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Cobalt(II) Acetylacetonate Hydrate

Co(CH3COCHCOCH3)2 • xH2O
CAS 123334-29-2


Product Product Code Request Quote
(2N) 99% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-02-P-XHYD Request Quote
(3N) 99.9% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-03-P-XHYD Request Quote
(4N) 99.99% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-04-P-XHYD Request Quote
(5N) 99.999% Cobalt(II) Acetylacetonate Hydrate CO2-ACAC-05-P-XHYD Request Quote

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Co(C5H7O2)2 • xH2O 123334-29-2 34174534 20833133 MFCD00149056 237-855-6 cobalt(2+); (Z)-4-oxopent-2-en-2-olate; hydrate N/A CC(=CC(=O)
C)[O-].CC(=
CC(=O)C)
[O-].O.[Co+2]
InChI=1S/2C5H8
O2.Co.H2O/c2*1-
4(6)3-5(2)7;;/h2*3
,6H,1-2H3;;1H2/q
;;+2;/p-2/b2*4-3-;;
CCSRIP
NIKKQYH
L-SUKNR
PLKSA-L

PROPERTIES Compound Formula Mol. Wt. Appearance Density Exact Mass Monoisotopic Mass Charge MSDS
C10H16CoO5 275.16 Pink powder N/A 275.032969 275.032969 0 Safety Data Sheet

Acetylaceton Formula Diagram (C5H8O2)Cobalt(II) Acetylacetonate is a Cobalt source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. Cobalt Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cobalt (Co) atomic and molecular weight, atomic number and elemental symbolCobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr Model The number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental Cobalt Cobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit." For more information on cobalt, including properties, safety data, research, and American Elements' catalog of cobalt products, visit the Cobalt element page.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H302-H312-H318-H332-H351
Hazard Codes Xn
Risk Codes 20/21/22-40-41
Safety Precautions 7-22-26-37/39
RTECS Number N/A
Transport Information N/A
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Exclamation Mark-Acute Toxicity Health Hazard Corrosion-Corrosive to metals    

COBALT(II) ACETYLACETONATE HYDRATE SYNONYMS
(3Z)-4-Hydroxy-3-penten-2-one - cobalt hydrate (2:1:1), Bis(2,4-pentanedionato)cobalt(II) Dihydrate, Cobalt,bis(2,4-pentanedionato-kO,kO')-, hydrate, (SP-4-1)- (9CI), Bis(acetylacetonato)cobalt hydrate

CUSTOMERS FOR COBALT(II) ACETYLACETONATE HYDRATE HAVE ALSO LOOKED AT
Cobalt Acetylacetonate Cobalt Sulfate Cobalt Bar Cobalt Oxide Nanopowder Cobalt Oxide Pellets
Cobalt Sputtering Target Cobalt Powder Cobalt Chloride Cobalt Nickel Chromium Alloy Cobalt Acetate
Cobalt Pellets Cobalt Foil Cobalt Molybdenum Alloy Cobalt Oxide Cobalt Metal
Show Me MORE Forms of Cobalt

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Cobalt

  • High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology Dependent Activity. Prashanth W. Menezes, Arindam Indra, Diego González-Flores, Nastaran Ranjbar Sahraie, Ivelina Zaharieva, Michael Schwarze, Peter Strasser, Holger Dau, and Matthias Driess. ACS Catal.: February 16, 2015
  • Light-Activated Protein Inhibition through Photoinduced Electron Transfer of a Ruthenium(II)-Cobalt(III) Bimetallic Complex. Robert J. Holbrook, David J. Weinberg, Mark D. Peterson, Emily A. Weiss, and Thomas J. Meade. J. Am. Chem. Soc.: February 11, 2015
  • In situ CobaltCobalt Oxide/N-Doped Carbon Hybrids As Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution. Haiyan Jin, Jing Wang, Diefeng Su, Zhongzhe Wei, Zhenfeng Pang, and Yong Wang. J. Am. Chem. Soc.: February 6, 2015
  • Cobalt-Embedded Nitrogen Doped Carbon Nanotubes: A Bifunctional Catalyst for Oxygen Electrode Reactions in a Wide pH Range. Zilong Wang, Shuang Xiao, Zonglong Zhu, Xia Long, Xiaoli Zheng, Xihong Lu, and Shihe Yang. ACS Appl. Mater. Interfaces: February 4, 2015
  • Carbon Dioxide/Epoxide Copolymerization via a Nanosized ZincCobalt(III) Double Metal Cyanide Complex: Substituent Effects of Epoxides on Polycarbonate Selectivity, Regioselectivity and Glass Transition Temperatures. Xing-Hong Zhang, Ren-Jian Wei, Ying?Ying Zhang, Bin-Yang Du, and Zhi-Qiang Fan. Macromolecules: January 29, 2015
  • Germanium Anode with Excellent Lithium Storage Performance in a Germanium/Lithium–Cobalt Oxide Lithium-Ion Battery. Xiuwan Li, Zhibo Yang, Yujun Fu, Li Qiao, Dan Li, Hongwei Yue, and Deyan He. ACS Nano: January 28, 2015
  • Global Mining Risk Footprint of Critical Metals Necessary for Low-Carbon Technologies: The Case of Neodymium, Cobalt, and Platinum in Japan. Keisuke Nansai, Kenichi Nakajima, Shigemi Kagawa, Yasushi Kondo, Yosuke Shigetomi, and Sangwon Suh. Environ. Sci. Technol.: 42030
  • Much Enhanced Catalytic Reactivity of Cobalt Chlorin Derivatives on Two-Electron Reduction of Dioxygen to Produce Hydrogen Peroxide. Kentaro Mase, Kei Ohkubo, and Shunichi Fukuzumi. Inorg. Chem.: January 22, 2015
  • Highly Active and Stable Hybrid Catalyst of Cobalt-Doped FeS2 Nanosheets–Carbon Nanotubes for Hydrogen Evolution Reaction. Di-Yan Wang, Ming Gong, Hung-Lung Chou, Chun-Jern Pan, Hsin-An Chen, Yingpeng Wu, Meng-Chang Lin, Mingyun Guan, Jiang Yang, Chun-Wei Chen, Yuh-Lin Wang, Bing-Joe Hwang, Chia-Chun Chen, and Hongjie Dai. J. Am. Chem. Soc.: January 14, 2015
  • Covalent Entrapment of Cobalt–Iron Sulfides in N-Doped Mesoporous Carbon: Extraordinary Bifunctional Electrocatalysts for Oxygen Reduction and Evolution Reactions. Mengxia Shen, Changping Ruan, Yan Chen, Chunhuan Jiang, Kelong Ai, and Lehui Lu. ACS Appl. Mater. Interfaces: December 22, 2014

Recent Research & Development for Acetylacetonates

  • An Oxygen-Chelate Complex, Palladium Bis-acetylacetonate, Induces Apoptosis in H460 Cells via Endoplasmic Reticulum Stress Pathway Rather than Interacting with DNA. Yi Wang, Jie Hu, Yuepiao Cai, Shanmei Xu, Bixia Weng, Kesong Peng, Xiaoyan Wei, Tao Wei, Huiping Zhou, Xiaokun Li, and Guang Liang. J. Med. Chem.: November 25, 2013
  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Chang Yi Kong, Tomoya Siratori, Guosheng Wang, Takeshi Sako, and Toshitaka Funazukuri. J. Chem. Eng. Data: October 15, 2013
  • Cyclometalated 4-Styryl-2-phenylpyridine Platinum(II) Acetylacetonate Complexes as Second-Order NLO Building Blocks for SHG Active Polymeric Films. Alessia Colombo, Claudia Dragonetti, Daniele Marinotto, Stefania Righetto, Dominique Roberto, Silvia Tavazzi, Muriel Escadeillas, Véronique Guerchais, Hubert Le Bozec, Abdou Boucekkine, and Camille Latouche. Organometallics: July 11, 2013
  • Single-Molecule Magnetism in Three Related {CoIII2DyIII2}-Acetylacetonate Complexes with Multiple Relaxation Mechanisms. Stuart K. Langley, Nicholas F. Chilton, Boujemaa Moubaraki, and Keith S. Murray. Inorg. Chem.: May 29, 2013
  • Oxidatively Induced P–O Bond Formation through Reductive Coupling between Phosphido and Acetylacetonate, 8-Hydroxyquinolinate, and Picolinate Groups. Andersson Arias, Juan Forniés, Consuelo Fortuño, and Antonio Martín , Piero Mastrorilli, Stefano Todisco, Mario Latronico, and Vito Gallo. Inorg. Chem.: April 18, 2013
  • Binding Modes of Carboxylate- and Acetylacetonate-Linked Chromophores to Homodisperse Polyoxotitanate Nanoclusters. Jesse D. Sokolow, Elzbieta Trzop, Yang Chen, Jiji Tang, Laura J. Allen, Robert H. Crabtree, Jason B. Benedict, and Philip Coppens. J. Am. Chem. Soc.: June 19, 2012
  • Dinuclear Cu(II) Complexes of Isomeric Bis-(3-acetylacetonate)benzene Ligands: Synthesis, Structure, and Magnetic Properties. Marzio Rancan, Alessandro Dolmella, Roberta Seraglia, Simonetta Orlandi, Silvio Quici, Lorenzo Sorace, Dante Gatteschi, and Lidia Armelao. Inorg. Chem.: April 19, 2012
  • Bis(acetylacetonate) Tungsten(IV) Complexes Containing a Basic Diazoalkane or Oxo Ligand. Chetna Khosla, Andrew B. Jackson, Peter S. White, and Joseph L. Templeton. Organometallics: January 17, 2012
  • Visible-Light-Driven Copper Acetylacetonate Decomposition by BiVO4. Shin-ichi Naya, Masanori Tanaka, Keisuke Kimura, and Hiroaki Tada. Langmuir: July 7, 2011
  • Metal-Acetylacetonate Synthesis Experiments: Which Is Greener?. M. Gabriela T. C. Ribeiro and Adélio A. S. C. Machado. J. Chem. Educ.: April 11, 2011