Cobalt Selenite is generally immediately available in most volumes. Hydrate or anhydrous forms may be purchased. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Cobalt is a Block D, Group 9, Period 4 element. The number of electrons in each of Cobalt's shells is 2, 8, 15, 2 and its electronic configuration is [Ar] 3d7 4s2. In its elemental form cobalt's CAS number is 7440-48-4. The cobalt atom has a radius of 125.3.pm and it's Van der Waals radius is 200.pm. Cobalt and its compounds are somewhat toxic by skin contact and moderately toxic by inhalation. Cobalt has a metallic permeability two thirds that of iron. It exists as a mixture of two allotropes over a wide temperature range. The transformation is slow and accounts in part for the wide variation in the physical properties of cobalt. It is alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many important uses. Samarium-cobalt is one of the highest strength magnet alloys known. Cobalt compounds produce a brilliant and permanent blue color in ceramic glazes, glass, pottery, tiles, and enamels. Co-60 is useful as a gamma ray source. Toxicity of cobalt and its compounds are mild by skin contact and moderate by ingestion. Cobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Cobalt was first discovered by George Brandt in 1737. The origin of the word Cobalt comes from the German word 'Kobalt or Kobold' which translates as "goblin", "elf" or "evil spirit". See Cobalt research below.
Selenium is a Block P, Group 16, Period 4 element. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electronic configuration is [Ar] 3d10 4s2 4p4. In its elemental form selenium's CAS number is 7782-49-2. The selenium atom has a radius of 116.pm and it's Van der Waals radius is 190.pm. The EPA does not classify selenium as carcinogenic, although selenium sulfide is a probable carcinogen. Selenates and selenites which are compounds of selenium, are highly toxic. Hydrogen selenide gas (SeH2) is the most acutely toxic compound of selenium. Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. of photocells and exposure meters for photographic use, as well as solar cells. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications. Selenium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Selenium was first discovered by Jons Berzelius in 1817. The origin of the name Selenium comes from the Greek word "Selênê" meaning moon. See selenium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Tetra-kis(3-cyano-pyridine-?N)bis-(thio-cyanato-?N)cobalt(II) 1,4-dioxane disolvate.
Diehr S, Wöhlert S, Boeckmann J, Näther C.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1898. Epub 2011 Nov 30.
PMID:
22199656
[PubMed - as supplied by publisher]
Bis(2,4-dioxo-5,5-diphenyl-imidazol-idin-ido-?N)bis-(propane-1,3-diamine-?N,N')cobalt(II).
Hu X, Jiang Q, Wang D, Liu H.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1885. Epub 2011 Nov 30.
PMID:
22199646
[PubMed - as supplied by publisher]
Poly[aqua-{?(3)-5-[(pyridin-2-ylmeth-yl)amino]-isophthalato-?N,N':O,O:O}cobalt(II)].
Zhu XH, Cheng XC.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1862. Epub 2011 Nov 30.
PMID:
22199630
[PubMed - as supplied by publisher]
catena-Poly[[[cis-aqua-dibromido-cobalt(II)]-?-(pyrazine-2-carb-oxy-lic acid)-?N,O:N] monohydrate].
Dares C, Fournier R, Lever AB.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1798-m1799. Epub 2011 Nov 23.
PMID:
22199583
[PubMed - as supplied by publisher]
Poly[di-?(2)-aqua-?(5)-(pyridine-2,6-dicarboxyl-ato)-?(3)-(pyridine-2,6-dicarboxyl-ato)-cobalt(II)disodium].
Boyko AN, Golenya IA, Izotova YA, Haukka M, Prisyazhnaya EV.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1782-m1783. Epub 2011 Nov 19.
PMID:
22199572
[PubMed - as supplied by publisher]
Diaqua-bis-(pyridine-2-sulfonato-?N,O)cobalt(II).
Li ZS, Ng SW.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1781. Epub 2011 Nov 19.
PMID:
22199571
[PubMed - as supplied by publisher]
Bis[tris-(ethyl-enediamine-?N,N')cobalt(III)] octa-kis-?-(3)-oxido-hexa-deca-?(2)-oxido-tetra-deca-oxido-?(12)-tetra-oxo-silicato-octa-molybdenum(VI)hexa-vanadium(IV,V) hexa-hydrate.
Lu YK, Tian MM, Xu SG, Lü RQ, Liu YQ.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1776-m1777. Epub 2011 Nov 19.
PMID:
22199568
[PubMed - as supplied by publisher]
Tetra-aqua-bis-(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetato)-cobalt(II) monohydrate.
Yang GR, Li GT.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1746-m1747. Epub 2011 Nov 12.
PMID:
22199545
[PubMed - as supplied by publisher]
Tetra-aqua-bis-[3-(pyridin-4-yl)benzoato-?N]cobalt(II).
Wang HR, Li GT.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1743. Epub 2011 Nov 12.
PMID:
22199542
[PubMed - as supplied by publisher]
Poly[[tetra-aqua-(?(4)-imidazole-4,5-dicarboxyl-ato)(?(3)-imidazole-4,5-dicarboxyl-ato)-?(3)-sulfato-?(2)-sulfato-cobalt(II)digadolinium(III)] monohydrate].
Zhu LC.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1741-m1742. Epub 2011 Nov 12.
PMID:
22199541
[PubMed - as supplied by publisher]
Hexaaqua-cobalt(II) bis-(5-acetyl-2-hy-droxy-benzoate) dihydrate.
Han LJ, Yang SP, Fu LL, Gao HL.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1733. Epub 2011 Nov 9.
PMID:
22199535
[PubMed - as supplied by publisher]
Dichlorido[(4E,11E)-5,7,12,14-tetra-benzyl-7,14-dimethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-4,11-diene]cobalt(III) perchlorate.
Roy TG, Hazari SK, Barua KK, Ng SW, Tiekink ER.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1722-m1723. Epub 2011 Nov 9.
PMID:
22199529
[PubMed - as supplied by publisher]
{1,2-Bis[(3,5-dimethyl-1H-pyrazol-1-yl-?N)meth-yl]benzene}-dichloridozinc(II).
Guzei IA, Spencer LC, Budhai A, Darkwa J.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1715-m1716. Epub 2011 Nov 9.
PMID:
22199525
[PubMed - as supplied by publisher]
catena-Poly[[bis-(2,4-dichloro-benzoato)bis-(methanol-?O)cobalt(II)]-?-4,4'-bipyridine-?N:N'].
Hyun MY, Kim PG, Kim C, Kim Y.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1705. Epub 2011 Nov 9.
PMID:
22199519
[PubMed - as supplied by publisher]
Bis(pentane-2,4-dionato-?O,O')(1,10-phenanthroline-?N,N')cobalt(II).
Perdih F.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1697. Epub 2011 Nov 5.
PMID:
22199513
[PubMed - as supplied by publisher]
Diaqua-bis-(dihydrogen 3-aza-niumyl-1-hy-droxy-propyl-idene-1,1-di-phos-phon-ato-?O,O')cobalt(II).
Tsaryk NV, Dudko AV, Kozachkova AN, Pekhnyo VI.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1694. Epub 2011 Nov 5.
PMID:
22199511
[PubMed - as supplied by publisher]
Tetra-aqua-bis-{3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzoato-?O}cobalt(II) dihydrate.
Bai L, Zhao J.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1689. Epub 2011 Nov 5.
PMID:
22199506
[PubMed - as supplied by publisher]
Tetra-aqua-bis-(2-methyl-1H-imidazole-?N)cobalt(II) naphthalene-1,5-disulfonate.
Jin Y.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1686. Epub 2011 Nov 5.
PMID:
22199503
[PubMed - as supplied by publisher]
Diaqua-bis-(dimethyl sulfoxide-?O)bis(saccharinato-?N)cobalt(II).
Potwana FS, Van Zyl WE.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1667-m1668. Epub 2011 Nov 5.
PMID:
22199492
[PubMed - as supplied by publisher]
Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles.
Roedel EQ, Cafasso DE, Lee KW, Pierce LM.
Toxicol Appl Pharmacol. 2011 Dec 16. [Epub ahead of print]
PMID:
22198552
[PubMed - as supplied by publisher]
Recent Research & Development for Selenite
Sodium selenite radiosensitizes hormone-refractory
prostate cancer xenograft tumors but Not intestinal crypt cells in In vivo. Tian J, Ning S, Knox SJ. Int J
Radiat Oncol Biol Phys. 2010 Jul 7. [Epub ahead of print] PubMed PMID: 20615620.
Development of morulae from the
oocytes of cultured sheep preantral follicles. Arunakumari G, Shanmugasundaram N, Rao VH. Theriogenology. 2010 Jul 6. [Epub
ahead of print] PubMed PMID: 20615540.
Aerobic biogenesis of selenium nanospheres by Bacillus
cereus isolated from coalmine soil. Dhanjal S, Cameotra SS. Microb Cell Fact. 2010 Jul 5;9(1):52. [Epub
ahead of print] PubMed PMID: 20602763.
Effect of selenium and vitamin E on oxidative stress in lambs
experimentally infected with Haemonchus contortus. do Reo Leal ML, de Camargo EV, Henrique Ross D, Molento MB, Dos Anjos Lopes
ST, da Rocha JB. Vet Res Commun. 2010 Jul 5.
[Epub ahead of print] PubMed PMID: 20607397.
Prevention
Effect in Selenite-Induced Cataract in Vivo and Antioxidative Effects in Vitro of
Crataegus pinnatifida Leaves. Wang T, Zhang P, Zhao C, Zhang Y, Liu H, Hu L, Gao X, Zhang D. Biol Trace Elem Res. 2010 Jul 2. [Epub ahead of
print] PubMed PMID: 20596791.
Speciation analysis of arsenic and
selenium compounds by CE-dynamic reaction cell-ICP-MS. Hsieh MW, Liu CL, Chen JH, Jiang SJ. Electrophoresis. 2010
Jul;31(13):2272-8. PubMed PMID: 20593404.
Response of nitrogen metabolism in lettuce plants subjected to
different doses and forms of selenium. Rios JJ, Blasco B, Rosales MA, Sanchez-Rodriguez E, Leyva R, Cervilla LM,
Romero L, Ruiz JM. J Sci Food Agric. 2010 Jun
10;90(11):1914-1919. [Epub ahead of print] PubMed PMID: 20602511.
Limited effects of
selenium substitution in the prevention of radiation-associated toxicities.
results of a randomized study in head and neck cancer patients. Büntzel J, Riesenbeck D, Glatzel M, Berndt-Skorka R, Riedel T, Mücke R,
Kisters K, Schönekaes KG, Schäfer U, Bruns F, Micke O. Anticancer Res.
2010 May;30(5):1829-32. PubMed PMID: 20592387.
Production of polyselenodipenicillamines, unique selenium compounds. Nishida H, Ando M, Itoh K, Ueda K, Nishida Y, Okamoto Y, Toda C, Kojima N. Chem Pharm
Bull (Tokyo). 2010;58(7):957-60. PubMed PMID: 20606346.
Characterization of Protein Targets of
Mammalian Thioredoxin Reductases. Turanov AA, Hatfield DL, Gladyshev VN. Methods Enzymol. 2010;474C:245-254. Epub 2010
Jun 20. PubMed PMID: 20609914.
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