

  • Manipulation of electron orbitals in hard-wall InAs/InP nanowire quantum dots. Roddaro S, Pescaglini A, Ercolani D, Sorba L, Beltram F. Nano Lett. 2011 Apr 13;11(4):1695-9. Epub 2011 Mar 29. PMID: 21446718 [PubMed - indexed for MEDLINE]

  • Ohmic contact of cadmium oxide, a transparent conducting oxide, to n-type indium phosphide. Ou F, Buchholz DB, Yi F, Liu B, Hseih C, Chang RP, Ho ST. ACS Appl Mater Interfaces. 2011 Apr;3(4):1341-5. Epub 2011 Apr 7. PMID: 21443255 [PubMed]



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