p>Cerium Trifluoromethanesulfonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. Cerium Trifluoromethanesulfonate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Cerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueoussolutions.It is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
Synonyms for Cerium Trifluoromethanesulfonate Include:
Cerium(III) Trifluoromethanesulfonate
Trifluoromethanesulfonic Acid Cerium(III) Salt
Cerium(III) Triflate
Cerium(III) triflate; Trifluoromethanesulfonic acid cerium(III) salt
cerium(3+); trifluoromethanesulfonate
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Redox control of a polymerization catalyst by changing the oxidation state of the metal center.
Broderick EM, Guo N, Wu T, Vogel CS, Xu C, Sutter J, Miller JT, Meyer K, Cantat T, Diaconescu PL.
Chem Commun (Camb). 2011 Aug 5. [Epub ahead of print]
PMID:
21818489
[PubMed - as supplied by publisher]
Influence of Crystallization State and Microstructure on the Chemical Durability of Cerium-Neodymium Mixed Oxides.
Claparede L, Clavier N, Dacheux N, Moisy P, Podor R, Ravaux J.
Inorg Chem. 2011 Aug 2. [Epub ahead of print]
PMID:
21809825
[PubMed - as supplied by publisher]
Colorimetric Biosensing Using Smart Materials.
Song Y, Wei W, Qu X.
Adv Mater. 2011 Jul 29. doi: 10.1002/adma.201101853. [Epub ahead of print]
PMID:
21800383
[PubMed - as supplied by publisher]
A facile and one pot synthesis of 1,4-disubstituted-1H-1,2,3-triazoles from terminal alkynes and phenacyl azides prepared from styrenes by CAN oxidant and sodium azide.
Keshavarz M, Badri R.
Mol Divers. 2011 Jul 29. [Epub ahead of print]
PMID:
21800069
[PubMed - as supplied by publisher]
Tuning the size and shape of colloidal cerium oxide nanocrystals through lanthanide doping.
Qiu H, Chen G, Fan R, Cheng C, Hao S, Chen D, Yang C.
Chem Commun (Camb). 2011 Jul 28. [Epub ahead of print]
PMID:
21799971
[PubMed - as supplied by publisher]
Lanthanide Complexes of Substituted ß-Diketone Hydrazone Derivatives: Synthesis, Characterization, and Biological Activities.
Hegazy WH, Al-Motawaa IH.
Bioinorg Chem Appl. 2011;2011:531946. Epub 2011 Jun 22.
PMID:
21799665
[PubMed - in process]
Plutonium uptake and behavior in vegetation of the desert southwest: A preliminary assessment.
Caldwell E, Duff M, Ferguson C, Coughlin D.
J Environ Monit. 2011 Jul 28. [Epub ahead of print]
PMID:
21796316
[PubMed - as supplied by publisher]
Effects of lanthanum, cerium, and neodymium on the nuclei and mitochondria of hepatocytes: Accumulation and oxidative damage.
Huang P, Li J, Zhang S, Chen C, Han Y, Liu N, Xiao Y, Wang H, Zhang M, Yu Q, Liu Y, Wang W.
Environ Toxicol Pharmacol. 2011 Jan;31(1):25-32. Epub 2010 Sep 15.
PMID:
21787666
[PubMed - in process]
Comparison study on the antibacterial activity of nano- or bulk-cerium oxide.
Kuang Y, He X, Zhang Z, Li Y, Zhang H, Ma Y, Wu Z, Chai Z.
J Nanosci Nanotechnol. 2011 May;11(5):4103-8.
PMID:
21780412
[PubMed - in process]
Effect of alkali metal hydroxides on the morphological development and optical properties of ceria nanocubes under hydrothermal conditions.
Kepenekçi O, Emirdag-Eanes M, Demir MM.
J Nanosci Nanotechnol. 2011 Apr;11(4):3565-77.
PMID:
21776738
[PubMed - in process]
Exposure to CeO(2) nanoparticles during flame spray process.
Leppänen M, Lyyränen J, Järvelä M, Auvinen A, Jokiniemi J, Pimenoff J, Tuomi T.
Nanotoxicology. 2011 Jul 19. [Epub ahead of print]
PMID:
21770722
[PubMed - as supplied by publisher]
CeO(2)-TiO(2) Catalysts for Catalytic Oxidation of Elemental Mercury in Low-Rank Coal Combustion Flue Gas.
Li H, Wu CY, Li Y, Zhang J.
Environ Sci Technol. 2011 Aug 2. [Epub ahead of print]
PMID:
21770402
[PubMed - as supplied by publisher]
Face-driven octanuclear cerium(iv) luminescence polyhedra: synthesis and luminescent sensing natural saccharides.
Zhao L, Qu S, He C, Zhang R, Duan C.
Chem Commun (Camb). 2011 Jul 18. [Epub ahead of print]
PMID:
21769346
[PubMed - as supplied by publisher]
Imaging the Active Surfaces of Cerium Dioxide Nanoparticles.
Haigh SJ, Young NP, Sawada H, Takayanagi K, Kirkland AI.
Chemphyschem. 2011 Jul 14. doi: 10.1002/cphc.201100376. [Epub ahead of print] No abstract available.
PMID:
21761547
[PubMed - as supplied by publisher]
Manipulation of Single-Stranded DNA by Using an Artificial Site-Selective DNA Cutter Composed of Cerium(IV)/EDTA and Phosphonate-Oligonucleotide Conjugates.
Aiba Y, Lönnberg T, Komiyama M.
Chem Asian J. 2011 Jul 13. doi: 10.1002/asia.201100238. [Epub ahead of print]
PMID:
21755600
[PubMed - as supplied by publisher]
catena-Poly[[bis-(dimethyl sulfoxide-?O)cerium(III)]tris-(µ(2)-3,5-dinitro-benzoato-?O:O')].
Zhou FL, Du ZH, Ng SW.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m673. Epub 2011 May 7.
PMID:
21754582
[PubMed]
An Amide-Containing Metal-Organic Tetrahedron Responding to a Spin-Trapping Reaction in a Fluorescent Enhancement Manner for Biological Imaging of NO in Living Cells.
Wang J, He C, Wu P, Wang J, Duan C.
J Am Chem Soc. 2011 Jul 21. [Epub ahead of print]
PMID:
21749065
[PubMed - as supplied by publisher]
Anti-erosive potential of amine fluoride, cerium chloride and laser irradiation application on dentine.
Wegehaupt FJ, Sener B, Attin T, Schmidlin PR.
Arch Oral Biol. 2011 Jul 5. [Epub ahead of print]
PMID:
21737063
[PubMed - as supplied by publisher]
'Old' clusters with new function: oxidation catalysis by high oxidation state manganese and cerium/manganese clusters using o(2) gas.
Maayan G, Christou G.
Inorg Chem. 2011 Aug 1;50(15):7015-21. Epub 2011 Jul 5.
PMID:
21728283
[PubMed - in process]
Surface Modification of Luminescent Lanthanide Phosphate Nanorods with Cationic "Quat-primer" Polymers.
Komban R, Beckmann R, Rode S, Ichilmann S, Ku¨hnle A, Beginn U, Haase M.
Langmuir. 2011 Jul 25. [Epub ahead of print]
PMID:
21721577
[PubMed - as supplied by publisher]
Model-derived dose rates per unit concentration of radon in air in a generic plant geometry.
Vives I Batlle J, Smith A, Vives-Lynch S, Copplestone D, Pröhl G, Strand T.
Radiat Environ Biophys. 2011 Jul 8. [Epub ahead of print]
PMID:
21739195
[PubMed - as supplied by publisher]
Deadly radon in montana? A rebuttal to dr. Larsson.
Hart J.
Dose Response. 2011;9(2):299-300. Epub 2010 Nov 19. No abstract available.
PMID:
21731542
[PubMed]
A Response to: Deadly Radon in Montana?
Larsson LS.
Dose Response. 2011;9(2):296-8. Epub 2010 Nov 19. No abstract available.
PMID:
21731541
[PubMed]
Self-assembly of a sulphur-terminated graphene nanoribbon within a single-walled carbon nanotube.
Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN.
Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print]
PMID:
21822259
[PubMed - as supplied by publisher]
Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p).
Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27.
PMID:
21821903
[PubMed - in process]
Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids.
Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J.
Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print]
PMID:
21821743
[PubMed - as supplied by publisher]
Characterization of the sulfurtransferase family from Oryza sativa L.
Guretzki S, Papenbrock J.
Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print]
PMID:
21821426
[PubMed - as supplied by publisher]
Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek.
Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T.
J Microbiol Methods. 2011 Jul 28. [Epub ahead of print]
PMID:
21821067
[PubMed - as supplied by publisher]
In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent-solute interaction and its activity toward adsorptive desulfurization of gas oil.
Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A.
J Hazard Mater. 2011 Jul 6. [Epub ahead of print]
PMID:
21820806
[PubMed - as supplied by publisher]
Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei.
Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD.
Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print]
PMID:
21820408
[PubMed - as supplied by publisher]
The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates.
Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159.
PMID:
21818814
[PubMed - in process]
Sulphur isotopes in animal hair track distance to sea.
Zazzo A, Monahan FJ, Moloney AP, Green S, Schmidt O.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2371-8. doi: 10.1002/rcm.5131.
PMID:
21818798
[PubMed - in process]
Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds.
Fang W, He Q, Tan ZF, Liu CY, Lu X, Murillo CA.
Chemistry. 2011 Aug 4. doi: 10.1002/chem.201003693. [Epub ahead of print]
PMID:
21818792
[PubMed - as supplied by publisher]
Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond.
Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C.
J Gen Appl Microbiol. 2011;57(3):145-51.
PMID:
21817826
[PubMed - in process]
Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources.
Wyman CE, Balan V, Dale BE, Elander RT, Falls M, Hames B, Holtzapple MT, Ladisch MR, Lee YY, Mosier N, Pallapolu VR, Shi J, Thomas SR, Warner RE.
Bioresour Technol. 2011 Jun 21. [Epub ahead of print]
PMID:
21816612
[PubMed - as supplied by publisher]
Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province.
Sullivan TJ, Cosby BJ, Jackson WA.
J Environ Manage. 2011 Aug 2. [Epub ahead of print]
PMID:
21816535
[PubMed - as supplied by publisher]
Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE.
Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM.
Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print]
PMID:
21816081
[PubMed - as supplied by publisher]
Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells.
Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC.
Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print]
PMID:
21815631
[PubMed - as supplied by publisher]
The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver.
Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB.
Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print]
PMID:
21815229
[PubMed - as supplied by publisher]
A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability.
Reyes-Palomares A, Montañez R, Sánchez-Jiménez F, Medina MA.
Amino Acids. 2011 Aug 4. [Epub ahead of print]
PMID:
21814788
[PubMed - as supplied by publisher]
Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume.
Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J.
ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print]
PMID:
21814288
[PubMed - as supplied by publisher]
1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives.
Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y.
Molecules. 2011 Aug 3;16(8):6502-11.
PMID:
21814162
[PubMed - in process]
Towards the Growth of an Aligned Single-Layer MoS2 Film.
Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L.
Langmuir. 2011 Aug 3. [Epub ahead of print]
PMID:
21812475
[PubMed - as supplied by publisher]
Proud sponsors of Aeromat 2012. Please join us and our customers & co-sponsors Boeing and ATI on
June 18-20, 2012
in Charlotte, North Carolina
metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. Cerium Trifluoromethanesulfonate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Cerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous
solutions.It is, therefore,
strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine 
and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
