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Chromium Bromide (CrBr2)
CrBr2

10049-25-9
Product Product Code Order or Specifications
(2N) 99% Chromium Bromide CR-BR-02 Contact American Elements
(3N) 99.9% Chromium Bromide CR-BR-03 Contact American Elements
(4N) 99.99% Chromium Bromide CR-BR-04 Contact American Elements
(5N) 99.999% Chromium Bromide CR-BR-05 Contact American Elements
Bromide IonChromium Bromide is a highly water soluble crystalline Chromium source for uses compatible with Bromides and lower (acidic) pH. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine. Chromium Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Chromium(Cr) atomic and molecular weight, atomic number and elemental symbolChromium is a Block D, Group 6, Period 4 element. The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electronic configuration is [Ar] 3d5 4s1. In its elemental form chromium's CAS number is 7440-47-3. The chromium atom has a radius of 124.9.pm and it's Van der Waals radius is 200.pm. Hexavalent chromium is toxic. Chromium is highly resistant to corrosion. This has led to its use in numerous alloying and steel producing applications. When chromium is added to glass or ceramic glazes, it produces a brilliant green. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used as a paint pigment for this purpose.Although chromium metal is an essential trace element, hexavalent Elemental Chromiumchromium (Cr(VI)) is especially toxic and carcinogenic. Recently, chromites have formed the basis for cathode compositions Chromium Bohr Modelfor oxygen generation and fuel cell applications. Chromium information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Chromium was first discovered by Anders Ekeberg in 1802. Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color. See Chromium research below.

Formula CAS No. Appearance Molecular Weight
CrBr2
10049-25-9 White Crystalline Solid 211.804
PRODUCT CATALOG Bromide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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Recent Research & Development for Chromium

  • trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0). Norlidah MN, Yazid MY, Shawkataly OB, Rosli MM, Fun HK. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1652-m1653. Epub 2011 Nov 2. PMID: 22199480 [PubMed - as supplied by publisher]

  • Preparation and characterization of La(III) encapsulated silica gel/chitosan composite and its metal uptake studies. Gandhi MR, Meenakshi S. J Hazard Mater. 2011 Nov 28. [Epub ahead of print] PMID: 22197561 [PubMed - as supplied by publisher]

  • Electro-migration of heavy metals in an aged electroplating contaminated soil affected by the coexisting hexavalent chromium. Zhang W, Zhuang L, Tong L, Lo IM, Qiu R. Chemosphere. 2011 Dec 23. [Epub ahead of print] PMID: 22197017 [PubMed - as supplied by publisher]

  • Angular momentum conservation in dipolar energy transfer. Guo D, Knight TE, McCusker JK. Science. 2011 Dec 23;334(6063):1684-7. PMID: 22194572 [PubMed - in process]

  • Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution. Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P. Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print] PMID: 22193863 [PubMed - as supplied by publisher]

  • Chromium and genomic stability. Wise SS, Wise JP Sr. Mutat Res. 2011 Dec 13. [Epub ahead of print] PMID: 22192535 [PubMed - as supplied by publisher]

  • A Theoretical Evaluation of Ethylene Insertion into Chromium Alkyl Bonds of Cp-Donor based Olefin Polymerization Catalysts. Xu R, Klatt G, Enders M, Koeppel H. J Phys Chem A. 2011 Dec 22. [Epub ahead of print] PMID: 22191673 [PubMed - as supplied by publisher]

  • Adsorption of hexavalent chromium from aqueous solution by modified corn stalk: A fixed-bed column study. Chen S, Yue Q, Gao B, Li Q, Xu X, Fu K. Bioresour Technol. 2011 Dec 3. [Epub ahead of print] PMID: 22189077 [PubMed - as supplied by publisher]

  • Occurrence of Multidrug-Resistant and Toxic-Metal Tolerant Enterococci in Fresh Feces from Urban Pigeons in Brazil. da Silva VL, Caçador NC, da Silva CD, Fontes CO, Garcia GD, Nicoli JR, Diniz CG. Microbes Environ. 2011 Dec 22. [Epub ahead of print] PMID: 22188908 [PubMed - as supplied by publisher]

  • Revision of a tibial baseplate using a customized oxinium component in a case of suspected metal allergy. A case report. Van Opstal N, Verheyden F. Acta Orthop Belg. 2011 Oct;77(5):691-5. PMID: 22187849 [PubMed - in process]

  • Retention Strength of Cobalt-Chromium vs Nickel-Chromium Titanium vs CP Titanium in a Cast Framework Association of Removable Partial Overdenture. Souza JE, Silva NR, Coelho PG, Zavanelli AC, Ferracioli RC, Zavanelli RA. J Contemp Dent Pract. 2011 May 1;12(3):179-86. PMID: 22186813 [PubMed - in process]

  • Metal analysis, phytotoxic, insecticidal and cytotoxic activities of selected medicinal plants of Khyber Pakhtunkhwa. Khuda F, Iqbal Z, Zakiullah -, Khan A, Nasir F, Muhammad N, Khan JA, Khan MS. Pak J Pharm Sci. 2012 Jan;25(1):51-58. PMID: 22186309 [PubMed - as supplied by publisher]

  • Correlation between metal allergy and treatment outcomes after ankle fracture fixation. So S, Harris IA, Naylor JM, Adie S, Mittal R. J Orthop Surg (Hong Kong). 2011 Dec;19(3):309-13. PMID: 22184160 [PubMed - in process]

  • Enhancement of the acute phase response to a lipopolysaccharide challenge in steers supplemented with chromium. Burdick NC, Bernhard BC, Carroll JA, Rathmann RJ, Johnson BJ. Innate Immun. 2011 Dec 16. [Epub ahead of print] PMID: 22180563 [PubMed - as supplied by publisher]

  • Identification and hexavalent chromium reduction characteristics of Pannonibacter phragmitetus. Shi Y, Chai L, Yang Z, Jing Q, Chen R, Chen Y. Bioprocess Biosyst Eng. 2011 Dec 18. [Epub ahead of print] PMID: 22179413 [PubMed - as supplied by publisher]

  • Exposure to particulate hexavalent chromium exacerbates allergic asthma pathology. Schneider BC, Constant SL, Patierno SR, Jurjus RA, Ceryak SM. Toxicol Appl Pharmacol. 2011 Dec 9. [Epub ahead of print] PMID: 22178736 [PubMed - as supplied by publisher]

  • Circulating levels of metals are related to carotid atherosclerosis in elderly. Lind PM, Olsén L, Lind L. Sci Total Environ. 2011 Dec 15. [Epub ahead of print] PMID: 22178028 [PubMed - as supplied by publisher]

  • Highly active nanoscale zero-valent iron (nZVI)-Fe(3)O(4) nanocomposites for the removal of chromium(VI) from aqueous solutions. Lv X, Xu J, Jiang G, Tang J, Xu X. J Colloid Interface Sci. 2011 Dec 1. [Epub ahead of print] PMID: 22177747 [PubMed - as supplied by publisher]

  • Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery. Lewis RC, Gaffney SH, Le MH, Unice KM, Paustenbach DJ. Int J Hyg Environ Health. 2011 Dec 14. [Epub ahead of print] PMID: 22177528 [PubMed - as supplied by publisher]

  • Simultaneous Synthesis of Both Rings of Chromenes via a Benzannulation/o-Quinone Methide Formation/Electrocyclization Cascade. Majumdar N, Korthals KA, Wulff WD. J Am Chem Soc. 2011 Dec 16. [Epub ahead of print] PMID: 22176537 [PubMed - as supplied by publisher]

 

Recent Research & Development for Bromides

  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

     

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