CAS #:

Linear Formula:

BaAl4

MDL Number:

MFCD00800217

EC No.:

235-493-3

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Barium Aluminide
BA-ALI-02
Pricing > SDS > Data Sheet >
(3N) 99.9% Barium Aluminide
BA-ALI-03
Pricing > SDS > Data Sheet >
(4N) 99.99% Barium Aluminide
BA-ALI-04
Pricing > SDS > Data Sheet >
(5N) 99.999% Barium Aluminide
BA-ALI-05
Pricing > SDS > Data Sheet >

Barium Aluminide Properties (Theoretical)

Compound Formula Al4Ba
Molecular Weight 245.253
Appearance solid
Melting Point N/A
Boiling Point N/A
Density 3.2 g/cm3
Solubility in H2O N/A
Exact Mass N/A
Monoisotopic Mass 245.830993652344 Da
Charge N/A

Barium Aluminide Health & Safety Information

Signal Word Warning
Hazard Statements H302-H332
Hazard Codes Xn
Risk Codes 20/22
Safety Statements 28
RTECS Number N/A
Transport Information UN 1393 4.3/PG II
WGK Germany 1

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/19/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Barium Aluminide

Product Number: All applicable American Elements product codes, e.g. BA-ALI-02 , BA-ALI-03 , BA-ALI-04 , BA-ALI-05

CAS #: 12672-79-6

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.
Label elements
Hazard symbol None.
Signal word None.
Hazard statement The substance does not meet the criteria for classification.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name / CAS number:
Barium Aluminide / 12672-79-6


SECTION 4. FIRST AID MEASURES

Inhalation:
Do not use mouth-to-mouth method if victim inhaled the substance. Call a physician or poison
control center immediately.
Skin Contact:
Remove and isolate contaminated clothing and shoes. Immediately flush skin with plenty of water.
Wash clothing separately before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing.
Ingestion:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth
thoroughly. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth
method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device.
Most important symptoms/effects, acute and delayed:
Direct contact with eyes may cause temporary irritation.
Indication of immediate medical attention and special treatment needed:
Treat symptomatically.
General Information:
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance.


SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media None known.
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Wear suitable protective equipment.
and precautions for firefighters
Fire fighting Use water spray to cool unopened containers.
equipment/instructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures:
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Local
authorities should be advised if significant spillages cannot be contained. For personal protection,
see section 8 of the SDS.
Methods and materials for containment and cleaning up:
Prevent entry into waterways, sewer, basements or confined areas. Following product recovery,
flush area with water. For waste disposal, see section 13 of the SDS.
Environmental precautions:
Avoid discharge into drains, water courses or onto the ground.


SECTION 7. HANDLING AND STORAGE

Precautions for safe handling:
Observe good industrial hygiene practices.
Conditions for safe storage, including any incompatibilities:
Store in original tightly closed container. Store in a well-ventilated place. Store away from
incompatible materials (see Section 10 of the SDS).


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Control parameters Follow standard monitoring procedures.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection Wear appropriate chemical resistant gloves
Other
Wear chemical protective equipment that is specifically recommended by the manufacturer. It may
provide little or no thermal protection.
Other
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state Solid.
Form Solid.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling
range
Not available.
Flash point Not available.
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available
Decomposition temperature Not available.
Viscosity Not available.
Other information
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.


SECTION 10. STABILITY AND REACTIVITY

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Contact with incompatible materials.
Incompatible materials None known.
Hazardous decomposition products No hazardous decomposition products are known.


SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure
Inhalation Due to lack of data the classification is not possible.
Skin contact Due to lack of data the classification is not possible.
Eye contact Due to lack of data the classification is not possible.
Ingestion Due to lack of data the classification is not possible.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity Not known.
Skin corrosion/irritation Due to lack of data the classification is not possible.
Serious eye damage/eye irritation Due to lack of data the classification is not possible.
Respiratory or skin sensitization
Respiratory sensitization Due to lack of data the classification is not possible.
Skin sensitization Due to lack of data the classification is not possible.
Germ cell mutagenicity Due to lack of data the classification is not possible.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity Due to lack of data the classification is not possible.
Specific target organ toxicity -
single exposure
Due to lack of data the classification is not possible.
Specific target organ toxicity -
repeated exposure
Due to lack of data the classification is not possible.
Aspiration hazard Due to lack of data the classification is not possible.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.


SECTION 13. DISPOSAL CONSIDERATIONS

Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in
accordance with all applicable regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.


SECTION 14. TRANSPORT INFORMATION

DOT
UN number UN1564
UN proper shipping name Barium compounds, n.o.s.
Class 6.1(PGIII)
Transport hazard class(es)
Subsidiary risk -
Label(s) 6.1
Packing group III
Read safety instructions, SDS and emergency procedures before handling. Read safety
instructions, SDS and emergency procedures before handling.
Special precautions for user
Special provisions IB8, IP3, T1, TP33
Packaging exceptions 153
Packaging non bulk 213
Packaging bulk 240
IATA
UN number UN1564
UN proper shipping name Barium compounds, n.o.s.
Class 6.1(PGIII)
Transport hazard class(es)
Subsidiary risk -
Label(s) 6.1
Packing group III
Environmental hazards No.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1564
UN proper shipping name Barium compounds, n.o.s.
Class 6.1(PGIII)
Transport hazard class(es)
Subsidiary risk -
Label(s) 6.1
Packing group III
Marine pollutant No.
Environmental hazards
EmS Not available.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.


SECTION 15. REGULATORY INFORMATION

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Barium Aluminide

Aluminide IonBarium Aluminide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Aluminide compounds contain aluminum and one or more electropositive elements. Since aluminum is adjactent to the nonmetals on the periodic table, it forms compounds with properties intermediate between those of a metallic alloy and an ionic compound. Aluminides have found applications in hydrogen storage technology, industrial manufacturing, and in coatings for furnaces and other high temperature applications. In a recent series of hypergravity experiments, the European Space Agency (ESA) created a unique alloy of titanium aluminide whose light weight and durability may prove critical to the aeronautical industry. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Barium Aluminide Synonyms

Aluminium - barium (4:1), barium aluminum alloy; Aluminum, compd. with barium (4:1)

Chemical Identifiers

Linear Formula BaAl4
MDL Number MFCD00800217
EC No. 235-493-3
Beilstein/Reaxys No. N/A
Pubchem CID 6337003
IUPAC Name aluminum; barium
SMILES [AlH3].[AlH3].[AlH3].[AlH3].[Ba]
InchI Identifier InChI=1S/4Al.Ba
InchI Key CNMLKYRHFLUEAL-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Aluminum

See more Aluminum products. Aluminum (or Aluminium) (atomic symbol: Al, atomic number: 13) is a Block P, Group 13, Period 3 element with an atomic weight of 26.9815386. It is the third most abundant element in the earth's crust and the most abundant metallic element. Aluminum Bohr Model Aluminum's name is derived from alumina, the mineral from which Sir Humphrey Davy attempted to refine it from in 1812. Aluminum was first predicted by Antoine Lavoisier 1787 and first isolated by Hans Christian Øersted in 1825. Aluminum is a silvery gray metal that possesses many desirable characteristics. It is light, nonmagnetic and non-sparking. It stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used in many industrial applications where a strong, light, easily constructed material is needed. Elemental AluminumAlthough it has only 60% of the electrical conductivity of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but alloyed with small amounts of copper, magnesium, silicon, manganese, or other elements, it imparts a variety of useful properties.

Barium

See more Barium products. Barium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental BariumIn its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getter," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum in load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4); it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy.

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