Chromium Nickel Silicon Metal is
available as disc, granules, Ingot, pellets, powder, rod, wire, foil, and sputtering target. See research below. Ultra high purity and high purity forms also include metal powder, submicron powder and nanoscale, quantum dots, targets for thin film deposition, pellets for evaporation and single crystal or polycrystalline forms. Elements can also be introduced into alloys or other systems as compounds such as fluorides, oxides or chlorides or as solutions. Chromium Nickel Silicon Metal is generally immediately available in most volumes.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Chromium is a Block D, Group 6, Period 4 element. The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electronic configuration is [Ar] 3d5 4s1. In its elemental form chromium's CAS number is 7440-47-3. The chromium atom has a radius of 124.9.pm and it's Van der Waals radius is 200.pm. Hexavalent chromium is toxic. Chromium is highly resistant to corrosion. This has led to its use in numerous alloying and steel producing applications. When chromium is added to glass or ceramic glazes, it produces a brilliant green. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used as a paint pigment for this purpose.Although chromium metal is an essential trace element, hexavalent chromium (Cr(VI)) is especially toxic and carcinogenic. Recently, chromites have formed the basis for cathode compositions for oxygen generation and fuel cell applications. Chromium information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Chromium was first discovered by Anders Ekeberg in 1802. Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color. See Chromium research below.
Nickel is a Block D, Group 4, Period 4 element. The number of electrons in each of Nickel's shells is 2, 8, 16, 2 and its electronic configuration is [Ar]3d8 4s2. In its elemental form nickel's CAS number is 7440-02-0. Nickel is sometimes found free in nature but is more commonly found in ores. The nickel atom has a radius of 149.pm and it's Van der Waals radius is 163.pm. Nickel and its compounds are considered to be carcinogenic. Nickel carbonyl is a very toxic gas. It is extensively alloyed with iron, chromium, molybdenum, tungsten and other metals produce stainless and other anti-corrosive steel and other corrosion-resistant alloys. It is highly electronically conductive and has many applications as a result. It is the basis of the nickel hydride battery. Most recently, its conductive properties have made it an ideal component for ceramic anode formulations used in oxygen generation and solid oxide fuel cell applications. Catalytic nickel is used to hydrogenate vegetable oils. Nickel additions to glass and ceramic glazes impart a bright green. It is also used in pigments for this purpose. Nickel information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Nickel was first discovered by Alex Constedt in 1751. The name originates from the German word 'kupfernickel' which means false copper from the illusory copper color of the ore. See Nickel research below.
Silicon is a Block P, Group 14, Period 3 element. The number of electrons in each of Silicon's shells is 2, 8, 4 and its electronic configuration is [Ne] 3s2 3p2. In its elemental form silicon's CAS number is 7440-21-3. The silicon atom has a radius of 117.6.pm and it's Van der Waals radius is 210.pm. Silicon is not toxic but can cause chronic respiratory problems if inhaled as a fine silica or silicate dust. Asbestos silicates are carcinogenic. Silicon is one of man's most useful elements. It makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, being exceeded only by oxygen. The Czochralski process is commonly used to produce single crystals of silicon used for solid-state or semiconductor devices. Silica, as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Silicon is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Ultra high purity silicon can be doped with boron, gallium, phosphorus , or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics and space-age industries. Hydrogenated amorphous silicon has shown promise in producing economical cells for converting solar energy into electricity. Silcones are important products of silicon. They range from liquids to hard, glasslike solids with many useful properties. Silicon was first discovered by Jons Berzelius in 1823. The name Silicon originates from the Latin word "silex" which means flint or hard stone. See Silicon research below.
trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).
Norlidah MN, Yazid MY, Shawkataly OB, Rosli MM, Fun HK.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1652-m1653. Epub 2011 Nov 2.
PMID:
22199480
[PubMed - as supplied by publisher]
Preparation and characterization of La(III) encapsulated silica gel/chitosan composite and its metal uptake studies.
Gandhi MR, Meenakshi S.
J Hazard Mater. 2011 Nov 28. [Epub ahead of print]
PMID:
22197561
[PubMed - as supplied by publisher]
Electro-migration of heavy metals in an aged electroplating contaminated soil affected by the coexisting hexavalent chromium.
Zhang W, Zhuang L, Tong L, Lo IM, Qiu R.
Chemosphere. 2011 Dec 23. [Epub ahead of print]
PMID:
22197017
[PubMed - as supplied by publisher]
Angular momentum conservation in dipolar energy transfer.
Guo D, Knight TE, McCusker JK.
Science. 2011 Dec 23;334(6063):1684-7.
PMID:
22194572
[PubMed - in process]
Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
[PubMed - as supplied by publisher]
Chromium and genomic stability.
Wise SS, Wise JP Sr.
Mutat Res. 2011 Dec 13. [Epub ahead of print]
PMID:
22192535
[PubMed - as supplied by publisher]
A Theoretical Evaluation of Ethylene Insertion into Chromium Alkyl Bonds of Cp-Donor based Olefin Polymerization Catalysts.
Xu R, Klatt G, Enders M, Koeppel H.
J Phys Chem A. 2011 Dec 22. [Epub ahead of print]
PMID:
22191673
[PubMed - as supplied by publisher]
Adsorption of hexavalent chromium from aqueous solution by modified corn stalk: A fixed-bed column study.
Chen S, Yue Q, Gao B, Li Q, Xu X, Fu K.
Bioresour Technol. 2011 Dec 3. [Epub ahead of print]
PMID:
22189077
[PubMed - as supplied by publisher]
Occurrence of Multidrug-Resistant and Toxic-Metal Tolerant Enterococci in Fresh Feces from Urban Pigeons in Brazil.
da Silva VL, Caçador NC, da Silva CD, Fontes CO, Garcia GD, Nicoli JR, Diniz CG.
Microbes Environ. 2011 Dec 22. [Epub ahead of print]
PMID:
22188908
[PubMed - as supplied by publisher]
Revision of a tibial baseplate using a customized oxinium component in a case of suspected metal allergy. A case report.
Van Opstal N, Verheyden F.
Acta Orthop Belg. 2011 Oct;77(5):691-5.
PMID:
22187849
[PubMed - in process]
Retention Strength of Cobalt-Chromium vs Nickel-Chromium Titanium vs CP Titanium in a Cast Framework Association of Removable Partial Overdenture.
Souza JE, Silva NR, Coelho PG, Zavanelli AC, Ferracioli RC, Zavanelli RA.
J Contemp Dent Pract. 2011 May 1;12(3):179-86.
PMID:
22186813
[PubMed - in process]
Metal analysis, phytotoxic, insecticidal and cytotoxic activities of selected medicinal plants of Khyber Pakhtunkhwa.
Khuda F, Iqbal Z, Zakiullah -, Khan A, Nasir F, Muhammad N, Khan JA, Khan MS.
Pak J Pharm Sci. 2012 Jan;25(1):51-58.
PMID:
22186309
[PubMed - as supplied by publisher]
Correlation between metal allergy and treatment outcomes after ankle fracture fixation.
So S, Harris IA, Naylor JM, Adie S, Mittal R.
J Orthop Surg (Hong Kong). 2011 Dec;19(3):309-13.
PMID:
22184160
[PubMed - in process]
Enhancement of the acute phase response to a lipopolysaccharide challenge in steers supplemented with chromium.
Burdick NC, Bernhard BC, Carroll JA, Rathmann RJ, Johnson BJ.
Innate Immun. 2011 Dec 16. [Epub ahead of print]
PMID:
22180563
[PubMed - as supplied by publisher]
Identification and hexavalent chromium reduction characteristics of Pannonibacter phragmitetus.
Shi Y, Chai L, Yang Z, Jing Q, Chen R, Chen Y.
Bioprocess Biosyst Eng. 2011 Dec 18. [Epub ahead of print]
PMID:
22179413
[PubMed - as supplied by publisher]
Exposure to particulate hexavalent chromium exacerbates allergic asthma pathology.
Schneider BC, Constant SL, Patierno SR, Jurjus RA, Ceryak SM.
Toxicol Appl Pharmacol. 2011 Dec 9. [Epub ahead of print]
PMID:
22178736
[PubMed - as supplied by publisher]
Circulating levels of metals are related to carotid atherosclerosis in elderly.
Lind PM, Olsén L, Lind L.
Sci Total Environ. 2011 Dec 15. [Epub ahead of print]
PMID:
22178028
[PubMed - as supplied by publisher]
Highly active nanoscale zero-valent iron (nZVI)-Fe(3)O(4) nanocomposites for the removal of chromium(VI) from aqueous solutions.
Lv X, Xu J, Jiang G, Tang J, Xu X.
J Colloid Interface Sci. 2011 Dec 1. [Epub ahead of print]
PMID:
22177747
[PubMed - as supplied by publisher]
Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.
Lewis RC, Gaffney SH, Le MH, Unice KM, Paustenbach DJ.
Int J Hyg Environ Health. 2011 Dec 14. [Epub ahead of print]
PMID:
22177528
[PubMed - as supplied by publisher]
Simultaneous Synthesis of Both Rings of Chromenes via a Benzannulation/o-Quinone Methide Formation/Electrocyclization Cascade.
Majumdar N, Korthals KA, Wulff WD.
J Am Chem Soc. 2011 Dec 16. [Epub ahead of print]
PMID:
22176537
[PubMed - as supplied by publisher]
Regioselective Cycloaddition of 3-Azetidinones and 3-Oxetanones with Alkynes through Nickel-Catalysed Carbon-Carbon Bond Activation.
Y T Ho K, Aïssa C.
Chemistry. 2012 Feb 22. doi: 10.1002/chem.201200167. [Epub ahead of print]
PMID:
22359347
[PubMed - as supplied by publisher]
The hydrogen evolution reaction in a room temperature ionic liquid: mechanism and electrocatalyst trends.
Meng Y, Aldous L, Belding SR, Compton RG.
Phys Chem Chem Phys. 2012 Feb 22. [Epub ahead of print]
PMID:
22358388
[PubMed - as supplied by publisher]
A cytosolic Ni(II) sensor in a cyanobacterium: Nickel-detection follows nickel-affinity across four families of metal-sensors.
Foster AW, Patterson CJ, Pernil R, Hess CR, Robinson NJ.
J Biol Chem. 2012 Feb 22. [Epub ahead of print]
PMID:
22356910
[PubMed - as supplied by publisher]
Incorporation of metal and color alteration of enamel in the presence of orthodontic appliances.
Gurgel Maia LH, de Lima Filho HL, Araújo MV, de Oliveira Ruellas AC, de Souza Araújo MT.
Angle Orthod. 2012 Feb 23. [Epub ahead of print]
PMID:
22356704
[PubMed - as supplied by publisher]
Nickel(II) and Palladium(II) Thiaethyneporphyrins. Intramolecular Metal(II)-?(2)-CC Interaction inside a Porphyrinoid Frame.
Nojman E, Berlicka A, Szterenberg L, Latos-Grazynski L.
Inorg Chem. 2012 Feb 22. [Epub ahead of print]
PMID:
22356285
[PubMed - as supplied by publisher]
General preparation for Pt-based alloy nanoporous nanoparticles as potential nanocatalysts.
Wang D, Zhao P, Li Y.
Sci Rep. 2011;1:37. Epub 2011 Jul 14.
PMID:
22355556
[PubMed - in process]
Pentacoordinate Ni(II) Complexes: Preparation, Magnetic Measurements, and Ab Initio Calculations of the Magnetic Anisotropy Terms.
Costes JP, Maurice R, Vendier L.
Chemistry. 2012 Feb 22. doi: 10.1002/chem.201103641. [Epub ahead of print]
PMID:
22354459
[PubMed - as supplied by publisher]
[Measurement of carbon dioxide in emergency medicine].
Timmermann A, Brokmann JC, Fitzka R, Nickel EA.
Anaesthesist. 2012 Feb;61(2):148-55. German.
PMID:
22354403
[PubMed - in process]
[Care Counselling - The Client's Expectations.]
Nickel W, Hanns S, Brähler E, Born A.
Gesundheitswesen. 2012 Feb 21. [Epub ahead of print] German.
PMID:
22354362
[PubMed - as supplied by publisher]
Community-based partnered research: new directions in mental health services research.
Alegría M, Wong Y, Mulvaney-Day N, Nillni A, Proctor E, Nickel M, Jones L, Green B, Koegel P, Wright A, Wells KB.
Ethn Dis. 2011 Summer;21(3 Suppl 1):S1-8-16.
PMID:
22352075
[PubMed - in process]
Inverse Suspension Polymerization as a New Tool for the Synthesis of Ion-Imprinted Polymers.
Meouche W, Branger C, Beurroies I, Denoyel R, Margaillan A.
Macromol Rapid Commun. 2012 Feb 21. doi: 10.1002/marc.201200039. [Epub ahead of print]
PMID:
22351426
[PubMed - as supplied by publisher]
Isolation and characterization of Bacillus cereus IST105 from electroplating effluent for detoxification of hexavalent chromium.
Naik UC, Srivastava S, Thakur IS.
Environ Sci Pollut Res Int. 2012 Feb 16. [Epub ahead of print]
PMID:
22351260
[PubMed - as supplied by publisher]
Production of a his-tagged canecystatin in transgenic sugarcane.
Henrique-Silva F, Soares-Costa A.
Methods Mol Biol. 2012;847:437-50.
PMID:
22351027
[PubMed - in process]
Seasonal variation in heavy metal contamination in water and sediments of river Sabarmati and Kharicut canal at Ahmedabad, Gujarat.
Kumar RN, Solanki R, Kumar JI.
Environ Monit Assess. 2012 Feb 21. [Epub ahead of print]
PMID:
22350445
[PubMed - as supplied by publisher]
Dakin-West reaction on 1-thyminyl acetic acid for the synthesis of 1,3-bis(1-thyminyl)-2-propanone, a heteroaromatic compound with nucleopeptide-binding properties.
Roviello GN, Roviello G, Musumeci D, Bucci EM, Pedone C.
Amino Acids. 2012 Feb 15. [Epub ahead of print]
PMID:
22349760
[PubMed - as supplied by publisher]
The chain structure of [Ni(C(4)H(2)O(4))(C(12)H(8)N(2))(H(2)O)](n) with different types of fumarate bridging.
Uhrinová A, Kuchár J, Cernák J.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m92-3. Epub 2012 Jan 7.
PMID:
22346891
[PubMed - in process]
trans-Tetra-aqua-bis-(isonicotinamide-?N)nickel(II) bis-(3-hy-droxy-benzoate) tetra-hydrate.
Zaman IG, Caylak Delibas N, Necefoglu H, Hökelek T.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m200-1. Epub 2012 Jan 21.
PMID:
22346867
[PubMed - in process]
{4,4',6,6'-Tetra-chloro-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]}nickel(II).
Kargar H, Kia R, Abbasian S, Tahir MN.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m193. Epub 2012 Jan 21.
PMID:
22346862
[PubMed - in process]
trans-Tetra-kis(1-allyl-1H-imidazole-?N)bis-(thio-cyanato-?N)nickel(II).
Zheng SM, Jin YL.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m188-9. Epub 2012 Jan 21.
PMID:
22346859
[PubMed - in process]
Poly[aqua-[?(3)-4-carb-oxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxyl-ato-?N,O:N,O:N]nickel(II)].
Jing XM, Gong SZ, Xiao LW.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m187. Epub 2012 Jan 21.
PMID:
22346858
[PubMed - in process]
Recent Research & Development for Metals
Rapid syntheses of a metal-organic framework material Cu(3)(BTC)(2)(H(2)O)(3) under microwave: a quantitative analysis of accelerated syntheses. Khan NA, Haque E, Jhung SH. Phys Chem Chem Phys. 2010 Mar 20;12(11):2625-31. Epub 2010 Jan 6. PMID: 20200739 [PubMed - in process]
Improved reliability from a plasma-assisted metal-insulator-metal capacitor comprising a high-k HfO(2) film on a flexible polyimide substrate. Singh Meena J, Chu MC, Kuo SW, Chang FC, Ko FH. Phys Chem Chem Phys. 2010 Mar 20;12(11):2582-9. Epub 2010 Jan 26. PMID: 20200734 [PubMed - in process]
Rational synthesis and characterization of porous Cu(ii) coordination polymers. Noro S. Phys Chem Chem Phys. 2010 Mar 20;12(11):2519-31. Epub 2010 Jan 18. PMID: 20200727 [PubMed - in process]
Construction of a monoanionic S,N,S-pincer ligand with a pyrrole core by sequential [1,2] phospho-Fries rearrangement. Characterization of palladium and silver coordination complexes. Fraix A, Lutz M, Spek AL, Gebbink RJ, van Koten G, Salaün JY, Jaffrès PA. Dalton Trans. 2010 Mar 21;39(11):2942-6. Epub 2010 Feb 5. PMID: 20200723 [PubMed - in process]
Zwitterionic dicopper helicates: anion encapsulation and binding studies. Wenzel M, Bruere SR, Knapp QW, Tasker PA, Plieger PG. Dalton Trans. 2010 Mar 21;39(11):2936-41. Epub 2010 Feb 8. PMID: 20200722 [PubMed - in process]
Organic-soluble optically pure anionic metal complexes PPh(4)[M(III)(S,S-EDDS)].2H(2)O (M = Fe, Co, Cr). Chmel NP, Howson SE, Allan LE, Barker J, Clarkson GJ, Turner SS, Scott P. Dalton Trans. 2010 Mar 21;39(11):2919-27. Epub 2010 Feb 9. PMID: 20200720 [PubMed - in process]
Crystallographic elucidation of purely structural, thermal and light-induced spin transitions in an iron(ii) binuclear complex. Kaiba A, Shepherd HJ, Fedaoui D, Rosa P, Goeta AE, Rebbani N, Létard JF, Guionneau P. Dalton Trans. 2010 Mar 21;39(11):2910-8. Epub 2010 Feb 9. PMID: 20200719 [PubMed - in process]
Anionic zinc-trimesic acid MOFs with unusual topologies: Reversible hydration studies. Davies K, Bourne SA, Ohrström L, Oliver CL. Dalton Trans. 2010 Mar 21;39(11):2869-74. Epub 2010 Feb 5. PMID: 20200714 [PubMed - in process]
A hexadentate bis(thiosemicarbazonato) ligand: rhenium(v), iron(iii) and cobalt(iii) complexes. Paterson BM, White JM, Donnelly PS. Dalton Trans. 2010 Mar 21;39(11):2831-7. Epub 2010 Feb 5. PMID: 20200709 [PubMed - in process]
Cu(ii) and Ni(ii) dioxotetraamine complexes integrated with tetrathiafulvalene moiety; structures and solution chemistry. Lu ZJ, Wang JP, Zhu QY, Huo LB, Qin YR, Dai J. Dalton Trans. 2010 Mar 21;39(11):2798-803. Epub 2010 Feb 9. PMID: 20200705 [PubMed - in process]
Synthesis, structure, and magnetic properties of bis(monosubstituted-pyrazine)dihalocopper(ii). Herringer SN, Longendyke AJ, Turnbull MM, Landee CP, Wikaira JL, Jameson GB, Telfer SG. Dalton Trans. 2010 Mar 21;39(11):2785-97. Epub 2010 Feb 4. PMID: 20200704 [PubMed - in process]
Tailor made synthesis of amphiphilic azoaromatics via regioselective C-N bond fusion. Comparative studies of surface properties of the two positional isomers and cobalt complexes. Joy S, Pal P, Mahato M, Talapatra GB, Goswami S. Dalton Trans. 2010 Mar 21;39(11):2775-84. Epub 2010 Feb 15. PMID: 20200703 [PubMed - in process]
Rational design of diphosphorus ligands - a route to superior catalysts. Gillespie JA, Dodds DL, Kamer PC. Dalton Trans. 2010 Mar 21;39(11):2751-64. Epub 2010 Jan 4. PMID: 20200699 [PubMed - in process]
Revascularization options in patients with chronic kidney disease. Ashrith G, Elayda MA, Wilson JM. Tex Heart Inst J. 2010;37(1):9-18. PMID: 20200622 [PubMed - in process]
[Antiplatelet treatment after percutaneous coronary intervention in a patient with idiopathic thrombocytopenic purpura.] Can MM, Tanboga IH, Boztosun B, Kaymaz C. Turk Kardiyol Dern Ars. 2009 Dec;37(8):575-7. Turkish.
Imaging and manipulation of the competing electronic phases near the Mott metal-insulator transition. Kim TH, Angst M, Hu B, Jin R, Zhang XG, Wendelken JF, Plummer EW, Li AP. Proc Natl Acad Sci U S A. 2010 Mar 3. [Epub ahead of print] PMID: 20200312 [PubMed - as supplied by publisher]
Respiratory Symptoms and Exposure-Response Relations in Workers exposed to Metalworking Fluid Aerosols. Lillienberg L, Andersson EM, Järvholm B, Torén K. Ann Occup Hyg. 2010 Mar 3. [Epub ahead of print] PMID: 20200090 [PubMed - as supplied by publisher]
Influences of properties of protein and adsorption surface on removal kinetics of protein adsorbed on metal surface by H(2)O(2)-electrolysis treatment. Imamura K, Oshita M, Iwai M, Kuroda T, Watanabe I, Sakiyama T, Nakanishi K. J Colloid Interface Sci. 2010 Feb 1. [Epub ahead of print] PMID: 20199779 [PubMed - as supplied by publisher]
Estimation of Risk Assessment of Some Heavy Metals Intake Through Black Scabbardfish (Aphanopus carbo) Consumption in Portugal. Cardoso C, Farias I, Costa V, Nunes M, Gordo L. Risk Anal. 2010 Feb 23. [Epub ahead of print] PMID: 20199650 [PubMed - as supplied by publisher]
Spectroscopic and Computational Studies of a mu-eta(2):eta(2)-Disulfido-Bridged Dinickel(II) Species, [{(PhTt(tBu))Ni}(2)(mu-eta(2):eta(2)-S(2))]: Comparison of Side-On Disulfido and Peroxo Bonding in (Ni(II))(2) and (Cu(II))(2) Species. Van Heuvelen KM, Cho J, Riordan CG, Brunold TC. Inorg Chem. 2010 Mar 3. [Epub ahead of print] PMID: 20199100 [PubMed - as supplied by publisher]
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