Calcium Naphthenate

SECTION 1. IDENTIFICATION

Product Name: Calcium Naphthenate

Product Number: All applicable American Elements product codes, e.g. CA-NAPH-01-LIQ

CAS #: 61789-36-4

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H335 May cause respiratory irritation.
Eye Irrit. 2B H320 Causes eye irritation.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms

GHS02 GHS07
Signal word Warning
Hazard statements
H226 Flammable liquid and vapor.
H315+H320 Causes skin and eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 3
Fire = 2
Reactivity = 0
HMIS-ratings (scale 0 - 4)
Health = 3
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Description: Calcium naphthenate, approx. 35% in mineral spirits (4% Ca)

SECTION 4. FIRST AID MEASURES

Description of first aid measures
If inhaled:
In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
In case of eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
If swallowed:
If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards caused by substance or mixture: No data available
Advice for firefighters
Protective equipment: No special measures required

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow to enter sewers/ surface or groundwater.
Methods and materials for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Protect from heat and direct sunlight.
Specific end use(s)
No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about de
sign of technical systems:
No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin
Personal protective equipment:
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies based on manufacturer.
Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection: Tightly sealed goggles

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Liquid
Color: Light yellow
Odor: Petrol-like
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
Flash point: 39 °C (102 °F)
Flammability (solid, gas): N/A
Ignition temperature: No data available.
Decomposition temperature: No data available.
Autoignition: No data available.
Danger of explosion:
Product is not explosive. However, formation of explosive air/vapor mixtures are possible.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: No data available.
Density at 20 °C (68 °F): 1.01 g/cm³ (8.428 lbs/gal)
Relative density: No data available.
Vapor density: No data available.
Evaporation rate: No data available.
Solubility in Water (H₂O): Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Organic solvents: 0.0 %
Other information
No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
No dangerous decomposition products known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity: LD/LC50 values that are relevant for classification:
Oral LD50 >6 mg/kg (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Additional toxicological information: ·
Carcinogenic categories
IARC (International Agency for Research on Cancer): Substance is not listed.
NTP (National Toxicology Program): Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration): Substance is not listed

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach groundwater, water courses, or sewage systems.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation: Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations

SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA: UN1993
UN proper shipping name
DOT: Flammable liquids, n.o.s.
IMDG, IATA: FLAMMABLE LIQUID, N.O.S.
Transport hazard class(es)
DOT
Class: 3 Flammable liquids
Label: 3
IMDG, IATA
Class: 3 Flammable liquids
Label: 3
Packing group
DOT, IMDG, IATA: III
Environmental hazards:
Marine pollutant: No
Special precautions for user
Warning: Flammable liquids
EMS Number: F-E,S-E
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: N/A
Transport/Additional information:
DOT:
Quantity limitations:
On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
IMDG
Limited quantities (LQ): 5L
Excepted quantities (EQ):
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation": UN1993, Flammable liquids, n.o.s., 3, II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances): Substance is not listed.
Section 313 (Specific toxic chemical listings): Substance is not listed.
TSCA (Toxic Substances Control Act): Substance is listed.
Proposition 65
Chemicals known to cause cancer: Substance is not listed.
Chemicals known to cause reproductive toxicity for females: Substance is not listed.
Chemicals known to cause reproductive toxicity for males: Substance is not listed.
Chemicals known to cause developmental toxicity: Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency): Substance is not listed
TLV (Threshold Limit Value established by ACGIH): Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health): Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS)
GHS02 GHS07
Signal word: Warning
Hazard statements
H226 Flammable liquid and vapor.
H315+H320 Causes skin and eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Do not expose to heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.