Cobalt(II) Acetylacetonate Hydrate

Co(CH3COCHCOCH3)2 • xH2O
CAS 123334-29-2


Product Product Code Order or Specifications
(2N) 99% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-02-P-XHYD Contact American Elements
(3N) 99.9% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-03-P-XHYD Contact American Elements
(4N) 99.99% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-04-P-XHYD Contact American Elements
(5N) 99.999% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-05-P-XHYD Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Co(C5H7O2)2 • xH2O 123334-29-2 34174534 20833133 MFCD00149056 237-855-6 cobalt(2+); (Z)-4-oxopent-2-en-2-olate; hydrate N/A CC(=CC(=O)
C)[O-].CC(=
CC(=O)C)
[O-].O.[Co+2]
InChI=1S/2C5H8
O2.Co.H2O/c2*1-
4(6)3-5(2)7;;/h2*3
,6H,1-2H3;;1H2/q
;;+2;/p-2/b2*4-3-;;
CCSRIP
NIKKQYH
L-SUKNR
PLKSA-L

PROPERTIES Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
C10H16CoO5 275.16 Pink powder N/A 275.032969 275.032969 0 Safety Data Sheet

Acetylaceton Formula Diagram (C5H8O2)Cobalt(II) Acetylacetonate is a Cobalt source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Cobalt Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cobalt(Co) atomic and molecular weight, atomic number and elemental symbolCobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195.Cobalt Bohr Model The number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental Cobalt Cobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit." For more information on cobalt, including properties, safety data, research, and American Elements' catalog of cobalt products, visit the Cobalt Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H302-H312-H318-H332-H351
Hazard Codes Xn
Risk Codes 20/21/22-40-41
Safety Precautions 7-22-26-37/39
RTECS Number N/A
Transport Information N/A
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Exclamation Mark-Acute Toxicity Health Hazard Corrosion-Corrosive to metals    

COBALT(II) ACETYLACETONATE HYDRATE SYNONYMS
(3Z)-4-Hydroxy-3-penten-2-one - cobalt hydrate (2:1:1), Bis(2,4-pentanedionato)cobalt(II) Dihydrate, Cobalt,bis(2,4-pentanedionato-kO,kO')-, hydrate, (SP-4-1)- (9CI), Bis(acetylacetonato)cobalt hydrate

CUSTOMERS FOR COBALT(II) ACETYLACETONATE HYDRATE HAVE ALSO LOOKED AT
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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Request an MSDS or Certificate of Analysis





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Recent Research & Development for Cobalt

  • Hui Fan, Michael Keane, Prabhakar Singh, Minfang Han, Electrochemical performance and stability of lanthanum strontium cobalt ferrite oxygen electrode with gadolinia doped ceria barrier layer for reversible solid oxide fuel cell, Journal of Power Sources, Volume 268, 5 December 2014
  • Panpan Xu, Ke Ye, Dianxue Cao, Jichun Huang, Tong Liu, Kui Cheng, Jinling Yin, Guiling Wang, Facile synthesis of cobalt manganese oxides nanowires on nickel foam with superior electrochemical performance, Journal of Power Sources, Volume 268, 5 December 2014
  • Hee-Je Kim, Su-Weon Kim, Chandu V.V.M. Gopi, Soo-Kyoung Kim, S. Srinivasa Rao, Myeong-Soo Jeong, Improved performance of quantum dot-sensitized solar cells adopting a highly efficient cobalt sulfide/nickel sulfide composite thin film counter electrode, Journal of Power Sources, Volume 268, 5 December 2014
  • Xuefei Gong, J.P. Cheng, Fu Liu, Li Zhang, Xiaobin Zhang, Nickel–Cobalt hydroxide microspheres electrodepositioned on nickel cobaltite nanowires grown on Ni foam for high-performance pseudocapacitors, Journal of Power Sources, Volume 267, 1 December 2014
  • Pouyan Paknahad, Masoud Askari, Milad Ghorbanzadeh, Application of sol–gel technique to synthesis of copper–cobalt spinel on the ferritic stainless steel used for solid oxide fuel cell interconnects, Journal of Power Sources, Volume 266, 15 November 2014
  • Alexander Schenk, Christoph Grimmer, Markus Perchthaler, Stephan Weinberger, Birgit Pichler, Christoph Heinzl, Christina Scheu, Franz-Andreas Mautner, Brigitte Bitschnau, Viktor Hacker, Platinum–cobalt catalysts for the oxygen reduction reaction in high temperature proton exchange membrane fuel cells – Long term behavior under ex-situ and in-situ conditions, Journal of Power Sources, Volume 266, 15 November 2014
  • Yaoming Xiao, Wei-Yan Wang, Shu-Wei Chou, Tsung-Wu Lin, Jeng-Yu Lin, In situ electropolymerization of polyaniline/cobalt sulfide decorated carbon nanotube composite catalyst toward triiodide reduction in dye-sensitized solar cells, Journal of Power Sources, Volume 266, 15 November 2014
  • Songying Liu, Ling Zhou, Liyuan Yao, Liya Chai, Li Li, Guo Zhang, Kankan, Keying Shi, One-pot reflux method synthesis of cobalt hydroxide nanoflake-reduced graphene oxide hybrid and their NOx gas sensors at room temperature, Journal of Alloys and Compounds, Volume 612, 5 November 2014
  • M.B. Lourenço, M.D. Carvalho, P. Fonseca, T. Gasche, G. Evans, M. Godinho, M.M. Cruz, Stability and magnetic properties of cobalt nitrides, Journal of Alloys and Compounds, Volume 612, 5 November 2014
  • Pankaj Kandwal, Prasanta Kumar Mohapatra, A highly efficient solvent system containing chlorinated cobalt dicarbollide in NPOE—Dodecane mixture for effective transport of radio-cesium from acidic wastes, Journal of Membrane Science, Volume 469, 1 November 2014
  • M.P. Popov, I.A. Starkov, S.F. Bychkov, A.P. Nemudry, Improvement of Ba0.5Sr0.5Co0.8Fe0.2O3-d functional properties by partial substitution of cobalt with tungsten, Journal of Membrane Science, Volume 469, 1 November 2014
  • Murat Rakap, Hydrogen generation from the hydrolytic dehydrogenation of ammonia borane using electrolessly deposited cobalt–phosphorus as reusable and cost-effective catalyst, Journal of Power Sources, Volume 265, 1 November 2014
  • L. Ajroudi, N. Mliki, L. Bessais, V. Madigou, S. Villain, Ch. Leroux, Magnetic, electric and thermal properties of cobalt ferrite nanoparticles, Materials Research Bulletin, Volume 59, November 2014
  • R. Ramchandra Kiran, R.A. Mondal, Sandhya Dwevedi, G. Markandeyulu, Structural, magnetic and magnetoelectric properties of Nb substituted Cobalt Ferrite, Journal of Alloys and Compounds, Volume 610, 15 October 2014
  • Jie Hou, Zhiwen Zhu, Jing Qian, Wei Liu, A new cobalt-free proton-blocking composite cathode La2NiO4+d–LaNi0.6Fe0.4O3-d for BaZr0.1Ce0.7Y0.2O3-d-based solid oxide fuel cells, Journal of Power Sources, Volume 264, 15 October 2014
  • Alamgir, Wasi Khan, Shabbir Ahmad, A.H. Naqvi, Formation of self-assembled spherical-flower like nanostructures of cobalt doped anatase TiO2 and its optical band-gap, Materials Letters, Volume 133, 15 October 2014
  • Mehdi Salehi, Mehdi Amirnasr, Soraia Meghdadi, Kurt Mereiter, Hamid R. Bijanzadeh, Ali Khaleghian, Synthesis, characterization, and X-ray crystal structure of cobalt(III) complexes with a N2O2-donor Schiff base and ancillary ligands. Spectral, antibacterial activity, and electrochemical studies, Polyhedron, Volume 81, 15 October 2014
  • T.L. Oliveira, L.H.G. Kalinke, E.J. Mascarenhas, R. Castro, F.T. Martins, J.R. Sabino, H.O. Stumpf, J. Ferrando, M. Julve, F. Lloret, D. Cangussu, Cobalt(II) and copper(II) assembling through a functionalized oxamate-type ligand, Polyhedron, Volume 81, 15 October 2014
  • Piotr Garczarek, Jan Janczak, Marek Duczmal, Jerzy Zon, The synthesis, structure and magnetic properties of two cobalt phosphonate salts, Polyhedron, Volume 81, 15 October 2014
  • Ankita Solanki, Sujit Baran Kumar, Syntheses and structural studies of cobalt(II), nickel(II), zinc(II) and cadmium(II) selenocyanate complexes with a tetradentate N4-donor ligand, Polyhedron, Volume 81, 15 October 2014

Recent Research & Development for Acetylacetonates

  • Sudipta Chatterjee, Sutanuva Mandal, Sucheta Joy, Chen-Hsiung Hung, Sreebrata Goswami, ortho-Carom–N bond fusion in aniline associated with electrophilic chlorination reactions at ruthenium(III) coordinated acetylacetonates, Inorganica Chimica Acta, Volume 374, Issue 1, 1 August 2011
  • János Madarász, Shoji Kaneko, Masayuki Okuya, György Pokol, Comparative evolved gas analyses of crystalline and amorphous titanium(IV)oxo-hydroxo-acetylacetonates by TG-FTIR and TG/DTA-MS, Thermochimica Acta, Volume 489, Issues 1–2, 20 May 2009
  • Satoshi Yoda, Yoko Mizuno, Takeshi Furuya, Yoshihiro Takebayashi, Katsuto Otake, Tomoya Tsuji, Toshihiko Hiaki, Solubility measurements of noble metal acetylacetonates in supercritical carbon dioxide by high performance liquid chromatography (HPLC), The Journal of Supercritical Fluids, Volume 44, Issue 2, March 2008
  • M. Aslam Siddiqi, Rehan A. Siddiqui, Burak Atakan, Thermal stability, sublimation pressures and diffusion coefficients of some metal acetylacetonates, Surface and Coatings Technology, Volume 201, Issues 22–23, 25 September 2007
  • María R. Pedrosa, Jaime Escribano, Rafael Aguado, Virginia Díez, Roberto Sanz, Francisco J. Arnáiz, Dinuclear oxomolybdenum(VI) acetylacetonates: Crystal and molecular structure of Mo2O5(acac)2L2 (L = D2O, DMF), Polyhedron, Volume 26, Issue 14, 31 August 2007
  • S.V. Samoilenkov, M.A. Stefan, G. Wahl, MOCVD of thick YSZ coatings using acetylacetonates, Surface and Coatings Technology, Volume 192, Issue 1, 1 March 2005
  • Thomas Behrsing, Alan M Bond, Glen B Deacon, Craig M Forsyth, Maria Forsyth, Kalpana J Kamble, Brian W Skelton, Allan H White, Cerium acetylacetonates—new aspects, including the lamellar clathrate [Ce(acac)4]·10H2O, Inorganica Chimica Acta, Volume 352, 6 August 2003
  • R Leboda, J Skubiszewska-Zięba, J Rynkowski, Preparation and porous structure of carbon–silica adsorbents obtained on the basis of Ti, Co, Ni, Cr, Zn and Zr acetylacetonates and acetylacetone, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 174, Issue 3, 1 December 2000
  • V.M. Gun'ko, R. Leboda, J. Skubiszewska-Ziȩba, J. Rynkowski, Silica Gel Modified Due to Pyrolysis of Acetylacetone and Metal (Ti, Cr, Co, Ni, Zn, Zr) Acetylacetonates, Journal of Colloid and Interface Science, Volume 231, Issue 1, 1 November 2000
  • V.G Isakova, I.A Baidina, N.B Morozova, I.K Igumenov, γ-Halogenated iridium(III) acetylacetonates, Polyhedron, Volume 19, Issue 9, 15 May 2000