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Iron Nickel Rhodium Metal
High Purity FeNiRh Metal
Product Product Code Order or Specifications
(2N) 99% Iron Nickel Rhodium Metal FENIRH-M-02 Contact American Elements
(3N) 99.9% Iron Nickel Rhodium Metal FENIRH-M-03 Contact American Elements
(4N) 99.99% Iron Nickel Rhodium Metal FENIRH-M-04 Contact American Elements
(5N) 99.999% Iron Nickel Rhodium Metal FENIRH-M-05 Contact American Elements
Ultra High Purity Ingot of Dysprosium Metal by DistillationIron Nickel Rhodium Metal is available as disc, granules, Ingot, pellets, powder, rod, wire, foil, and sputtering target. See research below. Ultra high purity and high purity forms also include metal powder, submicron powder and nanoscale, quantum dots, targets for thin film deposition, pellets for evaporation and single crystal or polycrystalline forms. Elements can also be introduced into alloys or other systems as compounds such as fluorides, oxides or chlorides or as solutions. Iron Nickel Rhodium Metal is generally immediately available in most volumes.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Iron(Fe) atomic and molecular weight, atomic number and elemental symbolIron is a Block D, Group 8, Period 4 element. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electronic configuration is [Ar] 3d6 4s2. In its elemental form iron's CAS number is 7439-89-6. The iron atom has a radius of 124.1.pm and it's Van der Waals radius is 200.pm. Iron is not toxic. Iron is the most commonly used metal for commercial applications due to its hardness, historical availability and low cost. Once used on its own, it is now alloyed with nickel and other elements to produce steel and other high strength, non-corrosive structural metals. Iron as a metal and as its many compounds has numerous uses. It is a primary colorant in glass and ceramics. It is a catalyst. It is the basis for low grade magnets and because of its magnetic properties is used extensively in memory tape. Recent applications for Iron nanoparticles includeIron Bohr Model in water treatment of carbon tetrachloride in contaminated groundwater, magnetic data storage and resonance imaging (MRI) and in certain alloy and catalyst applications. Iron can also be introduced into processes using iron foil, pellets, rod and wire by thin film Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Organometallic and Chemical Vapor Deposition (MOCVD) for specific applications such as fuel cells and solar energy. Iron is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iron was first discovered by Early Man.See Iron research below.

Nickel(Ni) atomic and molecular weight, atomic number and elemental symbolNickel is a Block D, Group 4, Period 4 element. The number of electrons in each of Nickel's shells is 2, 8, 16, 2 and its electronic configuration is [Ar]3d8 4s2. In its elemental form nickel's CAS number is 7440-02-0. Nickel is sometimes found free in nature but is more commonly found in ores. The nickel atom has a radius of 149.pm and it's Van der Waals radius is 163.pm. Nickel and its compounds are considered to be carcinogenic. Nickel carbonyl is a very toxic gas. It is extensively alloyed with iron, chromium, molybdenum, tungsten and other metals produce stainless and other anti-corrosive steel and other corrosion-resistant alloys. It is highly electronically conductive and has many applications as a result. It is the basis of the nickel hydride battery. Most recently, its Nickel Bohr Model conductive properties have Elemental Nickelmade it an ideal component for ceramic anode formulations used in oxygen generation and solid oxide fuel cell applications. Catalytic nickel is used to hydrogenate vegetable oils. Nickel additions to glass and ceramic glazes impart a bright green. It is also used in pigments for this purpose. Nickel information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included. Nickel was first discovered by Alex Constedt in 1751. The name originates from the German word 'kupfernickel' which means false copper from the illusory copper color of the ore. See Nickel research below.

Rhodium(Rh) atomic and molecular weight, atomic number and elemental symbolRhodium is a Block D, Group 9, Period 5 element. The number of electrons in each of Rhodium's shells is 2, 8, 18, 16, 1 and its electronic configuration is [Kr] 4d8 5s1. In its elemental form rhodium's CAS number is 7440-16-6. The rhodium atom has a radius of 134.5.pm and it's Van der Waals radius is 200.pm. Rhodium is not toxic. Rhodium is a member of the platinum group of metals. It has a higher melting point than platinum, Elemental Rhodiumbut a lower Rhodium Bohr Modeldensity. It is alloyed with platinum and palladium in electrodes for spark plugs, advanced laboratory equipment and in thermocouples. Rhodium compounds also have catalytic uses in automotive catalytic converters. Rhodium is used as a plating metal in jewelry production to enhance the whiteness of white gold. Rhodium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Rhodium was first discovered by William Wollaston in 1803. The name Rhodium, originates from the Greek word 'Rhodon' which means rose. See Rhodium research below.

 
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Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Iron

  • Cytochrome b mutation Y268S conferring the atovaquone resistance phenotype in the malaria parasite results in reduced parasite bc1 catalytic turnover and protein expression. Fisher N, Abd Majid R, Antoine T, Al-Helal M, Warman AJ, Johnson DJ, Lawrenson AS, Ranson H, O'Neill PM, Ward SA, Biagini GA. J Biol Chem. 2012 Jan 26. [Epub ahead of print] PMID: 22282497 [PubMed - as supplied by publisher]

  • Serum ferritin levels and endocrinopathy in medically treated patients with ß thalassemia major. Belhoul KM, Bakir ML, Saned MS, Kadhim AM, Musallam KM, Taher AT. Ann Hematol. 2012 Jan 28. [Epub ahead of print] PMID: 22281991 [PubMed - as supplied by publisher]

  • Iron supplementation to treat anemia in patients with chronic kidney disease. Besarab A, Coyne DW. Nat Rev Nephrol. 2012 Jan 27;8(2):63. doi: 10.1038/nrneph.2011.217. No abstract available. PMID: 22281971 [PubMed - in process]

  • Anemia in Critical Illness: Insights into Etiology, Consequences and Management. Hayden SJ, Albert TJ, Watkins TR, Swenson ER. Am J Respir Crit Care Med. 2012 Jan 26. [Epub ahead of print] PMID: 22281832 [PubMed - as supplied by publisher]

  • IRON fMRI measurements of CBV and implications for BOLD signal. Mandeville JB. Neuroimage. 2012 Jan 16. [Epub ahead of print] PMID: 22281669 [PubMed - as supplied by publisher]

  • Fatal idiopathic pulmonary haemosiderosis in association with pregnancy - Medico-legal evaluation. Töro K, Herjavecz I, Vereckei E, Kovács M. J Forensic Leg Med. 2012 Feb;19(2):101-104. Epub 2011 Oct 24. PMID: 22281220 [PubMed - as supplied by publisher]

  • Reduction of Fe(III)EDTA(-) in a NO(x) scrubbing solution by magnetic Fe(3)O(4)-chitosan microspheres immobilized mixed culture of iron-reducing bacteria. Jing G, Zhou J, Zhou Z, Lin T. Bioresour Technol. 2011 Dec 27. [Epub ahead of print] PMID: 22281145 [PubMed - as supplied by publisher]

  • Reactive oxygen species are involved in ferroportin degradation induced by ceruloplasmin mutant Arg701Trp. Persichini T, Francesco GD, Capone C, Cutone A, Bonaccorsi di Patti MC, Colasanti M, Musci G. Neurochem Int. 2012 Jan 20. [Epub ahead of print] PMID: 22281056 [PubMed - as supplied by publisher]

  • Effects of hypoxic preconditioning on the expression of iron influx and efflux proteins in primary neuron culture. Du F, Fan M, Gong Q, Zhu LL, Zhu ZJ, Lu L, Ke Y. Neurochem Int. 2012 Jan 18. [Epub ahead of print] PMID: 22281055 [PubMed - as supplied by publisher]

  • Iron deposition of the deep grey matter in patients with multiple sclerosis and neuromyelitis optica: A control quantitative study by 3D-enhanced susceptibility-weighted angiography (ESWAN). Chen X, Zeng C, Luo T, Ouyang Y, Lv F, Rumzan R, Wang Z, Li Q, Wang J, Hou H, Huang F, Li Y. Eur J Radiol. 2012 Jan 24. [Epub ahead of print] PMID: 22280874 [PubMed - as supplied by publisher]

  • Iron golf club with improved mass properties and vibration damping. Roach RL. J Acoust Soc Am. 2012 Jan;131(1):643. No abstract available. PMID: 22280652 [PubMed - in process]

  • Stability analysis of ultrasound thick-shell contrast agents. Lu X, Chahine GL, Hsiao CT. J Acoust Soc Am. 2012 Jan;131(1):24. PMID: 22280568 [PubMed - in process]

  • Role of Ureaplasma urealyticum in altering the endothelial metal concentration during preeclampsia. Padmini E, Uthra V. Placenta. 2012 Jan 24. [Epub ahead of print] PMID: 22280558 [PubMed - as supplied by publisher]

  • A polar corundum oxide displaying weak ferromagnetism at room temperature. Li MR, Adem U, McMitchell SR, Xu Z, Thomas CI, Warren JE, Giap DV, Niu HJ, Wan X, Palgrave RG, Schiffmann F, Cora F, Slater B, Burnett TL, Cain MG, Abakumov AM, Van Tendeloo G, Thomas MF, Rosseinsky MJ, Claridge JB. J Am Chem Soc. 2012 Jan 23. [Epub ahead of print] PMID: 22280499 [PubMed - as supplied by publisher]

  • Targeting Vascular Changes in Lesions in Multiple Sclerosis and Experimental Autoimmune Encephalomyelitis. Karlik SJ, Roscoe WA, Patinote C, Contino-Pépin C. Cent Nerv Syst Agents Med Chem. 2012 Jan 25. [Epub ahead of print] PMID: 22280405 [PubMed - as supplied by publisher]

  • [Transformation of copper and chromium in co-contaminated soil and its influence on bioavailability for pakchoi (Brassica chinensis)]. Wang D, Wei W, Liang DL, Wang SS, Hu B. Huan Jing Ke Xue. 2011 Oct;32(10):3113-20. Chinese. PMID: 22279932 [PubMed - in process]

  • [Distribution characteristic and assessment of soil heavy metal pollution in the iron mining of Baotou in Inner Mongolia]. Guo W, Zhao RX, Zhang J, Bao YY, Wang H, Yang M, Sun XL, Jin F. Huan Jing Ke Xue. 2011 Oct;32(10):3099-105. Chinese. PMID: 22279930 [PubMed - in process]

  • [Study of inactivating sulfate reducing bacteria with zero-valent iron nanoparticles]. Shu ZY, Wang J, Huang Y. Huan Jing Ke Xue. 2011 Oct;32(10):3040-4. Chinese. PMID: 22279921 [PubMed - in process]

  • [Combination of intersticial cystitis and adenomyosis in females suffering from chronic pelvic pain syndrome]. [No authors listed] Urologiia. 2011 Sep-Oct;(5):10, 12-4. Russian. PMID: 22279779 [PubMed - in process]

  • [Antidiabetes drug metformin is a donor of nitric oxide: ESR measurement of efficiency]. [No authors listed] Biofizika. 2011 Nov-Dec;56(6):1125-33. Russian. PMID: 22279758 [PubMed - in process]

 

Recent Research & Development for Nickel

  • In situ Raman studies during sulfidation, and operando Raman-GC during ammoxidation reaction using nickel-containing catalysts: a valuable tool to identify the transformations of catalytic species. Guerrero-Pérez MO, Rojas E, Gutiérrez-Alejandre A, Ramírez J, Sánchez-Minero F, Fernández-Vargas C, Bañares MA. Phys Chem Chem Phys. 2011 Apr 6. [Epub ahead of print] PMID: 21472171 [PubMed - as supplied by publisher]

  • Effect of Magnesium Deficiency on Various Mineral Concentrations in Rat Liver. Kim KH, Ishizaki N, Iguchi E, Funaba M, Matsui T. Biol Trace Elem Res. 2011 Apr 5. [Epub ahead of print] PMID: 21465284 [PubMed - as supplied by publisher]

  • Electronic Structures, Vibrational and Thermochemical Properties of Neutral and Charged Niobium Clusters Nb(n), n = 7-12. Nhat PV, Ngan VT, Tai TB, Nguyen MT. J Phys Chem A. 2011 Apr 21;115(15):3523-35. Epub 2011 Mar 29. PMID: 21446686 [PubMed - in process]

  • Surface structure of niobium-doped potassium tantalate KTa(1 - x)Nb(x)O(3) obtained from helium atom scattering studies. Trelenberg TW, Fatema R, Li JA, Akhadov EA, Van Winkle DH, Skofronick JG, Safron SA, Flaherty FA, Boatner LA. J Phys Condens Matter. 2010 Aug 4;22(30):304009. Epub 2010 Jul 13. PMID: 21399341 [PubMed - in process]

  • Structure and diffusion of intrinsic defect complexes in LiNbO(3) from density functional theory calculations. Xu H, Lee D, Sinnott SB, Dierolf V, Gopalan V, Phillpot SR. J Phys Condens Matter. 2010 Apr 7;22(13):135002. Epub 2010 Feb 25. PMID: 21389505 [PubMed - in process]

  • Lithium niobate nanowires for photocatalytic water splitting. Saito K, Koga K, Kudo A. Dalton Trans. 2011 Apr 21;40(15):3909-13. Epub 2011 Mar 8. PMID: 21384053 [PubMed - in process]

  • Simultaneous Spectroscopic and Topographic Near-Field Imaging of TiO(2) Single Surface States and Interfacial Electronic Coupling. Sevinc PC, Wang X, Wang Y, Zhang D, Meixner AJ, Lu HP. Nano Lett. 2011 Apr 13;11(4):1490-4. Epub 2011 Mar 4. PMID: 21375338 [PubMed - in process]

  • Matrix isolation spectroscopic and theoretical study of water adsorption and hydrolysis on molecular tantalum and niobium oxides. Zhou M, Zhuang J, Wang G, Chen M. J Phys Chem A. 2011 Mar 24;115(11):2238-46. Epub 2011 Feb 28. PMID: 21355623 [PubMed - in process]

  • Defect chemistry, redox kinetics, and chemical diffusion of lithium deficient lithium niobate. Shi J, Fritze H, Borchardt G, Becker KD. Phys Chem Chem Phys. 2011 Apr 21;13(15):6925-30. Epub 2011 Feb 23. PMID: 21347483 [PubMed - in process]

  • Effects of distortion of metal-oxygen octahedra on photocatalytic water-splitting performance of RuO2-loaded niobium and tantalum phosphate bronzes. Nishiyama H, Kobayashi H, Inoue Y. ChemSusChem. 2011 Feb 18;4(2):208-15. doi: 10.1002/cssc.201000294. PMID: 21328551 [PubMed - in process]

  • The influence of surface energy of titanium-zirconium alloy on osteoblast cell functions in vitro. Sista S, Wen C, Hodgson PD, Pande G. J Biomed Mater Res A. 2011 Feb 9. doi: 10.1002/jbm.a.33013. [Epub ahead of print] PMID: 21308982 [PubMed - as supplied by publisher]

  • Trialkyl imido niobium and tantalum compounds: synthesis, structural study and migratory insertion reactions. Galajov M, García C, Gómez M, Gómez-Sal P. Dalton Trans. 2011 Mar 28;40(12):2797-804. Epub 2011 Feb 7. PMID: 21298197 [PubMed - in process]

  • A series of new phases in the alkali metal-Nb(V)/Ta(V)-Se(IV)/Te(IV)-O systems. Gu QH, Hu CL, Zhang JH, Mao JG. Dalton Trans. 2011 Mar 21;40(11):2562-9. Epub 2011 Feb 4. PMID: 21293821 [PubMed - in process]

  • An ultralow noise current amplifier based on superconducting quantum interference device for high sensitivity applications. Granata C, Vettoliere A, Russo M. Rev Sci Instrum. 2011 Jan;82(1):013901. PMID: 21280839 [PubMed - in process]

  • Bijvoet in solution reveals unexpected stereoselectivity in a Michael addition. Sun H, d'Auvergne EJ, Reinscheid UM, Dias LC, Andrade CK, Rocha RO, Griesinger C. Chemistry. 2011 Feb 7;17(6):1811-7. doi: 10.1002/chem.201002520. Epub 2011 Jan 12. PMID: 21274932 [PubMed - indexed for MEDLINE]

  • Synthesis and reactivity of niobium complexes having a tripodal triaryloxide ligand in bidentate, tridentate, and tetradentate coordination modes. Akagi F, Ishida Y, Matsuo T, Kawaguchi H. Dalton Trans. 2011 Mar 14;40(10):2375-82. Epub 2011 Jan 20. PMID: 21249259 [PubMed - in process]

  • Bijvoet in Solution Reveals Unexpected Stereoselectivity in a Michael Addition. Sun H, d'Auvergne EJ, Reinscheid UM, Carlos Dias L, Kleber Z Andrade C, Oliveira Rocha R, Griesinger C. Chemistry. 2011 Jan 12. [Epub ahead of print] PMID: 21229527 [PubMed - as supplied by publisher]

  • Synthesis and photocatalytic activity of perovskite niobium oxynitrides with wide visible-light absorption bands. Siritanaratkul B, Maeda K, Hisatomi T, Domen K. ChemSusChem. 2011 Jan 17;4(1):74-8. doi: 10.1002/cssc.201000207. Epub 2010 Nov 4. PMID: 21226214 [PubMed - in process]

  • Synthesis and catalytic activity of group 5 metal amides with chiral biaryldiamine-based ligands. Zhang F, Song H, Zi G. Dalton Trans. 2011 Feb 21;40(7):1547-66. Epub 2011 Jan 10. PMID: 21218246 [PubMed - in process]

  • Sulfates of the refractory metals: crystal structure and thermal behavior of Nb2O2(SO4)3, MoO2(SO4), WO(SO4)2, and two modifications of Re2O5(SO4)2. Betke U, Wickleder MS. Inorg Chem. 2011 Feb 7;50(3):858-72. Epub 2011 Jan 5. PMID: 21207946 [PubMed - in process]

 

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Recent Research & Development for Rhodium

  • Direct Access to Parent Amido Complexes of Rhodium and Iridium through N?H Activation of Ammonia. Mena I, Casado MA, García-Orduña P, Polo V, Lahoz FJ, Fazal A, Oro LA. Angew Chem Int Ed Engl. 2011 Oct 12. doi: 10.1002/anie.201104745. [Epub ahead of print] No abstract available. PMID: 21994125 [PubMed - as supplied by publisher]

  • Asymmetric Hydrogenation of ?- and ?-Enamido Phosphonates: Rhodium(I)/Monodentate Phosphoramidite Catalyst. Zhang J, Li Y, Wang Z, Ding K. Angew Chem Int Ed Engl. 2011 Oct 11. doi: 10.1002/anie.201104912. [Epub ahead of print] No abstract available. PMID: 21990114 [PubMed - as supplied by publisher]

  • An operando DRIFTS investigation into the resistance against CO(2) poisoning of a Rh/alumina catalyst during toluene hydrogenation. Scalbert J, Meunier FC, Daniel C, Schuurman Y. Phys Chem Chem Phys. 2011 Oct 11. [Epub ahead of print] PMID: 21989590 [PubMed - as supplied by publisher]

  • Rh(III)-Catalyzed Oxidative Olefination of N-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes. Li X, Gong X, Zhao M, Song G, Deng J, Li X. Org Lett. 2011 Oct 11. [Epub ahead of print] PMID: 21988638 [PubMed - as supplied by publisher]

  • Synthesis of Isochromene and Related Derivatives by Rhodium-Catalyzed Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes. Morimoto K, Hirano K, Satoh T, Miura M. J Org Chem. 2011 Oct 11. [Epub ahead of print] PMID: 21988500 [PubMed - as supplied by publisher]

  • Pyridine synthesis from oximes and alkynes via rhodium(iii) catalysis: Cp* and Cp(t) provide complementary selectivity. Hyster TK, Rovis T. Chem Commun (Camb). 2011 Oct 10. [Epub ahead of print] PMID: 21986995 [PubMed - as supplied by publisher]

  • Rhodium-catalyzed redox allylation reactions of ketones. Williams FJ, Grote RE, Jarvo ER. Chem Commun (Camb). 2011 Oct 10. [Epub ahead of print] PMID: 21984365 [PubMed - as supplied by publisher]

  • Enantioselective Rhodium(I)-Catalyzed [3+2] Annulations of Aromatic Ketimines Induced by Directed C?H Activations. Tran DN, Cramer N. Angew Chem Int Ed Engl. 2011 Oct 4. doi: 10.1002/anie.201105766. [Epub ahead of print] No abstract available. PMID: 21976453 [PubMed - as supplied by publisher]

  • Asymmetric N?H Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids. Xu B, Zhu SF, Xie XL, Shen JJ, Zhou QL. Angew Chem Int Ed Engl. 2011 Oct 4. doi: 10.1002/anie.201105485. [Epub ahead of print] No abstract available. PMID: 21976452 [PubMed - as supplied by publisher]

  • Rhodium-Catalyzed Reaction of 1-Alkenylboronates with Aldehydes Leading to Allylation Products. Shimizu H, Igarashi T, Miura T, Murakami M. Angew Chem Int Ed Engl. 2011 Oct 4. doi: 10.1002/anie.201105148. [Epub ahead of print] No abstract available. PMID: 21976365 [PubMed - as supplied by publisher]

  • Rhodium-Catalyzed Annulation of N-Benzoylsulfonamide with Isocyanide through C?H Activation. Zhu C, Xie W, Falck JR. Chemistry. 2011 Oct 4. doi: 10.1002/chem.201102475. [Epub ahead of print] No abstract available. PMID: 21972033 [PubMed - as supplied by publisher]

  • "Cofactor"-Controlled Enantioselective Catalysis. Dydio P, Rubay C, Gadzikwa T, Lutz M, Reek JN. J Am Chem Soc. 2011 Oct 11. [Epub ahead of print] PMID: 21961536 [PubMed - as supplied by publisher]

  • Selective hydroformylation-hydrogenation tandem reaction of isoprene to 3-methylpentanal. Behr A, Reyer S, Tenhumberg N. Dalton Trans. 2011 Sep 29. [Epub ahead of print] PMID: 21960209 [PubMed - as supplied by publisher]

  • Synthesis of ?,?-Disubstituted Aryl Amines by Rhodium-Catalyzed Amination of Tertiary Allylic Trichloroacetimidates. Arnold JS, Cizio GT, Nguyen HM. Org Lett. 2011 Oct 21;13(20):5576-9. Epub 2011 Sep 29. PMID: 21958228 [PubMed - in process]

  • Unravelling the Reaction Path of Rhodium-MonoPhos-Catalysed Olefin Hydrogenation. Alberico E, Baumann W, de Vries JG, Drexler HJ, Gladiali S, Heller D, Henderickx HJ, Lefort L. Chemistry. 2011 Sep 28. doi: 10.1002/chem.201101793. [Epub ahead of print] PMID: 21956660 [PubMed - as supplied by publisher]

  • Fluorous Hydrosilylation. Carreira M, Contel M. Top Curr Chem. 2011 Sep 28. [Epub ahead of print] PMID: 21952841 [PubMed - as supplied by publisher]

  • The oxidative conversion of the N,S-bridged complexes [{RhLL'(?-X)}(2)] to [(RhLL')(3)(?-X)(2)](+) (X = mt or taz): a comparison with the oxidation of N,N-bridged analogues. Blagg RJ, López-Gómez MJ, Charmant JP, Connelly NG, Cowell JJ, Haddow MF, Hamilton A, Orpen AG, Riis-Johannessen T, Saithong S. Dalton Trans. 2011 Sep 27. [Epub ahead of print] PMID: 21952645 [PubMed - as supplied by publisher]

  • Ligand Fluorination to Optimize Preferential Oxidation (PROX) of Carbon Monoxide by Water-Soluble Rhodium Porphyrins. Biffinger JC, Uppaluri S, Sun H, Dimagno SG. ACS Catal. 2011 May 18;1(7):764-771. PMID: 21949596 [PubMed]

  • Rhodium-Catalyzed Intermolecular [2+2+2] Cross-Trimerization of Aryl Ethynyl Ethers and Carbonyl Compounds To Produce Dienyl Esters. Miyauchi Y, Kobayashi M, Tanaka K. Angew Chem Int Ed Engl. 2011 Sep 21. doi: 10.1002/anie.201105519. [Epub ahead of print] No abstract available. PMID: 21948312 [PubMed - as supplied by publisher]

  • Zinc-catalyzed allenylations of aldehydes and ketones. Fandrick DR, Saha J, Fandrick KR, Sanyal S, Ogikubo J, Lee H, Roschangar F, Song JJ, Senanayake CH. Org Lett. 2011 Oct 21;13(20):5616-9. Epub 2011 Sep 26. PMID: 21942658 [PubMed - in process]

 

 


Recent Research & Development for Metals

  • Rapid syntheses of a metal-organic framework material Cu(3)(BTC)(2)(H(2)O)(3) under microwave: a quantitative analysis of accelerated syntheses. Khan NA, Haque E, Jhung SH. Phys Chem Chem Phys. 2010 Mar 20;12(11):2625-31. Epub 2010 Jan 6. PMID: 20200739 [PubMed - in process]

  • Improved reliability from a plasma-assisted metal-insulator-metal capacitor comprising a high-k HfO(2) film on a flexible polyimide substrate. Singh Meena J, Chu MC, Kuo SW, Chang FC, Ko FH. Phys Chem Chem Phys. 2010 Mar 20;12(11):2582-9. Epub 2010 Jan 26. PMID: 20200734 [PubMed - in process]

  • Rational synthesis and characterization of porous Cu(ii) coordination polymers. Noro S. Phys Chem Chem Phys. 2010 Mar 20;12(11):2519-31. Epub 2010 Jan 18. PMID: 20200727 [PubMed - in process]

  • Construction of a monoanionic S,N,S-pincer ligand with a pyrrole core by sequential [1,2] phospho-Fries rearrangement. Characterization of palladium and silver coordination complexes. Fraix A, Lutz M, Spek AL, Gebbink RJ, van Koten G, Salaün JY, Jaffrès PA. Dalton Trans. 2010 Mar 21;39(11):2942-6. Epub 2010 Feb 5. PMID: 20200723 [PubMed - in process]

  • Zwitterionic dicopper helicates: anion encapsulation and binding studies. Wenzel M, Bruere SR, Knapp QW, Tasker PA, Plieger PG. Dalton Trans. 2010 Mar 21;39(11):2936-41. Epub 2010 Feb 8. PMID: 20200722 [PubMed - in process]

  • Organic-soluble optically pure anionic metal complexes PPh(4)[M(III)(S,S-EDDS)].2H(2)O (M = Fe, Co, Cr). Chmel NP, Howson SE, Allan LE, Barker J, Clarkson GJ, Turner SS, Scott P. Dalton Trans. 2010 Mar 21;39(11):2919-27. Epub 2010 Feb 9. PMID: 20200720 [PubMed - in process]

  • Crystallographic elucidation of purely structural, thermal and light-induced spin transitions in an iron(ii) binuclear complex. Kaiba A, Shepherd HJ, Fedaoui D, Rosa P, Goeta AE, Rebbani N, Létard JF, Guionneau P. Dalton Trans. 2010 Mar 21;39(11):2910-8. Epub 2010 Feb 9. PMID: 20200719 [PubMed - in process]

  • Anionic zinc-trimesic acid MOFs with unusual topologies: Reversible hydration studies. Davies K, Bourne SA, Ohrström L, Oliver CL. Dalton Trans. 2010 Mar 21;39(11):2869-74. Epub 2010 Feb 5. PMID: 20200714 [PubMed - in process]

  • A hexadentate bis(thiosemicarbazonato) ligand: rhenium(v), iron(iii) and cobalt(iii) complexes. Paterson BM, White JM, Donnelly PS. Dalton Trans. 2010 Mar 21;39(11):2831-7. Epub 2010 Feb 5. PMID: 20200709 [PubMed - in process]

  • Cu(ii) and Ni(ii) dioxotetraamine complexes integrated with tetrathiafulvalene moiety; structures and solution chemistry. Lu ZJ, Wang JP, Zhu QY, Huo LB, Qin YR, Dai J. Dalton Trans. 2010 Mar 21;39(11):2798-803. Epub 2010 Feb 9. PMID: 20200705 [PubMed - in process]

  • Synthesis, structure, and magnetic properties of bis(monosubstituted-pyrazine)dihalocopper(ii). Herringer SN, Longendyke AJ, Turnbull MM, Landee CP, Wikaira JL, Jameson GB, Telfer SG. Dalton Trans. 2010 Mar 21;39(11):2785-97. Epub 2010 Feb 4. PMID: 20200704 [PubMed - in process]

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