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Bismuth Oxide
High Purity Bi2O3
1304-76-3
Product Product Code Order or Specifications
(5N) 99.999% Bismuth Oxide Powder BI-OX-05-P Contact American Elements
(5N) 99.999% Bismuth Oxide Ingot BI-OX-05-I Contact American Elements
(5N) 99.999% Bismuth Oxide Chunk BI-OX-05-CK Contact American Elements
(5N) 99.999% Bismuth Oxide Lump BI-OX-05-L Contact American Elements
(5N) 99.999% Bismuth Oxide Sputtering Target BI-OX-05-ST Contact American Elements
(5N) 99.999% Bismuth Oxide Wafer BI-OX-05-WSX Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Bi2O3 1304-76-3 24852122 14776 MFCD00003462 215-134-7 Oxo(oxobismuthanyloxy) bismuthane   O=[Bi]O[Bi]=O InChI=1S/2Bi.3O WMWLMWRWZQELOS-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
Bi2O3 465.96 Yellow Powder 8.9 g/cm3 465.945 g/mol 465.945544 Da 0 Safety Data Sheet


Oxide IonBismuth Oxide or Bismuth Trioxide is a highly insoluble thermally stable Bismuth source suitable for glass, optic and ceramic applications. Bismuth oxide is found naturally as the mineral bismite and sphaerobismoite but can also be achieved as a by-product of the smelting of copper and lead ores. Bismuth oxide is the most industrially vital compound of bismuth. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic High Purity (99.999%) Bismuth Oxide(Bi2O3) Powderconductivity. Metal oxide compounds arebasic anhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Bismuth Oxide is also available in pellets, pieces, powders, sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). See Nanotechnology for more nanotechnology applications information. Bismuth Oxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. See safety data and research below and pricing/lead time above.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Bismuth(Bi) atomic and molecular weight, atomic number and elemental symbolBismuth is a Block P, Group 15, Period 6 element. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electronic configuration is [Xe] 4f14 5d10 6s2 6p3. In its elemental form bismuth's CAS number is 7440-69-9. The bismuth atom has a radius of 154.5.pm and it's Van der Waals radius is 200.pm. Bismuth is the most diamagnetic of all metals, and the thermal conductivity is lower than any metal, except mercury. Bismuth is not toxic. It has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth expands on solidification. This property makes bismuth alloys particularly suited to the making of sharp castings of objects subject to damage by high temperatures. With other metalsElemental Bismuth such as tin, cadmium , etc., bismuth forms low-melting alloys which Bismuth Bohr Modelare extensively used for safety devices in fire detection and extinguishing systems. Bismuth is used in producing malleable irons and is finding use as a catalyst for making acrylic fibers. When bismuth is heated in air it burns with a blue flame, forming yellow fumes of the oxide. The metal is also used as a thermocoupling material, and has found application as a carrier for 235 U or 233 U fuel in nuclear reactors. Its soluble salts are characterized by forming unsoluble basic salts on the addition of water, a property sometimes used in detection work. Bismuth oxychloride is used extensively in cosmetics. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth' meaning white mass. See Bismuth research below.

American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:

  • Crystal "pulling" by the Czochaiski method for production of semiconductor materials
  • Flux growth and gradient freeze
  • Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques

Have a Question? Ask a Chemical Engineer or Material Scientist   Request an MSDS or Certificate of Analysis

 
Safety &
Handling
  Exclamation Mark-Acute Toxicity
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Warning H315-H319-H335 Xi 36/37/38 26-36/37 EB2984460   2

 

Synonyms for Bismuth Oxide Include:


Dibismuth trioxide
Bismuth trioxide
Bismutum-oxydatum
Dioxodibismoxane
Bismuth(III) oxide
Keto-ketobismuthanyloxy-bismuthane
Bismuth sesquioxide
Bismuth Yellow
Bismuth(3+) oxide

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 


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Production Catalog Available in 36 Countries & Languages

Recent Research & Development for Bismuth

  • Helicobacter pylori antibiotic resistance in Brazil: clarithromycin is still a good option. Jaime Natan E, Silva FM, Barbuti RC, Navarro-Rodriguez T, Moraes-Filho JP, Pedrazzoli J Jr. Arq Gastroenterol. 2011 Dec;48(4):261-4. PMID: 22147131 [PubMed - in process]

  • Towards better photocatalysts: first-principles studies of the alloying effects on the photocatalytic activities of bismuth oxyhalides under visible light. Zhang H, Liu L, Zhou Z. Phys Chem Chem Phys. 2011 Dec 7. [Epub ahead of print] PMID: 22146949 [PubMed - as supplied by publisher]

  • A stannum-bismuth composite film electrode for simultaneous determination of zinc(ii) and cadmium(ii) using differential pulse anodic stripping voltammetry. Li NB, Zhu WW, Luo JH, Luo HQ. Analyst. 2011 Dec 6. [Epub ahead of print] PMID: 22145153 [PubMed - as supplied by publisher]

  • Conductive scanning probe microscopy of nanostructured Bi(2)Te(3). Souier T, Li G, Santos S, Stefancich M, Chiesa M. Nanoscale. 2011 Dec 6. [Epub ahead of print] PMID: 22143255 [PubMed - as supplied by publisher]

  • Near-infrared ultrabroadband luminescence spectra properties of subvalent bismuth in CsI halide crystals. Su L, Zhao H, Li H, Zheng L, Ren G, Xu J, Ryba-Romanowski W, Lisiecki R, Solarz P. Opt Lett. 2011 Dec 1;36(23):4551-3. doi: 10.1364/OL.36.004551. PMID: 22139239 [PubMed - in process]

  • Bismuth Shields for CT Dose Reduction: Do They Help or Hurt? McCollough CH, Wang J, Berland LL. J Am Coll Radiol. 2011 Dec;8(12):878-9. No abstract available. PMID: 22137008 [PubMed - in process]

  • Treatment and diagnostic accuracy of neurosyphilis at Boston City Hospital's Neurological Unit, 1930-1979. Patterson D, Vilensky JA, Robertson WM, Berger J. J Neurol Sci. 2011 Nov 29. [Epub ahead of print] PMID: 22129939 [PubMed - as supplied by publisher]

  • Three novel Bi(iii) complexes with in situ generated anilate ligands: unusual oxidation of cyclohexanedione to dihydroxy benzoquinone. Gao H, Zhang XM. Dalton Trans. 2011 Nov 29. [Epub ahead of print] PMID: 22124341 [PubMed - as supplied by publisher]

  • Microfabricated disposable lab-on-a-chip sensors with integrated bismuth microelectrode arrays for voltammetric determination of trace metals. Kokkinos C, Economou A, Raptis I. Anal Chim Acta. 2012 Jan 13;710:1-8. Epub 2011 Nov 3. PMID: 22123106 [PubMed - in process]

  • Novel in situ N-Doped (BiO)2CO3 Hierarchical Microspheres Self-Assembled by Nanosheets as Efficient and Durable Visible Light Driven Photocatalyst. Dong F, Sun Y, Fu M, Ho WK, Lee SC, Wu Z. Langmuir. 2011 Nov 28. [Epub ahead of print] PMID: 22122119 [PubMed - as supplied by publisher]

  • From {Bi(22) O(26) } to Chiral Ligand-Protected {Bi(38) O(45) }-Based Bismuth Oxido Clusters. Mansfeld D, Miersch L, Rüffer T, Schaarschmidt D, Lang H, Böhle T, Troff RW, Schalley CA, Müller J, Mehring M. Chemistry. 2011 Nov 25. doi: 10.1002/chem.201102437. [Epub ahead of print] PMID: 22120957 [PubMed - as supplied by publisher]

  • Status of development of gamma-ray detector response function code or GAMDRF. Li F, Han X. Appl Radiat Isot. 2011 Nov 18. [Epub ahead of print] PMID: 22118837 [PubMed - as supplied by publisher]

  • Metronidazole-based quadruple versus standard triple therapy: which is better as first-line therapy for Helicobacter pylori eradication? Suzuki H, Matsuzaki J, Hibi T. Expert Rev Clin Pharmacol. 2011 Sep;4(5):579-82. PMID: 22114887 [PubMed - in process]

  • Characteristics of rational harmonic mode-locked short-cavity fiber ring laser using a bismuth-oxide-based erbium-doped fiber and a bismuth-oxide-based highly nonlinear fiber. Fukuchi Y, Maeda J. Opt Express. 2011 Nov 7;19(23):22502-9. doi: 10.1364/OE.19.022502. PMID: 22109128 [PubMed - in process]

  • Fabrication and supercontinuum generation in dispersion flattened bismuth microstructured optical fiber. Zhang WQ, Ebendorff-Heidepriem H, Monro TM, Afshar V S. Opt Express. 2011 Oct 24;19(22):21135-44. doi: 10.1364/OE.19.021135. PMID: 22108964 [PubMed - in process]

  • Structural motifs in phenylbismuth heterocyclic carboxylates - secondary interactions leading to oligomers. Anjaneyulu O, Maddileti D, Kumara Swamy KC. Dalton Trans. 2011 Nov 21. [Epub ahead of print] PMID: 22105914 [PubMed - as supplied by publisher]

  • Influences of Oxygen Pressure on Optical Properties and Interband Electronic Transitions in Multiferroic Bismuth Ferrite Nanocrystalline Films Grown by Pulsed Laser Deposition. Jiang K, Zhu J, Wu J, Sun J, Hu Z, Chu J. ACS Appl Mater Interfaces. 2011 Nov 21. [Epub ahead of print] PMID: 22103473 [PubMed - as supplied by publisher]

  • Hydride generation in-atomizer collection atomic absorption spectrometry for the determination of antimony in acetic acid leachates from pewter cups. Dessuy MB, Kratzer J, Vale MG, Welz B, Dedina J. Talanta. 2011 Dec 15;87:255-61. Epub 2011 Oct 17. PMID: 22099676 [PubMed - in process]

  • Preparation and characterization of bismuth oxide nanoparticles-multiwalled carbon nanotube composite for the development of horseradish peroxidase based H(2)O(2) biosensor. Periasamy AP, Yang S, Chen SM. Talanta. 2011 Dec 15;87:15-23. Epub 2011 Oct 5. PMID: 22099642 [PubMed - in process]

  • Etiopathogenetic principles and peptic ulcer disease classification. Tytgat GN. Dig Dis. 2011;29(5):454-8. Epub 2011 Nov 16. PMID: 22095009 [PubMed - in process]

     

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