Cesium Oxalate

Cs2C2O4
CAS 1068-63-9


Product Product Code Order or Specifications
(2N) 99% Cesium Oxalate CS-OXL-02 Contact American Elements
(3N) 99.9% Cesium Oxalate CS-OXL-03 Contact American Elements
(4N) 99.99% Cesium Oxalate CS-OXL-04 Contact American Elements
(5N) 99.999% Cesium Oxalate CS-OXL-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Cs2C2O4 1068-63-9 37613238 13628982 MFCD00054352 213-950-8 cesium; oxalate 3709030 [Cs+].[Cs+].[O-]C(=O)C([O-])=O InChI=1S/C2H2O4.2Cs/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2 HEQUOWMMDQTGCX-UHFFFAOYSA-L

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
C2Cs2O4 353.83 White powder N/A N/A N/A 353.790562 353.790558 Da 0 Safety Data Sheet

Oxalate IonCesium Oxalate is highly insoluble in water and converts to the oxide when heated (calcined). Cesium Oxalate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Cesium (Cs) and molecular weight, atomic number and elemental symbolCesium or Caesium (atomic symbol: Ce, atomic number: 55) is a Block S, Group 1, Period 6 element with an atomic weight of 132.9054519. The number of electrons in each of Cesium's shells is 2, 8, 18, 18, 8, 1 and its electron configuration is [Xe] 6s1. Cesium Bohr ModelThe cesium atom has a radius of 265 pm and a Van der Waals radius of 343 pm. Cesium is a member of the alkali group of metals. Elemental CesiumIt is one of three metals that occur as a liquid at room temperature, the others being mercury and gallium. Cesium's main commercial source is pollucite ore; however, it is also found in beryl, avogadrite, pezzottaite, and londonite. Cesium was discovered by Robert Bunsen and Gustav Kirchhoff in 1860 and first isolated by Carl Setterberg in 1882. In its elemental form, cesium has a silvery gold appearance. The word Cesium originates from the Latin word "caesius," meaning "sky blue," which refers to the vibrant blue lines in its spectrum. For more information on cesium, including properties, safety data, research, and American Elements' catalog of cesium products, visit the Cesium Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Warning
Hazard Statements H302-H312
Hazard Codes Xn
Risk Codes 21/22
Safety Precautions 24/25
RTECS Number N/A
Transport Information UN 2923 8/PG 3
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Exclamation Mark-Acute Toxicity        

CESIUM OXALATE SYNONYMS
Oxalic acid cesium salt, Dicesium oxalate, Dicaesium oxalate, Caesium ethanedioate

CUSTOMERS FOR CESIUM OXALATE HAVE ALSO LOOKED AT
Cesium Oxide Cesium Nitrate Cesium Oxide Pellets Cesium Sulfate Cesium Chloride
Cesium Acetate Cesium Metal Cesium Oxide Pellets Cesium Oxide Pieces Cesium Oxide Powder
Cesium Chloride Cesium Oxalate Cesium Chromate Cesium Nitrate Cesium Bromate
Show Me MORE Forms of Cesium

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


Have a Question? Ask a Chemical Engineer or Material Scientist
Request an MSDS or Certificate of Analysis





German   Korean   French   Japanese   Spanish   Chinese (Simplified)   Portuguese   Russian   Chinese (Taiwan)  Italian   Turkish   Polish   Dutch   Czech   Swedish   Hungarian   Danish   Hebrew

Production Catalog Available in 36 Countries & Languages


Recent Research & Development for Cesium

  • Sathasivam Pratheep Kumar, Buvaneswari Gopal, Synthesis and leachability study of a new cesium immobilized langbeinite phosphate: KCsFeZrP3O12, Journal of Alloys and Compounds, Volume 615, 5 December 2014
  • Jakub Drnec, David A. Harrington, Oxygen and iodine adsorption on cesium-precovered Pt(111), Surface Science, Volume 630, December 2014, Pages 9-15, ISSN 0039-6028, http://dx.doi.org/10.1016/j.susc.2014
  • Pankaj Kandwal, Prasanta Kumar Mohapatra, A highly efficient solvent system containing chlorinated cobalt dicarbollide in NPOE—Dodecane mixture for effective transport of radio-cesium from acidic wastes, Journal of Membrane Science, Volume 469, 1 November 2014
  • Andrey Vendilo, Konstantin Popov, Marja Lajunen, Vyacheslav Chistov, Dmitry Djigailo, Hannu Rönkkömäki, Viktor Privalov, Igor Pletnev, A cesium-133 nuclear magnetic resonance study of the cesium cation ?omplexation by macrocyclic polyethers in hydrophobic RITLs, Polyhedron, Volume 81, 15 October 2014
  • Shunsuke Aramomi, Yu Matsuda, Seiji Kojima, High temperature Brillouin scattering study on elastic properties of lithium cesium borate glasses, crystals and melts, Journal of Non-Crystalline Solids, Volume 401, 1 October 2014
  • Helena Kaper, Jimmy Nicolle, Julien Cambedouzou, Agnès Grandjean, Multi-method analysis of functionalized single-walled carbon nanotubes for cesium liquid–solid extraction, Materials Chemistry and Physics, Volume 147, Issues 1–2, 15 September 2014
  • Hang Long, Pingxiao Wu, Lin Yang, Zhujian Huang, Nengwu Zhu, Zhixian Hu, Efficient removal of cesium from aqueous solution with vermiculite of enhanced adsorption property through surface modification by ethylamine, Journal of Colloid and Interface Science, Volume 428, 15 August 2014
  • Kitheri Joseph, K.V. Govindan Kutty, M.C. Goswami, P.R. Vasudeva Rao, Viscosity and crystallization mechanism of cesium loaded iron phosphate glasses, Thermochimica Acta, Volume 587, 10 July 2014
  • Hyosung Choi, Jaeki Jeong, Hak-Beom Kim, Seongbeom Kim, Bright Walker, Gi-Hwan Kim, Jin Young Kim, Cesium-doped methylammonium lead iodide perovskite light absorber for hybrid solar cells, Nano Energy, Volume 7, July 2014
  • Jing Liu, Xinshuai Zhang, Gangqiang Dong, Yuanxun Liao, Bo Wang, Tianchong Zhang, Futing Yi, The performance of silicon solar cell with selective pillars fabricated by Cesium Chloride self-assembly lithography and UV-lithography, Solar Energy, Volume 105, July 2014
  • Yan-Hong Deng, Yan-Qing Li, Qing-Dong Ou, Qian-Kun Wang, Fu-Zhou Sun, Xiang-Yu Chen, Jian-Xin Tang, The doping effect of cesium-based compounds on carrier transport and operational stability in organic light-emitting diodes, Organic Electronics, Volume 15, Issue 6, June 2014
  • Alfred K. Hill, Laura Torrente-Murciano, In-situ H2 production via low temperature decomposition of ammonia: Insights into the role of cesium as a promoter, International Journal of Hydrogen Energy, Volume 39, Issue 15, 15 May 2014
  • Anyun Zhang, Jinying Li, Ying Dai, Lei Xu, Development of a new simultaneous separation of cesium and strontium by extraction chromatograph utilization of a hybridized macroporous silica-based functional material, Separation and Purification Technology, Volume 127, 30 April 2014
  • S. Yu. Bratskaya, V.V. Zheleznov, Yu. O. Privar, A.V. Mechaev, Yu.L. Zub, A.V. Pestov, Pentacyanoferrate(II) complexes with N-containing derivatives of chitosan and polyallylamine: Synthesis and cesium uptake properties, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Available online 18 April 2014
  • Haitao Guo, Yantao Xu, Hongyan Chen, Xin He, Xiaoxia Cui, Pengfei Wang, Min Lu, Weinan Li, Chaoqi Hou, Bo Peng, Near- and mid-infrared emissions of Dy3+ doped and Dy3+/Tm3+co-doped lead cesium iodide modified chalcohalide glasses, Journal of Luminescence, Volume 148, April 2014
  • A. Barbot, B. Lucas, C. Di Bin, B. Ratier, Cesium carbonate-doped 1,4,5,8-naphthalene-tetracarboxylic-dianhydride used as efficient electron transport material in polymer solar cells, Organic Electronics, Volume 15, Issue 4, April 2014
  • Xinlong Chen, Jing Zhao, Benkang Chang, Guanghui Hao, Yuan Xu, Yijun Zhang, Muchun Jin, Roles of cesium and oxides in the processing of gallium aluminum arsenide photocathodes, Materials Science in Semiconductor Processing, Volume 18, February 2014
  • Jing Liu, Xinshuai Zhang, Gangqiang Dong, Yuanxun Liao, Bo Wang, Tianchong Zhang, Futing Yi, Fabrication of silicon nanopillar arrays by cesium chloride self-assembly and wet electrochemical etching for solar cell, Applied Surface Science, Volume 289, 15 January 2014
  • F. Fujishiro, K. Ishii, S. Matsuyama, H. Arai, A. Ishizaki, N. Osada, H. Sugai, K. Kusano, Y. Nozawa, S. Yamauchi, M. Karahashi, S. Oshikawa, K. Kikuchi, S. Koshio, K. Watanabe, Y. Suzuki, Micro-PIXE evaluation of radioactive cesium transfer in contaminated soil samples, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Volume 318, Part A, 1 January 2014
  • N. Osada, K. Ishii, S. Matsuyama, H. Sugai, K. Kusano, Y. Nozawa, S. Yamauchi, M. Karahashi, S. Oshikawa, K. Kikuchi, S. Koshio, K. Watanabe, S. Itoh, Y. Suzuki, A. Terakawa, Y. Kikuchi, F. Fujishiro, A. Ishizaki, H. Arai, Remediation of plants contaminated with cesium by aqueous cleaning, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Volume 318, Part A, 1 January 2014

Recent Research & Development for Oxalates

  • David Yaohui Wang, N.N. Sinha, J.C. Burns, R. Petibon, J.R. Dahn, A high precision study of the electrolyte additives vinylene carbonate, vinyl ethylene carbonate and lithium bis(oxalate)borate in LiCoO2/graphite pouch cells, Journal of Power Sources, Volume 270, 15 December 2014
  • Ioana Mindru, Dana Gingasu, Gabriela Marinescu, Luminita Patron, Jose Maria Calderon-Moreno, Cristina Bartha, Cristian Andronescu, Alina Crisan, Cobalt chromite obtained by thermal decomposition of oxalate coordination compounds, Ceramics International, Volume 40, Issue 9, Part B, November 2014
  • Francesco Delogu, Mechanochemical decomposition of Ag and Ni oxalates, Materials Chemistry and Physics, Volume 147, Issue 3, 15 October 2014
  • E. Amadio, L. Toniolo, Efficient oxidative carbonylation of iPrOH to oxalate catalyzed by Pd(II)–PPh3 complexes using benzoquinone as a stoichiometric oxidant, Journal of Organometallic Chemistry, Volume 767, 15 September 2014
  • Michael L. Tarlton, Alexander E. Anderson, Michael P. Weberski Jr., Xavier Riart-Ferrer, Brandon M. Nelson, Craig C. McLauchlan, Synthesis, characterization, and electrochemical properties of µ-oxalate bridged vanadium(III) and (IV) dimers incorporating the Kläui ligand, CpPORCo (R = Me, Et), Inorganica Chimica Acta, Volume 420, 24 August 2014
  • Lizhen Long, Liangpeng Wu, Xu Yang, Xinjun Li, Photoelectrochemical Performance of Nb-doped TiO2 Nanoparticles Fabricated by Hydrothermal Treatment of Titanate Nanotubes in Niobium Oxalate Aqueous Solution, Journal of Materials Science & Technology, Volume 30, Issue 8, August 2014
  • A. Verganelaki, V. Kilikoglou, I. Karatasios, P. Maravelaki-Kalaitzaki, A biomimetic approach to strengthen and protect construction materials with a novel calcium-oxalate–silica nanocomposite, Construction and Building Materials, Volume 62, 15 July 2014
  • Juan-Juan Hou, Xia Xu, Ning Jiang, Ya-Qin Wu, Xian-Ming Zhang, Selective adsorption in two porous triazolate–oxalate-bridged antiferromagnetic metal-azolate frameworks obtained via in situ decarboxylation of 3-amino-1,2,4-triazole-5-carboxylic acid, Journal of Solid State Chemistry, Available online 20 June 2014
  • Xingmei Guo, Yingxin Gong, Xiaoting Huang, Yuanyuan Tian, Yanlin Zhang, Shengrun Zheng, Ronghua Zeng, Mengqing Xu, Self-assembled microporous lanthanide coordination polymers built by 2-hydroxynicotinic acid and oxalate ligands, Inorganic Chemistry Communications, Volume 44, June 2014
  • Yuchun Jiang, Benzhi Li, Yu Wang, Daliang Liu, Ximing Song, Xiaohong Chang, Self-assembly of Schiff-base palladacycle-based discrete pseudo-macrocycles: Evidence for hemilability of oxalate ligand, Journal of Organometallic Chemistry, Volume 759, 1 June 2014
  • Wang Kaituo, Wu Xuehang, Wu Wenwei, Li Yongni, Liao Sen, Synthesis of perovskite LaCoO3 by thermal decomposition of oxalates: Phase evolution and kinetics of the thermal transformation of the precursor, Ceramics International, Volume 40, Issue 4, May 2014
  • A. Switlicka-Olszewska, B. Machura, J. Mrozinski, Synthesis, magnetic behavior and structural characterization of novel one-dimensional copper(II) coordination polymer based on azide and oxalate bridges, Inorganic Chemistry Communications, Volume 43, May 2014
  • Claudia Conti, Irene Aliatis, Marco Casati, Chiara Colombo, Mauro Matteini, Riccardo Negrotti, Marco Realini, Giuseppe Zerbi, Diethyl oxalate as a new potential conservation product for decayed carbonatic substrates, Journal of Cultural Heritage, Volume 15, Issue 3, May–June 2014
  • Juan Song, Ji-Jiang Wang, Huai-Ming Hu, Qing-Ran Wu, Juan Xie, Fa-Xin Dong, Meng-Lin Yang, Gang-Lin Xue, Syntheses, structures and properties of four 3D microporous lanthanide coordination polymers based on 3,5-pyrazoledicarboxylate and oxalate ligands, Journal of Solid State Chemistry, Volume 212, April 2014
  • A. Tuncay Ozyilmaz, Abdurrahman Akdag, I. Hakki Karahan, Gul Ozyilmaz, Electrochemical synthesis of polyaniline films on zinc-cobalt alloy deposited carbon steel surface in sodium oxalate, Progress in Organic Coatings, Volume 77, Issue 4, April 2014
  • Francesco Delogu, Ag–Ni Janus nanoparticles by mechanochemical decomposition of Ag and Ni oxalates, Acta Materialia, Volume 66, March 2014
  • Tong Wu, Daibing Luo, Chunmei Duan, Zhonghua Shi, Yaoqiang Chen, Zhien Lin, From 1D chain to 2D layer and 3D network: Solvent-free syntheses of new metal oxalates, Inorganic Chemistry Communications, Volume 41, March 2014
  • Nina Lah, Rodolphe Clérac, Cu(II) oxalate coordination polymer based on 3-pyridinepropanol bridging ligand: Synthesis, characterization and magnetic properties, Inorganic Chemistry Communications, Volume 41, March 2014
  • Xiao-Liang Zhou, Zheng-Guang Yan, Xiao-Dong Han, From ascorbic acid to oxalate: Hydrothermal synthesis of copper oxalate microspheres and conversion to oxide, Materials Letters, Volume 118, 1 March 2014
  • Chunhua Ge, Lixia Wang, Lili Xue, Zhong-Shuai Wu, Hehe Li, Zailin Gong, Xiang-Dong Zhang, Synthesis of novel organic-ligand-doped sodium bis(oxalate)-borate complexes with tailored thermal stability and enhanced ion conductivity for sodium ion batteries, Journal of Power Sources, Volume 248, 15 February 2014