Cerium Selenide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Cerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is moderately toxic. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueoussolutions.It is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.
Selenium is a Block P, Group 16, Period 4 element. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electronic configuration is [Ar] 3d10 4s2 4p4. In its elemental form selenium's CAS number is 7782-49-2. The selenium atom has a radius of 116.pm and it's Van der Waals radius is 190.pm. The EPA does not classify selenium as carcinogenic, although selenium sulfide is a probable carcinogen. Selenates and selenites which are compounds of selenium, are highly toxic. Hydrogen selenide gas (SeH2) is the most acutely toxic compound of selenium. Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. of photocells and exposure meters for photographic use, as well as solar cells. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications. Selenium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Selenium was first discovered by Jons Berzelius in 1817. The origin of the name Selenium comes from the Greek word "Selęnę" meaning moon. See selenium research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(iii) bromide.
Vasudevan KV, Smith NA, Scott BL, Bennett BL, Muenchausen RE, Gordon JC.
Dalton Trans. 2011 Dec 23. [Epub ahead of print]
PMID:
22193947
[PubMed - as supplied by publisher]
Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
[PubMed - as supplied by publisher]
Electrooxidation of nitrite on a silica-cerium mixed oxide carbon paste electrode.
Silveira G, Morais AD, Villis PC, Maroneze CM, Gushikem Y, Lucho AM, Pissetti FL.
J Colloid Interface Sci. 2011 Dec 6. [Epub ahead of print]
PMID:
22192596
[PubMed - as supplied by publisher]
Ceria-engineered nanomaterial distribution in, and clearance from, blood: size matters.
Dan M, Wu P, Grulke EA, Graham UM, Unrine JM, Yokel RA.
Nanomedicine (Lond). 2012 Jan;7(1):95-110.
PMID:
22191779
[PubMed - in process]
Effect of Ce(3+) on soluble microbial products production in anaerobic granular sludge digestion.
Fu B, Liang R, Xia Q, Ding L, Xu K, Ren H.
Water Sci Technol. 2011;64(7):1459-65.
PMID:
22179643
[PubMed - in process]
[Removal of gaseous elemental mercury over cerium doped low vanadium loading V2O5-WO3/TiO2 in simulated coal-fired flue gas].
Wan Q, Duan L, He KB, Chen L, Li JH.
Huan Jing Ke Xue. 2011 Sep;32(9):2800-4. Chinese.
PMID:
22165254
[PubMed - in process]
Operando DRIFTS study of the redox and catalytic properties of CuO/Ce(1-x)Tb(x)O(2-d) (x = 0-0.5) catalysts: evidence of an induction step during CO oxidation.
Martínez-Arias A, Hungría AB, Fernández-García M, Iglesias-Juez A, Soria J, Conesa JC, Anderson JA, Munuera G.
Phys Chem Chem Phys. 2011 Dec 8. [Epub ahead of print]
PMID:
22159154
[PubMed - as supplied by publisher]
Classical oxidant induced chemiluminescence of fluorescent carbon dots.
Lin Z, Xue W, Chen H, Lin JM.
Chem Commun (Camb). 2011 Dec 8. [Epub ahead of print]
PMID:
22158939
[PubMed - as supplied by publisher]
Gamma-ray fast-timing coincidence measurements from the (18)O+(18)O fusion-evaporation reaction using a mixed LaBr(3)-HPGe array.
Alharbi T, Mason PJ, Regan PH, Podolyák Z, Marginean N, Nakhostin M, Bowry M, Bucurescu D, Cata-Danil G, Cata-Danil I, Deleanu D, Filipescu D, Glodariu T, Ghita D, Marginean R, Mihai C, Negret A, Pascu S, Sava T, Stroe L, Suliman G, Zamfir NV, Bruce AM, Rodriguez Triguero C, Bender PC, Garg U, Erduran MN, Kusoglu A, Bostan M, Detistov P, Alkhomashi N, Sinha AK, Chakrabarti R, Ghugre SS.
Appl Radiat Isot. 2011 Dec 3. [Epub ahead of print]
PMID:
22154387
[PubMed - as supplied by publisher]
Cationic Surface Reconstructions on Cerium Oxide Nanocrystals: An Aberration Corrected HRTEM Study.
Bhatta UM, Ross IM, Sayle TX, Sayle DC, Parker SC, Reid D, Seal S, Kumar A, Moebus G.
ACS Nano. 2011 Dec 13. [Epub ahead of print]
PMID:
22148265
[PubMed - as supplied by publisher]
In-house SAD phasing with surface-bound cerium ions.
Vennila KN, Velmurugan D.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Dec 1;67(Pt 12):1662-5. Epub 2011 Nov 25.
PMID:
22139192
[PubMed - in process]
High concentrations of cadmium, cerium and lanthanum in indoor air due to environmental tobacco smoke.
Böhlandt A, Schierl R, Diemer J, Koch C, Bolte G, Kiranoglu M, Fromme H, Nowak D.
Sci Total Environ. 2011 Dec 1. [Epub ahead of print]
PMID:
22137652
[PubMed - as supplied by publisher]
A cholesterol and actinide dependent shadow biosphere of archaea and viroids in autoimmune diseases.
Kurup R, Kurup PA.
Immunobiology. 2011 Oct 25. [Epub ahead of print]
PMID:
22137029
[PubMed - as supplied by publisher]
On the interaction of Mg with the (111) and (110) surfaces of ceria.
Nolan M, Lykhach Y, Tsud N, Skála T, Staudt T, Prince KC, Matolín V, Libuda J.
Phys Chem Chem Phys. 2011 Dec 14;14(3):1293-301. Epub 2011 Dec 1.
PMID:
22134463
[PubMed - in process]
Measurement of redox potential in nanoecotoxicological investigations.
Tantra R, Cackett A, Peck R, Gohil D, Snowden J.
J Toxicol. 2012;2012:270651. Epub 2011 Oct 31.
PMID:
22131988
[PubMed - in process]
In situ characterization of Pt catalysts supported on ceria modified TiO(2) for the WGS reaction: influence of ceria loading.
Barrio L, Zhou G, González ID, Estrella M, Hanson J, Rodriguez JA, Navarro RM, Fierro JL.
Phys Chem Chem Phys. 2011 Dec 1. [Epub ahead of print]
PMID:
22130010
[PubMed - as supplied by publisher]
The oxidation state of Hadean magmas and implications for early Earth's atmosphere.
Trail D, Watson EB, Tailby ND.
Nature. 2011 Nov 30;480(7375):79-82. doi: 10.1038/nature10655.
PMID:
22129728
[PubMed - in process]
Preparation methods and thermal stability of Ba-Mn-Ce oxide catalyst for NO(x)-assisted soot oxidation.
Wu X, Lin F, Wang L, Weng D, Zhou Z.
J Environ Sci (China). 2011;23(7):1205-10.
PMID:
22125916
[PubMed - indexed for MEDLINE]
The oxidative degradation of dibenzoazepine derivatives by cerium(iv) complexes in acidic sulfate media.
Wisniewska J, Wrzeszcz G, Kurzawa M, van Eldik R.
Dalton Trans. 2011 Nov 29. [Epub ahead of print]
PMID:
22124379
[PubMed - as supplied by publisher]
Effect of support size on the catalytic activity of metal-oxide-doped silica particles in the glycolysis of polyethylene terephthalate.
Wi R, Imran M, Lee KG, Yoon SH, Cho BG, Kim do H.
J Nanosci Nanotechnol. 2011 Jul;11(7):6544-9.
PMID:
22121753
[PubMed - in process]
Toenail selenium status and the risk of Barrett's esophagus: the Netherlands Cohort Study.
Steevens J, Schouten LJ, Driessen AL, Huysentruyt CJ, Keulemans YC, Goldbohm RA, van den Brandt PA.
Cancer Causes Control. 2010 Oct 10. [Epub ahead of print]PMID: 20936529 [PubMed - as supplied by publisher]Related citations
Promotion of Growth in Mungbean (Phaseolus aureus Roxb.) by Selenium is Associated with Stimulation of Carbohydrate Metabolism.
Malik JA, Kumar S, Thakur P, Sharma S, Kaur N, Kaur R, Pathania D, Bhandhari K, Kaushal N, Singh K, Srivastava A, Nayyar H.
Biol Trace Elem Res. 2010 Oct 9. [Epub ahead of print]PMID: 20936436 [PubMed - as supplied by publisher]Related citations
Transition metal chemistry of cyclodiphosphanes containing phosphine and amide-phosphine functionalities: Formation of a stable dipalladium(II) complex containing a Pd-P s-bond.
Balakrishna MS, Venkateswaran R, Mague JT.
Dalton Trans. 2010 Oct 8. [Epub ahead of print]PMID: 20936211 [PubMed - as supplied by publisher]Related citations
Associations between blood metals and fecundity among women residing in New York State.
Bloom MS, Louis GM, Sundaram R, Kostyniak PJ, Jain J.
Reprod Toxicol. 2010 Oct 6. [Epub ahead of print]PMID: 20933593 [PubMed - as supplied by publisher]Related citations
The protective role of selenium in recalcitrant Acer saccharium L. seeds subjected to desiccation.
Pukacka S, Ratajczak E, Kalemba E.
J Plant Physiol. 2010 Oct 6. [Epub ahead of print]PMID: 20933296 [PubMed - as supplied by publisher]Related citations
Trace element concentrations in nesting flatback turtles (Natator depressus) from Curtis Island, Queensland, Australia.
Ikonomopoulou MP, Olszowy H, Limpus C, Francis R, Whittier J.
Mar Environ Res. 2010 Sep 25. [Epub ahead of print]PMID: 20933265 [PubMed - as supplied by publisher]Related citations
Correlation between serum selenium level and febrile seizures.
Mahyar A, Ayazi P, Fallahi M, Javadi A.
Pediatr Neurol. 2010 Nov;43(5):331-4.PMID: 20933176 [PubMed - in process]Related citations
Anti-Tumor Activity of Aloe vera Against DMBA/Croton Oil-Induced Skin Papillomagenesis in Swiss Albino Mice.
Saini M, Goyal PK, Chaudhary G.
J Environ Pathol Toxicol Oncol. 2010;29(2):127-35.PMID: 20932247 [PubMed - in process]Related citations
Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb(3)(AlQ(2))(3)(GeQ(2))(7) (Q = S, Se).
Rothenberger A, Shafaei-Fallah M, Kanatzidis MG.
Inorg Chem. 2010 Oct 8. [Epub ahead of print]PMID: 20932019 [PubMed - as supplied by publisher]Related citations
A Nutrient Approach to Prostate Cancer Prevention: The Selenium and Vitamin E Cancer Prevention Trial (SELECT).
Dunn BK, Richmond ES, Minasian LM, Ryan AM, Ford LG.
Nutr Cancer. 2010 Oct;62(7):896-918.PMID: 20924966 [PubMed - in process]Related citations
Serum levels of selenium in patients with breast cancer before and after treatment of external beam radiotherapy.
Franca CA, Nogueira CR, Ramalho A, Carvalho AC, Vieira SL, Penna AB.
Ann Oncol. 2010 Oct 5. [Epub ahead of print]PMID: 20924074 [PubMed - as supplied by publisher]Related citations
Kenji Soda--researching enzymes with the spirit of an alpinist.
Yoshimura T, Mihara H, Ohshima T, Tanizawa K.
J Biochem. 2010 Oct;148(4):371-9.PMID: 20924059 [PubMed - in process]Related citations
Inhibitory effect of arsenic on aerobic gut flora in rat.
Choudhry ZK, Misbahuddin M, Hosain AK, Saleh AA.
Bangladesh Med Res Counc Bull. 2009 Dec;35(3):79-83.PMID: 20922909 [PubMed - in process]Related citations
[Endemic and biogeochemical features of the territory of Chuvash Republic]
[No authors listed]
Vestn Ross Akad Med Nauk. 2010;(8):40-6. Russian. PMID: 20922843 [PubMed - in process]Related citations
Interaction of uranyl with Se(IV) and Se(VI) in aqueous acid solutions by means of capillary electrophoresis.
Sladkov V.
Electrophoresis. 2010 Oct 4. [Epub ahead of print]PMID: 20922762 [PubMed - as supplied by publisher]Related citations
Ensemble Modeling Coupled with Six Element Concentrations in Human Blood for Cancer Diagnosis.
Chen H, Tan C, Wu T.
Biol Trace Elem Res. 2010 Oct 5. [Epub ahead of print]PMID: 20922500 [PubMed - as supplied by publisher]Related citations
Use of dietary vitamin E and selenium (Se) to increase the shelf life of modified atmosphere packaged light lamb meat.
Ripoll G, Joy M, Muñoz F.
Meat Sci. 2010 Sep 18. [Epub ahead of print]PMID: 20920835 [PubMed - as supplied by publisher]Related citations
Impacts of maternal selenium and nutritional level on growth, adiposity, and glucose tolerance in female offspring in sheep.
Vonnahme KA, Luther JS, Reynolds LP, Hammer CJ, Carlson DB, Redmer DA, Caton JS.
Domest Anim Endocrinol. 2010 Nov;39(4):240-8. Epub 2010 Jul 25.PMID: 20920781 [PubMed - in process]Related citations
Mutations disrupting selenocysteine formation cause progressive cerebello-cerebral atrophy.
Agamy O, Ben Zeev B, Lev D, Marcus B, Fine D, Su D, Narkis G, Ofir R, Hoffmann C, Leshinsky-Silver E, Flusser H, Sivan S, Söll D, Lerman-Sagie T, Birk OS.
Am J Hum Genet. 2010 Oct 8;87(4):538-44.PMID: 20920667 [PubMed - in process]Related citations
Developmental toxicity of selenium to Dolly Varden char (Salvelinus malma).
McDonald BG, Debruyn AM, Elphick JR, Davies M, Bustard D, Chapman PM.
Environ Toxicol Chem. 2010 Aug 3. [Epub ahead of print]PMID: 20891017 [PubMed - as supplied by publisher]Related citations
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