Cerium Molybdenum Oxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Cerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueoussolutions.It is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.
Molybdenum is a Block D, Group 6, Period 5 element. The number of electrons in each of Molybdenum's shells is 2, 8, 18, 13, 1 and its electronic configuration is [Kr] 4d5 5s1. In its elemental form molybdenum's CAS number is 7439-98-7. The molybdenum atom has a radius of 136.3.pm and it's Van der Waals radius is 200.pm. Molybdenum is toxic unless it is in small quantities. Molybdenum has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum is a catalyst in the oil refining. It has many other applications, including in catalysts, pigments, corrosion inhibitors and lubricants. It has a very high elastic modulus. Molybdenum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is used in steel alloys to add hardness and raise melting points. It is a component in Hastelloys brand steel. Molybdenum is used in nuclear reactors and aerospace components. Molybdenum was first discovered by Carl Wilhelm in 1778. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead. See Molybdenum research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(iii) bromide.
Vasudevan KV, Smith NA, Scott BL, Bennett BL, Muenchausen RE, Gordon JC.
Dalton Trans. 2011 Dec 23. [Epub ahead of print]
PMID:
22193947
[PubMed - as supplied by publisher]
Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
[PubMed - as supplied by publisher]
Electrooxidation of nitrite on a silica-cerium mixed oxide carbon paste electrode.
Silveira G, Morais AD, Villis PC, Maroneze CM, Gushikem Y, Lucho AM, Pissetti FL.
J Colloid Interface Sci. 2011 Dec 6. [Epub ahead of print]
PMID:
22192596
[PubMed - as supplied by publisher]
Ceria-engineered nanomaterial distribution in, and clearance from, blood: size matters.
Dan M, Wu P, Grulke EA, Graham UM, Unrine JM, Yokel RA.
Nanomedicine (Lond). 2012 Jan;7(1):95-110.
PMID:
22191779
[PubMed - in process]
Effect of Ce(3+) on soluble microbial products production in anaerobic granular sludge digestion.
Fu B, Liang R, Xia Q, Ding L, Xu K, Ren H.
Water Sci Technol. 2011;64(7):1459-65.
PMID:
22179643
[PubMed - in process]
[Removal of gaseous elemental mercury over cerium doped low vanadium loading V2O5-WO3/TiO2 in simulated coal-fired flue gas].
Wan Q, Duan L, He KB, Chen L, Li JH.
Huan Jing Ke Xue. 2011 Sep;32(9):2800-4. Chinese.
PMID:
22165254
[PubMed - in process]
Operando DRIFTS study of the redox and catalytic properties of CuO/Ce(1-x)Tb(x)O(2-d) (x = 0-0.5) catalysts: evidence of an induction step during CO oxidation.
Martínez-Arias A, Hungría AB, Fernández-García M, Iglesias-Juez A, Soria J, Conesa JC, Anderson JA, Munuera G.
Phys Chem Chem Phys. 2011 Dec 8. [Epub ahead of print]
PMID:
22159154
[PubMed - as supplied by publisher]
Classical oxidant induced chemiluminescence of fluorescent carbon dots.
Lin Z, Xue W, Chen H, Lin JM.
Chem Commun (Camb). 2011 Dec 8. [Epub ahead of print]
PMID:
22158939
[PubMed - as supplied by publisher]
Gamma-ray fast-timing coincidence measurements from the (18)O+(18)O fusion-evaporation reaction using a mixed LaBr(3)-HPGe array.
Alharbi T, Mason PJ, Regan PH, Podolyák Z, Marginean N, Nakhostin M, Bowry M, Bucurescu D, Cata-Danil G, Cata-Danil I, Deleanu D, Filipescu D, Glodariu T, Ghita D, Marginean R, Mihai C, Negret A, Pascu S, Sava T, Stroe L, Suliman G, Zamfir NV, Bruce AM, Rodriguez Triguero C, Bender PC, Garg U, Erduran MN, Kusoglu A, Bostan M, Detistov P, Alkhomashi N, Sinha AK, Chakrabarti R, Ghugre SS.
Appl Radiat Isot. 2011 Dec 3. [Epub ahead of print]
PMID:
22154387
[PubMed - as supplied by publisher]
Cationic Surface Reconstructions on Cerium Oxide Nanocrystals: An Aberration Corrected HRTEM Study.
Bhatta UM, Ross IM, Sayle TX, Sayle DC, Parker SC, Reid D, Seal S, Kumar A, Moebus G.
ACS Nano. 2011 Dec 13. [Epub ahead of print]
PMID:
22148265
[PubMed - as supplied by publisher]
In-house SAD phasing with surface-bound cerium ions.
Vennila KN, Velmurugan D.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Dec 1;67(Pt 12):1662-5. Epub 2011 Nov 25.
PMID:
22139192
[PubMed - in process]
High concentrations of cadmium, cerium and lanthanum in indoor air due to environmental tobacco smoke.
Böhlandt A, Schierl R, Diemer J, Koch C, Bolte G, Kiranoglu M, Fromme H, Nowak D.
Sci Total Environ. 2011 Dec 1. [Epub ahead of print]
PMID:
22137652
[PubMed - as supplied by publisher]
A cholesterol and actinide dependent shadow biosphere of archaea and viroids in autoimmune diseases.
Kurup R, Kurup PA.
Immunobiology. 2011 Oct 25. [Epub ahead of print]
PMID:
22137029
[PubMed - as supplied by publisher]
On the interaction of Mg with the (111) and (110) surfaces of ceria.
Nolan M, Lykhach Y, Tsud N, Skála T, Staudt T, Prince KC, Matolín V, Libuda J.
Phys Chem Chem Phys. 2011 Dec 14;14(3):1293-301. Epub 2011 Dec 1.
PMID:
22134463
[PubMed - in process]
Measurement of redox potential in nanoecotoxicological investigations.
Tantra R, Cackett A, Peck R, Gohil D, Snowden J.
J Toxicol. 2012;2012:270651. Epub 2011 Oct 31.
PMID:
22131988
[PubMed - in process]
In situ characterization of Pt catalysts supported on ceria modified TiO(2) for the WGS reaction: influence of ceria loading.
Barrio L, Zhou G, González ID, Estrella M, Hanson J, Rodriguez JA, Navarro RM, Fierro JL.
Phys Chem Chem Phys. 2011 Dec 1. [Epub ahead of print]
PMID:
22130010
[PubMed - as supplied by publisher]
The oxidation state of Hadean magmas and implications for early Earth's atmosphere.
Trail D, Watson EB, Tailby ND.
Nature. 2011 Nov 30;480(7375):79-82. doi: 10.1038/nature10655.
PMID:
22129728
[PubMed - in process]
Preparation methods and thermal stability of Ba-Mn-Ce oxide catalyst for NO(x)-assisted soot oxidation.
Wu X, Lin F, Wang L, Weng D, Zhou Z.
J Environ Sci (China). 2011;23(7):1205-10.
PMID:
22125916
[PubMed - indexed for MEDLINE]
The oxidative degradation of dibenzoazepine derivatives by cerium(iv) complexes in acidic sulfate media.
Wisniewska J, Wrzeszcz G, Kurzawa M, van Eldik R.
Dalton Trans. 2011 Nov 29. [Epub ahead of print]
PMID:
22124379
[PubMed - as supplied by publisher]
Effect of support size on the catalytic activity of metal-oxide-doped silica particles in the glycolysis of polyethylene terephthalate.
Wi R, Imran M, Lee KG, Yoon SH, Cho BG, Kim do H.
J Nanosci Nanotechnol. 2011 Jul;11(7):6544-9.
PMID:
22121753
[PubMed - in process]
Simultaneous determination of chromium, selenium, and molybdenum in nutritional products by inductively coupled plasma/mass spectrometry: single-laboratory validation.
Pacquette LH, Szabo A, Thompson JJ.
J AOAC Int. 2011 Jul-Aug;94(4):1240-52.
PMID:
21919358
[PubMed - in process]
Structural studies of the molybdenum center of mitochondrial amidoxime reducing component (mARC) by pulsed EPR spectroscopy and 17O-labeling.
Rajapakshe A, Astashkin AV, Klein EL, Reichmann D, Mendel RR, Bittner F, Enemark JH.
Biochemistry. 2011 Sep 14. [Epub ahead of print]
PMID:
21916412
[PubMed - as supplied by publisher]
Clinical neuroimaging features and outcome in molybdenum cofactor deficiency.
Vijayakumar K, Gunny R, Grunewald S, Carr L, Chong KW, Devile C, Robinson R, McSweeney N, Prabhakar P.
Pediatr Neurol. 2011 Oct;45(4):246-52.
PMID:
21907887
[PubMed - in process]
SNP-based association mapping of Arachnomelia in Fleckvieh cattle.
Seichter D, Russ I, Förster M, Medugorac I.
Anim Genet. 2011 Oct;42(5):544-7. doi: 10.1111/j.1365-2052.2010.02167.x. Epub 2011 Jan 25.
PMID:
21906105
[PubMed - in process]
White monkey syndrome and presumptive copper deficiency in wild savannah baboons.
Markham AC, Gesquiere LR, Bellenger JP, Alberts SC, Altmann J.
Am J Primatol. 2011 Sep 6. doi: 10.1002/ajp.20983. [Epub ahead of print]
PMID:
21898510
[PubMed - as supplied by publisher]
Study of Molybdenum(4+) Quinoxalyldithiolenes as Models for the Noninnocent Pyranopterin in the Molybdenum Cofactor.
Matz KG, Mtei RP, Rothstein R, Kirk ML, Burgmayer SJ.
Inorg Chem. 2011 Sep 6. [Epub ahead of print]
PMID:
21894968
[PubMed - as supplied by publisher]
Nature of Halide Binding to the Molybdenum Site of Sulfite Oxidase.
Pushie MJ, Doonan CJ, Wilson HL, Rajagopalan KV, George GN.
Inorg Chem. 2011 Sep 6. [Epub ahead of print]
PMID:
21894921
[PubMed - as supplied by publisher]
Purity-enhanced bulk synthesis of thin single-wall carbon nanotubes using iron-copper catalysts.
Lim HE, Miyata Y, Nakayama T, Chen S, Kitaura R, Shinohara H.
Nanotechnology. 2011 Sep 30;22(39):395602. Epub 2011 Sep 2.
PMID:
21891846
[PubMed - in process]
Photoelastic analysis of forces generated by T-loop springs made with stainless steel or titanium-molybdenum alloy.
Maia LG, de Moraes Maia ML, da Costa Monini A, Vianna AP, Gandini LG Jr.
Am J Orthod Dentofacial Orthop. 2011 Sep;140(3):e123-8.
PMID:
21889060
[PubMed - in process]
Metallic ions released from stainless steel, nickel-free, and titanium orthodontic alloys: Toxicity and DNA damage.
Ortiz AJ, Fernández E, Vicente A, Calvo JL, Ortiz C.
Am J Orthod Dentofacial Orthop. 2011 Sep;140(3):e115-22.
PMID:
21889059
[PubMed - in process]
Arabidopsis LOS5/ABA3 overexpression in transgenic tobacco (Nicotiana tabacum cv. Xanthi-nc) results in enhanced drought tolerance.
Yue Y, Zhang M, Zhang J, Duan L, Li Z.
Plant Sci. 2011 Oct;181(4):405-11. Epub 2011 Jun 29.
PMID:
21889046
[PubMed - in process]
Toluene and chlorobenzene dinitration over solid H(3)PO(4)/MoO(3)/SiO(2) catalyst.
Adamiak J, Kalinowska-Alichnewicz D, Szadkowski M, Skupinski W.
J Hazard Mater. 2011 Aug 16. [Epub ahead of print]
PMID:
21885194
[PubMed - as supplied by publisher]
Molybdate modulates mitogen and cyclosporin responses of human peripheral blood lymphocytes.
Michelis FV, Delitheos A, Tiligada E.
J Trace Elem Med Biol. 2011 Jul;25(3):138-42. Epub 2011 Aug 30.
PMID:
21880474
[PubMed - in process]
Structure and stability of the molybdenum cofactor intermediate cyclic pyranopterin monophosphate.
Santamaria-Araujo JA, Wray V, Schwarz G.
J Biol Inorg Chem. 2011 Aug 30. [Epub ahead of print]
PMID:
21877100
[PubMed - as supplied by publisher]
Differences in urine cadmium associations with kidney outcomes based on serum creatinine and cystatin C.
Weaver VM, Kim NS, Lee BK, Parsons PJ, Spector J, Fadrowski J, Jaar BG, Steuerwald AJ, Todd AC, Simon D, Schwartz BS.
Environ Res. 2011 Aug 24. [Epub ahead of print]
PMID:
21871619
[PubMed - as supplied by publisher]
Analysis of Trace and Major Elements in Bronchoalveolar Lavage Fluid of Mycoplasma Bronchopneumonia in Calves.
Suzuki K, Higuchi H, Iwano H, Lakritz J, Sera K, Koiwa M, Taguchi K.
Biol Trace Elem Res. 2011 Aug 26. [Epub ahead of print]
PMID:
21870151
[PubMed - as supplied by publisher]
Redox tunable reversible molecular sieves: orthorhombic molybdenum vanadium oxide.
Sadakane M, Ohmura S, Kodato K, Fujisawa T, Kato K, Shimidzu KI, Murayama T, Ueda W.
Chem Commun (Camb). 2011 Aug 23. [Epub ahead of print]
PMID:
21860863
[PubMed - as supplied by publisher]
The Identification of a novel protein involved in molybdenum cofactor biosynthesis in Escherichia coli.
Dahl JU, Urban A, Bolte A, Sirabhaya P, Donahue JL, Nimtz M, Larson TJ, Leimkuhler S.
J Biol Chem. 2011 Aug 19. [Epub ahead of print]
PMID:
21856748
[PubMed - as supplied by publisher]
Urinary heavy metals and associated medical conditions in the US adult population.
Mendy A, Gasana J, Vieira ER.
Int J Environ Health Res. 2011 Aug 19. [Epub ahead of print]
PMID:
21854105
[PubMed - as supplied by publisher]
Tuning of the Spin Distribution between Ligand- and Metal-Based Spin: Electron Paramagnetic Resonance of Mixed-Ligand Molybdenum Tris(dithiolene) Complex Anions.
Fekl U, Sarkar B, Kaim W, Zimmer-De Iuliis M, Nguyen N.
Inorg Chem. 2011 Sep 19;50(18):8685-7. Epub 2011 Aug 19.
PMID:
21853970
[PubMed - in process]