Aluminum Bromide is a highly water soluble crystalline Aluminum source for uses compatible with Bromides and lower (acidic) pH. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine. Aluminum Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Hydrate or anhydrous forms may be purchased. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Aluminum is a Block P, Group 13, Period 3 element. The number of electrons in each of Aluminum's shells is 2, 8, 3 and its electronic configuration is [Ne] 3s2 3p1. In its elemental form aluminum's CAS number is 7429-90-5. The aluminum atom has a radius of 143.2.pm and it's Van der Waals radius is 200.pm. Aluminum is not known to be harmful but ingestion may cause Alzheimer's disease.Aluminum is a silvery-white metal that possesses many desirable characteristics. It is light, nonmagnetic and nonsparking.
It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Although it's electrical conductivity is only about 60% that of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements impart a variety of useful properties. These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. They are used to coat telescope mirrors. Aluminum is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. See Aluminum research below.
Substrate Effects on the Wettability of Electrospun Titania-Poly(vinylpyrrolidone) Fiber Mats. Jabal JM, McGarry L, Sobczyk A, Aston DE. Langmuir. 2010 Aug 17;26(16):13550-5. PubMed PMID: 20695603.
Breakage and regrowth of Al-humic flocs - effect of additional coagulant dosage. Yu WZ, Gregory J, Campos L. Environ Sci Technol. 2010 Aug 15;44(16):6371-6. PubMed PMID: 20704237.
Characteristics of Lead Corrosion Scales Formed during Drinking Water Distribution and Their Potential Influence on the Release of Lead and Other Contaminants. Kim EJ, Herrera JE. Environ Sci Technol. 2010 Aug 15;44(16):6054-61. PubMed PMID: 20704199.
Charge Partitioning at Gas-Solid Interfaces: Humidity Causes Electricity Buildup on Metals. Ducati TR, Simo~es LH, Galembeck F. Langmuir. 2010 Aug 12. [Epub ahead of print] PubMed PMID: 20704354.
Chronic and Acute Effects of Coal Tar Pitch Exposure and Cardiopulmonary Mortality Among Aluminum Smelter Workers. Friesen MC, Demers PA, Spinelli JJ, Eisen EA, Lorenzi MF, Le ND. Am J Epidemiol. 2010 Aug 11. [Epub ahead of print] PubMed PMID: 20702507.
A practical method of determining cross-calibration factors of PET scanners by moving a point-like (22)Na radioactive source. Hasegawa T, Oda K, Wada Y, Sato Y, Yamada T, Yoshida E, Murayama H, Saito K, Takeda T, Kikuchi K. Ann Nucl Med. 2010 Aug 11. [Epub ahead of print] PubMed PMID: 20700667.
The Safety and Immunogenicity of Recombinant EBA 175-RII NG Malaria Vaccine in Healthy Adults Living in a Non-Endemic Area. El Sahly HM, Patel SM, Atmar RL, Lanford TA, Dube T, Thompson D, Lee Sim BK, Long C, Keitel WA. Clin Vaccine Immunol. 2010 Aug 11. [Epub ahead of print] PubMed PMID: 20702657.
Evaluation of Heterogeneous Metal-Organic Framework Organocatalysts Prepared by Postsynthetic Modification. Garibay SJ, Wang Z, Cohen SM. Inorg Chem. 2010 Aug 10. [Epub ahead of print] PubMed PMID: 20698561.
Synthesis of 5-Amino-oxazole-4-carboxylates from alpha-Chloroglycinates. Zhang J, Coqueron PY, Vors JP, Ciufolini MA. Org Lett. 2010 Aug 10. [Epub ahead of print] PubMed PMID: 20698488.
Stability assessment of gas mixtures containing terpenes at nominal 5 nmol/mol contained in treated aluminum gas cylinders. Rhoderick GC. Anal Bioanal Chem. 2010 Aug 9. [Epub ahead of print] PubMed PMID: 20694720.
Contribution of Li-Ion Batteries to the Environmental Impact of Electric Vehicles. Notter DA, Gauch M, Widmer R, Wa¨ger P, Stamp A, Zah R, Althaus HJ. Environ Sci Technol. 2010 Aug 9. [Epub ahead of print] PubMed PMID: 20695466.
Radiologic evaluation of putty versus powder form of demineralized bone matrix in sinus floor elevation. Güven A, Ungör C, Cizmeci Senel F, Icten O. J Oral Implantol. 2010 Aug 6. [Epub ahead of print] PubMed PMID: 20690854.
A feasibility study using radiochromic films for fast neutron 2D passive dosimetry. Brady SL, Gunasingha R, Yoshizumi TT, Howell CR, Crowell AS, Fallin B, Tonchev AP, Dewhirst MW. Phys Med Biol. 2010 Aug 6;55(17):4977-4992. [Epub ahead of print] PubMed PMID: 20693612.
Safety and immunogenicity of the malaria vaccine candidate GMZ2 in malaria-exposed, adult individuals from Lambaréné, Gabon. Mordmüller B, Szywon K, Greutelaers B, Esen M, Mewono L, Treut C, Mürbeth RE, Chilengi R, Noor R, Kilama WL, Imoukhuede EB, Imbault N, Leroy O, Theisen M, Jepsen S, Milligan P, Fendel R, Kremsner PG, Issifou S. Vaccine. 2010 Aug 6. [Epub ahead of print] PubMed PMID: 20696154.
Application of advanced characterization techniques to assess DOM treatability of micro-polluted and un-polluted drinking source waters in China. Wang D, Xing L, Xie J, Chow CW, Xu Z, Zhao Y, Drikas M. Chemosphere. 2010 Aug 5. [Epub ahead of print] PubMed PMID: 20692013.
Effect of landfill characteristics on leachate organic matter properties and coagulation treatability. Comstock SE, Boyer TH, Graf KC, Townsend TG. Chemosphere. 2010 Aug 4. [Epub ahead of print] PubMed PMID: 20691462.
Antimicrobial activity of commercial zeolite A on Acinetobacter junii and Saccharomyces cerevisiae. Hrenovic J, Zeljezic D, Kopjar N, Sarpola A, Bronic J, Sekovanic L. J Hazard Mater. 2010 Jul 27. [Epub ahead of print] PubMed PMID: 20705392.
[Rapid elimination of surface organophosphorous pollutants using hydroxyl radical]. Yang XL, Bai MD, Han F. Huan Jing Ke Xue. 2010 Jun;31(6):1670-4. Chinese. PubMed PMID: 20698288.
[Relationship among coagulation effect of Al-based coagulant, content and speciation of residual aluminum]. Yang ZL, Gao BY, Yue QY, Jiang YS. Huan Jing Ke Xue. 2010 Jun;31(6):1542-7. Chinese. PubMed PMID: 20698270.
The use of aluminum nanostructures as platforms for metal enhanced fluorescence of the intrinsic emission of biomolecules in the ultra-violet. Chowdhury MH, Ray K, Gray SK, Pond J, Lakowicz JR. Proc Soc Photo Opt Instrum Eng. 2010 Feb;7577:75770O. PubMed PMID: 20706552.
Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids.
Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C.
Org Lett. 2010 Jan 5. [Epub ahead of print]
PMID: 19689116 [PubMed - as supplied by publisher]
Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides.
Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL.
Science. 2009 Aug 13. [Epub ahead of print]
PMID: 19679769 [PubMed - as supplied by publisher]
(2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides.
Zhang Q, Wang D, Wang X, Ding K.
J Org Chem. 2009 Aug 12. [Epub ahead of print]
PMID: 19673481 [PubMed - as supplied by publisher]
Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides.
Vechorkin O, Barmaz D, Proust V, Hu X.
J Am Chem Soc. 2009 Aug 11. [Epub ahead of print]
PMID: 19670863 [PubMed - as supplied by publisher]
Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia.
Huang JM, Dong Y.
Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28.
PMID: 19662260 [PubMed - in process]
Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols.
Salvi L, Kim JG, Walsh PJ.
J Am Chem Soc. 2009 Aug 4. [Epub ahead of print]
PMID: 19653691 [PubMed - as supplied by publisher]
Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines.
Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J.
J Comb Chem. 2009 Jul 31. [Epub ahead of print]
PMID: 19645499 [PubMed - as supplied by publisher]
Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids.
del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N.
Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29.
PMID: 19641822 [PubMed - in process]
Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides.
Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639999 [PubMed - as supplied by publisher]
Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies.
Snelders DJ, van Koten G, Klein Gebbink RJ.
J Am Chem Soc. 2009 Jul 29. [Epub ahead of print]
PMID: 19639941 [PubMed - as supplied by publisher]
Can One Predict Changes from S(N)1 to S(N)2 Mechanisms?
Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H.
J Am Chem Soc. 2009 Jul 27. [Epub ahead of print]
PMID: 19634906 [PubMed - as supplied by publisher]
A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides.
Liao Q, Wang Y, Zhang L, Xi C.
J Org Chem. 2009 Jul 15. [Epub ahead of print]
PMID: 19603753 [PubMed - as supplied by publisher]
Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides.
Shi L, Chu Y, Knochel P, Mayr H.
Org Lett. 2009 Jul 14. [Epub ahead of print]
PMID: 19601592 [PubMed - as supplied by publisher]
C5-Modified nucleosides exhibiting anticancer activity.
Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH.
Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21.
PMID: 19596579 [PubMed - in process]
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines.
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J Am Chem Soc. 2009 Jul 10. [Epub ahead of print]
PMID: 19591470 [PubMed - as supplied by publisher]
New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes.
Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B.
Org Lett. 2009 Jul 2. [Epub ahead of print]
PMID: 19572730 [PubMed - as supplied by publisher]
The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives.
Jo Y, Ju J, Choe J, Song KH, Lee S.
J Org Chem. 2009 Jul 2. [Epub ahead of print]
PMID: 19572571 [PubMed - as supplied by publisher]
Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents.
Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH.
Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8.
PMID: 19557114 [PubMed - in process]
A facile route to C2-substituted imidazolium ionic liquids.
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Molecules. 2009 Jun 19;14(6):2235-45.
PMID: 19553895 [PubMed - in process]
Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines.
McCall WS, Comins DL.
Org Lett. 2009 Jul 2;11(13):2940-2.
PMID: 19552467 [PubMed - indexed for MEDLINE]