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Aluminum Acetylacetonate
Al(CH3COCHCOCH3)3
13963-57-0

Product Product Code Order or Specifications
(2N) 99% Aluminum Acetylacetonate AL-ACAC-02 Contact American Elements
(3N) 99.9% Aluminum Acetylacetonate AL-ACAC-03 Contact American Elements
(4N) 99.99% Aluminum Acetylacetonate AL-ACAC-04 Contact American Elements
(5N) 99.999% Aluminum Acetylacetonate AL-ACAC-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Al(CH3COCHCOCH3)3 13963-57-0 24885236 16683006 MFCD00000013 237-741-6 (Z)-4-bis[[(Z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one 4157942 [Al+3].O=C(C)\C=C(/[O-])C.[O-]\C(C)=C/C(C)=O.[O-]\C(C)=C/C(C)=O InChI=1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; KILURZWTCGSYRE-LNTINUHCSA-K

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
C15H21AlO6 324.31 White g/cm3 324.115 g/mol 324.115351 Da 0 Safety Data Sheet


Acetylaceton Formula Diagram (C5H8O2)Aluminum Acetylacetonate is a Aluminum source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, Acetylacetonate Packaging, Lab Quantityorgano-inorganic and metallo-organic compounds). The High Purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Aluminum Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Aluminum Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Aluminum include the coating of telescope mirrors and the construction of modern aircrafts and rockets.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Aluminum(Al) atomic and molecular weight, atomic number and elemental symbolAluminum is a Block P, Group 13, Period 3 element. The number of electrons in each of Aluminum's shells is 2, 8, 3 and its electronic configuration is [Ne] 3s2 3p1. In its elemental form aluminum's CAS number is 7429-90-5. The aluminum atom has a radius of 143.2.pm and it's Van der Waals radius is 200.pm. Aluminum is not known to be harmful but ingestion may cause Alzheimer's disease.Aluminum is a silvery-white metal that possesses many desirable characteristics. It is light, nonmagnetic and nonsparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in manyAluminum Bohr Model industrial applications where a strong, light, easily constructed material is needed. Although it's electrical conductivity is only about 60% that of copper, it is used in electrical transmission Elemental Aluminumlines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements impart a variety of useful properties. These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. They are used to coat telescope mirrors. Aluminum is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. See Aluminum research below.

Have a Question? Ask a Chemical Engineer or Material Scientist   Request an MSDS or Certificate of Analysis

 
Safety &
Handling
  Skull and Crossbones-Acute Toxicity               
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Danger H300-H315-H319-H335 T 25-36/37/38 26-36/37/39-45 BD2230000 UN 3467 6.1/PG 2 3

 

Synonyms for Aluminum Acetylacetonate Include:


Aluminum 2,4-pentanedionate
Aluminum tris[(2Z)-4-oxopent-2-en-2-olate]
Tris(acetylacetonato)aluminum(III)
Al(acac)3
3-penten-2-one, 4-hydroxy-, aluminum salt, (3Z)- (3:1)
aluminium, tris(pentane-2,4-dionato)- Aluminum(III) acetylacetonate

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 


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Recent Research & Development for Aluminum

  • Selective separation of samarium(III) by synergistic extraction with ß-diketone and methylphenylphenanthroline carboxamide. Hasegawa Y, Tamaki S, Yajima H, Hashimoto B, Yaita T. Talanta. 2011 Sep 15;85(3):1543-8. Epub 2011 Jun 21. PMID: 21807220 [PubMed - in process]

  • Integral Stereocontrolled Synthesis of a Spiro-norlignan, Sequosempervirin A: Revision of Absolute Configuration. Ito Y, Takahashi K, Nagase H, Honda T. Org Lett. 2011 Aug 1. [Epub ahead of print] PMID: 21805972 [PubMed - as supplied by publisher]

  • Interactions between metal ions and carbohydrates. Syntheses and spectroscopic studies of several lanthanide nitrate-d-galactitol complexes. Yu L, Hua X, Pan Q, Yang L, Xu Y, Zhao G, Wang H, Wang H, Wu J, Liu K, Chen J. Carbohydr Res. 2011 Jun 30. [Epub ahead of print] PMID: 21784418 [PubMed - as supplied by publisher]

  • Chemical synthesis and evaluation of 17a-alkylated derivatives of estradiol as inhibitors of steroid sulfatase. Fournier D, Poirier D. Eur J Med Chem. 2011 Jun 28. [Epub ahead of print] PMID: 21782294 [PubMed - as supplied by publisher]

  • Concise Syntheses of Strychnine and Englerin A: the Power of Reductive Cyclizations Triggered by Samarium Iodide. Szostak M, Procter DJ. Angew Chem Int Ed Engl. 2011 Jul 20. doi: 10.1002/anie.201103128. [Epub ahead of print] No abstract available. PMID: 21780264 [PubMed - as supplied by publisher]

  • Preparation and Quality Control of the [Sm]-Samarium Maltolate Complex as a Lanthanide Mobilization Product in Rats. Naseri Z, Hakimi A, Jalilian AR, Nemati Kharat A, Bahrami-Samani A, Ghannadi-Maragheh M. Sci Pharm. 2011 Jun;79(2):265-275. Epub 2011 Feb 24. PMID: 21773065 [PubMed - as supplied by publisher]

  • Synthesis and characterization of heterobimetallic oxo-bridged aluminum-rare Earth metal complexes. Hao J, Li J, Cui C, Roesky HW. Inorg Chem. 2011 Aug 15;50(16):7453-9. Epub 2011 Jul 15. PMID: 21761836 [PubMed - in process]

  • Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril. Chen K, Liang LL, Zhang YQ, Zhu QJ, Xue SF, Tao Z. Inorg Chem. 2011 Aug 15;50(16):7754-60. Epub 2011 Jul 15. PMID: 21761833 [PubMed - in process]

  • Total Synthesis of 10-Isocyano-4-cadinene and Its Stereoisomers and Evaluations of Antifouling Activities. Nishikawa K, Nakahara H, Shirokura Y, Nogata Y, Yoshimura E, Umezawa T, Okino T, Matsuda F. J Org Chem. 2011 Jul 26. [Epub ahead of print] PMID: 21755975 [PubMed - as supplied by publisher]

  • Tris[6-meth-oxy-2-(phenyl-iminiometh-yl)phenolato]-?O,O';?O-tris-(thio-cyanato-?N)samarium(III). Ge GD, Shen JB, Zhao GL. Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m706-7. Epub 2011 May 7. PMID: 21754608 [PubMed]

  • {µ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methanylyl-idene)]di-phenolato}dimethano-ltrinitrato-samarium(III)zinc(II) methanol disolvate. Liu F, Zhang F. Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m525. Epub 2011 Apr 7. PMID: 21754267 [PubMed]

  • Samarium Diiodide Induced Cyclizations of ?-, d- and e-Indolyl Ketones: Reductive Coupling, Intermolecular Trapping, and Subsequent Transformations of Indolines. Beemelmanns C, Lentz D, Reissig HU. Chemistry. 2011 Jul 8. doi: 10.1002/chem.201100981. [Epub ahead of print] PMID: 21744405 [PubMed - as supplied by publisher]

  • 177Lu-Labeled methylene diphosphonate. Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011. 2011 May 24 [updated 2011 Jun 30]. PMID: 21735586 [PubMed]

  • Radioisotopes for metastatic bone pain. Roqué I Figuls M, Martinez-Zapata MJ, Scott-Brown M, Alonso-Coello P. Cochrane Database Syst Rev. 2011 Jul 6;(7):CD003347. Review. PMID: 21735393 [PubMed - indexed for MEDLINE]

  • Cubic and doubly-fused cubic samarium clusters from Sm(ii)-mediated reduction of organic azides and azobenzenes. Pan CL, Chen W, Su S, Pan YS, Wang J. Dalton Trans. 2011 Aug 21;40(31):7941-5. Epub 2011 Jun 30. PMID: 21717024 [PubMed - in process]

  • ACR-ASTRO Practice Guideline for the Performance of Therapy With Unsealed Radiopharmaceutical Sources. Henkin RE, Del Rowe JD, Grigsby PW, Hartford AC, Jadvar H, Macklis RM, Parker JA, Wong JY, Rosenthal SA. Clin Nucl Med. 2011 Aug;36(8):e72-e80. PMID: 21716005 [PubMed - as supplied by publisher]

  • Synthesis and molecular structure of piperazidine-bridged bis(phenolate) samarium(ii) complex and its reactivity to carbodiimides. Du Z, Zhang Y, Yao Y, Shen Q. Dalton Trans. 2011 Aug 7;40(29):7639-44. Epub 2011 Jun 24. PMID: 21701733 [PubMed - in process]

  • Theoretical Treatment of Redox Processes Involving Lanthanide(II) Compounds: Reactivity of Organosamarium(II) and Organothulium(II) Complexes with CO(2) and Pyridine. Labouille S, Nief F, Maron L. J Phys Chem A. 2011 Jul 28;115(29):8295-8301. Epub 2011 Jul 6. PMID: 21675778 [PubMed - as supplied by publisher]

  • 177Lu-Labeled ethylenediamine tetramethylene phosphonic acid. Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011. 2011 Apr 28 [updated 2011 May 26]. PMID: 21656987 [PubMed]

  • [170Tm]-Labeled ethylenediamine tetramethylene phosphonic acid. Chopra A. Molecular Imaging and Contrast Agent Database (MICAD) [Internet]. Bethesda (MD): National Center for Biotechnology Information (US); 2004-2011. 2011 Apr 27 [updated 2011 May 26]. PMID: 21656985 [PubMed]

     

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