Cerium(III) 2,4-pentanedionate Hydrate

Ce(CH3COCHCOCH3)3 • xH2O
CAS 206996-61-4


Product Product Code Order or Specifications
(2N) 99% Cerium(III) 2,4-pentanedionate Hydrate CE-OM1-02-XHYD Contact American Elements
(2N5) 99.5% Cerium(III) 2,4-pentanedionate Hydrate CE-OM1-025-XHYD Contact American Elements
(3N) 99.9% Cerium(III) 2,4-pentanedionate Hydrate CE-OM1-03-XHYD Contact American Elements
(3N5) 99.95% Cerium(III) 2,4-pentanedionate Hydrate CE-OM1-035-XHYD Contact American Elements
(4N) 99.99% Cerium(III) 2,4-pentanedionate Hydrate CE-OM1-04-XHYD Contact American Elements
(5N) 99.999% Cerium(III) 2,4-pentanedionate Hydrate CE-OM1-05-XHYD Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Ce(C5H7O2)3 • H2O 206996-61-4 24863813 16212434 MFCD00150164 239-720-7 cerium;(Z)-4-hydroxypent-3-en-2-one; hydrate N/A [Ce+3].O=C(/C=C(
\[O-])C)C.[O-]\C(=
C/C(=O)C)C.[O-]
\C(=C/C(=O)C)C
InChI=1S/3C5H8O2.Ce/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; AHGQVCBMBCKNFG-KJVLTGTBSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
C15H26CeO7 458.47874 Crystalline powder 131-132°C N/A N/A 458.073292 458.073292 0 Safety Data Sheet

Acetylaceton Formula Diagram (C5H8O2)Cerium(III) 2,4-pentanedionate Hydrate is a cerium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Cerium(III) 2,4-pentanedionate Hydrate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Cerium include metallurgy, glass and glass polishing, ceramics, catalysts, and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cerium (Ce) atomic and molecular weight, atomic number and elemental symbolCerium (atomic symbol: Ce, atomic number: 58) is a Block F, Group 3, Period 6 element with an atomic weight of 140.116. The number of electrons in each of cerium's shells is 2, 8, 18, 19, 9, 2 and its electron configuration is [Xe]4f2 6s2. Cerium Bohr ModelThe cerium atom has a radius of 182.5 pm and a Van der Waals radius of 235 pm. In its elemental form, cerium has a silvery white appearance. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states, the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. Elemental CeriumIt is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer. The cerous state closely resembles the other trivalent rare earths. Cerium is found in the minerals allanite, bastnasite, hydroxylbastnasite, monazite, rhabdophane, synchysite and zircon. Cerium was discovered by Martin Heinrich Klaproth, Jöns Jakob Berzelius, and Wilhelm Hisinger in 1803 and first isolated by Carl Gustaf Mosander in 1839. The element was named after the asteroid Ceres. For more information on cerium, including properties, safety data, research, and American Elements' catalog of cerium products, visit the Cerium Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Warning
H315-H319-H335-H361
Xn
36/37/38-63
7-26-36/37/39
N/A
N/A
3
Exclamation Mark-Acute Toxicity Health Hazard      

CERIUM(III) 2,4-PENTANEDIONATE HYDRATE SYNONYMS
Ce(acac)3; Cerium(III) acetylacetonate hydrate; (3Z)-4-Hydroxy-3-penten-2-one - cerium hydrate (3:1:1)

CUSTOMERS FOR CERIUM(III) 2,4-PENTANEDIONATE HYDRATE HAVE ALSO LOOKED AT
Show Me MORE Forms of Cerium

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Cerium

  • Gordon A. Alanko, Brian Jaques, Allyssa Bateman, Darryl P. Butt, Mechanochemical synthesis and spark plasma sintering of the cerium silicides, Journal of Alloys and Compounds, Volume 616, 15 December 2014
  • Chao Lu, Hao Wu, Yun Zhang, Heng Liu, Baojun Chen, Naiteng Wu, Sen Wang, Cerium fluoride coated layered oxide Li1.2Mn0.54Ni0.13Co0.13O2 as cathode materials with improved electrochemical performance for lithium ion batteries, Journal of Power Sources, Volume 267, 1 December 2014
  • Martynas Misevicius, Martynas Kilmanas, Serdar Culunlu, Simas Sakirzanovas, Ayse Uztetik Morkan, Aldona Beganskiene, Aivaras Kareiva, On the sol–gel fabrication and characterization of undoped and cerium-doped Sr4Al14O25, Journal of Alloys and Compounds, Volume 614, 25 November 2014
  • Horng-Huey Ko, Guoli Yang, Moo-Chin Wang, Xiujian Zhao, Thermal behavior and crystallization kinetics of cerium dioxide precursor powders, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Lingguang Sun, Qiang Chen, Jiagang Wu, Zhihang Peng, Zhi Tan, Dingquan Xiao, Jianguo Zhu, Dielectric and piezoelectric properties of cerium-doped (NaBi)0.49[ ]0.02Bi2Nb1.98Ta0.02O9-based piezoceramics, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Junghwa Park, Dukjoon Kim, Effect of cerium/18-crown-6-ether coordination complex OH quencher on the properties of sulfonated poly(ether ether ketone) fuel cell electrolyte membranes, Journal of Membrane Science, Volume 469, 1 November 2014
  • Leopold Kokou, Jincheng Du, Short- and medium-range structures of cerium aluminophosphate glasses: A molecular dynamics study, Journal of Non-Crystalline Solids, Volume 403, 1 November 2014
  • R. Suresh, V. Ponnuswamy, R. Mariappan, Consequence of source material on the surface properties of nebulizer spray coated cerium oxide thin films, Vacuum, Volume 109, November 2014
  • B. Valdez, S. Kiyota, M. Stoytcheva, R. Zlatev, J.M. Bastidas, Cerium-based conversion coatings to improve the corrosion resistance of aluminium alloy 6061-T6, Corrosion Science, Volume 87, October 2014
  • Yongdeuk Gong, Daewoong Choi, Bo-Young Han, Jonghyun Yoo, Song-Hee Han, Yonghoon Lee, Remote quantitative analysis of cerium through a shielding window by stand-off laser-induced breakdown spectroscopy, Journal of Nuclear Materials, Volume 453, Issues 1–3, October 2014
  • Christofer E. Whiting, John M. Douglas, Bethany M. Cremeans, Chadwick D. Barklay, Daniel P. Kramer, Oxygen exchange reaction kinetics for cerium(IV) oxide at 1000 °C, Journal of Solid State Chemistry, Volume 218, October 2014
  • J.P. Winterstein, C.B. Carter, Electron-beam damage and point defects near grain boundaries in cerium oxide, Journal of the European Ceramic Society, Volume 34, Issue 12, October 2014
  • Saadi Berri, Djamel Maouche, Miloud Ibrir, Badis Bakri, Electronic structure and magnetic properties of the perovskite cerium manganese oxide from ab initio calculations, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • Jayapalan Saranya, Kugalur Shanmugam Ranjith, Padmanaban Saravanan, Devanesan Mangalaraj, Ramasamy Thangavelu Rajendra Kumar, Cobalt-doped cerium oxide nanoparticles: Enhanced photocatalytic activity under UV and visible light irradiation, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • Mahdi Robat Sarpoushi, Mahdi Nasibi, Mohammad Ali Golozar, Mohammad Reza Shishesaz, Mohammad Reza Borhani, Sajad Noroozi, Electrochemical investigation of graphene/cerium oxide nanoparticles as an electrode material for supercapacitors, Materials Science in Semiconductor Processing, Volume 26, October 2014
  • M. van Soestbergen, V. Baukh, S.J.F. Erich, H.P. Huinink, O.C.G. Adan, Release of cerium dibutylphosphate corrosion inhibitors from highly filled epoxy coating systems, Progress in Organic Coatings, Volume 77, Issue 10, October 2014
  • D. Naga Durgasri, T. Vinodkumar, Fangjian Lin, Ivo Alxneit, Benjaram M. Reddy, Gadolinium doped cerium oxide for soot oxidation: Influence of interfacial metal–support interactions, Applied Surface Science, Volume 314, 30 September 2014
  • Cui Ye, Huan Guo, Menghuan Zhang, Hongguo Zhu, Jianqiang Hu, Xuandi Lai, Aiqing Li, Synthesis and enhanced electrochemical property of Au-doped cerium phosphate nanowires, Materials Letters, Volume 131, 15 September 2014
  • Jie Sun, Gang Wang, Preparation and corrosion resistance of cerium conversion coatings on AZ91D magnesium alloy by a cathodic electrochemical treatment, Surface and Coatings Technology, Volume 254, 15 September 2014
  • X. Jiang, S.-H. Song, Enhanced hot ductility of a Cr–Mo low alloy steel by rare earth cerium, Materials Science and Engineering: A, Volume 613, 8 September 2014

Recent Research & Development for Acetylacetonates

  • Sudipta Chatterjee, Sutanuva Mandal, Sucheta Joy, Chen-Hsiung Hung, Sreebrata Goswami, ortho-Carom–N bond fusion in aniline associated with electrophilic chlorination reactions at ruthenium(III) coordinated acetylacetonates, Inorganica Chimica Acta, Volume 374, Issue 1, 1 August 2011
  • János Madarász, Shoji Kaneko, Masayuki Okuya, György Pokol, Comparative evolved gas analyses of crystalline and amorphous titanium(IV)oxo-hydroxo-acetylacetonates by TG-FTIR and TG/DTA-MS, Thermochimica Acta, Volume 489, Issues 1–2, 20 May 2009
  • Satoshi Yoda, Yoko Mizuno, Takeshi Furuya, Yoshihiro Takebayashi, Katsuto Otake, Tomoya Tsuji, Toshihiko Hiaki, Solubility measurements of noble metal acetylacetonates in supercritical carbon dioxide by high performance liquid chromatography (HPLC), The Journal of Supercritical Fluids, Volume 44, Issue 2, March 2008
  • M. Aslam Siddiqi, Rehan A. Siddiqui, Burak Atakan, Thermal stability, sublimation pressures and diffusion coefficients of some metal acetylacetonates, Surface and Coatings Technology, Volume 201, Issues 22–23, 25 September 2007
  • María R. Pedrosa, Jaime Escribano, Rafael Aguado, Virginia Díez, Roberto Sanz, Francisco J. Arnáiz, Dinuclear oxomolybdenum(VI) acetylacetonates: Crystal and molecular structure of Mo2O5(acac)2L2 (L = D2O, DMF), Polyhedron, Volume 26, Issue 14, 31 August 2007
  • S.V. Samoilenkov, M.A. Stefan, G. Wahl, MOCVD of thick YSZ coatings using acetylacetonates, Surface and Coatings Technology, Volume 192, Issue 1, 1 March 2005
  • Thomas Behrsing, Alan M Bond, Glen B Deacon, Craig M Forsyth, Maria Forsyth, Kalpana J Kamble, Brian W Skelton, Allan H White, Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2O, Inorganica Chimica Acta, Volume 352, 6 August 2003
  • R Leboda, J Skubiszewska-Zieba, J Rynkowski, Preparation and porous structure of carbon–silica adsorbents obtained on the basis of Ti, Co, Ni, Cr, Zn and Zr acetylacetonates and acetylacetone, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 174, Issue 3, 1 December 2000
  • V.M. Gun'ko, R. Leboda, J. Skubiszewska-Zi?ba, J. Rynkowski, Silica Gel Modified Due to Pyrolysis of Acetylacetone and Metal (Ti, Cr, Co, Ni, Zn, Zr) Acetylacetonates, Journal of Colloid and Interface Science, Volume 231, Issue 1, 1 November 2000
  • V.G Isakova, I.A Baidina, N.B Morozova, I.K Igumenov, ?-Halogenated iridium(III) acetylacetonates, Polyhedron, Volume 19, Issue 9, 15 May 2000
  • V.V. Turov, R. Leboda, J. Skubiszewska-Zi ?, Changes in Hydration Properties of Silica Gel in a Process of Its Carbonization by Pyrolysis of Acetylacetone Zn (Ti) Acetylacetonates, Journal of Colloid and Interface Science, Volume 206, Issue 1, 1 October 1998
  • Claudia Neyertz, María Volpe, Preparation of binary palladium-vanadium supported catalysts from metal acetylacetonates, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 136, Issues 1–2, 30 April 1998
  • Shoichi Katsuta, Tomohiko Nakatani, Evaluation of Distribution Constants of Lanthanoid(III) Acetylacetonates between Sodium Dodecyl Sulfate Micelles and Water by Micellar Capillary Electrophoresis, Journal of Colloid and Interface Science, Volume 195, Issue 2, 15 November 1997
  • Z. Zhang, Y. Tanigami, R. Terai, Catalytic effect of acetylacetonates on gel formation of CH3SiO32, Journal of Non-Crystalline Solids, Volume 191, Issue 3, 1 December 1995
  • Irina G. Zaitzeva, Nataliya P. Kuzmina, Larissa I. Martynenko, The volatile rare earth element tetrakis-acetylacetonates, Journal of Alloys and Compounds, Volume 225, Issues 1–2, 15 July 1995
  • J.C. Machado, C.F. Carvalho, W.F. Magalhães, A. Marques Netto, J.Ch. Abbé, G. Duplâtre, Positronium formation and inhibition in binary solid solutions on Al(III) and Co(III) tris(acetylacetonates), Chemical Physics, Volume 170, Issue 2, 1 March 1993
  • I.C. McNeill, J.J. Liggat, The effect of metal acetylacetonates on the thermal degradation of poly(methyl methacrylate): Part II—Manganese (III) acetylacetonate, Polymer Degradation and Stability, Volume 37, Issue 1, 1992
  • Pilar Gómez-Sal, Avelino Martín, Miguel Mena, Pascual Royo, Ricardo Serrano, Monopentamethylcyclopentadienyltitanium(IV) halo-alkoxides, alkyl-alkoxides and acetylacetonates, Journal of Organometallic Chemistry, Volume 419, Issues 1–2, 12 November 1991
  • I.C. McNeill, J.J. Liggat, The effect of metal acetylacetonates on the thermal degradation of poly(methyl methacrylate)—I. Cobalt (III) acetylacetonate, Polymer Degradation and Stability, Volume 29, Issue 1, 1990
  • B.L. Khandelwal, A.K. Singh, N.S. Bhandari, Preparative and spectral investigations on C3 bonded acetylacetonates of tellurium(IV), Journal of Organometallic Chemistry, Volume 320, Issue 3, 17 February 1987