American Elements specializes in producing high purity cerium fluoride sputtering targets with the highest possible density and smallest possible average grain sizes for use in semiconductor, chemical vapor deposition (CVD) and physical vapor deposition (PVD) display and optical applications. Our standard Sputtering Targets for thin film are available monoblock or bonded with dimensions and configurations up to 820 mm with hole drill locations and threading, beveling, grooves and backing designed to work with both older sputtering devises as well as the latest process equipment, such as large area coating for solar energy or fuel cells and flip-chip applications. Research sized targets are also produced as well as custom sizes and alloys. All targets are analyzed using best demonstrated techniques including X-Ray Fluorescence (XRF), Glow Discharge Mass Spectrometry (GDMS), and Inductively Coupled Plasma (ICP). "Sputtering" allows for thin film deposition of an ultra high purity sputtering metallic or oxide material onto another solid substrate by the controlled removal and conversion of the target material into a directed gaseous/plasma phase through ionic bombardment. We can also provide targets outside this range in addition to just about any size rectangular, annular, or oval target. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and in the form of solutions and organometallics. We also produce Cerium Fluoride as rods, powder and plates. Other shapes are available by request.
Cerium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f26s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. It is, therefore, strongly acidic. It is also a strong oxidizer. The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Kinetic aspects and swelling changes of magnesium and cerium titano-antimonates in aqueous and mixed solvents.
Zakaria ES, Ali IM, Aly HF.
J Colloid Interface Sci. 2009 Jun 18. [Epub ahead of print]
PMID: 19616784 [PubMed - as supplied by publisher]
Exploiting the oxidative coupling reaction of MBTH for indapamide determination.
Ribeiro DS, Prior JA, Santos JL, Lopes JA, Lima JL.
Talanta. 2009 Sep 15;79(4):1161-8. Epub 2009 Mar 9.
PMID: 19615526 [PubMed - in process]
Fate and effects of CeO2 nanoparticles in aquatic ecotoxicity tests.
Van Hoecke K, Quik JT, Mankiewicz-Boczek J, De Schamphelaere KA, Elsaesser A, Van der Meeren P, Barnes C, McKerr G, Howard CV, Van de Meent D, Rydzynski K, Dawson KA, Salvati A, Lesniak A, Lynch I, Silversmit G, De Samber B, Vincze L, Janssen CR.
Environ Sci Technol. 2009 Jun 15;43(12):4537-46.
PMID: 19603674 [PubMed - in process]
Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH](-) Bridging Ligand as an Intermediate for Catalytic Water Oxidation.
Duan L, Fischer A, Xu Y, Sun L.
J Am Chem Soc. 2009 Jul 14. [Epub ahead of print]
PMID: 19601625 [PubMed - as supplied by publisher]
Mass Cytometry: Technique for Real Time Single Cell Multitarget Immunoassay Based on Inductively Coupled Plasma Time-of-Flight Mass Spectrometry.
Bandura DR, Baranov VI, Ornatsky OI, Antonov A, Kinach R, Lou X, Pavlov S, Vorobiev S, Dick JE, Tanner SD.
Anal Chem. 2009 Jul 14. [Epub ahead of print]
PMID: 19601617 [PubMed - as supplied by publisher]
Trinitratobis{N'-[1-(2-pyridyl)ethylidene]isonicotinohydrazide}cerium(III): a three-dimensional cerium-organic supramolecular structure.
Zhang YY, Liu SX.
Acta Crystallogr C. 2009 Jul;65(Pt 7):m269-72. Epub 2009 Jun 24.
PMID: 19578261 [PubMed - in process]
Total oxidation of naphthalene with high selectivity using a ceria catalyst prepared by a combustion method employing ethylene glycol.
Aranda A, López JM, Murillo R, Mastral AM, Dejoz A, Vázquez I, Solsona B, Taylor SH, García T.
J Hazard Mater. 2009 Jun 12. [Epub ahead of print]
PMID: 19576687 [PubMed - as supplied by publisher]
Electrosteric Enhanced Stability of Functional Sub-10 nm Cerium and Iron Oxide Particles in Cell Culture Medium.
Chanteau B, Fresnais J, Berret JF.
Langmuir. 2009 Jul 2. [Epub ahead of print]
PMID: 19572532 [PubMed - as supplied by publisher]
Monodisperse Samarium and Cerium Orthovanadate Nanocrystals and Metal Oxidation States on the Nanocrystal Surface.
Nguyen TD, Dinh CT, Do TO.
Langmuir. 2009 Jul 2. [Epub ahead of print]
PMID: 19572496 [PubMed - as supplied by publisher]
Chemiluminescence from reactions with bis-cyclometalated iridium complexes in acidic aqueous solution.
Kiran RV, Zammit EM, Hogan CF, James BD, Barnett NW, Francis PS.
Analyst. 2009 Jul;134(7):1297-8. Epub 2009 Apr 21.
PMID: 19562192 [PubMed - in process]
Effect of cerium oxide nanoparticles on inflammation in vascular endothelial cells.
Gojova A, Lee JT, Jung HS, Guo B, Barakat AI, Kennedy IM.
Inhal Toxicol. 2009 Jul;21(S1):123-130.
PMID: 19558244 [PubMed - as supplied by publisher]
Uptake and inflammatory effects of nanoparticles in a human vascular endothelial cell line.
Kennedy IM, Wilson D, Barakat AI.
Res Rep Health Eff Inst. 2009 Jan;(136):3-21; discussion 23-32.
PMID: 19552347 [PubMed - in process]
Cerium(IV) Ammonium Nitrate Is an Excellent, General Catalyst for the Friedlander and Friedlander-Borsche Quinoline Syntheses: Very Efficient Access to the Antitumor Alkaloid Luotonin A.
Sridharan V, Ribelles P, Ramos MT, Mene´ndez JC.
J Org Chem. 2009 Jun 17. [Epub ahead of print]
PMID: 19534479 [PubMed - as supplied by publisher]
Comment on "Thermal signatures of the Kondo volume collapse in cerium".
Johansson B, Ruban AV, Abrikosov IA.
Phys Rev Lett. 2009 May 8;102(18):189601. Epub 2009 May 6. No abstract available.
PMID: 19518926 [PubMed - in process]
Catalytic wet oxidation of phenol: the role of promoter and ceramic support.
Hussain ST, Jamil S, Mazhar M.
Environ Technol. 2009 Apr 14;30(5):511-24.
PMID: 19507443 [PubMed - indexed for MEDLINE]
Biomimetic studies towards the cardinalins: synthesis of (+)-ventiloquinone L and an unusual dimerisation.
Sperry J, Sejberg JJ, Stiemke FM, Brimble MA.
Org Biomol Chem. 2009 Jun 21;7(12):2599-603. Epub 2009 Apr 28.
PMID: 19503935 [PubMed - in process]
Study of the dissolution of thin films of cerium oxide by using a GaPO4 crystal microbalance.
Jakab S, Picart S, Tribollet B, Rousseau P, Perrot H, Gabrielli C.
Anal Chem. 2009 Jul 1;81(13):5139-45.
PMID: 19496612 [PubMed - in process]
Determination of ultratrace amounts of Ce3+ in the presence of Sm3+, La3+, Dy3+, and Yb3+ in water and soils by inductively coupled plasma-optical emission spectroscopy after preconcentration with thio-functionalized MCM-41 at controlled pH.
Saberyan K.
J AOAC Int. 2009 Mar-Apr;92(2):555-60.
PMID: 19485216 [PubMed - indexed for MEDLINE]
Catalytic ozonation of dimethyl phthalate over cerium supported on activated carbon.
Li L, Ye W, Zhang Q, Sun F, Lu P, Li X.
J Hazard Mater. 2009 May 3. [Epub ahead of print]
PMID: 19467775 [PubMed - as supplied by publisher]
Differential scanning calorimetry investigation on vinyl ester resin curing process for polymer nanocomposite fabrication.
Guo Z, Ng HW, Yee GL, Hahn HT.
J Nanosci Nanotechnol. 2009 May;9(5):3278-85.
PMID: 19453004 [PubMed]
Information pertaining to particular dangers for man and environment
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
4 First aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek immediate medical advice.
Information for doctor
The following symptoms may occur:
Gastric or intestinal trouble
Sickness
Thirst
5 Fire fighting measures
Suitable extinguishing agents
Use fire fighting measures that suit the environment.
Special hazards caused by the material, its products of combustion or flue gases:
Can be released in case of fire:
Hydrogen fluoride (HF)
Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Handle under dry protective gas.
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from water.
Further information about storage conditions:
Store under dry inert gas.
Protect from humidity and keep away from water.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Fluorides (as F)
mg/m3
ACGIH TLV 2.5
Austria TWA 2.5
Belgium TWA 2.5
Finland TWA 2.5
France TWA 2.5
Germany MAK 2.5
Hungary TWA 1; 2-STEL
Netherlands TWA 3.5
Norway TWA 0.6
Poland TWA 1; 3-STEL
Sweden NGV 2
Switzerland MAK-W 1.5
United Kingdom TWA 2.5
Russia TWA 2
Denmark TWA 2.5
USA PEL 2.5
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection:
Safety glasses
Face protection
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Powder
Colour:
White
Light yellow
Pink
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: 1460 ° C
Boiling point/Boiling range: 2300 ° C (approx)
Sublimation temperature / start: Not determined
Flash point: Not applicable
Ignition temperature: Not determined
Decomposition temperature: Not determined
Danger of explosion: Product is not explosive.
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density at 20 ° C 6.16 g/cm³
Solubility in / Miscibility with
Water: Insoluble
Not miscible or difficult to mix
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided: Acids
Dangerous reactions: No dangerous reactions known
Dangerous products of decomposition:
Hydrogen fluoride
Metal oxide
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant for skin and mucous membranes.
on the eye: Irritant effect.
Sensitization: No sensitizing effect known.
Additional toxicological information:
Danger by skin resorption.
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
Code letter and hazard designation of product: Xn Harmful
Risk phrases:
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37 Wear suitable protective clothing and gloves.
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
American Elements Products can also be sourced at
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