Bismuth Oxide

High Purity Bi2O3
CAS 1304-76-3


Product Product Code Order or Specifications
(5N) 99.999% Bismuth Oxide Powder BI-OX-05-P Contact American Elements
(5N) 99.999% Bismuth Oxide Ingot BI-OX-05-I Contact American Elements
(5N) 99.999% Bismuth Oxide Chunk BI-OX-05-CK Contact American Elements
(5N) 99.999% Bismuth Oxide Lump BI-OX-05-L Contact American Elements
(5N) 99.999% Bismuth Oxide Sputtering Target BI-OX-05-ST Contact American Elements
(5N) 99.999% Bismuth Oxide Wafer BI-OX-05-WSX Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Bi2O3 1304-76-3 14776 MFCD00003462 215-134-7 oxo(oxobismuthanyloxy) bismuthane N/A O=[Bi]O[Bi]=O InChI=1S/2Bi.3O WMWLMWRWZQELOS-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
Bi2O3 465.96 Yellow Powder 817° C
(1,503° F)
1890 °C
(3434 °F)
8.9 g/cm3 465.945541 465.945541 0 Safety Data Sheet

Oxide IonBismuth Oxide is a highly insoluble thermally stable Bismuth source suitable for glass, optic and ceramic applications. Bismuth oxide is found naturally as the mineral bismite and sphaerobismoite but can also be achieved as a by-product of the smelting of copper and lead ores. Bismuth oxide is the most industrially vital compound of bismuth. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic High Purity (99.999%) Bismuth Oxide(Bi2O3) Powderconductivity. Metal oxide compounds arebasic anhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Bismuth Oxide is also available in pellets, pieces, powders, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). See Nanotechnology for more nanotechnology applications information. Bismuth Oxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. See safety data and research below and pricing/lead time above. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Bismuth (Bi) atomic and molecular weight, atomic number and elemental symbol Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040(. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental Bismuth Bismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass. For more information on bismuth, including properties, safety data, research, and American Elements' catalog of bismuth products, visit the Bismuth Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Warning
H315-H319-H335
Xi
36/37/38
26-36/37
EB2984460
N/A
2
Exclamation Mark-Acute Toxicity        

BISMUTH OXIDE SYNONYMS
Dibismuth trioxide, Bismuth trioxide, Bismutum-oxydatum, Dioxodibismoxane, Bismuth(III) oxide, Keto-ketobismuthanyloxy-bismuthane, Bismuth sesquioxide, Bismuth Yellow, Bismuth(3+) oxide

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Bismuth

  • Jorge Omar Gil Posada, Peter J. Hall, Post-hoc comparisons among iron electrode formulations based on bismuth, bismuth sulphide, iron sulphide, and potassium sulphide under strong alkaline conditions, Journal of Power Sources, Volume 268, 5 December 2014
  • Xiaohua Zhang, Wei Ren, Feng Xin, Peng Shi, Structures and electric properties of cubic bismuth based pyrochlore thin films grown by pulsed laser deposition, Journal of Alloys and Compounds, Volume 614, 25 November 2014
  • Masayuki Takashiri, Kazuo Imai, Masato Uyama, Harutoshi Hagino, Saburo Tanaka, Koji Miyazaki, Yoshitake Nishi, Effects of homogeneous irradiation of electron beam on crystal growth and thermoelectric properties of nanocrystalline bismuth selenium telluride thin films, Journal of Alloys and Compounds, Volume 612, 5 November 2014
  • Lingxia Li, Dan Xu, Shihui Yu, Helei Dong, Yuxin Jin, Haoran Zheng, Effect of substrate on the dielectric properties of bismuth magnesium niobate thin films prepared by RF magnetron sputtering, Vacuum, Volume 109, November 2014
  • Qing Liao, Yanjie Wang, Yan Chen, Yanying Wei, Haihui Wang, Novel bifunctional tantalum and bismuth co-doped perovskite BaBi0.05Co0.8Ta0.15O3-d with high oxygen permeation, Journal of Membrane Science, Volume 468, 15 October 2014
  • Dong Hoon Son, Bok Hyeon Kim, Seung Ho Lee, Seongjae Boo, Won-Taek Han, Ultra-broadband near-infrared emission in bismuth borosilicate glasses incorporated with Er3 +, Tm3 +, and Yb3 + ions, Journal of Non-Crystalline Solids, Volume 402, 15 October 2014
  • Xijia He, Jianbei Qiu, Yong Yang, Dacheng Zhou, Xuhui Xu, Shengxian Wei, Abnormal near-infrared luminescence property of bismuth doped calcium germanate glasses, Journal of Non-Crystalline Solids, Volume 402, 15 October 2014
  • ZhangSheng Liu, HuaShen Ran, JiNan Niu, PeiZhong Feng, YaBo Zhu, One-pot synthesis of Bismuth Oxyhalide/Oxygen-rich bismuth oxyhalide Heterojunction and its photocatalytic activity, Journal of Colloid and Interface Science, Volume 431, 1 October 2014
  • Xue Lin, Zongxiao Liu, Xiaoyu Guo, Chunbo Liu, Hongju Zhai, Qingwei Wang, Limin Chang, Controllable synthesis and photocatalytic activity of spherical, flower-like and nanofibrous bismuth tungstates, Materials Science and Engineering: B, Volume 188, October 2014
  • Gowrish K. Rao, Doping ZnS and ZnSe thin films with bismuth: A comparison between sandwiching technique and nano-particle incorporation, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • R. Wongmaneerung, J. Padchasri, R. Tipakontitikul, T.H. Loan, P. Jantaratana, R. Yimnirun, S. Ananta, Phase formation, dielectric and magnetic properties of bismuth ferrite–lead magnesium niobate multiferroic composites, Journal of Alloys and Compounds, Volume 608, 25 September 2014
  • Arda Aytimur, Ibrahim Uslu, Senol Durmusoglu, Ahmet Akdemir, Polymer-derived yttria stabilized bismuth oxide nanocrystalline ceramics, Ceramics International, Volume 40, Issue 8, Part B, September 2014
  • C.M. Bedoya-Hincapié, E. Restrepo-Parra, J.J. Olaya-Flórez, J.E. Alfonso, F.J. Flores-Ruiz, F.J. Espinoza-Beltrán, Ferroelectric behavior of bismuth titanate thin films grown via magnetron sputtering, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • Lingxia Li, Dan Xu, Shihui Yu, Helei Dong, Yuxin Jin, Effect of thickness on the dielectric properties of bismuth magnesium niobium thin films deposited by rf magnetron sputtering, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • R.N.P. Choudhary, C. Behera, Piyush R. Das, R.R. Das, Development of bismuth-based electronic materials from Indian red mud, Ceramics International, Volume 40, Issue 8, Part A, September 2014
  • M. Zannen, M. Dietze, H. Khemakhem, A. Kabadou, M. Es-Souni, The erbium?s amphoteric behavior effects on sodium bismuth titanate properties, Ceramics International, Volume 40, Issue 8, Part B, September 2014
  • David A. McKeown, Hao Gan, Ian L. Pegg, Raman and X-ray absorption spectroscopy studies of chromium–phosphorus interactions in high-bismuth high-level waste glasses, Journal of Nuclear Materials, Volume 452, Issues 1–3, September 2014
  • Mohsen K. Keshavarz, Dimitri Vasilevskiy, Remo A. Masut, Sylvain Turenne, Synthesis and characterization of bismuth telluride-based thermoelectric nanocomposites containing MoS2 nano-inclusions, Materials Characterization, Volume 95, September 2014
  • P. Srinivasa Rao, P. Ramesh Babu, R. Vijay, T. Narendrudu, N. Veeraiah, D. Krishna Rao, Spectroscopic and dielectric response of zinc bismuth phosphate glasses as a function of chromium content, Materials Research Bulletin, Volume 57, September 2014
  • Saihua Jiang, Zhou Gui, Yongqian Shi, Keqing Zhou, Bihe Yuan, Chenlu Bao, Siuming Lo, Yuan Hu, Bismuth subcarbonate nanoplates for thermal stability, fire retardancy and smoke suppression applications in polymers: A new strategy, Polymer Degradation and Stability, Volume 107, September 2014