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Aluminum Acetylacetonate

Al(CH3COCHCOCH3)3
CAS 13963-57-0


Product Product Code Request Quote
(2N) 99% Aluminum Acetylacetonate AL-ACAC-02 Request Quote
(3N) 99.9% Aluminum Acetylacetonate AL-ACAC-03 Request Quote
(4N) 99.99% Aluminum Acetylacetonate AL-ACAC-04 Request Quote
(5N) 99.999% Aluminum Acetylacetonate AL-ACAC-05 Request Quote

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Al(CH3COCHCOCH3)3 13963-57-0 134990717 16683006 MFCD00000013 237-741-6 (Z)-4-bis[[(Z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one 4157942 [Al+3].O=C
(C)\C=C(/[O
-])C.[O-]\C(
C)=C/C(C)=
O.[O-]\C(C)
=C/C(C)=O
InChI=1S/3C5H
8O2.Al/c3*1-4(
6)3-5(2)7;/h3*3
,6H,1-2H3;/q;;;
+3/p-3/b3*4-3-;
KILURZWTCGSYRE-LNTINUHCSA-K

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density Exact Mass Monoisotopic Mass Charge MSDS
C15H21AlO6 324.31 White 190-193 °C 315 °C N/A 324.115352 324.115352 0 Safety Data Sheet

Acetylaceton Formula Diagram (C5H8O2)Aluminum Acetylacetonate is an Aluminum source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, Acetylacetonate Packaging, Lab Quantityorgano-inorganic and metallo-organic compounds). It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Aluminum Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Aluminum include the coating of telescope mirrors and the construction of modern aircrafts and rockets. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Aluminum (Al) atomic and molecular weight, atomic number and elemental symbolAluminum, also known as Aluminium, (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element.Aluminum Bohr ModelAluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. It wasn't until 1825 that Aluminum was first isolated by Hans Christian Oersted. Aluminum is a silvery gray metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental Aluminum Although it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements it imparts a variety of useful properties. Aluminum was first predicted by Antoine Lavoisierin 1787 and first isolated by Friedrich Wöhler in 1827. For more information on aluminum, including properties, safety data, research, and American Elements' catalog of aluminum products, visit the Aluminum element page.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H300-H315-H319-H335
Hazard Codes T
Risk Codes 25-36/37/38
Safety Precautions 26-36/37/39-45
RTECS Number BD2230000
Transport Information UN 3467 6.1/PG 2
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Skull and Crossbones-Acute Toxicity         

ALUMINUM ACETYLACETONATE SYNONYMS
Aluminum 2,4-pentanedionate; Aluminum tris[(2Z)-4-oxopent-2-en-2-olate]; Tris(acetylacetonato)aluminum(III); Al(acac)3; 3-penten-2-one, 4-hydroxy-, aluminum salt, (3Z)- (3:1); aluminium, tris(pentane-2,4-dionato); Aluminum(III) acetylacetonate

CUSTOMERS FOR ALUMINUM ACETYLACETONATE HAVE ALSO LOOKED AT
Aluminum Wire Aluminum Copper Silicon Metal Aluminum Oxide Pellets Aluminum Metal Aluminum Acetate
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Aluminum Nanoparticles Aluminum Powder Aluminum Sputtering Target Aluminum Nitrate Aluminum Oxide
Show Me MORE Forms of Aluminum

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Aluminum

  • Coagulation behavior and floc properties of compound bioflocculant-polyaluminum chloride dual-coagulants and polymeric aluminum in low temperature surface water treatment. Huang X, Sun S, Gao B, Yue Q, Wang Y, Li Q. J Environ Sci (China). 2015 Apr 1: J Environ Sci (China)
  • Tannoid principles of Emblica officinalis renovate cognitive deficits and attenuate amyloid pathologies against aluminum chloride induced rat model of Alzheimer's disease. Justin Thenmozhi A, Dhivyabharathi M, William Raja TR, Manivasagam T, Mohamed Essa M. Nutr Neurosci. 2015 Apr 4. : Nutr Neurosci
  • Vertically-aligned carbon nanotubes on aluminum as a light-weight positive electrode for lithium-polysulfide batteries. Liatard S, Benhamouda K, Fournier A, Ramos R, Barchasz C, Dijon J. Chem Commun (Camb). 2015 Apr 8. : Chem Commun (Camb)
  • Treatment of Melasma in Men With Low-Fluence Q-Switched Neodymium-Doped Yttrium-Aluminum-Garnet Laser Versus Combined Laser and Glycolic Acid Peeling. Vachiramon V, Sahawatwong S, Sirithanabadeekul P. Dermatol Surg. 2015 Mar 9.
  • Cytotoxic and genotoxic characterization of aluminum and silicon oxide nanoparticles in macrophages. Hashimoto M, Imazato S. Dent Mater. 2015 Mar 5.
  • Hybrid Structures of Polycationic aluminum phthalocyanines and quantum dots. Maksimov EG, Gvozdev DA, Strakhovskaya MG, Paschenko VZ. Biochemistry (Mosc). 2015 Mar
  • Chitosan-aluminum monostearate composite sponge dressing containing asiaticoside for wound healing and angiogenesis promotion in chronic wound. Phaechamud T, Yodkhum K, Charoenteeraboon J, Tabata Y. Mater Sci Eng C Mater Biol Appl. 2015 May
  • The Metal-Organic Framework MIL-53(Al) Constructed from Multiple Metal Sources: Alumina, Aluminum Hydroxide, and Boehmite. Li Z, Wu YN, Li J, Zhang Y, Zou X, Li F. Chemistry. 2015 Mar 10.
  • ZnO-based thin film transistors employing aluminum titanate gate dielectrics deposited by spray pyrolysis at ambient air. Afouxenidis D, Mazzocco R, Vourlias G, Livesley PJ, Krier A, Milne WI, Kolosov OV, Adamopoulos G. ACS Appl Mater Interfaces. 2015 Mar 16.
  • The impact of thickness and thermal annealing on refractive index for aluminum oxide thin films deposited by atomic layer deposition. Wang ZY, Zhang RJ, Lu HL, Chen X, Sun Y, Zhang Y, Wei YF, Xu JP, Wang SY, Zheng YX, Chen LY. Nanoscale Res Lett. 2015 Feb 6: Nanoscale Res Lett

Recent Research & Development for Acetylacetonates

  • An oxygen-chelate complex, palladium bis-acetylacetonate, induces apoptosis in H460 cells via endoplasmic reticulum stress pathway rather than interacting with DNA. Wang Y, Hu J, Cai Y, Xu S, Weng B, Peng K, Wei X, Wei T, Zhou H, Li X, Liang G. J Med Chem. 2013 Dec 12
  • Enhancing the Deperoxidation Activity of Cobalt(II)Acetylacetonate by the Addition of Octanoic Acid. Spier E, Hermans I. Chemphyschem. 2013 Jul 24.
  • Single-molecule magnetism in three related {Co(III)2Dy(III)2}-acetylacetonate complexes with multiple relaxation mechanisms. Langley SK, Chilton NF, Moubaraki B, Murray KS. Inorg Chem. 2013 Jun 17
  • [Differentiated fluorescence centers in europium acetylacetonate hydrate doped poly methyl methacrylate]. Zhang YY, Zhong H, Chen BJ, Xia Y, Lin H. Guang Pu Xue Yu Guang Pu Fen Xi. 2014 Jun
  • Synthesis, characterization and cell viability test of six vanadyl complexes with acetylacetonate derivatives. Sgarbossa S, Diana E, Marabello D, Deagostino A, Cadamuro S, Barge A, Laurenti E, Gallicchio M, Boscaro V, Ghibaudi E. J Inorg Biochem. 2013 Nov
  • Photophysical properties of an unusual bichromophoric species constructed from a cyclometalated Pt(II) chromophore and a blue Bodipy-acetylacetonate species. Nastasi F, Puntoriero F, Serroni S, Campagna S, Olivier JH, Ziessel R. Dalton Trans. 2014 Dec 21
  • Monodentate and bridging behaviour of the sulfur-containing ligand 4'-[4-(methylsulfanyl)phenyl]-4,2':6',4''-terpyridine in two discrete zinc(II) complexes with acetylacetonate. Granifo J, Gaviño R, Freire E, Baggio R. Acta Crystallogr C. 2012 Oct
  • Photocytotoxic oxovanadium(IV) complexes of ferrocenyl-terpyridine and acetylacetonate derivatives. Balaji B, Balakrishnan B, Perumalla S, Karande AA, Chakravarty AR. Eur J Med Chem. 2015 Mar 6
  • Cyclometalated Pd(II) and Ir(III) 2-(4-bromophenyl)pyridine complexes with N-heterocyclic carbenes (NHCs) and acetylacetonate (acac): synthesis, structures, luminescent properties and application in one-pot oxidation/Suzuki coupling of aryl chlorides containing hydroxymethyl. Xu C, Li HM, Xiao ZQ, Wang ZQ, Tang SF, Ji BM, Hao XQ, Song MP. Dalton Trans. 2014 Jul 14
  • High performance polymer solar cells with as-prepared zirconium acetylacetonate film as cathode buffer layer. Tan Z, Li S, Wang F, Qian D, Lin J, Hou J, Li Y. Sci Rep. 2014 Apr 15
  • Design of layered silicate by grafting with metal acetylacetonate for high activity and chemoselectivity in photooxidation of cyclohexane. Tsunoji N, Ide Y, Yagenji Y, Sadakane M, Sano T. ACS Appl Mater Interfaces. 2014 Apr 9
  • cis-{MoO2}(2+) assisted Mannich-type addition of acetylacetonate methine to the azomethine of tridentate Schiff bases: racemic complexes with chiral transformed ligands. Kurapati SK, Pal S. Dalton Trans. 2015 Feb 7
  • Intratumoral administration of holmium-166 acetylacetonate microspheres: antitumor efficacy and feasibility of multimodality imaging in renal cancer. Bult W, Kroeze SG, Elschot M, Seevinck PR, Beekman FJ, de Jong HW, Uges DR, Kosterink JG, Luijten PR, Hennink WE, van het Schip AD, Bosch JL, Nijsen JF, Jans JJ. PLoS One. 2013
  • Vanadyl acetylacetonate upregulates PPARγ and adiponectin expression in differentiated rat adipocytes. Wu Y, Huang M, Zhao P, Yang X. J Biol Inorg Chem. 2013 Aug
  • A novel drug "copper acetylacetonate" loaded in folic acid-tagged chitosan nanoparticle for efficient cancer cell targeting. Pramanik A, Laha D, Pramanik P, Karmakar P. J Drug Target. 2014 Jan
  • Oxidatively induced P-O bond formation through reductive coupling between phosphido and acetylacetonate, 8-hydroxyquinolinate, and picolinate groups. Arias A, Forniés J, Fortuño C, Martín A, Mastrorilli P, Todisco S, Latronico M, Gallo V. Inorg Chem. 2013 May 6
  • Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x <
  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Kong CY, Siratori T, Wang G, Sako T, Funazukuri T. J Chem Eng Data. 2013 Nov 14
  • Effect of magnesium acetylacetonate on the signal of organic forms of vanadium in graphite furnace atomic absorption spectrometry. Kowalewska Z, Welz B, Castilho IN, Carasek E. Talanta. 2013 Jan 15
  • Antitumor efficacy and tolerability of systemically administered gallium acetylacetonate-loaded gelucire-stabilized nanoparticles. Wehrung D, Bi L, Geldenhuys WJ, Oyewumi MO. J Biomed Nanotechnol. 2013 Jun