Barium Phosphide

Ba3P2
CAS 12380-72-2


Product Product Code Order or Specifications
(5N) 99.999% Barium Phosphide Powder BA-P-05-P Contact American Elements
(5N) 99.999% Barium Phosphide Ingot BA-P-05-I Contact American Elements
(5N) 99.999% Barium Phosphide Chunk BA-P-05-CK Contact American Elements
(5N) 99.999% Barium Phosphide Lump BA-P-05-L Contact American Elements
(5N) 99.999% Barium Phosphide Sputtering Target BA-P-05-ST Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Ba3P2 12380-72-2 42981161 6337012 N/A 235-621-8 barium; phosphane N/A [Ba].[Ba].[Ba].P.P InChI=1S/3Ba.2H3P/h;;;2*1H3 ZBOPGLLDGXMBJG-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
H6Ba3P2 479.976164 N/A N/A N/A N/A 481.710215 481.710215 0 Safety Data Sheet

Phosphide IonBarium Phosphide is a semiconductor used in high power, high frequency applications and in laser diodes. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Barium (Ba) and molecular weight, atomic number and elemental symbolBarium (atomic symbol: Ba, atomic number: 56) is a Block S, Group 2, Period 6 element with an atomic weight of 137.27. The number of electrons in each of barium's shells is [2, 8, 18, 18, 8, 2] and its electron configuration is [Xe] 6s2. Barium Bohr ModelBarium is a member of the alkaline-earth metals. The barium atom has a radius of 222 pm and a Van der Waals radius of 268 pm. Barium was discovered by Carl Wilhelm Scheele in 1772 and first isolated by Humphry Davy in 1808. Elemental Barium In its elemental form, barium is a soft, silvery-gray metal. Industrial applications for barium include acting as a "getterer," or unwanted gas remover, for vacuum tubes, and as an additive to steel and cast iron. Barium is also alloyed with silicon and aluminum as load-bearing alloys. The main commercial source of barium is the mineral barite (BaSO4); it does not occur naturally as a free element . The name barium is derived from the Greek word "barys," meaning heavy. For more information on barium, including properties, safety data, research, and American Elements' catalog of barium products, visit the Barium Information Center.

Phosphorus(P) atomic and molecular weight, atomic number and elemental symbolPhosphorus Bohr ModelPhosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus; its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669; its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation. For more information on phosphorus, including properties, safety data, research, and American Elements' catalog of phosphorus products, visit the Phosphorus Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany N/A
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

BARIUM PHOSPHIDE SYNONYMS
Tribarium diphosphide; Barium - phosphine (3:2)

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Barium

  • Ningning Dai, Zhenhua Wang, Taizhi Jiang, Jie Feng, Wang Sun, Jinshuo Qiao, David Rooney, Kening Sun, A new family of barium-doped Sr2Fe1.5Mo0.5O6−δ perovskites for application in intermediate temperature solid oxide fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Yong Li, Pei-Chen Su, Lai Mun Wong, Shijie Wang, Chemical stability study of nanoscale thin film yttria-doped barium cerate electrolyte for micro solid oxide fuel cells, Journal of Power Sources, Volume 268, 5 December 2014
  • Renan Azevedo da Rocha, Carolina Leão Quintanilha, Thayná Viana Lanxin, Júlio Carlos Afonso, Cláudio Augusto Vianna, Valdir Gante, José Luiz Mantovano, Production of potassium manganate and barium manganate from spent zinc–MnO2 dry cells via fusion with potassium hydroxide, Journal of Power Sources, Volume 268, 5 December 2014
  • Hye-Lim Kim, Shin Kim, Kyu-Hyung Lee, Hong-Lim Lee, Ki-Tae Lee, Oxygen ion conduction in barium doped LaInO3 perovskite oxides, Journal of Power Sources, Volume 267, 1 December 2014
  • Saptasree Bose, Radhaballabh Debnath, Strong crystal-field effect and efficient phonon assisted Yb3+→Tm3+ energy transfer in a (Yb3+/Tm3+) co-doped high barium–tellurite glass, Journal of Luminescence, Volume 155, November 2014
  • Mazeyar Parvinzadeh Gashti, Matthias Burgener, Manuela Stir, Jürg Hulliger, Barium hydrogen phosphate/gelatin composites versus gelatin-free barium hydrogen phosphate: Synthesis and characterization of properties, Journal of Colloid and Interface Science, Volume 431, 1 October 2014
  • A. Friederich, C. Kohler, M. Nikfalazar, A. Wiens, M. Sazegar, R. Jakoby, W. Bauer, J.R. Binder, Microstructure and microwave properties of inkjet printed barium strontium titanate thick-films for tunable microwave devices, Journal of the European Ceramic Society, Volume 34, Issue 12, October 2014
  • Tatjana S. Pochekutova, Vyacheslav K. Khamylov, Sergey Yu. Ketkov, Georgy K. Fukin, Nadia M. Khamaletdinova, Boris I. Petrov, Olga V. Kuznetsova, Synthesis, X-ray investigation and DFT calculations of solvated barium β-diketonate complexes with 18-dibenzocrown-6: [Ba(pta)2(18DBC6)](C6H5CH3)2 and [Ba(pta)2(18DBC6)](CH2Cl2) (pta = 1,1,1-trifluoro-5,5-dimethylhexanedionato-2,4; 18DBC6 = 18-dibenzocrown-6), Polyhedron, Volume 79, 5 September 2014
  • José Pedro Rino, An interaction potential for barium sulfide: A molecular dynamics study, Computational Materials Science, Volume 92, September 2014
  • Yin Xia, Qinglin Ma, Zhiguo Zhang, Zhendong Liu, Jian Feng, Anding Shao, Weifeng Wang, Qianli Fu, Development of Chinese barium copper silicate pigments during the Qin Empire based on Raman and polarized light microscopy studies, Journal of Archaeological Science, Volume 49, September 2014

Recent Research & Development for Phosphides

  • Peapod-Like Composite with Nickel Phosphide Nanoparticles Encapsulated in Carbon Fibers as Enhanced Anode for Li-Ion Batteries. Zhang H, Feng Y, Zhang Y, Fang L, Li W, Liu Q, Wu K, Wang Y. ChemSusChem. 2014.
  • Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes. Gardner BM, Balázs G, Scheer M, Tuna F, McInnes EJ, McMaster J, Lewis W, Blake AJ, Liddle ST. Angew Chem Int Ed Engl. 2014.
  • The Stannylphosphide Anion Reagent Sodium Bis(triphenylstannyl) Phosphide: Synthesis, Structural Characterization, and Reactions with Indium, Tin, and Gold Electrophiles. Cummins CC, Huang C, Miller TJ, Reintinger MW, Stauber JM, Tannou I, Tofan D, Toubaei A, Velian A, Wu G. Inorg Chem. 2014.
  • Hexanuclear Gold(I) Phosphide Complexes as Platforms for Multiple Redox-Active Ferrocenyl Units. Lee TK, Cheng EC, Zhu N, Yam VW. Chemistry. 2013 Dec.
  • Easily-prepared dinickel phosphide (Ni2P) nanoparticles as an efficient and robust electrocatalyst for hydrogen evolution. Feng L, Vrubel H, Bensimon M, Hu X. Phys Chem Chem Phys. 2014 Feb.
  • Abdominal imaging in zinc phosphide poisoning. Hassanian-Moghaddam H, Shahnazi M, Zamani N, Bahrami-Motlagh H. Emerg Radiol 2014.
  • Gas phase catalytic hydrodechlorination of chlorobenzene over cobalt phosphide catalysts with different P contents. J Hazard Mater. 2013 | first author:Cecilia JA
  • Successful treatment of cardiogenic shock with an intra-aortic balloon pump following aluminium phosphide poisoning. Mehrpour O, Amouzeshi A, Dadpour B, Oghabian Z, Zamani N, Amini S, Hoffman RS. Arh Hig Rada Toksikol. 2014 Jan.
  • Aluminium phosphide-induced leukopenia. Ntelios D, Mandros C, Potolidis E, Fanourgiakis P. BMJ Case Rep. 2013 Oct.
  • 25th anniversary article: exploring nanoscaled matter from speciation to phase diagrams: metal phosphide nanoparticles as a case of study. Carenco S, Portehault D, Boissière C, Mézailles N, Sanchez C. Adv Mater. 2014 Jan.
  • Pulse-reverse electrodeposition of transparent nickel phosphide film with porous nanospheres as a cost-effective counter electrode for dye-sensitized solar cells. Wu MS, Wu JF. Chem Commun (Camb). 2013 Oct.
  • 25th Anniversary Article: Exploring Nanoscaled Matter from Speciation to Phase Diagrams: Metal Phosphide Nanoparticles as a Case of Study. Carenco S, Portehault D, Boissière C, Mézailles N, Sanchez C. Adv Mater. 2013 Dec.
  • A Common Misconception in the Management of Aluminium Phosphide Poisoning. Arh Hig Rada Toksikol. 2013 | first author:Marashi SM.
  • Pulse-reverse electrodeposition of transparent nickel phosphide film with porous nanospheres as a cost-effective counter electrode for dye-sensitized solar cells. Wu MS, Wu JF. Chem Commun (Camb). 2013
  • Solution-Processed Zinc Phosphide (α-Zn(3)P(2)) Colloidal Semiconducting Nanocrystals for Thin Film Photovoltaic Applications. ACS Nano. 2013 create date:2013/08/21 | first author:Luber EJ
  • From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes. Breit NC, Szilvási T, Suzuki T, Gallego D, Inoue S. J Am Chem Soc. 2013 Nov.
  • Structural transitions at the nanoscale: the example of palladium phosphides synthesized from white phosphorus. Carenco S, Hu Y, Florea I, Ersen O, Boissière C, Sanchez C, Mézailles N. Dalton Trans. 2013 Aug.
  • From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes. Breit NC, Szilvási T, Suzuki T, Gallego D, Inoue S. J Am Chem Soc. 2013 Oct.
  • Ingestion of gallium phosphide" nanowires has no adverse effect on Drosophila tissue function. Adolfsson K, Schneider M, Hammarin G, Häcker U, Prinz CN. Nanotechnology.
  • Is the Use of Cardioactive Steroids Appropriate in Managing Aluminium Phosphide Poisoning-Induced Heart Failure? Arh Hig Rada Toksikol. 2013 create date:2013/10/03 | first author:Marashi SM