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Europium Nitrate
Eu(NO3)3.6H2O
Product
Product Code
Order or Specifications
99% Europium Nitrate
EU-N-01
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99.9% Europium Nitrate
EU-N-03
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99.99% Europium Nitrate
EU-N-04
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99.999% Europium Nitrate
EU-N-05
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Europium Nitrate is a highly water soluble crystalline Europium source for uses compatible with nitrates and lower (acidic) pH. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. In energy efficient fluorescent lighting, Europium provides not only the neccessary red, but also the blue. Europium Nitrate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.We also produce Europium Nitrate Solution. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Europium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f76s2. In its elemental form europium's CAS number is 7440-53-1. The europium atom has a radius of 199.5.pm and it's Van der Waals radius is unknown. Europium is utilized primarily for its unique luminescent behavior. Europium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Excitation of the Europium atom by absorption of ultra violet radiation can result in specific energy level transitions within the atom creating an emission of visible radiation.In energy efficient fluorescent lighting, Europium provides not only the necessary red, but also the blue. Several commercial blue phosphors are based on Europium.

Formula CAS No. Appearance Molecular Weight Solubility Stability
Eu(NO3)3.6H2O 10031-53-5 Crystal 337.97 Soluble in water, moderately soluble in strong mineral acids Slightly hygroscopic
PRODUCT CATALOG Europium Research, Properties, & Information Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. MSDS
 
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Recent Research & Development for Europium

  • Covalently Bonded Assembly of Lanthanide/Silicon-Oxygen Network/Polyethylene Glycol Hybrid Materials through Functionalized 2-Thenoyltrifluoroacetone Linkage. Qiao XF, Yan B. J Phys Chem B. 2009 Aug 6. [Epub ahead of print] PMID: 19658417 [PubMed - as supplied by publisher]

  • Surface potential of spherical polyelectrolyte brushes in the presence of trivalent counterions. Hoffmann M, Jusufi A, Schneider C, Ballauff M. J Colloid Interface Sci. 2009 Jun 18. [Epub ahead of print] PMID: 19651414 [PubMed - as supplied by publisher]

  • Crystal Growth, Structural Properties, and Photophysical Characterization of Ln(4)Na(2)K(2)M(2)O(13) (M = Nb, Ta; Ln = Nd, Sm, Eu, Gd). Jagau TC, Roof IP, Smith MD, Zur Loye HC. Inorg Chem. 2009 Jul 30. [Epub ahead of print] PMID: 19642658 [PubMed - as supplied by publisher]

  • Synthesis and luminescence properties of a trinucleotide-europium(III) complex conjugate. Escudier JM, Dupouy C, Fountain MA, del Mundo IM, Jacklin EM, Morrow JR. Org Biomol Chem. 2009 Aug 21;7(16):3251-7. Epub 2009 Jun 23. PMID: 19641782 [PubMed - in process]

  • Circularly Polarized Luminescence in Enantiopure Europium and Terbium Complexes with Modular, All-Oxygen Donor Ligands. Seitz M, Do K, Ingram AJ, Moore EG, Muller G, Raymond KN. Inorg Chem. 2009 Jul 29. [Epub ahead of print] PMID: 19639983 [PubMed - as supplied by publisher]

  • Photochemical Mineralization of Europium, Titanium, and Iron Oxyhydroxide Nanoparticles in the Ferritin Protein Cage. Klem MT, Mosolf J, Young M, Douglas T. Inorg Chem. 2009 Jul 27. [Epub ahead of print] No abstract available. PMID: 19634892 [PubMed - as supplied by publisher]

  • Chemiluminescence determination of naproxen based on europium(III)-sensitized KIO(4)-H(2)O(2) reaction. Du J, Li D, Lu J. Luminescence. 2009 Jul 23. [Epub ahead of print] PMID: 19630092 [PubMed - as supplied by publisher]

  • Synthesis and luminescent properties of Eu(TTA)(3).3H(2)O nanocrystallines. Liu Q, Wang DM, Li YY, Yan M, Wei Q, Du B. Luminescence. 2009 Jul 23. [Epub ahead of print] PMID: 19630091 [PubMed - as supplied by publisher]

  • A Miniaturized Linear pH Sensor Based on a Highly Photoluminescent Self-Assembled Europium(III) Metal-Organic Framework. Harbuzaru BV, Corma A, Rey F, Jordá JL, Ananias D, Carlos LD, Rocha J. Angew Chem Int Ed Engl. 2009 Jul 23. [Epub ahead of print] No abstract available. PMID: 19630048 [PubMed - as supplied by publisher]

  • [Spectral analysis and photoluminescence properties of Eu-Tb codoped polymer] Li J, Xu BS, Li YC, Xie JB. Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Apr;29(4):891-5. Chinese. PMID: 19626866 [PubMed - in process]

  • [Preparation and luminescence properties of EuVO4] Namila, Wang XG, Zheng XF, Ao CH, Kang YY. Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Apr;29(4):887-90. Chinese. PMID: 19626865 [PubMed - in process]

  • Spherical core-shell structured nanophosphors on the basis of europium-doped lutetium compounds. Yermolayeva YV, Tolmachev AV, Korshikova TI, Yavetskiy RP, Dobrotvorskaya MV, Danylenko NI, Sofronov DS. Nanotechnology. 2009 Aug 12;20(32):325601. Epub 2009 Jul 21. PMID: 19620751 [PubMed - in process]

  • In vivo toxicity studies of europium hydroxide nanorods in mice. Patra CR, Abdel Moneim SS, Wang E, Dutta S, Patra S, Eshed M, Mukherjee P, Gedanken A, Shah VH, Mukhopadhyay D. Toxicol Appl Pharmacol. 2009 Jul 17. [Epub ahead of print] PMID: 19616569 [PubMed - as supplied by publisher]

  • Mixed Valence Europium Nitridosilicate Eu(2)SiN(3). Zeuner M, Pagano S, Matthes P, Bichler D, Johrendt D, Harmening T, Po¨ttgen R, Schnick W. J Am Chem Soc. 2009 Jul 17. [Epub ahead of print] PMID: 19610643 [PubMed - as supplied by publisher]

  • Layer silicates modified with 1,4-bis(3-aminopropyl)piperazine for the removal of Th(IV), U(VI) and Eu(III) from aqueous media. Guerra DL, Pinto AA, Viana RR, Airoldi C. J Hazard Mater. 2009 Jun 17. [Epub ahead of print] PMID: 19604631 [PubMed - as supplied by publisher]

  • Polarized Luminescence of Non-mesogenic Europium(III) Complexes Doped into a Nematic Liquid Crystal. Driesen K, Vaes C, Cardinaels T, Goossens K, Go¨rller-Walrand C, Binnemans K. J Phys Chem B. 2009 Jul 14. [Epub ahead of print] PMID: 19601595 [PubMed - as supplied by publisher]

  • Aggregation in methanol and formation of molecular glasses for europium(iii) N-acylaminocarboxylates: effects of alkyl chain length and head group. Naren G, Yasuda A, Iida M, Harada M, Suzuki T, Kato M. Dalton Trans. 2009 Jul 28;(28):5512-22. Epub 2009 May 29. PMID: 19587995 [PubMed - in process]

  • Metal-pi interactions dominate in the solid-state structures of molecular heterobimetallic alkali-metal-europium(II) aryloxo complexes. Deacon GB, Junk PC, Moxey GJ. Chem Asian J. 2009 Aug 3;4(8):1309-17. PMID: 19585640 [PubMed - in process]

  • A color-tunable europium complex emitting three primary colors and white light. He G, Guo D, He C, Zhang X, Zhao X, Duan C. Angew Chem Int Ed Engl. 2009;48(33):6132-5. No abstract available. PMID: 19585629 [PubMed - in process]

  • A novel europium(III) complex with versatility in excitation ranging from infrared to ultraviolet. Shi M, Ding C, Dong J, Wang H, Tian Y, Hu Z. Phys Chem Chem Phys. 2009 Jul 7;11(25):5119-23. Epub 2009 Apr 3. PMID: 19562143 [PubMed - in process]

 

 

Material Safety Data Sheet
  • 1 Identification of substance

    • Product details

    • Trade name Europium nitrate
  • 2 Composition/Data on components:

    • Chemical characterization:
                 Designation: (CAS#)                                        
      Europium nitrate, hexahydrate (CAS# 10031-53-5), 100%
    • Identification number(s):
    • EINECS Number: 233-380-3
  • 3 Hazards identification

    • Hazard designation:
      Xi Irritant
      O  Oxidising
    • Information pertaining to particular dangers for man and environment
      R 8        Contact with combustible material may cause fire.
      R 36/37/38 Irritating to eyes, respiratory system and skin.
  • 4 First aid measures

    • After inhalation
      Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
      Seek immediate medical advice.
    • After skin contact
      Instantly wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
    • After eye contact
      Rinse opened eye for several minutes under running water. Then consult doctor.
    • After swallowing Seek immediate medical advice.
  • 5 Fire fighting measures

    • Suitable extinguishing agents
      Use fire fighting measures that suit the environment.
    • Special hazards caused by the material, its products of combustion or
        flue gases:
      This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
    • Protective equipment:
      Wear self-contained breathing apparatus.
      Wear full protective suit.
  • 6 Accidental release measures

    • Person-related safety precautions:
      Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:
      Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting: Ensure adequate ventilation.
    • Additional information:
      See Section 7 for information on safe handling
      See section 8 for information on personal protection equipment.
      See Section 13 for information on disposal.
  • 7 Handling and storage


    • Handling
    • Information for safe handling:
      Keep containers tightly sealed.
      Store in cool, dry place in tightly closed containers.
      Ensure good ventilation/exhaustion at the workplace.
    • Information about protection against explosions and fires:
      Substance/product can reduce the ignition temperature of flammable substances.
      This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
      The product is not flammable

    • Storage
    • Requirements to be met by storerooms and containers:
      No special requirements.
    • Information about storage in one common storage facility:
      Store away from flammable substances.
      Store away from reducing agents.
    • Further information about storage conditions:
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  • 8 Exposure controls and personal protection

    • Additional information about design of technical systems:
      Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

    • Components with critical values that require monitoring at the
      workplace:                                                             
      Not required.
    • Additional information: No data

    • Personal protective equipment
    • General protective and hygienic measures
      The usual precautionary measures should be adhered to in handling the chemicals.
      Keep away from foodstuffs, beverages and food.
      Instantly remove any soiled and impregnated garments.
      Wash hands during breaks and at the end of the work.
      Avoid contact with the eyes and skin.
    • Breathing equipment: Use breathing protection with high concentrations.
    • Protection of hands: Impervious gloves
    • Eye protection:
      Safety glasses
      Face protection
    • Body protection: Protective work clothing.
  • 9 Physical and chemical properties:

    • General Information

    • Form: Crystalline
    • Colour: Colourless
    • Smell: Odourless
    •   Value/Range  Unit    Method      
    • Change in condition
    • Melting point/Melting range:                    85 ° C     sealed tube
    • Boiling point/Boiling range:       Not determined
    • Sublimation temperature / start:   Not determined

    • Flash point:                       Not applicable

    • Inflammability (solid, gaseous)
      Contact with combustible material may cause fire.

    • Ignition temperature:              Not determined

    • Decomposition temperature:         Not determined

    • Critical values for explosion:
    • Lower:                             Not determined
    • Upper:                             Not determined

    • Steam pressure:                    Not determined

    • Density                            Not determined

    • Solubility in / Miscibility with
    • Water:                             Soluble
      Fully miscible
  • 10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:
      No decomposition if used and stored according to specifications.
    • Materials to be avoided:
      Reducing agents
      Reducing agents, easily oxidized materials
      Organic materials
      Metal powders
    • Dangerous reactions:
      Reacts with reducing agents
      Reacts with flammable substances
    • Dangerous products of decomposition:
      Nitrogen oxides (NOx)
      Metal oxide
  • 11 Toxicological information

    • Acute toxicity:
      LD/LC50 values that are relevant for classification:                   
      Oral: LD50: >5000 mg/kg (rat)
    • Primary irritant effect:
    • on the skin: Irritant for skin and mucous membranes.
    • on the eye: Irritant effect.
    • Sensitization: No sensitizing effect known.
    • Additional toxicological information:
      To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  • 12 Ecological information:

    • General notes:
      Do not allow material to be released to the environment without proper governmental permits.
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
      Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
  • 13 Disposal considerations


    • Product:
    • Recommendation
      Consult state, local or national regulations for proper disposal.
      Hand over to disposers of hazardous waste.
      Must be specially treated under adherence to official regulations.

    • Uncleaned packagings:
    • Recommendation:
      Disposal must be made according to official regulations.
    • Recommended cleaning agent: Water, if necessary with cleaning agent.
  • 14 Transport information


    • Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
    • ADR/RID-GGVS/E Class:     5.1 (O2) Oxidizing substances.
    • Kemler Number:            50
    • UN-Number:                1477
    • Packaging group:          III
    • Label                     5.1
    • Designation of goods:     1477 NITRATES, INORGANIC, N.O.S. (Europium
                                 nitrate)

    • Maritime transport IMDG/GGVSea:
    • IMDG/GGVSea Class:        5.1
    • UN Number:                1477
    • Label                     5.1
    • Packaging group:          III
    • Correct technical name:   NITRATES, INORGANIC, N.O.S.

    • Air transport ICAO-TI and IATA-DGR:
    • ICAO/IATA Class:          5.1
    • UN/ID Number:             1477
    • Label                     5.1
    • Packaging group:          III
    • Correct technical name:   NITRATES, INORGANIC, N.O.S.
  • 15 Regulatory information


    • Designation according to EC guidelines:

    • Code letter and hazard designation of product:
      Xi Irritant O Oxidising

    • Risk phrases:
      8        Contact with combustible material may cause fire.
      36/37/38 Irritating to eyes, respiratory system and skin.

    • Safety phrases:
      17       Keep away from combustible material.
      26       In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

    • National regulations

    • Information about limitation of use:
      For use only by technically qualified individuals.
      Employment restrictions concerning young persons must be observed.

    • Water hazard class:
      Water hazard class 1 (Self-assessment): slightly hazardous for water.
  • 16 Other information:

      Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
  •  

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