Chromium is a Block D, Group 6, Period 4 element. The number of electrons in each of Chromium's shells is 2, 8, 13, 1 and its electronic configuration is [Ar] 3d5 4s1. In its elemental form chromium's CAS number is 7440-47-3. The chromium atom has a radius of 124.9.pm and it's Van der Waals radius is 200.pm. Hexavalent chromium is toxic. Chromium is highly resistant to corrosion. This has led to its use in numerous alloying and steel producing applications. When chromium is added to glass or ceramic glazes, it produces a brilliant green. Chromium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is also used as a paint pigment for this purpose.Although chromium metal is an essential trace element, hexavalent chromium (Cr(VI)) is especially toxic and carcinogenic. Recently, chromites have formed the basis for cathode compositions for oxygen generation and fuel cell applications. Chromium information, including Technical Data, Safety Data and its High Purity properties, research, applications and other useful facts are discussed here. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Chromium was first discovered by Anders Ekeberg in 1802. Due to its various colorful compounds, Chromium was named after the Greek word 'chroma' meaning color. See Chromium research below.
Tin is a Block P, Group 14, Period 5 element. The number of electrons in each of Tin's shells is 2, 8, 18, 18, 4 and its electronic configuration is [Kr] 4d10 5s2 5p2. In its elemental form tin's CAS number is 7440-31-5. The tin atom has a radius of 140.5.pm and it's Van der Waals radius is 217.pm. Organometallic compounds of tin are very toxic and tin salts are also considered to be toxic. Tin as single atoms or molecules are not toxic. Tin compounds sprayed onto glass are used to produce electrically conductive coatings. These have been used for panel lighting and for frost-free windshields. Most window glass is now made by floating molten glass on molten tin (float glass) to produce a flat surface. Crystalline tin-niobium alloy is superconductive at very low temperatures. This promises to be important in the construction of superconductive magnets that generate enormous field strengths but use practically no power. Tin is the basis for many eutectic alloys and the discovery by early man that copper could be better formed and crafted if tin were added producing the first bronze and launching what we refer to as the "Bronze Age" and the first Neolithic metal tools, cooking utensils, and jewelry produced from rudimentary bronze. An important tin compound is the chloride, which is used as a reducing agent and as a mordant in calico printing. Tin is also used in various metal alloys (See AE Alloys). Tin was first discovered by Early Man.
trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).
Norlidah MN, Yazid MY, Shawkataly OB, Rosli MM, Fun HK.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1652-m1653. Epub 2011 Nov 2.
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Preparation and characterization of La(III) encapsulated silica gel/chitosan composite and its metal uptake studies.
Gandhi MR, Meenakshi S.
J Hazard Mater. 2011 Nov 28. [Epub ahead of print]
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22197561
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Electro-migration of heavy metals in an aged electroplating contaminated soil affected by the coexisting hexavalent chromium.
Zhang W, Zhuang L, Tong L, Lo IM, Qiu R.
Chemosphere. 2011 Dec 23. [Epub ahead of print]
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22197017
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Angular momentum conservation in dipolar energy transfer.
Guo D, Knight TE, McCusker JK.
Science. 2011 Dec 23;334(6063):1684-7.
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22194572
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Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
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Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
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22193863
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Chromium and genomic stability.
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Mutat Res. 2011 Dec 13. [Epub ahead of print]
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22192535
[PubMed - as supplied by publisher]
A Theoretical Evaluation of Ethylene Insertion into Chromium Alkyl Bonds of Cp-Donor based Olefin Polymerization Catalysts.
Xu R, Klatt G, Enders M, Koeppel H.
J Phys Chem A. 2011 Dec 22. [Epub ahead of print]
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22191673
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Adsorption of hexavalent chromium from aqueous solution by modified corn stalk: A fixed-bed column study.
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Bioresour Technol. 2011 Dec 3. [Epub ahead of print]
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22189077
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Occurrence of Multidrug-Resistant and Toxic-Metal Tolerant Enterococci in Fresh Feces from Urban Pigeons in Brazil.
da Silva VL, Caçador NC, da Silva CD, Fontes CO, Garcia GD, Nicoli JR, Diniz CG.
Microbes Environ. 2011 Dec 22. [Epub ahead of print]
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22188908
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Revision of a tibial baseplate using a customized oxinium component in a case of suspected metal allergy. A case report.
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Acta Orthop Belg. 2011 Oct;77(5):691-5.
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22187849
[PubMed - in process]
Retention Strength of Cobalt-Chromium vs Nickel-Chromium Titanium vs CP Titanium in a Cast Framework Association of Removable Partial Overdenture.
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J Contemp Dent Pract. 2011 May 1;12(3):179-86.
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22186813
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Metal analysis, phytotoxic, insecticidal and cytotoxic activities of selected medicinal plants of Khyber Pakhtunkhwa.
Khuda F, Iqbal Z, Zakiullah -, Khan A, Nasir F, Muhammad N, Khan JA, Khan MS.
Pak J Pharm Sci. 2012 Jan;25(1):51-58.
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Correlation between metal allergy and treatment outcomes after ankle fracture fixation.
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J Orthop Surg (Hong Kong). 2011 Dec;19(3):309-13.
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Enhancement of the acute phase response to a lipopolysaccharide challenge in steers supplemented with chromium.
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Innate Immun. 2011 Dec 16. [Epub ahead of print]
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22180563
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Identification and hexavalent chromium reduction characteristics of Pannonibacter phragmitetus.
Shi Y, Chai L, Yang Z, Jing Q, Chen R, Chen Y.
Bioprocess Biosyst Eng. 2011 Dec 18. [Epub ahead of print]
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22179413
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Exposure to particulate hexavalent chromium exacerbates allergic asthma pathology.
Schneider BC, Constant SL, Patierno SR, Jurjus RA, Ceryak SM.
Toxicol Appl Pharmacol. 2011 Dec 9. [Epub ahead of print]
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22178736
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Circulating levels of metals are related to carotid atherosclerosis in elderly.
Lind PM, Olsén L, Lind L.
Sci Total Environ. 2011 Dec 15. [Epub ahead of print]
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22178028
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Highly active nanoscale zero-valent iron (nZVI)-Fe(3)O(4) nanocomposites for the removal of chromium(VI) from aqueous solutions.
Lv X, Xu J, Jiang G, Tang J, Xu X.
J Colloid Interface Sci. 2011 Dec 1. [Epub ahead of print]
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Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.
Lewis RC, Gaffney SH, Le MH, Unice KM, Paustenbach DJ.
Int J Hyg Environ Health. 2011 Dec 14. [Epub ahead of print]
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Simultaneous Synthesis of Both Rings of Chromenes via a Benzannulation/o-Quinone Methide Formation/Electrocyclization Cascade.
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J Am Chem Soc. 2011 Dec 16. [Epub ahead of print]
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Recent Research & Development for Tin
RECONSTRUCTION OF THE THUMB WITH A MODIFIED WRAP-AROUND FLAP IN A PATIENT SUFFERING FROM ?-THALASSEMIA MINOR.
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Hand Surg. 2011;16(3):361-5.
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[PubMed - in process]
Isolated complete volar dislocation of the capitate: a case report.
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Hand Surg. 2011;16(3):353-6.
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Dielectrophoretic chip with multilayer electrodes and micro-cavity array for trapping and programmably releasing single cells.
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Biomed Microdevices. 2011 Nov 10. [Epub ahead of print]
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Structures of medium sized tin cluster anions.
Wiesel A, Drebov N, Rapps T, Ahlrichs R, Schwarz U, Kelting R, Weis P, Kappes MM, Schooss D.
Phys Chem Chem Phys. 2011 Nov 9. [Epub ahead of print]
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Discrimination task reveals differences in neural bases of tinnitus and hearing impairment.
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PLoS One. 2011;6(10):e26639. Epub 2011 Oct 31.
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A suggested technique for the application of the cone beam computed tomography periapical index.
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Dentomaxillofac Radiol. 2011 Dec;40(8):506-12.
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22065800
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(4-Chloro-3-nitro-benzoato)triphenyl-tin(IV).
Win YF, Choong CS, Teoh SG, Quah CK, Fun HK.
Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1270-1. Epub 2011 Aug 27.
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22065496
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Bis{2-[(E)-(5-tert-butyl-2-hy-droxy-phen-yl)diazen-yl]benzoato}dimethyl-tin(IV).
Basu Baul TS, Paul A, Tiekink ER.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1383-4. Epub 2011 Sep 14.
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22065466
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Win YF, Choong CS, Teoh SG, Quah CK, Fun HK.
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Dual detection strategy for electrochemical analysis of glucose and nitrite using a partitionally modified electrode.
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Analyst. 2011 Nov 7. [Epub ahead of print]
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22064849
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fac-(2-Amido-ethyl-?C,O)trichlorido(urea-?O)tin(IV).
Howie RA, de Lima GM, Tiekink ER, Wardell JL, Wardell SM.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1420-1. Epub 2011 Sep 30.
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22064619
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Highly sensitive nonenzymatic glucose sensor based on electrospun copper oxide-doped nickel oxide composite microfibers.
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Talanta. 2011 Oct 30;86:214-20. Epub 2011 Sep 8.
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22063533
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Cross-Linked Perylene Diimide-Based n-Type Interfacial Layer for Inverted Organic Photovoltaic Devices.
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ACS Appl Mater Interfaces. 2011 Nov 7. [Epub ahead of print]
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22059439
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Bis-(chloro-acetato-?O)bis(trimethyl-silylmethyl)tin(IV).
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Acta Crystallogr E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1190. Epub 2011 Aug 2.
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22058841
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A new langbeinite-type phosphate: K(2)AlSn(PO(4))(3).
Li HY, Zhao D.
Acta Crystallogr E Struct Rep Online. 2011 Oct 1;67(Pt 10):i56. Epub 2011 Sep 20.
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22058680
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Enhanced resistance of yeast mutants deficient in low-affinity iron and zinc transporters to stannous-induced toxicity.
Viau CM, Cardone JM, Guecheva TN, Yoneama ML, Dias JF, Pungartnik C, Brendel M, Saffi J, Henriques JA.
Chemosphere. 2011 Nov 2. [Epub ahead of print]
PMID:
22055569
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Allylsilanes in "Tin-free" Oximation, Alkenylation, and Allylation of Alkyl Halides.
Rouquet G, Robert F, Méreau R, Castet F, Landais Y.
Chemistry. 2011 Nov 3. doi: 10.1002/chem.201101842. [Epub ahead of print]
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22052660
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Surface Modification of Indium-Tin-Oxide Via Self-Assembly of a Donor-Acceptor Complex: A Density Functional Theory Study.
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Adv Mater. 2011 Nov 3. doi: 10.1002/adma.201103009. [Epub ahead of print] No abstract available.
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22052626
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Minimally invasive video-assisted cardiac surgery: operative techniques, application fields and clinical outcomes.
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Future Cardiol. 2011 Nov;7(6):775-87.
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Tailoring nanostructured, graded, and particle-reinforced Al laminates by accumulative roll bonding.
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Adv Mater. 2011 Jun 17;23(22-23):2663-8.
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Highly monodisperse core-shell particles created by solid-state reactions.
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Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3077. [Epub ahead of print]
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21822262
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Aerosol Deposition of Hydroxyapatite and 4-Hexylresorcinol Coatings on Titanium Alloys for Dental Implants.
Kim SG, Hahn BD, Park DS, Lee YC, Choi EJ, Chae WS, Baek DH, Choi JY.
J Oral Maxillofac Surg. 2011 Aug 6. [Epub ahead of print]
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21821331
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Progress in the Removal of Di-[2-Ethylhexyl]-Phthalate as Plasticizer in Blood Bags.
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Transfus Med Rev. 2011 Aug 4. [Epub ahead of print]
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21820855
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Antibacterial effect of silver-platinum coating for orthodontic appliances.
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Angle Orthod. 2011 Aug 2. [Epub ahead of print]
PMID:
21810004
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Influence of metal alloy and the profile of coronary stents in patients with multivessel coronary disease.
Abreu Filho LM, Forte AA, Sumita MK, Favarato D, Meireles GC.
Clinics (Sao Paulo). 2011;66(6):985-9.
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21808863
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A combined arc-melting and tilt-casting furnace for the manufacture of high-purity bulk metallic glass materials.
Soinila E, Pihlajama¨ki T, Bossuyt S, Ha¨nninen H.
Rev Sci Instrum. 2011 Jul;82(7):073901.
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Waste-recycling Monte Carlo with optimal estimates: Application to free energy calculations in alloys.
Adjanor G, Athe`nes M, Rodgers JM.
J Chem Phys. 2011 Jul 28;135(4):044127.
PMID:
21806110
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Role of electronic excitation in the amorphization of ge-sb-te alloys.
Li XB, Liu XQ, Liu X, Han D, Zhang Z, Han XD, Sun HB, Zhang SB.
Phys Rev Lett. 2011 Jul 1;107(1):015501. Epub 2011 Jun 29.
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Prediction of the operating point of dendrites growing under coupled thermosolutal control at high growth velocity.
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Phys Rev E Stat Nonlin Soft Matter Phys. 2011 Jun;83(6-1):061601. Epub 2011 Jun 2.
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Metal Anion-Alkyl Ammonium Complexes as Direct Write Precursors to Produce Nanopatterns of Metals, Nitrides, Oxides, Sulfides, And Alloys.
Radha B, Kiruthika S, Kulkarni GU.
J Am Chem Soc. 2011 Jul 26. [Epub ahead of print]
PMID:
21790160
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Characteristics of InGaN-based concentrator solar cells operating under 150X solar concentration.
Yang CC, Jang CH, Sheu JK, Lee ML, Tu SJ, Huang FW, Yeh YH, Lai WC.
Opt Express. 2011 Jul 4;19 Suppl 4:A695-700. doi: 10.1364/OE.19.00A695.
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21747536
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Determination of the magnetic ground state in the martensite phase of Ni-Mn-Z (Z = In, Sn and Sb) off-stoichiometric Heusler alloys by nonlinear AC susceptibility.
Umetsu RY, Fujita A, Ito W, Kanomata T, Kainuma R.
J Phys Condens Matter. 2011 Aug 17;23(32):326001. Epub 2011 Jul 25.
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Effects of phase constitution on magnetic susceptibility and mechanical properties of Zr-rich Zr-Mo alloys.
Suyalatu, Kondo R, Tsutsumi Y, Doi H, Nomura N, Hanawa T.
Acta Biomater. 2011 Jul 19. [Epub ahead of print]
PMID:
21784180
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Bioactive glass microspheres as osteopromotive inlays in macrotextured surfaces of Ti and CoCr alloy bone implants: Trapezoidal surface grooves without inlay most efficient in resisting torsional forces.
Keränen P, Moritz N, Alm JJ, Ylänen H, Kommonen B, Aro HT.
J Mech Behav Biomed Mater. 2011 Oct;4(7):1483-91. Epub 2011 May 30.
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21783158
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Effect of the combination of dithiooctanoate monomers and acidic adhesive monomers on adhesion to precious metals, precious metal alloys and non-precious metal alloys.
Ikemura K, Kojima K, Endo T, Kadoma Y.
Dent Mater J. 2011 Jul 28;30(4):469-77. Epub 2011 Jul 21.
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21778614
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Nanoporous PtAg and PtCu alloys with hollow ligaments for enhanced electrocatalysis and glucose biosensing.
Xu C, Liu Y, Su F, Liu A, Qiu H.
Biosens Bioelectron. 2011 Sep 15;27(1):160-6. Epub 2011 Jul 7.
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21778046
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Pt/Cr and Pt/Ni catalysts for oxygen reduction reaction: to alloy or not to alloy?
Escaño MC, Gyenge E, Nakanishi H, Kasai H.
J Nanosci Nanotechnol. 2011 Apr;11(4):2944-51.
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In vitro evaluation of the electrochemical behaviour of stainless steel and Ni-Ti orthodontic archwires at different temperatures.
Pakshir M, Bagheri T, Kazemi MR.
Eur J Orthod. 2011 Jul 19. [Epub ahead of print]
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21771804
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Multifrequency atomic force microscopy: compositional imaging with electrostatic force measurements.
Magonov S, Alexander J.
Microsc Microanal. 2011 Aug;17(4):587-97. Epub 2011 Jul 19.
PMID:
21771386
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Magnetic resonance imaging evaluation of intervertebral test spacers: an experimental comparison of magnesium versus titanium and carbon fiber reinforced polymers as biomaterials.
Ernstberger T, Buchhorn G, Heidrich G.
Ir J Med Sci. 2009 Aug 20. [Epub ahead of print]
PMID: 19693644 [PubMed - as supplied by publisher]
Ultrasonic irradiation and its application for improving the corrosion resistance of phosphate coatings on aluminum alloys.
Sheng M, Wang C, Zhong Q, Wei Y, Wang Y.
Ultrason Sonochem. 2010 Jan;17(1):21-5. Epub 2009 Aug 6.
PMID: 19692286 [PubMed - in process]
Plasma reduction of bronze corrosion developed under long-term artificial ageing.
Novakovic J, Papadopoulou O, Vassiliou P, Filippaki E, Bassiakos Y.
Anal Bioanal Chem. 2009 Aug 15. [Epub ahead of print]
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First-principles studies on alloying and simplified thermodynamic aqueous chemical stability of calcium-, zinc-, aluminum-, yttrium- and iron-doped magnesium alloys.
Velikokhatnyi OI, Kumta PN.
Acta Biomater. 2009 Aug 14. [Epub ahead of print]
PMID: 19683600 [PubMed - as supplied by publisher]
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