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Periodic table of the elements science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. American Elements is a U.S. Registered Trademark. © 2001-2009.American Elements. All rights reserved. |
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Recent Research & Development for Cerium
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Kinetic aspects and swelling changes of magnesium and cerium titano-antimonates in aqueous and mixed solvents.
Zakaria ES, Ali IM, Aly HF.
J Colloid Interface Sci. 2009 Jun 18. [Epub ahead of print]
PMID: 19616784 [PubMed - as supplied by publisher]
- Exploiting the oxidative coupling reaction of MBTH for indapamide determination.
Ribeiro DS, Prior JA, Santos JL, Lopes JA, Lima JL.
Talanta. 2009 Sep 15;79(4):1161-8. Epub 2009 Mar 9.
PMID: 19615526 [PubMed - in process]
- Fate and effects of CeO2 nanoparticles in aquatic ecotoxicity tests.
Van Hoecke K, Quik JT, Mankiewicz-Boczek J, De Schamphelaere KA, Elsaesser A, Van der Meeren P, Barnes C, McKerr G, Howard CV, Van de Meent D, Rydzynski K, Dawson KA, Salvati A, Lesniak A, Lynch I, Silversmit G, De Samber B, Vincze L, Janssen CR.
Environ Sci Technol. 2009 Jun 15;43(12):4537-46.
PMID: 19603674 [PubMed - in process]
- Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH](-) Bridging Ligand as an Intermediate for Catalytic Water Oxidation.
Duan L, Fischer A, Xu Y, Sun L.
J Am Chem Soc. 2009 Jul 14. [Epub ahead of print]
PMID: 19601625 [PubMed - as supplied by publisher]
- Mass Cytometry: Technique for Real Time Single Cell Multitarget Immunoassay Based on Inductively Coupled Plasma Time-of-Flight Mass Spectrometry.
Bandura DR, Baranov VI, Ornatsky OI, Antonov A, Kinach R, Lou X, Pavlov S, Vorobiev S, Dick JE, Tanner SD.
Anal Chem. 2009 Jul 14. [Epub ahead of print]
PMID: 19601617 [PubMed - as supplied by publisher]
- Trinitratobis{N'-[1-(2-pyridyl)ethylidene]isonicotinohydrazide}cerium(III): a three-dimensional cerium-organic supramolecular structure.
Zhang YY, Liu SX.
Acta Crystallogr C. 2009 Jul;65(Pt 7):m269-72. Epub 2009 Jun 24.
PMID: 19578261 [PubMed - in process]
- Total oxidation of naphthalene with high selectivity using a ceria catalyst prepared by a combustion method employing ethylene glycol.
Aranda A, López JM, Murillo R, Mastral AM, Dejoz A, Vázquez I, Solsona B, Taylor SH, García T.
J Hazard Mater. 2009 Jun 12. [Epub ahead of print]
PMID: 19576687 [PubMed - as supplied by publisher]
- Electrosteric Enhanced Stability of Functional Sub-10 nm Cerium and Iron Oxide Particles in Cell Culture Medium.
Chanteau B, Fresnais J, Berret JF.
Langmuir. 2009 Jul 2. [Epub ahead of print]
PMID: 19572532 [PubMed - as supplied by publisher]
- Monodisperse Samarium and Cerium Orthovanadate Nanocrystals and Metal Oxidation States on the Nanocrystal Surface.
Nguyen TD, Dinh CT, Do TO.
Langmuir. 2009 Jul 2. [Epub ahead of print]
PMID: 19572496 [PubMed - as supplied by publisher]
- Chemiluminescence from reactions with bis-cyclometalated iridium complexes in acidic aqueous solution.
Kiran RV, Zammit EM, Hogan CF, James BD, Barnett NW, Francis PS.
Analyst. 2009 Jul;134(7):1297-8. Epub 2009 Apr 21.
PMID: 19562192 [PubMed - in process]
- Effect of cerium oxide nanoparticles on inflammation in vascular endothelial cells.
Gojova A, Lee JT, Jung HS, Guo B, Barakat AI, Kennedy IM.
Inhal Toxicol. 2009 Jul;21(S1):123-130.
PMID: 19558244 [PubMed - as supplied by publisher]
- Uptake and inflammatory effects of nanoparticles in a human vascular endothelial cell line.
Kennedy IM, Wilson D, Barakat AI.
Res Rep Health Eff Inst. 2009 Jan;(136):3-21; discussion 23-32.
PMID: 19552347 [PubMed - in process]
- Cerium(IV) Ammonium Nitrate Is an Excellent, General Catalyst for the Friedlander and Friedlander-Borsche Quinoline Syntheses: Very Efficient Access to the Antitumor Alkaloid Luotonin A.
Sridharan V, Ribelles P, Ramos MT, Mene´ndez JC.
J Org Chem. 2009 Jun 17. [Epub ahead of print]
PMID: 19534479 [PubMed - as supplied by publisher]
- Comment on "Thermal signatures of the Kondo volume collapse in cerium".
Johansson B, Ruban AV, Abrikosov IA.
Phys Rev Lett. 2009 May 8;102(18):189601. Epub 2009 May 6. No abstract available.
PMID: 19518926 [PubMed - in process]
- Catalytic wet oxidation of phenol: the role of promoter and ceramic support.
Hussain ST, Jamil S, Mazhar M.
Environ Technol. 2009 Apr 14;30(5):511-24.
PMID: 19507443 [PubMed - indexed for MEDLINE]
- Biomimetic studies towards the cardinalins: synthesis of (+)-ventiloquinone L and an unusual dimerisation.
Sperry J, Sejberg JJ, Stiemke FM, Brimble MA.
Org Biomol Chem. 2009 Jun 21;7(12):2599-603. Epub 2009 Apr 28.
PMID: 19503935 [PubMed - in process]
- Study of the dissolution of thin films of cerium oxide by using a GaPO4 crystal microbalance.
Jakab S, Picart S, Tribollet B, Rousseau P, Perrot H, Gabrielli C.
Anal Chem. 2009 Jul 1;81(13):5139-45.
PMID: 19496612 [PubMed - in process]
- Determination of ultratrace amounts of Ce3+ in the presence of Sm3+, La3+, Dy3+, and Yb3+ in water and soils by inductively coupled plasma-optical emission spectroscopy after preconcentration with thio-functionalized MCM-41 at controlled pH.
Saberyan K.
J AOAC Int. 2009 Mar-Apr;92(2):555-60.
PMID: 19485216 [PubMed - indexed for MEDLINE]
- Catalytic ozonation of dimethyl phthalate over cerium supported on activated carbon.
Li L, Ye W, Zhang Q, Sun F, Lu P, Li X.
J Hazard Mater. 2009 May 3. [Epub ahead of print]
PMID: 19467775 [PubMed - as supplied by publisher]
- Differential scanning calorimetry investigation on vinyl ester resin curing process for polymer nanocomposite fabrication.
Guo Z, Ng HW, Yee GL, Hahn HT.
J Nanosci Nanotechnol. 2009 May;9(5):3278-85.
PMID: 19453004 [PubMed]
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Material Safety Data Sheet |
1 Identification of substance
- Product details
- Trade name Cerium (III) nitrate
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2 Composition/Data on components:
- Chemical characterization:
Designation: (CAS#)
cerium (III) nitrate, hydrate (CAS# 10294-41-4); 100%
- Identification number(s):
- EINECS Number: 233-297-2
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3 Hazards identification
- Hazard designation:
Xi Irritant
O Oxidising
- Information pertaining to particular dangers for man and environment
R 8 Contact with combustible material may cause fire.
R 36/37/38 Irritating to eyes, respiratory system and skin.
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4 First aid measures
- After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
- After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
- After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
- After swallowing Seek immediate medical advice.
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5 Fire fighting measures
- Suitable extinguishing agents
Use fire fighting measures that suit the environment.
- Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
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6 Accidental release measures
- Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
- Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
- Measures for cleaning/collecting: Ensure adequate ventilation.
- Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
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7 Handling and storage
- Handling
- Information for safe handling:
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
- Information about protection against explosions and fires:
Substance/product can reduce the ignition temperature of flammable substances.
- Storage
- Requirements to be met by storerooms and containers:
No special requirements.
- Information about storage in one common storage facility:
Store away from flammable substances.
Store away from reducing agents.
- Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
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8 Exposure controls and personal protection
- Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
- Components with critical values that require monitoring at the
workplace:
Not required.
- Additional information: No data
- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
- Breathing equipment: Use breathing protection with high concentrations.
- Protection of hands: Impervious gloves
- Eye protection:
Safety glasses
Face protection
- Body protection: Protective work clothing.
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9 Physical and chemical properties:
- General Information
- Form: Crystalline
- Colour: White
- Smell: Acidic
- Value/Range Unit Method
- Change in condition
- Melting point/Melting range: Not determined
- Boiling point/Boiling range: Not determined
- Sublimation temperature / start: Not determined
- Flash point: Not applicable
- Inflammability (solid, gaseous)
Contact with combustible material may cause fire.
- Ignition temperature: Not determined
- Decomposition temperature: Not determined
- Critical values for explosion:
- Lower: Not determined
- Upper: Not determined
- Steam pressure: Not determined
- Density at 20 ° C 1.67 g/cm³
- Solubility in / Miscibility with
- Water: at 25 ° C 1754 g/l
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10 Stability and reactivity
- Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
- Materials to be avoided: Reducing agents, easily oxidized materials
- Dangerous reactions:
Reacts with reducing agents
Reacts with flammable substances
- Dangerous products of decomposition:
Nitrous vitriol gases
Toxic metal compounds
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11 Toxicological information
- Acute toxicity:
LD/LC50 values that are relevant for classification:
Oral: LD50: 4200 mg/kg (rat)
- Primary irritant effect:
- on the skin: Irritant for skin and mucous membranes.
- on the eye: Irritant effect.
- Sensitization: No sensitizing effect known.
- Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
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12 Ecological information:
- General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
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13 Disposal considerations
- Product:
- Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
- Uncleaned packagings:
- Recommendation:
Disposal must be made according to official regulations.
- Recommended cleaning agent: Water, if necessary with cleaning agent.
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14 Transport information
- Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
- ADR/RID-GGVS/E Class: 5.1 (O2) Oxidizing substances.
- Kemler Number: 50
- UN-Number: 1477
- Packaging group: II
- Label 5.1
- Designation of goods: 1477 NITRATES, INORGANIC, N.O.S. (cerium
(III) nitrate)
- Maritime transport IMDG/GGVSea:
- IMDG/GGVSea Class: 5.1
- UN Number: 1477
- Label 5.1
- Packaging group: II
- EMS Number: F-A,S-Q
- Correct technical name: NITRATES, INORGANIC, N.O.S.
- Air transport ICAO-TI and IATA-DGR:
- ICAO/IATA Class: 5.1
- UN/ID Number: 1477
- Label 5.1
- Packaging group: II
- Correct technical name: NITRATES, INORGANIC, N.O.S.
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15 Regulatory information
- Designation according to EC guidelines:
- Code letter and hazard designation of product:
Xi Irritant O Oxidising
- Risk phrases:
8 Contact with combustible material may cause fire.
36/37/38 Irritating to eyes, respiratory system and skin.
- Safety phrases:
17 Keep away from combustible material.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
- National regulations
- Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
- Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
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16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
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