Bis(ethylcyclopentadienyl)cobalt(III) hexafluorophosphate  

C14C18CoF6P
CAS 52308-79-9


Product Product Code Order or Specifications
(2N) 99% Bis(ethylcyclopentadienyl)cobalt(III) hexafluorophosphate  CO-OM3-02-PF6 Contact American Elements
(3N) 99.9% Bis(ethylcyclopentadienyl)cobalt(III) hexafluorophosphate CO-OM3-03-PF6 Contact American Elements
(4N) 99.99% Bis(ethylcyclopentadienyl)cobalt(III) hexafluorophosphate CO-OM3-04-PF6 Contact American Elements
(5N) 99.999% Bis(ethylcyclopentadienyl)cobalt(III) hexafluorophosphate CO-OM3-05-PF6 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name SMILES
Identifier
InChI
Identifier
InChI
Key
Co(C7H9)2(PF6) 52308-79-9 40717351 16213736 MFCD01863702 N/A cobalt; ethylcyclopentane; hexafluorophosphate CC[C]1[CH]
[CH][CH][CH]
1.CC[C]1[CH]
[CH][CH][CH
]1.F[P-](F)
(F)(F)(F)F.[Co]
InChI=1S/2C7H9.
Co.F6P/c2*1-2-7
-5-3-4-6-7;;1-7(2,
3,4,5)6/h2*3-6H,
2H2,1H3;;/q;;;-1
OKNORMJNKPIKBH-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
C14C18CoF6P 390.19 Solid 148-151 °C N/A N/A 390.038227 390.038227 -1 Safety Data Sheet

Bis(ethylcyclopentadienyl)cobalt(III) hexafluorophosphate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cobalt(Co) atomic and molecular weight, atomic number and elemental symbolCobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195.Cobalt Bohr Model The number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar] 3d7 4s2The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental Cobalt Cobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit." For more information on cobalt, including properties, safety data, research, and American Elements' catalog of cobalt products, visit the Cobalt Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Warning
Hazard Statements H315-H319-H335
Hazard Codes Xi
Risk Codes 36/37/38
Safety Precautions 26-36
RTECS Number N/A
Transport Information N/A
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Exclamation Mark-Acute Toxicity        


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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Cobalt

  • Changbai Liu, Xiao Chi, Xingyi Liu, Shenglei Wang, Comparison of ethanol sensitivity based on cobalt–indium combined oxide nanotubes and nanofibers, Journal of Alloys and Compounds, Volume 616, 15 December 2014
  • E.M.S. Barbieri, E.P.C. Lima, M.F.F. Lelis, M.B.J.G. Freitas, Recycling of cobalt from spent Li-ion batteries as ß-Co(OH)2 and the application of Co3O4 as a pseudocapacitor, Journal of Power Sources, Volume 270, 15 December 2014
  • Baiju Vidyadharan, Radhiyah Abd Aziz, Izan Izwan Misnon, Gopinathan M. Anil Kumar, Jamil Ismail, Mashitah M. Yusoff, Rajan Jose, High energy and power density asymmetric supercapacitors using electrospun cobalt oxide nanowire anode, Journal of Power Sources, Volume 270, 15 December 2014
  • Chien-Te Hsieh, Yu-Fu Chen, Chun-Ting Pai, Chung-Yu Mo, Synthesis of lithium nickel cobalt manganese oxide cathode materials by infrared induction heating, Journal of Power Sources, Volume 269, 10 December 2014
  • John Wang, Justin Purewal, Ping Liu, Jocelyn Hicks-Garner, Souren Soukazian, Elena Sherman, Adam Sorenson, Luan Vu, Harshad Tataria, Mark W. Verbrugge, Degradation of lithium ion batteries employing graphite negatives and nickel–cobalt–manganese oxide + spinel manganese oxide positives: Part 1, aging mechanisms and life estimation, Journal of Power Sources, Volume 269, 10 December 2014
  • E.M.S. Barbieri, E.P.C. Lima, S.J. Cantarino, M.F.F. Lelis, M.B.J.G. Freitas, Recycling of spent ion-lithium batteries as cobalt hydroxide, and cobalt oxide films formed under a conductive glass substrate, and their electrochemical properties, Journal of Power Sources, Volume 269, 10 December 2014
  • Guiqiang Wang, Juan Zhang, Shuai Kuang, Shaomin Liu, Shuping Zhuo, The production of cobalt sulfide/graphene composite for use as a low-cost counter-electrode material in dye-sensitized solar cells, Journal of Power Sources, Volume 269, 10 December 2014
  • Mohamed Bakr Mohamed, M. Yehia, Cation distribution and magnetic properties of nanocrystalline gallium substituted cobalt ferrite, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • R.K. Panda, R. Muduli, S.K. Kar, D. Behera, Dielectric relaxation and conduction mechanism of cobalt ferrite nanoparticles, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • J.J. Ruan, C.P. Wang, S.Y. Yang, R. Kainuma, X.J. Liu, New cobalt-based intermetallic compound Co2VMn with B2 structure and phase equilibria in the Co–V–Mn ternary system, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Hui Fan, Michael Keane, Prabhakar Singh, Minfang Han, Electrochemical performance and stability of lanthanum strontium cobalt ferrite oxygen electrode with gadolinia doped ceria barrier layer for reversible solid oxide fuel cell, Journal of Power Sources, Volume 268, 5 December 2014
  • Panpan Xu, Ke Ye, Dianxue Cao, Jichun Huang, Tong Liu, Kui Cheng, Jinling Yin, Guiling Wang, Facile synthesis of cobalt manganese oxides nanowires on nickel foam with superior electrochemical performance, Journal of Power Sources, Volume 268, 5 December 2014
  • Hee-Je Kim, Su-Weon Kim, Chandu V.V.M. Gopi, Soo-Kyoung Kim, S. Srinivasa Rao, Myeong-Soo Jeong, Improved performance of quantum dot-sensitized solar cells adopting a highly efficient cobalt sulfide/nickel sulfide composite thin film counter electrode, Journal of Power Sources, Volume 268, 5 December 2014
  • Xuefei Gong, J.P. Cheng, Fu Liu, Li Zhang, Xiaobin Zhang, Nickel–Cobalt hydroxide microspheres electrodepositioned on nickel cobaltite nanowires grown on Ni foam for high-performance pseudocapacitors, Journal of Power Sources, Volume 267, 1 December 2014
  • Pouyan Paknahad, Masoud Askari, Milad Ghorbanzadeh, Application of sol–gel technique to synthesis of copper–cobalt spinel on the ferritic stainless steel used for solid oxide fuel cell interconnects, Journal of Power Sources, Volume 266, 15 November 2014
  • Alexander Schenk, Christoph Grimmer, Markus Perchthaler, Stephan Weinberger, Birgit Pichler, Christoph Heinzl, Christina Scheu, Franz-Andreas Mautner, Brigitte Bitschnau, Viktor Hacker, Platinum–cobalt catalysts for the oxygen reduction reaction in high temperature proton exchange membrane fuel cells – Long term behavior under ex-situ and in-situ conditions, Journal of Power Sources, Volume 266, 15 November 2014
  • Yaoming Xiao, Wei-Yan Wang, Shu-Wei Chou, Tsung-Wu Lin, Jeng-Yu Lin, In situ electropolymerization of polyaniline/cobalt sulfide decorated carbon nanotube composite catalyst toward triiodide reduction in dye-sensitized solar cells, Journal of Power Sources, Volume 266, 15 November 2014
  • Robert Iano?, Highly sinterable cobalt ferrite particles prepared by a modified solution combustion synthesis, Materials Letters, Volume 135, 15 November 2014
  • Songying Liu, Ling Zhou, Liyuan Yao, Liya Chai, Li Li, Guo Zhang, Kankan, Keying Shi, One-pot reflux method synthesis of cobalt hydroxide nanoflake-reduced graphene oxide hybrid and their NOx gas sensors at room temperature, Journal of Alloys and Compounds, Volume 612, 5 November 2014
  • M.B. Lourenço, M.D. Carvalho, P. Fonseca, T. Gasche, G. Evans, M. Godinho, M.M. Cruz, Stability and magnetic properties of cobalt nitrides, Journal of Alloys and Compounds, Volume 612, 5 November 2014

Recent Research & Development for Phosphates

  • Ercan Avci, Enhanced cathode performance of nano-sized lithium iron phosphate composite using polytetrafluoroethylene as carbon precursor, Journal of Power Sources, Volume 270, 15 December 2014
  • Yuexia Yang, Wenwen Xu, Ruisong Guo, Lan Liu, Shanshan Wang, Dong Xie, Yizao Wan, Synthesis and electrochemical properties of Zn-doped, carbon coated lithium vanadium phosphate cathode materials for lithium-ion batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Zhipeng Ma, Guangjie Shao, Xiujuan Qin, Yuqian Fan, Guiling Wang, Jianjun Song, Tingting Liu, Ionic conductor cerous phosphate and carbon hybrid coating LiFePO4 with improved electrochemical properties for lithium ion batteries, Journal of Power Sources, Volume 269, 10 December 2014
  • Sathasivam Pratheep Kumar, Buvaneswari Gopal, Synthesis and leachability study of a new cesium immobilized langbeinite phosphate: KCsFeZrP3O12, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Si-yao Guo, Song Han, Constructing a novel hierarchical 3D flower-like nano/micro titanium phosphate with efficient hydrogen evolution from water splitting, Journal of Power Sources, Volume 267, 1 December 2014
  • Pingxue Li, Yifei Yao, Junjie Chi, Haowei Hu, Chun Yang, Ziqiang Zhao, Guangju Zhang, 980 nm all-fiber NPR mode-locking Yb-doped phosphate fiber oscillator and its amplifier, Optics Communications, Volume 332, 1 December 2014
  • Tsuyoshi Honma, Atsushi Sato, Noriko Ito, Takuya Togashi, Kenji Shinozaki, Takayuki Komatsu, Crystallization behavior of sodium iron phosphate glass Na2 - xFe1 + 0.5xP2O7 for sodium ion batteries, Journal of Non-Crystalline Solids, Volume 404, 15 November 2014
  • Aleksandra Matraszek, Irena Szczygiel, Bogdan Szczygiel, Hydrothermal synthesis and characterization of Na3Y(PO4)2 phosphate, Journal of Alloys and Compounds, Volume 612, 5 November 2014
  • Hongyan Ma, Biwan Xu, Zongjin Li, Magnesium potassium phosphate cement paste: Degree of reaction, porosity and pore structure, Cement and Concrete Research, Volume 65, November 2014
  • A. Venkateswara Rao, V. Veeraiah, A.V. Prasada Rao, B. Kishore Babu, K.Vijaya Kumar, Influence of Zr4+ doping on structural, spectroscopic and conductivity studies of lithium titanium phosphate, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Chengbin Cao, Hao Li, Jun Li, Chen Liu, Huilin Yang, Bin Li, Mechanical reinforcement of injectable calcium phosphate cement/silk fibroin (SF) composite by mineralized SF, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Chi-Jen Shih, Pei-Shan Lu, Wen-Cheng Chen, Yeo-Wan Chiang, Chi-Sheng Chien, Evaluation of gentamicin encapsulated hierarchically meso-macroporous silica-based calcium phosphates glass powders, Ceramics International, Volume 40, Issue 9, Part B, November 2014
  • Emerson Colonetti, Eduardo Hobold Kammer, Agenor De Noni Junior, Chemically-bonded phosphate ceramics obtained from aluminum anodizing waste for use as coatings, Ceramics International, Volume 40, Issue 9, Part A, November 2014
  • Toshiki Miyazaki, Toru Tanaka, Yuki Shirosaki, Masakazu Kawashita, Yttrium phosphate microspheres with enriched phosphorus content prepared for radiotherapy of deep-seated cancer, Ceramics International, Volume 40, Issue 9, Part B, November 2014
  • Andrea Bencini, Francesco Bartoli, Claudia Caltagirone, Vito Lippolis, Zinc(II)-based fluorescent dyes: Luminescence modulation by phosphate anion binding, Dyes and Pigments, Volume 110, November 2014
  • Wanying Geng, Ge Zhu, Yurong Shi, Yuhua Wang, Luminescent characteristics of Dy3+ doped calcium zirconium phosphate CaZr4(PO4)6 (CZP) phosphor for warm-white LEDs, Journal of Luminescence, Volume 155, November 2014
  • Giulia Broglia, Consuelo Mugoni, Jincheng Du, Cristina Siligardi, Monia Montorsi, Lithium vanado-phosphate glasses: Structure and dynamics properties studied by molecular dynamics simulations, Journal of Non-Crystalline Solids, Volume 403, 1 November 2014
  • P. Rajesh, Urit Charoen In, Prapun Manyum, P. Ramasamy, Effect of the purity of starting materials on the growth and properties of potassium dihydrogen phosphate single crystals – A comparative study, Materials Research Bulletin, Volume 59, November 2014
  • Yakub Fam, Toyoko Imae, Jonathan Miras, Maria Martinez, Jordi Esquena, pH-dependent loading of Pt nanoparticles protected by dendrimer in calcium phosphate matrices, Microporous and Mesoporous Materials, Volume 198, 1 November 2014
  • Chun-Xiao Liu, Jun Xu, Wei-Nan Li, Xiao-Li Xu, Hai-Tao Guo, Wei Wei, Gen-Gen Wu, Yue Hu, Bo Peng, Fabrication and annealing optimization of oxygen-implanted Yb3+-doped phosphate glass planar waveguides, Optics & Laser Technology, Volume 63, November 2014