Cobalt Boride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Cobalt is a Block D, Group 9, Period 4 element. The number of electrons in each of Cobalt's shells is 2, 8, 15, 2 and its electronic configuration is [Ar] 3d7 4s2. In its elemental form cobalt's CAS number is 7440-48-4. The cobalt atom has a radius of 125.3.pm and it's Van der Waals radius is 200.pm. Cobalt and its compounds are somewhat toxic by skin contact and moderately toxic by inhalation. Cobalt has a metallic permeability two thirds that of iron. It exists as a mixture of two allotropes over a wide temperature range. The transformation is slow and accounts in part for the wide variation in the physical properties of cobalt. It is alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many important uses. Samarium-cobalt is one of the highest strength magnet alloys known. Cobalt compounds produce a brilliant and permanent blue color in ceramic glazes, glass, pottery, tiles, and enamels. Co-60 is useful as a gamma ray source. Toxicity of cobalt and its compounds are mild by skin contact and moderate by ingestion. Cobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Cobalt was first discovered by George Brandt in 1737. The origin of the word Cobalt comes from the German word 'Kobalt or Kobold' which translates as "goblin", "elf" or "evil spirit". See Cobalt research below.
Boron is a Block P, Group 13, Period 2 element. The number of electrons in each of Boron's shells is 2, 3 and its electronic configuration is [He] 2s2 2p1. In its elemental form boron's CAS number is 7440-42-8. The boron atom has a radius of 79.5.pm and it's Van der Waals radius is 200.pm. Boron is not toxic. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Optical characteristics include transmitting portions of the infrared. Boron is a poor conductor of electricity at room temperature but a good conductor at high temperature. Boron in its elemental form is not toxic. Amorphous boron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter Boric acid is also an important boron compound with major markets in textile products. Boron compounds are also extensively used in the manufacture of borosilicate glasses. The isotope Boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal. Boron also has lubricating properties similar to graphite. Boron was first discovered by Sir Humphry Davy and J.L Gay-Lussac in 1808. The name Boron originates from a combination of carbon and the Arabic word 'buraqu meaning borax. See Boron research below.
Borides are all hard, high-melting materials with metal-like conductivity. They are stable to nonoxidizing acids but break down in strong oxidizing agents and strong alkalis. Borides are used in semiconductors, superconductors, diamagnetic, paramagnetic, ferromagnetic, anti-ferromagnetic, turbine blades, and rocket nozzles. Boride have recently been discovered to be superconductive and the ultra-incompressible.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Tetra-kis(3-cyano-pyridine-?N)bis-(thio-cyanato-?N)cobalt(II) 1,4-dioxane disolvate.
Diehr S, Wöhlert S, Boeckmann J, Näther C.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1898. Epub 2011 Nov 30.
PMID:
22199656
[PubMed - as supplied by publisher]
Bis(2,4-dioxo-5,5-diphenyl-imidazol-idin-ido-?N)bis-(propane-1,3-diamine-?N,N')cobalt(II).
Hu X, Jiang Q, Wang D, Liu H.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1885. Epub 2011 Nov 30.
PMID:
22199646
[PubMed - as supplied by publisher]
Poly[aqua-{?(3)-5-[(pyridin-2-ylmeth-yl)amino]-isophthalato-?N,N':O,O:O}cobalt(II)].
Zhu XH, Cheng XC.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1862. Epub 2011 Nov 30.
PMID:
22199630
[PubMed - as supplied by publisher]
catena-Poly[[[cis-aqua-dibromido-cobalt(II)]-?-(pyrazine-2-carb-oxy-lic acid)-?N,O:N] monohydrate].
Dares C, Fournier R, Lever AB.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1798-m1799. Epub 2011 Nov 23.
PMID:
22199583
[PubMed - as supplied by publisher]
Poly[di-?(2)-aqua-?(5)-(pyridine-2,6-dicarboxyl-ato)-?(3)-(pyridine-2,6-dicarboxyl-ato)-cobalt(II)disodium].
Boyko AN, Golenya IA, Izotova YA, Haukka M, Prisyazhnaya EV.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1782-m1783. Epub 2011 Nov 19.
PMID:
22199572
[PubMed - as supplied by publisher]
Diaqua-bis-(pyridine-2-sulfonato-?N,O)cobalt(II).
Li ZS, Ng SW.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1781. Epub 2011 Nov 19.
PMID:
22199571
[PubMed - as supplied by publisher]
Bis[tris-(ethyl-enediamine-?N,N')cobalt(III)] octa-kis-?-(3)-oxido-hexa-deca-?(2)-oxido-tetra-deca-oxido-?(12)-tetra-oxo-silicato-octa-molybdenum(VI)hexa-vanadium(IV,V) hexa-hydrate.
Lu YK, Tian MM, Xu SG, Lü RQ, Liu YQ.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1776-m1777. Epub 2011 Nov 19.
PMID:
22199568
[PubMed - as supplied by publisher]
Tetra-aqua-bis-(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetato)-cobalt(II) monohydrate.
Yang GR, Li GT.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1746-m1747. Epub 2011 Nov 12.
PMID:
22199545
[PubMed - as supplied by publisher]
Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-?N]cobalt(II).
Wang HR, Li GT.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1743. Epub 2011 Nov 12.
PMID:
22199542
[PubMed - as supplied by publisher]
Poly[[tetra-aqua-(?(4)-imidazole-4,5-dicarboxyl-ato)(?(3)-imidazole-4,5-dicarboxyl-ato)-?(3)-sulfato-?(2)-sulfato-cobalt(II)digadolinium(III)] monohydrate].
Zhu LC.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1741-m1742. Epub 2011 Nov 12.
PMID:
22199541
[PubMed - as supplied by publisher]
Hexaaqua-cobalt(II) bis-(5-acetyl-2-hy-droxy-benzoate) dihydrate.
Han LJ, Yang SP, Fu LL, Gao HL.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1733. Epub 2011 Nov 9.
PMID:
22199535
[PubMed - as supplied by publisher]
Dichlorido[(4E,11E)-5,7,12,14-tetra-benzyl-7,14-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-4,11-diene]cobalt(III) perchlorate.
Roy TG, Hazari SK, Barua KK, Ng SW, Tiekink ER.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1722-m1723. Epub 2011 Nov 9.
PMID:
22199529
[PubMed - as supplied by publisher]
{1,2-Bis[(3,5-dimethyl-1H-pyrazol-1-yl-?N)meth-yl]benzene}-dichloridozinc(II).
Guzei IA, Spencer LC, Budhai A, Darkwa J.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1715-m1716. Epub 2011 Nov 9.
PMID:
22199525
[PubMed - as supplied by publisher]
catena-Poly[[bis-(2,4-dichloro-benzoato)bis-(methanol-?O)cobalt(II)]-?-4,4'-bipyridine-?N:N'].
Hyun MY, Kim PG, Kim C, Kim Y.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1705. Epub 2011 Nov 9.
PMID:
22199519
[PubMed - as supplied by publisher]
Bis(pentane-2,4-dionato-?O,O')(1,10-phenanthroline-?N,N')cobalt(II).
Perdih F.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1697. Epub 2011 Nov 5.
PMID:
22199513
[PubMed - as supplied by publisher]
Diaqua-bis-(dihydrogen 3-aza-niumyl-1-hy-droxy-propyl-idene-1,1-di-phos-phon-ato-?O,O')cobalt(II).
Tsaryk NV, Dudko AV, Kozachkova AN, Pekhnyo VI.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1694. Epub 2011 Nov 5.
PMID:
22199511
[PubMed - as supplied by publisher]
Tetra-aqua-bis-{3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzoato-?O}cobalt(II) dihydrate.
Bai L, Zhao J.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1689. Epub 2011 Nov 5.
PMID:
22199506
[PubMed - as supplied by publisher]
Tetra-aqua-bis-(2-methyl-1H-imidazole-?N)cobalt(II) naphthalene-1,5-disulfonate.
Jin Y.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1686. Epub 2011 Nov 5.
PMID:
22199503
[PubMed - as supplied by publisher]
Diaqua-bis-(dimethyl sulfoxide-?O)bis(saccharinato-?N)cobalt(II).
Potwana FS, Van Zyl WE.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1667-m1668. Epub 2011 Nov 5.
PMID:
22199492
[PubMed - as supplied by publisher]
Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles.
Roedel EQ, Cafasso DE, Lee KW, Pierce LM.
Toxicol Appl Pharmacol. 2011 Dec 16. [Epub ahead of print]
PMID:
22198552
[PubMed - as supplied by publisher]
Recent Research & Development for Boride
Effects of heat treatment on evolution of microstructure of boron free and boron containing biomedical Ti-13Zr-13Nb alloys.
Majumdar P.
Micron. 2012 Mar 8. [Epub ahead of print]
PMID:
22459252
[PubMed - as supplied by publisher]
Boron oxynitride nanoclusters on tungsten trioxide as a metal-free cocatalyst for photocatalytic oxygen evolution from water splitting.
Xie YP, Liu G, Lu GQ, Cheng HM.
Nanoscale. 2012 Feb 21;4(4):1267-70. Epub 2012 Jan 13.
PMID:
22241455
[PubMed - in process]
Effect of the disinfection agents chlorine, UV irradiation, silver ions, and TiO2 nanoparticles/near-UV on DNA molecules.
Van Aken B, Lin LS.
Water Sci Technol. 2011;64(6):1226-32.
PMID:
22214074
[PubMed - indexed for MEDLINE]
Crystal structure refinement and bonding patterns of CrB4: a boron-rich boride with a framework of tetrahedrally coordinated B atoms.
Knappschneider A, Litterscheid C, Kurzman J, Seshadri R, Albert B.
Inorg Chem. 2011 Nov 7;50(21):10540-2. Epub 2011 Oct 10.
PMID:
21985336
[PubMed]
Tailored materials for high-performance MgB(2) wire.
Kim JH, Oh S, Kumakura H, Matsumoto A, Heo YU, Song KS, Kang YM, Maeda M, Rindfleisch M, Tomsic M, Choi S, Dou SX.
Adv Mater. 2011 Nov 9;23(42):4942-6. doi: 10.1002/adma.201101243. Epub 2011 Sep 28. No abstract available.
PMID:
21956864
[PubMed - indexed for MEDLINE]
Synthesis, characterization, and electronic structure of new type of heterometallic boride clusters.
Bose SK, Geetharani K, Sahoo S, Reddy KH, Varghese B, Jemmis ED, Ghosh S.
Inorg Chem. 2011 Oct 3;50(19):9414-22. Epub 2011 Aug 29.
PMID:
21875060
[PubMed]
Scaffolding, ladders, chains, and rare ferrimagnetism in intermetallic borides: synthesis, crystal chemistry and magnetism.
Goerens C, Brgoch J, Miller GJ, Fokwa BP.
Inorg Chem. 2011 Jul 4;50(13):6289-96. Epub 2011 Jun 2.
PMID:
21634389
[PubMed]
Wet-chemical synthesis of nanoscale iron boride, XAFS analysis and crystallisation to a-FeB.
Rades S, Kornowski A, Weller H, Albert B.
Chemphyschem. 2011 Jun 20;12(9):1756-60. doi: 10.1002/cphc.201001072. Epub 2011 May 12.
PMID:
21567704
[PubMed]
Nickel bis-muth boride, Ni(23-x)Bi(x)B(6) [x = 2.44 (1)].
Berthebaud D, Sato A, Mori T.
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):i17.
PMID:
21522814
[PubMed]
Thermal and stress studies of normal incidence Mo/B4C multilayers for a 6.7 nm wavelength.
Barthelmess M, Bajt S.
Appl Opt. 2011 Apr 10;50(11):1610-9. doi: 10.1364/AO.50.001610.
PMID:
21478937
[PubMed]
New nickel gallium boride, B14Ga3Ni27: synthesis and crystal structure.
Tillard M, Belin C.
Inorg Chem. 2011 May 2;50(9):3907-12. Epub 2011 Apr 6.
PMID:
21469649
[PubMed]
A general solution route toward metal boride nanocrystals.
Portehault D, Devi S, Beaunier P, Gervais C, Giordano C, Sanchez C, Antonietti M.
Angew Chem Int Ed Engl. 2011 Mar 28;50(14):3262-5. doi: 10.1002/anie.201006810. Epub 2011 Feb 25. No abstract available.
PMID:
21432954
[PubMed]
Complete titanium substitution by boron in a tetragonal prism: exploring the complex boride series Ti(3-x)Ru(5-y)Ir(y)B(2+x) (0 = x = 1 and 1 < y < 3) by experiment and theory.
Fokwa BP, Hermus M.
Inorg Chem. 2011 Apr 18;50(8):3332-41. Epub 2011 Mar 23.
PMID:
21428308
[PubMed - in process]
Two-dimensional intrinsic ferromagnetism at nitride-boride interfaces.
Gohda Y, Tsuneyuki S.
Phys Rev Lett. 2011 Jan 28;106(4):047201. Epub 2011 Jan 25.
PMID:
21405354
[PubMed]
A General Solution Route toward Metal Boride Nanocrystals.
Portehault D, Devi S, Beaunier P, Gervais C, Giordano C, Sanchez C, Antonietti M.
Angew Chem Int Ed Engl. 2011 Mar 7. doi: 10.1002/anie.201101207. [Epub ahead of print] No abstract available.
PMID:
21384481
[PubMed - as supplied by publisher]
LiB(12) PC, the First Boron-Rich Metal Boride with Phosphorus-Synthesis, Crystal Structure, Hardness, Spectroscopic Investigations.
Vojteer N, Sagawe V, Stauffer J, Schroeder M, Hillebrecht H.
Chemistry. 2011 Feb 9. doi: 10.1002/chem.201002968. [Epub ahead of print]
PMID:
21308812
[PubMed - as supplied by publisher]
Effects of laser pulsing on analysis of steels by atom probe tomography.
Liu F, Andrén HO.
Ultramicroscopy. 2011 May;111(6):633-41. Epub 2010 Dec 19.
PMID:
21239116
[PubMed]
Binary boron-rich borides of magnesium: single-crystal investigations and properties of MgB(7) and the new boride Mg(~5)B(44).
Pediaditakis A, Schroeder M, Sagawe V, Ludwig T, Hillebrecht H.
Inorg Chem. 2010 Dec 6;49(23):10882-93. Epub 2010 Nov 2.
PMID:
21043472
[PubMed]
A photoelectrochemical immunosensor based on Au-doped TiO2 nanotube arrays for the detection of a-synuclein.
An Y, Tang L, Jiang X, Chen H, Yang M, Jin L, Zhang S, Wang C, Zhang W.
Chemistry. 2010 Dec 27;16(48):14439-46.
PMID:
21038326
[PubMed - indexed for MEDLINE]
Study on boron-film thermal neutron converter prepared by pulsed laser deposition.
Song ZF, Ye SZ, Chen ZY, Song L, Shen J.
Appl Radiat Isot. 2011 Feb;69(2):443-7. Epub 2010 Sep 25.
PMID:
20951052
[PubMed]
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