Potassium Hexacyanochromate(III) is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. Potassium Hexacyanochromate(III)
is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Potassium is a Block S, Group 1, Period 4 element. The number of electrons in each of Potassium's shells is 2, 8, 8, 1 and its electronic configuration is [Ar] 4s1. In its elemental form potassium's CAS number is 7440-09-7. The potassium atom has a radius of 227.2 .pm and it's Van der Waals radius is 275.pm. Potassium is not toxic. Potassium is the seventh most abundant element on earth. In its metallic form it is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other metals of the alkali group, the metal decomposes in water with the evolution of hydrogen. It catches fire spontaneously in water. In high purity, potassium compounds have numerous pharmacological, medical, and electronics applications. Important compounds include the hydroxide, nitrate, carbonate, chloride, bromide, iodide, and sulfate. Lower purity compounds are used in pyrotechnics for its violet color on ignition and in glass and ceramic glazes to produce this color. Potassium also used as a nutrient in plant growth. Potassium was first discovered by Sir Humphrey Davy in 1807. The origin of the element name comes from the English word 'potash' meaning pot ashes and the Arabic word 'qali' which means alkali. The symbol K originates from the Latin word 'kalium'. See Potassium research below.
Chromium is a Block D, Group 6, Period 4 element. The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electronic configuration is [Ar] 3d5 4s1. In its elemental form chromium's CAS number is 7440-47-3. The chromium atom has a radius of 124.9.pm and it's Van der Waals radius is 200.pm. Hexavalent chromium is toxic. Chromium is highly resistant to corrosion. This has led to its use in numerous alloying and steel producing applications. When chromium is added to glass or ceramic glazes, it produces a brilliant green. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used as a paint pigment for this purpose.Although chromium metal is an essential trace element, hexavalent chromium (Cr(VI)) is especially toxic and carcinogenic. Recently, chromites have formed the basis for cathode compositions for oxygen generation and fuel cell applications. Chromium information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Chromium was first discovered by Anders Ekeberg in 1802. Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color. See Chromium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Aluminum potassium sulfate and tannic Acid injection for hemorrhoids.
Lim SW.
J Korean Soc Coloproctol. 2012 Apr;28(2):73-7. Epub 2012 Apr 30.
PMID:
22606645
[PubMed - in process]
Suppression of Ribosomal Function Triggers Innate Immune Signaling through Activation of the NLRP3 Inflammasome.
Vyleta ML, Wong J, Magun BE.
PLoS One. 2012;7(5):e36044. Epub 2012 May 14.
PMID:
22606244
[PubMed - as supplied by publisher]
Stroke preceding autoimmune encephalitis with neuronal potassium channel antibody.
Simal P, Garcia-García AM, Serna-Candel C, Egido JA.
BMJ Case Rep. 2012 May 8;2012. pii: bcr0820114637. doi: 10.1136/bcr.08.2011.4637.
PMID:
22605845
[PubMed - in process]
Life-threatening hyperkalemia - an overlooked acute kidney injury with a serum creatinine rise in the 'normal' range.
Latus J, Braun N, Alscher MD, Kimmel M.
BMJ Case Rep. 2012 May 8;2012. pii: bcr0120125691. doi: 10.1136/bcr.01.2012.5691.
PMID:
22605836
[PubMed - in process]
Ethylene glycol ingestion masked by concomitant ethanol intoxication.
Head JM.
BMJ Case Rep. 2012 Mar 20;2012. pii: bcr1220115326. doi: 10.1136/bcr.12.2011.5326.
PMID:
22605713
[PubMed - in process]
Neuroanatomy of melanocortin-4 receptor pathway in the lateral hypothalamic area.
Cui H, Sohn JW, Gautron L, Funahashi H, Williams KW, Elmquist JK, Lutter M.
J Comp Neurol. 2012 May 17. doi: 10.1002/cne.23145. [Epub ahead of print]
PMID:
22605619
[PubMed - as supplied by publisher]
Microvascular responses to aldosterone in hamster cheek pouch microcirculation.
Lapi D, Emdin M, Mastantuono T, Sapio D, Santillo M, Colantuoni A.
Clin Hemorheol Microcirc. 2012 May 16. [Epub ahead of print]
PMID:
22596229
[PubMed - as supplied by publisher]
Prevalence and Factors Associated with Hyperkalemia in Predialysis Patients Followed in a Low-Clearance Clinic.
Sarafidis PA, Blacklock R, Wood E, Rumjon A, Simmonds S, Fletcher-Rogers J, Ariyanayagam R, Al-Yassin A, Sharpe C, Vinen K.
Clin J Am Soc Nephrol. 2012 May 17. [Epub ahead of print]
PMID:
22595825
[PubMed - as supplied by publisher]
Chemical punch packed in venoms makes centipedes excellent predators.
Yang S, Liu Z, Xiao Y, Li Y, Rong M, Liang S, Zhang Z, Yu H, King GF, Lai R.
Mol Cell Proteomics. 2012 May 17. [Epub ahead of print]
PMID:
22595790
[PubMed - as supplied by publisher]
21 Days head-down bed rest induces weakening of cell-mediated immunity - Some spaceflight findings confirmed in a ground-based analog.
Kelsen J, Bartels LE, Dige A, Hvas CL, Frings-Meuthen P, Boehme G, Thomsen MK, Fenger-Grøn M, Dahlerup JF.
Cytokine. 2012 May 15. [Epub ahead of print]
PMID:
22595648
[PubMed - as supplied by publisher]
Efficient production of ultrapure manganese oxides via electrodeposition.
Cheney MA, Joo SW, Banerjee A, Min BK.
J Colloid Interface Sci. 2012 Apr 25. [Epub ahead of print]
PMID:
22595552
[PubMed - as supplied by publisher]
Radiolytic formation of non-toxic Cr(III) from toxic Cr(VI) in formate containing aqueous solutions: A system for water treatment.
Djouider F.
J Hazard Mater. 2012 May 3. [Epub ahead of print]
PMID:
22595544
[PubMed - as supplied by publisher]
Comparative effect of angiotensin II type I receptor blockers and calcium channel blockers on laboratory parameters in hypertensive patients with type 2 diabetes.
Nishida Y, Takahashi Y, Nakayama T, Asai S.
Cardiovasc Diabetol. 2012 May 17;11(1):53. [Epub ahead of print]
PMID:
22594344
[PubMed - as supplied by publisher]
Functional significance of M-type potassium channels in nociceptive cutaneous sensory endings.
Passmore GM, Reilly JM, Thakur M, Keasberry VN, Marsh SJ, Dickenson AH, Brown DA.
Front Mol Neurosci. 2012;5:63. Epub 2012 May 14.
PMID:
22593734
[PubMed - in process]
Growth, root formation, and nutrient value of triticale plants fertilized with biosolids.
Rauw WM, Teglas MB, Chandra S, Forister ML.
ScientificWorldJournal. 2012;2012:467052. Epub 2012 Apr 19.
PMID:
22593686
[PubMed - in process]
Electrochemistry/mass spectrometry as a tool in the investigation of the potent skin sensitizer p-phenylenediamine and its reactivity toward nucleophiles.
Jahn S, Faber H, Zazzeroni R, Karst U.
Rapid Commun Mass Spectrom. 2012 Jun 30;26(12):1453-64. doi: 10.1002/rcm.6249.
PMID:
22592989
[PubMed - in process]
One-step sonochemical synthesis of a graphene oxide-manganese oxide nanocomposite for catalytic glycolysis of poly(ethylene terephthalate).
Park G, Bartolome L, Lee KG, Lee SJ, Kim DH, Park TJ.
Nanoscale. 2012 May 16. [Epub ahead of print]
PMID:
22592889
[PubMed - as supplied by publisher]
Interventions for non-oliguric hyperkalaemia in preterm neonates.
Vemgal P, Ohlsson A.
Cochrane Database Syst Rev. 2012 May 16;5:CD005257.
PMID:
22592703
[PubMed - in process]
Ultrasound assisted free radical polymerization of glycidyl methacrylate by a new disite phase-transfer catalyst system: A kinetic study.
Sankar K, Rajendran V.
Ultrason Sonochem. 2012 Feb 22. [Epub ahead of print]
PMID:
22592149
[PubMed - as supplied by publisher]
Comparison of the Effects of Sevoflurane, Isoflurane, and Desflurane on Microcirculation in Coronary Artery Bypass Graft Surgery.
Ozarslan NG, Ayhan B, Kanbak M, Celebiog?lu B, Demircin M, Ince C, Aypar U.
J Cardiothorac Vasc Anesth. 2012 May 14. [Epub ahead of print]
PMID:
22592139
[PubMed - as supplied by publisher]
trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).
Norlidah MN, Yazid MY, Shawkataly OB, Rosli MM, Fun HK.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1652-m1653. Epub 2011 Nov 2.
PMID:
22199480
[PubMed - as supplied by publisher]
Preparation and characterization of La(III) encapsulated silica gel/chitosan composite and its metal uptake studies.
Gandhi MR, Meenakshi S.
J Hazard Mater. 2011 Nov 28. [Epub ahead of print]
PMID:
22197561
[PubMed - as supplied by publisher]
Electro-migration of heavy metals in an aged electroplating contaminated soil affected by the coexisting hexavalent chromium.
Zhang W, Zhuang L, Tong L, Lo IM, Qiu R.
Chemosphere. 2011 Dec 23. [Epub ahead of print]
PMID:
22197017
[PubMed - as supplied by publisher]
Angular momentum conservation in dipolar energy transfer.
Guo D, Knight TE, McCusker JK.
Science. 2011 Dec 23;334(6063):1684-7.
PMID:
22194572
[PubMed - in process]
Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
[PubMed - as supplied by publisher]
Chromium and genomic stability.
Wise SS, Wise JP Sr.
Mutat Res. 2011 Dec 13. [Epub ahead of print]
PMID:
22192535
[PubMed - as supplied by publisher]
A Theoretical Evaluation of Ethylene Insertion into Chromium Alkyl Bonds of Cp-Donor based Olefin Polymerization Catalysts.
Xu R, Klatt G, Enders M, Koeppel H.
J Phys Chem A. 2011 Dec 22. [Epub ahead of print]
PMID:
22191673
[PubMed - as supplied by publisher]
Adsorption of hexavalent chromium from aqueous solution by modified corn stalk: A fixed-bed column study.
Chen S, Yue Q, Gao B, Li Q, Xu X, Fu K.
Bioresour Technol. 2011 Dec 3. [Epub ahead of print]
PMID:
22189077
[PubMed - as supplied by publisher]
Occurrence of Multidrug-Resistant and Toxic-Metal Tolerant Enterococci in Fresh Feces from Urban Pigeons in Brazil.
da Silva VL, Caçador NC, da Silva CD, Fontes CO, Garcia GD, Nicoli JR, Diniz CG.
Microbes Environ. 2011 Dec 22. [Epub ahead of print]
PMID:
22188908
[PubMed - as supplied by publisher]
Revision of a tibial baseplate using a customized oxinium component in a case of suspected metal allergy. A case report.
Van Opstal N, Verheyden F.
Acta Orthop Belg. 2011 Oct;77(5):691-5.
PMID:
22187849
[PubMed - in process]
Retention Strength of Cobalt-Chromium vs Nickel-Chromium Titanium vs CP Titanium in a Cast Framework Association of Removable Partial Overdenture.
Souza JE, Silva NR, Coelho PG, Zavanelli AC, Ferracioli RC, Zavanelli RA.
J Contemp Dent Pract. 2011 May 1;12(3):179-86.
PMID:
22186813
[PubMed - in process]
Metal analysis, phytotoxic, insecticidal and cytotoxic activities of selected medicinal plants of Khyber Pakhtunkhwa.
Khuda F, Iqbal Z, Zakiullah -, Khan A, Nasir F, Muhammad N, Khan JA, Khan MS.
Pak J Pharm Sci. 2012 Jan;25(1):51-58.
PMID:
22186309
[PubMed - as supplied by publisher]
Correlation between metal allergy and treatment outcomes after ankle fracture fixation.
So S, Harris IA, Naylor JM, Adie S, Mittal R.
J Orthop Surg (Hong Kong). 2011 Dec;19(3):309-13.
PMID:
22184160
[PubMed - in process]
Enhancement of the acute phase response to a lipopolysaccharide challenge in steers supplemented with chromium.
Burdick NC, Bernhard BC, Carroll JA, Rathmann RJ, Johnson BJ.
Innate Immun. 2011 Dec 16. [Epub ahead of print]
PMID:
22180563
[PubMed - as supplied by publisher]
Identification and hexavalent chromium reduction characteristics of Pannonibacter phragmitetus.
Shi Y, Chai L, Yang Z, Jing Q, Chen R, Chen Y.
Bioprocess Biosyst Eng. 2011 Dec 18. [Epub ahead of print]
PMID:
22179413
[PubMed - as supplied by publisher]
Exposure to particulate hexavalent chromium exacerbates allergic asthma pathology.
Schneider BC, Constant SL, Patierno SR, Jurjus RA, Ceryak SM.
Toxicol Appl Pharmacol. 2011 Dec 9. [Epub ahead of print]
PMID:
22178736
[PubMed - as supplied by publisher]
Circulating levels of metals are related to carotid atherosclerosis in elderly.
Lind PM, Olsén L, Lind L.
Sci Total Environ. 2011 Dec 15. [Epub ahead of print]
PMID:
22178028
[PubMed - as supplied by publisher]
Highly active nanoscale zero-valent iron (nZVI)-Fe(3)O(4) nanocomposites for the removal of chromium(VI) from aqueous solutions.
Lv X, Xu J, Jiang G, Tang J, Xu X.
J Colloid Interface Sci. 2011 Dec 1. [Epub ahead of print]
PMID:
22177747
[PubMed - as supplied by publisher]
Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.
Lewis RC, Gaffney SH, Le MH, Unice KM, Paustenbach DJ.
Int J Hyg Environ Health. 2011 Dec 14. [Epub ahead of print]
PMID:
22177528
[PubMed - as supplied by publisher]
Simultaneous Synthesis of Both Rings of Chromenes via a Benzannulation/o-Quinone Methide Formation/Electrocyclization Cascade.
Majumdar N, Korthals KA, Wulff WD.
J Am Chem Soc. 2011 Dec 16. [Epub ahead of print]
PMID:
22176537
[PubMed - as supplied by publisher]
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