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Ammonium Chloroiride
(NH4)2IrCl6
16940-92-4
Product Product Code Order or Specifications
(2N) 99% Ammonium Chloroiride IR-AMCL-02 Contact American Elements
(3N) 99.9% Ammonium Chloroiride IR-AMCL-03 Contact American Elements
(4N) 99.99% Ammonium Chloroiride IR-AMCL-04 Contact American Elements
(5N) 99.999% Ammonium Chloroiride IR-AMCL-05 Contact American Elements

Chloride Ion Ammonium Chloroiride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Iridium(Ir) atomic and molecular weight, atomic number and elemental symbolIridium is a Block D, Group 9, Period 6 element. The number of electrons in each of Iridium's shells is 2, 8, 18, 32, 15, 2 and its electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm. Iridium is only slightly toxic. Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react Iridium Bohr Modelwith any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical Elemental Iridiumcontacts for spark plugs. Iridium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iridium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed here. Iridium was first discovered by Smithson Tennant in 1804. See Iridium research below.

Formula CAS No. Appearance Molecular Weight
(NH4)2IrCl6 16940-92-4   441.01
PRODUCT CATALOG Iridium Products News Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Iridium

  • Visible Light-Triggered Photoswitchable Diarylethene-Based Iridium(III) Complexes for Imaging Living Cells. Tan W, Zhou J, Li F, Yi T, Tian H. Chem Asian J. 2011 Mar 10. doi: 10.1002/asia.201000820. [Epub ahead of print] PMID: 21394917 [PubMed - as supplied by publisher]

  • Synthesis and coordination chemistry of organoiridium complexes supported by an anionic tridentate ligand. Leonard NG, Williard PG, Bernskoetter WH. Dalton Trans. 2011 Mar 11. [Epub ahead of print] PMID: 21394366 [PubMed - as supplied by publisher]

  • Dynamics of triplet migration in films of N, N'-diphenyl-N, N'-bis(1-naphthyl)-1, 1'-biphenyl-4, 4''-diamine. Jankus V, Winscom C, Monkman AP. J Phys Condens Matter. 2010 May 12;22(18):185802. Epub 2010 Apr 20. PMID: 21393693 [PubMed - in process]

  • Organic synthesis involving iridium-catalyzed oxidation. Suzuki T. Chem Rev. 2011 Mar 9;111(3):1825-45. No abstract available. PMID: 21391567 [PubMed - in process]

  • Dehydrogenation and related reactions catalyzed by iridium pincer complexes. Choi J, Macarthur AH, Brookhart M, Goldman AS. Chem Rev. 2011 Mar 9;111(3):1761-79. No abstract available. PMID: 21391566 [PubMed - in process]

  • A novel electrochemiluminescent reagent of cyclometalated iridium complex-based DNA biosensor and its application in cancer cell detection. Li C, Lin J, Guo Y, Zhang S. Chem Commun (Camb). 2011 Mar 9. [Epub ahead of print] PMID: 21390365 [PubMed - as supplied by publisher]

  • Synthesis and X-ray crystal structure of a novel organometallic (?(3)-oxido)(?(3)-imido) trinuclear iridium complex. Schau-Magnussen M, Malcho P, Herbst K, Brorson M, Bendix J. Dalton Trans. 2011 Mar 9. [Epub ahead of print] PMID: 21387064 [PubMed - as supplied by publisher]

  • Surgical perspectives from a prospective, nonrandomized, multicenter study of breast conserving surgery and adjuvant electronic brachytherapy for the treatment of breast cancer. Dooley WC, Algan O, Dowlatshahi K, Francescatti D, Tito E, Beatty JD, Lerner AG, Ballard B, Boolbol SK. World J Surg Oncol. 2011 Mar 7;9(1):30. [Epub ahead of print] PMID: 21385371 [PubMed - as supplied by publisher]

  • Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes. Vicente BC, Huang Z, Brookhart M, Goldman AS, Scott SL. Dalton Trans. 2011 Mar 8. [Epub ahead of print] PMID: 21384048 [PubMed - as supplied by publisher]

  • Enantioselective Iridium-Catalyzed Vinylogous Reformatsky-Aldol Reaction from the Alcohol Oxidation Level: Linear Regioselectivity by Way of Carbon-Bound Enolates. Hassan A, Zbieg JR, Krische MJ. Angew Chem Int Ed Engl. 2011 Mar 4. doi: 10.1002/anie.201100646. [Epub ahead of print] No abstract available. PMID: 21381171 [PubMed - as supplied by publisher]

  • Zwitterionic Iridium Complexes with P,N-Ligands as Catalysts for the Asymmetric Hydrogenation of Alkenes. Franzke A, Pfaltz A. Chemistry. 2011 Mar 4. doi: 10.1002/chem.201003314. [Epub ahead of print] PMID: 21381140 [PubMed - as supplied by publisher]

  • Enhanced anti-Diastereo- and Enantioselectivity in Alcohol-Mediated Carbonyl Crotylation Using an Isolable Single Component Iridium Catalyst. Gao X, Townsend IA, Krische MJ. J Org Chem. 2011 Mar 4. [Epub ahead of print] PMID: 21375283 [PubMed - as supplied by publisher]

  • Reversible Insertion of Aldehydes and Ketones into C?sp?3?H Bonds of Chiral Bis(oxazoline)/Iridium Complexes. Castillo MR, Martín M, Fraile JM, Mayoral JA, Sola E. Angew Chem Int Ed Engl. 2011 Mar 1. doi: 10.1002/anie.201007292. [Epub ahead of print] No abstract available. PMID: 21365727 [PubMed - as supplied by publisher]

  • Iridium(III) Complexes of a Dicyclometalated Phosphite Tripod Ligand: Strategy to Achieve Blue Phosphorescence Without Fluorine Substituents and Fabrication of OLEDs. Lin CH, Chang YY, Hung JY, Lin CY, Chi Y, Chung MW, Lin CL, Chou PT, Lee GH, Chang CH, Lin WC. Angew Chem Int Ed Engl. 2011 Mar 1. doi: 10.1002/anie.201005624. [Epub ahead of print] No abstract available. PMID: 21365718 [PubMed - as supplied by publisher]

  • Room-temperature combinatorial screening of cyclometallated iridium(iii) complexes for a step towards molecular control of colour purity. Baranoff E, Jung I, Scopelliti R, Solari E, Grätzel M, Nazeeruddin MK. Dalton Trans. 2011 Mar 1. [Epub ahead of print] PMID: 21359398 [PubMed - as supplied by publisher]

  • [Postoperative accelerated partial radiotherapy for breast cancer]. Molnárová A, Bezák L. Klin Onkol. 2010;23(6):433-8. Czech. PMID: 21351421 [PubMed - in process]

  • Access to high levels of molecular complexity by one-pot iridium/enamine asymmetric catalysis. Quintard A, Alexakis A, Mazet C. Angew Chem Int Ed Engl. 2011 Mar 1;50(10):2354-8. doi: 10.1002/anie.201007001. Epub 2011 Feb 3. No abstract available. PMID: 21351353 [PubMed - in process]

  • Carbon-Sulfur Bond Formation via Iridium-Catalyzed Asymmetric Allylation of Aliphatic Thiols. Gao N, Zheng S, Yang W, Zhao X. Org Lett. 2011 Mar 18;13(6):1514-6. Epub 2011 Feb 24. PMID: 21348506 [PubMed - in process]

  • Chiral iridium spiro aminophosphine complexes: asymmetric hydrogenation of simple ketones, structure, and plausible mechanism. Xie JB, Xie JH, Liu XY, Zhang QQ, Zhou QL. Chem Asian J. 2011 Mar 1;6(3):899-908. doi: 10.1002/asia.201000716. Epub 2010 Dec 15. PMID: 21344665 [PubMed - in process]

  • Highly enantioselective amido iridium catalysts for the hydrogenation of simple ketones. Irrgang T, Friedrich D, Kempe R. Angew Chem Int Ed Engl. 2011 Feb 25;50(9):2183-6. doi: 10.1002/anie.201004665. Epub 2011 Jan 26. No abstract available. PMID: 21344581 [PubMed - in process]

 

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