Barium Phosphide

Ba3P2
CAS 12380-72-2


Product Product Code Order or Specifications
(5N) 99.999% Barium Phosphide Powder BA-P-05-P Contact American Elements
(5N) 99.999% Barium Phosphide Ingot BA-P-05-I Contact American Elements
(5N) 99.999% Barium Phosphide Chunk BA-P-05-CK Contact American Elements
(5N) 99.999% Barium Phosphide Lump BA-P-05-L Contact American Elements
(5N) 99.999% Barium Phosphide Sputtering Target BA-P-05-ST Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Ba3P2 12380-72-2 42981161 6337012 N/A 235-621-8 barium; phosphane N/A [Ba].[Ba].[Ba].P.P InChI=1S/3Ba.2H3P/h;;;2*1H3 ZBOPGLLDGXMBJG-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
H6Ba3P2 479.976164 N/A N/A N/A N/A 481.710215 481.710215 0 Safety Data Sheet

Phosphide IonBarium Phosphide is a semiconductor used in high power, high frequency applications and in laser diodes. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Barium (Ba) and molecular weight, atomic number and elemental symbolBarium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental Barium In its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getterer," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum as load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4); it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy. For more information on barium, including properties, safety data, research, and American Elements' catalog of barium products, visit the Barium Information Center.

Phosphorus(P) atomic and molecular weight, atomic number and elemental symbolPhosphorus Bohr ModelPhosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus; its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669; its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation. For more information on phosphorus, including properties, safety data, research, and American Elements' catalog of phosphorus products, visit the Phosphorus Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany N/A
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

BARIUM PHOSPHIDE SYNONYMS
Tribarium diphosphide; Barium - phosphine (3:2)

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Barium

  • Jen-Hsien Hsu, Cheol-Woon Kim, Richard K. Brow, Joe Szabo, Ray Crouch, Rob Baird, An alkali-free barium borosilicate viscous sealing glass for solid oxide fuel cells, Journal of Power Sources, Volume 270, 15 December 2014
  • Gan Jet Hong Melvin, Qing-Qing Ni, Toshiaki Natsuki, Electromagnetic wave absorption properties of barium titanate/carbon nanotube hybrid nanocomposites, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Junhai Shen, Keyu Chen, Liangchao Li, Weixiang Wang, Ye Jin, Fabrication and microwave absorbing properties of (Z-type barium ferrite/silica)@polypyrrole composites, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Hongyi Li, Lingyun Dong, Yi Lu, Shilie Pan, Xiaoquan Lu, Hongwei Yu, Hongping Wu, Xin Su, Zhihua Yang, Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa2(B3O6)2, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Yongbo Zhang, Fei Xu, Guoguo Tan, Junli Zhang, Tao Wang, Fashen Li, Improvement of microwave-absorbing properties of Co2Z barium ferrite composite by coating Ag nanoparticles, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Ningning Dai, Zhenhua Wang, Taizhi Jiang, Jie Feng, Wang Sun, Jinshuo Qiao, David Rooney, Kening Sun, A new family of barium-doped Sr2Fe1.5Mo0.5O6-d perovskites for application in intermediate temperature solid oxide fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Yong Li, Pei-Chen Su, Lai Mun Wong, Shijie Wang, Chemical stability study of nanoscale thin film yttria-doped barium cerate electrolyte for micro solid oxide fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Renan Azevedo da Rocha, Carolina Leão Quintanilha, Thayná Viana Lanxin, Júlio Carlos Afonso, Cláudio Augusto Vianna, Valdir Gante, José Luiz Mantovano, Production of potassium manganate and barium manganate from spent zinc–MnO2 dry cells via fusion with potassium hydroxide, Journal of Power Sources, Volume 268, 5 December 2014
  • Hye-Lim Kim, Shin Kim, Kyu-Hyung Lee, Hong-Lim Lee, Ki-Tae Lee, Oxygen ion conduction in barium doped LaInO3 perovskite oxides, Journal of Power Sources, Volume 267, 1 December 2014
  • Satoshi Tanaka, Takuma Takahashi, Keizo Uematsu, Fabrication of transparent crystal-oriented polycrystalline strontium barium niobate ceramics for electro-optical application, Journal of the European Ceramic Society, Volume 34, Issue 15, December 2014
  • L.A. Reznichenko, V.A. Alyoshin, L.A. Shilkina, M.V. Talanov, S.I. Dudkina, Variations in the microstructure and properties of multicomponent ferroelectric ceramics as a result of its modification by barium, Ceramics International, Volume 40, Issue 9, Part B, November 2014
  • Saptasree Bose, Radhaballabh Debnath, Strong crystal-field effect and efficient phonon assisted Yb3+?Tm3+ energy transfer in a (Yb3+/Tm3+) co-doped high barium–tellurite glass, Journal of Luminescence, Volume 155, November 2014
  • Kaladhar Kamalasanan, Anupriya, M.K. Deepa, Chandra P. Sharma, Supramolecular curcumin–barium prodrugs for formulating with ceramic particles, Colloids and Surfaces B: Biointerfaces, Volume 122, 1 October 2014
  • Mazeyar Parvinzadeh Gashti, Matthias Burgener, Manuela Stir, Jürg Hulliger, Barium hydrogen phosphate/gelatin composites versus gelatin-free barium hydrogen phosphate: Synthesis and characterization of properties, Journal of Colloid and Interface Science, Volume 431, 1 October 2014
  • Maha Rai, Gavin Mountjoy, Molecular dynamics modelling of the structure of barium silicate glasses BaO–SiO2, Journal of Non-Crystalline Solids, Volume 401, 1 October 2014
  • A. Friederich, C. Kohler, M. Nikfalazar, A. Wiens, M. Sazegar, R. Jakoby, W. Bauer, J.R. Binder, Microstructure and microwave properties of inkjet printed barium strontium titanate thick-films for tunable microwave devices, Journal of the European Ceramic Society, Volume 34, Issue 12, October 2014
  • C.B. Boothroyd, M.S. Moreno, M. Duchamp, A. Kovács, N. Monge, G.M. Morales, C.A. Barbero, R.E. Dunin-Borkowski, Atomic resolution imaging and spectroscopy of barium atoms and functional groups on graphene oxide, Ultramicroscopy, Volume 145, October 2014
  • Tatjana S. Pochekutova, Vyacheslav K. Khamylov, Sergey Yu. Ketkov, Georgy K. Fukin, Nadia M. Khamaletdinova, Boris I. Petrov, Olga V. Kuznetsova, Synthesis, X-ray investigation and DFT calculations of solvated barium ß-diketonate complexes with 18-dibenzocrown-6: [Ba(pta)2(18DBC6)](C6H5CH3)2 and [Ba(pta)2(18DBC6)](CH2Cl2) (pta = 1,1,1-trifluoro-5,5-dimethylhexanedionato-2,4; 18DBC6 = 18-dibenzocrown-6), Polyhedron, Volume 79, 5 September 2014
  • José Pedro Rino, An interaction potential for barium sulfide: A molecular dynamics study, Computational Materials Science, Volume 92, September 2014

Recent Research & Development for Phosphides

  • Yuanyuan Tan, Dongbai Sun, Hongying Yu, Tao Wu, Bin Yang, Yu Gong, Shi Yan, Rong Du, Zhongjun Chen, Xueqing Xing, Guang Mo, Quan Cai, Zhonghua Wu, Optimal synthesis and magnetic properties of size-controlled nickel phosphide nanoparticles, Journal of Alloys and Compounds, Volume 605, 25 August 2014
  • Zihab Sohbatzadeh, M.R. Roknabadi, Nasser Shahtahmasebi, Mohammad Behdani, Spin-dependent transport properties of an armchair boron-phosphide nanoribbon embedded between two graphene nanoribbon electrodes, Physica E: Low-dimensional Systems and Nanostructures, Available online 13 August 2014
  • Kristian Smistrup, Jesper Nørregaard, Andrej Mironov, Tobias H. Bro, Brian Bilenberg, Theodor Nielsen, Johan Eriksen, Anil H. Thilsted, Ole Hansen, Anders Kristensen, Stephen Rishton, Ferdous Khan, Mark Emanuel, Yong Ma, Yin Zhang, Nanoimprinted DWDM laser arrays on indium phosphide substrates, Microelectronic Engineering, Volume 123, 1 July 2014
  • Kathleen Lee, Sarah Synnestvedt, Maverick Bellard, Kirill Kovnir, GeP and (Ge1-xSnx)(P1-yGey) (x˜0.12, y˜0.05): Synthesis, structure, and properties of two-dimensional layered tetrel phosphides, Journal of Solid State Chemistry, Available online 2 May 2014
  • Shuna Zhang, Shujuan Zhang, Limin Song, Xiaoqing Wu, Sheng Fang, Three-dimensional interconnected nickel phosphide networks with hollow microstructures and desulfurization performance, Materials Research Bulletin, Volume 53, May 2014
  • Xuguang Liu, Lei Xu, Baoquan Zhang, Essential elucidation for preparation of supported nickel phosphide upon nickel phosphate precursor, Journal of Solid State Chemistry, Volume 212, April 2014
  • Nicole A. Kotulak, Martin Diaz, Allen Barnett, Robert L. Opila, Toward a tandem gallium phosphide on silicon solar cell through liquid phase epitaxy growth, Thin Solid Films, Volume 556, 1 April 2014
  • Shuna Zhang, Shujuan Zhang, Limin Song, Qingwu Wei, A general approach to the synthesis of metal phosphide catalysts, Powder Technology, Volume 253, February 2014
  • Paulin Buchwalter, Jacky Rosé, Bénédicte Lebeau, Pierre Rabu, Pierre Braunstein, Jean-Louis Paillaud, Stoichiometric molecular single source precursors to cobalt phosphides, Inorganica Chimica Acta, Volume 409, Part B, 1 January 2014
  • C. Kamal, Aparna Chakrabarti, Arup Banerjee, S.K. Deb, Ab initio studies of effect of intercalation on the properties of single walled carbon and gallium phosphide nanotubes, Physica E: Low-dimensional Systems and Nanostructures, Volume 54, December 2013
  • Jian Wang, Sheng-Qing Xia, Xu-Tang Tao, Marion C. Schäfer, Svilen Bobev, New ternary phosphides and arsenides. Syntheses, crystal structures, physical properties of Eu2ZnP2, Eu2Zn2P3 and Eu2Cd2As3, Journal of Solid State Chemistry, Volume 205, September 2013
  • Enrique San Andrés, María Ángela Pampillón, Pedro Carlos Feijoo, Raúl Pérez, Carmina Cañadilla, High permittivity gadolinium oxide deposited on indium phosphide by high-pressure sputtering without interface treatments, Microelectronic Engineering, Volume 109, September 2013
  • N. Fressengeas, C. Dan, D. Wolfersberger, Microsecond infrared beam bending in photorefractive iron doped indium phosphide, Optics & Laser Technology, Volume 48, June 2013
  • Shan Liu, Haisheng Fang, Bin Yang, Yaochun Yao, Wenhui Ma, Yongnian Dai, Improving rate performance of LiMnPO4 based material by forming electron-conducting iron phosphides, Journal of Power Sources, Volume 230, 15 May 2013
  • Kazuyuki Edamoto, The electronic properties of nickel phosphide surfaces: Angle-resolved and resonant photoemission studies, Applied Surface Science, Volume 269, 15 March 2013
  • Stanislav Hasenöhrl, Peter Eliáš, Ján Šoltýs, Roman Stoklas, Agáta Dujavová-Laurencíková, Jozef Novák, Zinc-doped gallium phosphide nanowires for photovoltaic structures, Applied Surface Science, Volume 269, 15 March 2013
  • Erik Busby, Arthur Thibert, Jack Fuzell, Deisy C. Arrington, Ali M. Jawaid, Preston T. Snee, Delmar S. Larsen, Ultrafast exciton dynamics in colloidal aluminum phosphide nanocrystals, Chemical Physics Letters, Volume 557, 5 February 2013
  • D. Philippon, M.-I. De Barros-Bouchet, Th. Le Mogne, B. Vacher, O. Lerasle, J.-M. Martin, A multi-technique approach to the characterization of iron phosphide tribofilm, Thin Solid Films, Volume 524, 1 December 2012
  • Wei Liu, Hailing Tu, Hai Yang, Shuyu Zhang, Lanqin Yan, Chengsong Huo, Xiaoping Su, Structural, mechanical properties and composition analysis of boron phosphide coatings, Journal of Alloys and Compounds, Volume 538, 15 October 2012
  • Hairui Liu, Jian Liang, Xuguang Liu, Husheng Jia, Bingshe Xu, Self-assembly of indium phosphide with an urchin-like architecture through a hydrothermal route, Materials Letters, Volume 82, 1 September 2012