Aluminum Acetylacetonate

Al(CH3COCHCOCH3)3
CAS 13963-57-0


Product Product Code Order or Specifications
(2N) 99% Aluminum Acetylacetonate AL-ACAC-02 Contact American Elements
(3N) 99.9% Aluminum Acetylacetonate AL-ACAC-03 Contact American Elements
(4N) 99.99% Aluminum Acetylacetonate AL-ACAC-04 Contact American Elements
(5N) 99.999% Aluminum Acetylacetonate AL-ACAC-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Al(CH3COCHCOCH3)3 13963-57-0 134990717 16683006 MFCD00000013 237-741-6 (Z)-4-bis[[(Z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one 4157942 [Al+3].O=C
(C)\C=C(/[O
-])C.[O-]\C(
C)=C/C(C)=
O.[O-]\C(C)
=C/C(C)=O
InChI=1S/3C5H
8O2.Al/c3*1-4(
6)3-5(2)7;/h3*3
,6H,1-2H3;/q;;;
+3/p-3/b3*4-3-;
KILURZWTCGSYRE-LNTINUHCSA-K

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
C15H21AlO6 324.31 White 190-193 °C 315 °C N/A 324.115352 324.115352 0 Safety Data Sheet

Acetylaceton Formula Diagram (C5H8O2)Aluminum Acetylacetonate is an Aluminum source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, Acetylacetonate Packaging, Lab Quantityorgano-inorganic and metallo-organic compounds). It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Aluminum Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Aluminum include the coating of telescope mirrors and the construction of modern aircrafts and rockets. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Aluminum (Al) atomic and molecular weight, atomic number and elemental symbolAluminum, also known as Aluminium, (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element.Aluminum Bohr ModelAluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. It wasn't until 1825 that Aluminum was first isolated by Hans Christian Oersted. Aluminum is a silvery gray metallic metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental Aluminum Although it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements it imparts a variety of useful properties. Aluminum was first predicted by Antoine Lavoisierin 1787 and first isolated by Friedrich Wöhler in 1827. For more information on aluminum, including properties, safety data, research, and American Elements' catalog of aluminum products, visit the Aluminum Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H300-H315-H319-H335
Hazard Codes T
Risk Codes 25-36/37/38
Safety Precautions 26-36/37/39-45
RTECS Number BD2230000
Transport Information UN 3467 6.1/PG 2
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Skull and Crossbones-Acute Toxicity         

ALUMINUM ACETYLACETONATE SYNONYMS
Aluminum 2,4-pentanedionate; Aluminum tris[(2Z)-4-oxopent-2-en-2-olate]; Tris(acetylacetonato)aluminum(III); Al(acac)3; 3-penten-2-one, 4-hydroxy-, aluminum salt, (3Z)- (3:1); aluminium, tris(pentane-2,4-dionato); Aluminum(III) acetylacetonate

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Aluminum

  • Jing Li, Enbo Shangguan, Dan Guo, Meng Tian, Yanbin Wang, Quanmin Li, Zhaorong Chang, Xiao-Zi Yuan, Haijiang Wang, Synthesis, characterization and electrochemical performance of high-density aluminum substituted a-nickel hydroxide cathode material for nickel-based rechargeable batteries, Journal of Power Sources, Volume 270, 15 December 2014
  • Gabriel Oltean, Cheuk-Wai Tai, Kristina Edström, Leif Nyholm, On the origin of the capacity fading for aluminium negative electrodes in Li-ion batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Y.S. Zheng, G.Y. Tang, J. Kuang, X.P. Zheng, Effect of electropulse on solid solution treatment of 6061 aluminum alloy, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • M.A. Deyab, Corrosion protection of aluminum bipolar plates with polyaniline coating containing carbon nanotubes in acidic medium inside the polymer electrolyte membrane fuel cell, Journal of Power Sources, Volume 268, 5 December 2014
  • Feng Wang, Wei Wang, Ran Ran, Moses O. Tade, Zongping Shao, Aluminum oxide as a dual-functional modifier of Ni-based anodes of solid oxide fuel cells for operation on simulated biogas, Journal of Power Sources, Volume 268, 5 December 2014
  • E. Linga Reddy, J. Karuppiah, Hyun Chan Lee, Dong Hyun Kim, Steam reforming of methanol over copper loaded anodized aluminum oxide (AAO) prepared through electrodeposition, Journal of Power Sources, Volume 268, 5 December 2014
  • H.X. Meng, N. Wang, Y.M. Dong, Z.L. Jia, L.J. Gao, Y.J. Chai, Influence of M–B (M = Fe, Co, Ni) on aluminum–water reaction, Journal of Power Sources, Volume 268, 5 December 2014
  • Wassima El Mofid, Svetlozar Ivanov, Alexander Konkin, Andreas Bund, A high performance layered transition metal oxide cathode material obtained by simultaneous aluminum and iron cationic substitution, Journal of Power Sources, Volume 268, 5 December 2014
  • Qin Xu, Wen-Jiang Ye, Shun-Zhen Feng, Hui-Yuan Sun, Synthesis and properties of iridescent Co-containing anodic aluminum oxide films, Dyes and Pigments, Volume 111, December 2014
  • Norazwani Muhammad Zain, Sahrim Hj Ahmad, Ernie Suzana Ali, Effect of surface treatments on the durability of green polyurethane adhesive bonded aluminium alloy, International Journal of Adhesion and Adhesives, Volume 55, December 2014
  • Rong Xu, Luoxing Li, Liqiang Zhang, Biwu Zhu, Xiao Liu, Xiaobing Bu, Influence of pressure and surface roughness on the heat transfer efficiency during water spray quenching of 6082 aluminum alloy, Journal of Materials Processing Technology, Volume 214, Issue 12, December 2014
  • Krishna P. Yagati, Ravi N. Bathe, Koteswararao V. Rajulapati, K. Bhanu Sankara Rao, G. Padmanabham, Fluxless arc weld-brazing of aluminium alloy to steel, Journal of Materials Processing Technology, Volume 214, Issue 12, December 2014
  • Akira Azushima, Kosuke Uda, Hiroki Matsuda, Thermal behavior of aluminum-coated 22MnB5 in hot stamping under dry and lubricated conditions, Journal of Materials Processing Technology, Volume 214, Issue 12, December 2014
  • Yi Meng, Sumio Sugiyama, Jianbo Tan, Jun Yanagimoto, Effects of forming conditions on homogeneity of microstructure and mechanical properties of A6061 aluminum alloy manufactured by time-dependent rheoforging on a mechanical servo press, Journal of Materials Processing Technology, Volume 214, Issue 12, December 2014
  • Fang He, Zhibiao Hu, Kaiyu Liu, Shuirong Zhang, Hongtao Liu, Shangbin Sang, In situ fabrication of nickel aluminum-layered double hydroxide nanosheets/hollow carbon nanofibers composite as a novel electrode material for supercapacitors, Journal of Power Sources, Volume 267, 1 December 2014
  • Bin Li, Kun Liu, Chang-Rui Zhang, Si-Qing Wang, Fabrication and properties of borazine derived boron nitride bonded porous silicon aluminum oxynitride wave-transparent composite, Journal of the European Ceramic Society, Volume 34, Issue 15, December 2014
  • F. D’Elia, C. Ravindran, D. Sediako, K.U. Kainer, N. Hort, Hot tearing mechanisms of B206 aluminum–copper alloy, Materials & Design, Volume 64, December 2014
  • Jingqing Zhang, Yifu Shen, Xin Yao, Haisheng Xu, Bo Li, Investigation on dissimilar underwater friction stir lap welding of 6061-T6 aluminum alloy to pure copper, Materials & Design, Volume 64, December 2014
  • Jinlong Yang, Songbai Xue, Peng Xue, Zhaoping Lv, Wei Dai, Junxiong Zhang, Development of novel CsF–RbF–AlF3 flux for brazing aluminum to stainless steel with Zn–Al filler metal, Materials & Design, Volume 64, December 2014
  • M.S. Salleh, M.Z. Omar, J. Syarif, K.S. Alhawari, M.N. Mohammed, Microstructure and mechanical properties of thixoformed A319 aluminium alloy, Materials & Design, Volume 64, December 2014

Recent Research & Development for Acetylacetonates

  • Sudipta Chatterjee, Sutanuva Mandal, Sucheta Joy, Chen-Hsiung Hung, Sreebrata Goswami, ortho-Carom–N bond fusion in aniline associated with electrophilic chlorination reactions at ruthenium(III) coordinated acetylacetonates, Inorganica Chimica Acta, Volume 374, Issue 1, 1 August 2011
  • János Madarász, Shoji Kaneko, Masayuki Okuya, György Pokol, Comparative evolved gas analyses of crystalline and amorphous titanium(IV)oxo-hydroxo-acetylacetonates by TG-FTIR and TG/DTA-MS, Thermochimica Acta, Volume 489, Issues 1–2, 20 May 2009
  • Satoshi Yoda, Yoko Mizuno, Takeshi Furuya, Yoshihiro Takebayashi, Katsuto Otake, Tomoya Tsuji, Toshihiko Hiaki, Solubility measurements of noble metal acetylacetonates in supercritical carbon dioxide by high performance liquid chromatography (HPLC), The Journal of Supercritical Fluids, Volume 44, Issue 2, March 2008
  • M. Aslam Siddiqi, Rehan A. Siddiqui, Burak Atakan, Thermal stability, sublimation pressures and diffusion coefficients of some metal acetylacetonates, Surface and Coatings Technology, Volume 201, Issues 22–23, 25 September 2007
  • María R. Pedrosa, Jaime Escribano, Rafael Aguado, Virginia Díez, Roberto Sanz, Francisco J. Arnáiz, Dinuclear oxomolybdenum(VI) acetylacetonates: Crystal and molecular structure of Mo2O5(acac)2L2 (L = D2O, DMF), Polyhedron, Volume 26, Issue 14, 31 August 2007
  • S.V. Samoilenkov, M.A. Stefan, G. Wahl, MOCVD of thick YSZ coatings using acetylacetonates, Surface and Coatings Technology, Volume 192, Issue 1, 1 March 2005
  • Thomas Behrsing, Alan M Bond, Glen B Deacon, Craig M Forsyth, Maria Forsyth, Kalpana J Kamble, Brian W Skelton, Allan H White, Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2O, Inorganica Chimica Acta, Volume 352, 6 August 2003
  • R Leboda, J Skubiszewska-Zieba, J Rynkowski, Preparation and porous structure of carbon–silica adsorbents obtained on the basis of Ti, Co, Ni, Cr, Zn and Zr acetylacetonates and acetylacetone, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 174, Issue 3, 1 December 2000
  • V.M. Gun'ko, R. Leboda, J. Skubiszewska-Zi?ba, J. Rynkowski, Silica Gel Modified Due to Pyrolysis of Acetylacetone and Metal (Ti, Cr, Co, Ni, Zn, Zr) Acetylacetonates, Journal of Colloid and Interface Science, Volume 231, Issue 1, 1 November 2000
  • V.G Isakova, I.A Baidina, N.B Morozova, I.K Igumenov, ?-Halogenated iridium(III) acetylacetonates, Polyhedron, Volume 19, Issue 9, 15 May 2000
  • V.V. Turov, R. Leboda, J. Skubiszewska-Zi ?, Changes in Hydration Properties of Silica Gel in a Process of Its Carbonization by Pyrolysis of Acetylacetone Zn (Ti) Acetylacetonates, Journal of Colloid and Interface Science, Volume 206, Issue 1, 1 October 1998
  • Claudia Neyertz, María Volpe, Preparation of binary palladium-vanadium supported catalysts from metal acetylacetonates, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 136, Issues 1–2, 30 April 1998
  • Shoichi Katsuta, Tomohiko Nakatani, Evaluation of Distribution Constants of Lanthanoid(III) Acetylacetonates between Sodium Dodecyl Sulfate Micelles and Water by Micellar Capillary Electrophoresis, Journal of Colloid and Interface Science, Volume 195, Issue 2, 15 November 1997
  • Z. Zhang, Y. Tanigami, R. Terai, Catalytic effect of acetylacetonates on gel formation of CH3SiO32, Journal of Non-Crystalline Solids, Volume 191, Issue 3, 1 December 1995
  • Irina G. Zaitzeva, Nataliya P. Kuzmina, Larissa I. Martynenko, The volatile rare earth element tetrakis-acetylacetonates, Journal of Alloys and Compounds, Volume 225, Issues 1–2, 15 July 1995
  • J.C. Machado, C.F. Carvalho, W.F. Magalhães, A. Marques Netto, J.Ch. Abbé, G. Duplâtre, Positronium formation and inhibition in binary solid solutions on Al(III) and Co(III) tris(acetylacetonates), Chemical Physics, Volume 170, Issue 2, 1 March 1993
  • I.C. McNeill, J.J. Liggat, The effect of metal acetylacetonates on the thermal degradation of poly(methyl methacrylate): Part II—Manganese (III) acetylacetonate, Polymer Degradation and Stability, Volume 37, Issue 1, 1992
  • Pilar Gómez-Sal, Avelino Martín, Miguel Mena, Pascual Royo, Ricardo Serrano, Monopentamethylcyclopentadienyltitanium(IV) halo-alkoxides, alkyl-alkoxides and acetylacetonates, Journal of Organometallic Chemistry, Volume 419, Issues 1–2, 12 November 1991
  • I.C. McNeill, J.J. Liggat, The effect of metal acetylacetonates on the thermal degradation of poly(methyl methacrylate)—I. Cobalt (III) acetylacetonate, Polymer Degradation and Stability, Volume 29, Issue 1, 1990
  • B.L. Khandelwal, A.K. Singh, N.S. Bhandari, Preparative and spectral investigations on C3 bonded acetylacetonates of tellurium(IV), Journal of Organometallic Chemistry, Volume 320, Issue 3, 17 February 1987