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Cerium Acetylacetonate
Ce(CH3COCHCOCH3)3 • xH2O 15653-01-7
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Product Code |
Order or Specifications |
99% Cerium Acetylacetonate |
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99.9% Cerium Acetylacetonate |
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99.99% Cerium Acetylacetonate |
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99.999% Cerium Acetylacetonate |
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Cerium Acetylacetonate is a cerium source that is soluble in organic solvents. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Cerium Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Cerium Acetylacetonate is one of numerous organo-metallic compounds sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Cerium include metallurgy, glass and glass polishing, ceramics, catalysts, and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Cerium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f26s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. It is, therefore, strongly acidic. It is also a strong oxidizer. The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors.
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| Formula |
CAS No. |
Appearance |
Molecular Weight |
Density |
Melting Point |
Boiling Point |
Solubility |
Stability |
| Ce(CH3COCHCOCH3)3 • xH2O |
15653-01-7 |
Tan |
437.44 |
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Soluble in organic solvents |
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Recent Research & Development for Cerium
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Cerium dioxide/polyaniline core-shell nanocomposites.
J Colloid Interface Sci. 2008 Apr 1;320(1):194-201. Epub 2008 Jan 17.
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Ultrastructural localization of acid phosphatase in arbusculate coils of mycorrhizal Phoenix canariensis roots.
Physiol Plant. 2008 Apr;132(4):503-13.
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A novel method for the modification of zinc powder by ultrasonic impregnation in cerium nitrate solution.
Ultrason Sonochem. 2008 Apr;15(4):393-401. Epub 2007 Oct 13.
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Oxidative stress induced by cerium oxide nanoparticles in cultured BEAS-2B cells.
Toxicology. 2008 Mar 12;245(1-2):90-100. Epub 2008 Jan 3.
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Efficient transformation of azides to primary amines using the mild and easily accessible CeCl3.7H2O/NaI system.
J Org Chem. 2008 Mar 7;73(5):1919-24. Epub 2008 Feb 12.
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Lipidomic analysis reveals differential defense responses of Taxus cuspidata cells to two elicitors, methyl jasmonate and cerium (Ce(4+)).
Biochim Biophys Acta. 2008 Mar;1781(3):123-34. Epub 2007 Dec 8.
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Influences of Calcium Deficiency and Cerium on Growth of Spinach Plants.
Biol Trace Elem Res. 2008 Mar;121(3):266-275. Epub 2007 Oct 25.
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Fluorescence spectroscopic characterization of DOM fractions isolated from a filtered river water after ozonation and catalytic ozonation.
Chemosphere. 2008 Mar;71(5):911-21. Epub 2008 Jan 10.
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Determination of total chromium by flame atomic absorption spectrometry after coprecipitation by cerium (IV) hydroxide.
Environ Monit Assess. 2008 Mar;138(1-3):167-72. Epub 2007 Jun 12.
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Measuring the redox activity of individual catalytic nanoparticles in cerium-based oxides.
Nano Lett. 2008 Mar;8(3):962-7. Epub 2008 Feb 6.
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Cerium Ion-Chelated Magnetic Silica Microspheres for Enrichment and Direct Determination of Phosphopeptides by Matrix-Assisted Laser Desorption Ionization Mass Spectrometry.
J Proteome Res. 2008 Feb 29; [Epub ahead of print]
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Effects of Lanthanum and Cerium on the Growth and Mineral Nutrition of Corn and Mungbean.
Ann Bot (Lond). 2008 Feb 21; [Epub ahead of print]
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A Ceric Ammonium Nitrate N-Dearylation of N-p-Anisylazoles Applied to Pyrazole, Triazole, Tetrazole, and Pentazole Rings: Release of Parent Azoles. Generation of Unstable Pentazole, HN(5)/N(5)(-), in Solution.
J Org Chem. 2008 Feb 15;73(4):1354-64. Epub 2008 Jan 17.
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Controlled synthesis and upconverted avalanche luminescence of cerium(III) and neodymium(III) orthovanadate nanocrystals with high uniformity of size and shape.
J Am Chem Soc. 2008 Feb 13;130(6):2032-40. Epub 2008 Jan 17.
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Destruction of organic pollutants by cerium(IV) MEO process: a study on the influence of process conditions for EDTA mineralization.
J Hazard Mater. 2008 Feb 11;150(3):596-603. Epub 2007 May 10.
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A density functional study of Ce@C82: explanation of the Ce preferential bonding site.
J Phys Chem A. 2008 Feb 7;112(5):1071-5. Epub 2008 Jan 16.
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Scalable synthesis of the VEGF-R2 kinase inhibitor JNJ-17029259 using ultrasound-mediated addition of MeLi-CeCl3 to a nitrile.
J Org Chem. 2008 Feb 1;73(3):1121-3. Epub 2008 Jan 3.
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Catalytic oxidative treatment of diluted black liquor at mild conditions using copper oxide/cerium oxide catalyst.
Water Environ Res. 2008 Feb;80(2):136-41.
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Decomposition kinetics of ammonia in gaseous stream by a nanoscale copper-cerium bimetallic catalyst.
J Hazard Mater. 2008 Jan 15;150(1):53-61. Epub 2007 Apr 20.
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New sialyl Lewis(x) mimic containing an alpha-substituted beta(3)-amino acid spacer.
Carbohydr Res. 2008 Jan 14;343(1):31-8. Epub 2007 Oct 7.
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