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Gallium Acetylacetonate

Ga(CH3COCHCOCH3)3
CAS 14405-43-7


Product Product Code Request Quote
(2N) 99% Gallium Acetylacetonate GA-ACAC-02 Request Quote
(3N) 99.9% Gallium Acetylacetonate GA-ACAC-03 Request Quote
(4N) 99.99% Gallium Acetylacetonate GA-ACAC-04 Request Quote
(5N) 99.999% Gallium Acetylacetonate GA-ACAC-05 Request Quote

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Ga(CH3COCHCOCH3)3 14405-43-7 16717626 MFCD00013492 238-377-0 (Z)-4-bis[(Z)-1-methyl-3-oxobut-1-enoxy]gallanyloxypent-3-en-2-one N/A [Ga+3].O=C(/C=C(\[O-])C)C.[O-]\C(=C/C(=O)C)C.[O-]\C(=C/C(=O)C)C InChI=1S/3C5H8O2.Ga/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; ZVYYAYJIGYODSD-LNTINUHCSA-K

PROPERTIES Compound Formula Mol. Wt. Appearance Density Exact Mass Monoisotopic Mass Charge MSDS
C15H21GaO6 367.05 White to Pale Yellow 1.42 g/cm3 366.059 366.059 0 Safety Data Sheet

Acetylaceton Formula Diagram (C5H8O2)Gallium Acetylacetonate is a Gallium source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic Acetylacetonate Packaging, Lab Quantitycompounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring; because of this property, acetylacetonates are commonly used in various catalysts and catalytic reagents for organic synthesis, including the fabrication of various shapes of carbon nanostructures (as demonstrated by a 2013 experiment by researchers at the Leibniz Institute for Solid State and Materials Research Dresden) via the use of chemical vapor deposition (CVD) and laser evaporation techniques. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Gallium Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The application of Gallium that has received the most attention is the production of semiconducting compounds. Nowadays gallium arsenide (Ga-As) is undoubtedly the most used. This compound is used in the production of several electronic parts such as diodes and transistors, made for voltage rectification, signal amplification, etc. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Gallium (Ga) atomic and molecular weight, atomic number and elemental symbolGallium (atomic symbol: Ga, atomic number: 31) is a Block P, Group 13, Period 4 element with an atomic weight of 69.723.The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electron configuration is [Ar] 3d10 4s2 4p1. The gallium atom has a radius of 122.1 pm and a Van der Waals radius of 187 pm. Gallium Bohr ModelGallium was predicted by Dmitri Mendeleev in 1871. It was first discovered and isolated by Lecoq de Boisbaudran in 1875. In its elemental form, gallium has a silvery appearance. Elemental GalliumGallium is one of three elements that occur naturally as a liquid at room temperature, the other two being mercury and cesium. Gallium does not exist as a free element in nature and is sourced commercially from bauxite and sphalerite. Currently, gallium is used in semiconductor devices for microelectronics and optics. The element name originates from the Latin word 'Gallia', the old name of France, and the word 'Gallus,' meaning rooster. For more information on gallium, including properties, safety data, research, and American Elements' catalog of gallium products, visit our Gallium element page.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335-H351
Hazard Codes Xn
Risk Codes 20/21/22-36/37/38-40
Safety Precautions 26-36/37/39
RTECS Number N/A
Transport Information N/A
WGK Germany 3
Globally Harmonized System of
Classification and Labelling (GHS)
Exclamation Mark-Acute Toxicity Health Hazard      

GALLIUM ACETYLACETONATE SYNONYMS
Gallium(III) acetylacetonate; 3-penten-2-one, 4-hydroxy-, gallium salt, (3Z)- (3:1); tris(pentane-2,4-dionato-O,O')gallium; Ga(acac)3; Gallium tris[(2Z)-4-oxopent-2-en-2-olate]; Gallium(III) 2,4-pentanedionate; Gallium(III) 2,4-pentanedionate

CUSTOMERS FOR GALLIUM ACETYLACETONATE HAVE ALSO LOOKED AT
Gallium Acetylacetonate Gallium Acetate Gallium Fluoride Gallium Antimonide Triethylgallium
Copper Indium Gallium Selenide - CIGS Gallium Arsenide Gallium Oxide Nanopowder Gallium Oxide Powder Gallium Nitride Wafer
Gadolinium Gallium Garnet - GGG Copper Gallium Sputtering Target Trimethylgallium Gallium doped Zinc Oxide - GZO Gallium Oxide
Show Me MORE Forms of Gallium

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Gallium

  • Nanoscale Optical Properties of Indium Gallium Nitride/Gallium Nitride Nanodisk-in-Rod Heterostructures. Xiang Zhou, Ming-Yen Lu, Yu-Jung Lu, Eric J. Jones, Shangjr Gwo, and Silvija Gradeak. ACS Nano: February 7, 2015
  • Gallium Plasmonics: Deep Subwavelength Spectroscopic Imaging of Single and Interacting Gallium Nanoparticles. Mark W. Knight, Toon Coenen, Yang Yang, Benjamin J. M. Brenny, Maria Losurdo, April S. Brown, Henry O. Everitt, and Albert Polman. ACS Nano: January 28, 2015
  • Influence of Source and Drain Contacts on the Properties of Indium–Gallium–Zinc-Oxide Thin-Film Transistors based on Amorphous Carbon Nanofilm as Barrier Layer. Dongxiang Luo, Hua Xu, Mingjie Zhao, Min Li, Miao Xu, Jianhua Zou, Hong Tao, Lei Wang, and Junbiao Peng. ACS Appl. Mater. Interfaces: January 26, 2015
  • Insertion of Benzonitrile into Al–N and Ga–N Bonds: Formation of Fused Carbatriaza-Gallanes/Alanes and Their Subsequent Synthesis from Amidines and Trimethyl-Gallium/Aluminum. K. Maheswari, A. Ramakrishna Rao, and N. Dastagiri Reddy. Inorg. Chem.: January 26, 2015
  • Mixed Pentele-Chalcogen Cationic Chains from Aluminum and Gallium Halide Melts. Andreas Eich, Thomas Bredow, and Johannes Beck. Inorg. Chem.: December 30, 2014
  • Temperature Dependent EXAFS Study of Chromium-Doped GaFeO3 at Gallium and Iron Edges. S. Basu, Ripandeep Singh, A. Das, T. Roy, A. Chakrabarti, A. K. Nigam, S. N. Jha, and D. Bhattacharyya. J. Phys. Chem. C: December 24, 2014
  • Solvothermal Synthesis of Gallium–Indium-Zinc-Oxide Nanoparticles for Electrolyte-Gated Transistors. Lídia Santos, Daniela Nunes, Tomás Calmeiro, Rita Branquinho, Daniela Salgueiro, Pedro Barquinha, Luís Pereira, Rodrigo Martins, and Elvira Fortunato. ACS Appl. Mater. Interfaces: December 17, 2014
  • Surface Characterization of Gallium Nitride Modified with Peptides before and after Exposure to Ionizing Radiation in Solution. Nora G. Berg, Michael W. Nolan, Tania Paskova, and Albena Ivanisevic. Langmuir: December 5, 2014
  • Influence of Water on the Interfacial Behavior of Gallium Liquid Metal Alloys. Mohammad R. Khan, Chris Trlica, Ju-Hee So, Michael Valeri, and Michael D. Dickey. ACS Appl. Mater. Interfaces: December 3, 2014
  • Low-Temperature Growth of Crystalline Gallium Nitride Films Using Vibrational Excitation of Ammonia Molecules in Laser-Assisted Metalorganic Chemical Vapor Deposition. Hossein Rabiee Golgir, Yang Gao, Yun Shen Zhou, Lisha Fan, Premkumar Thirugnanam, Kamran Keramatnejad, Lan Jiang, Jean-François Silvain, and Yong Feng Lu. Crystal Growth & Design: November 11, 2014
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Recent Research & Development for Acetylacetonates

  • An Oxygen-Chelate Complex, Palladium Bis-acetylacetonate, Induces Apoptosis in H460 Cells via Endoplasmic Reticulum Stress Pathway Rather than Interacting with DNA. Yi Wang, Jie Hu, Yuepiao Cai, Shanmei Xu, Bixia Weng, Kesong Peng, Xiaoyan Wei, Tao Wei, Huiping Zhou, Xiaokun Li, and Guang Liang. J. Med. Chem.: November 25, 2013
  • Binary Diffusion Coefficients of Platinum(II) Acetylacetonate in Supercritical Carbon Dioxide. Chang Yi Kong, Tomoya Siratori, Guosheng Wang, Takeshi Sako, and Toshitaka Funazukuri. J. Chem. Eng. Data: October 15, 2013
  • Cyclometalated 4-Styryl-2-phenylpyridine Platinum(II) Acetylacetonate Complexes as Second-Order NLO Building Blocks for SHG Active Polymeric Films. Alessia Colombo, Claudia Dragonetti, Daniele Marinotto, Stefania Righetto, Dominique Roberto, Silvia Tavazzi, Muriel Escadeillas, Véronique Guerchais, Hubert Le Bozec, Abdou Boucekkine, and Camille Latouche. Organometallics: July 11, 2013
  • Single-Molecule Magnetism in Three Related {CoIII2DyIII2}-Acetylacetonate Complexes with Multiple Relaxation Mechanisms. Stuart K. Langley, Nicholas F. Chilton, Boujemaa Moubaraki, and Keith S. Murray. Inorg. Chem.: May 29, 2013
  • Oxidatively Induced P–O Bond Formation through Reductive Coupling between Phosphido and Acetylacetonate, 8-Hydroxyquinolinate, and Picolinate Groups. Andersson Arias, Juan Forniés, Consuelo Fortuño, and Antonio Martín , Piero Mastrorilli, Stefano Todisco, Mario Latronico, and Vito Gallo. Inorg. Chem.: April 18, 2013
  • Binding Modes of Carboxylate- and Acetylacetonate-Linked Chromophores to Homodisperse Polyoxotitanate Nanoclusters. Jesse D. Sokolow, Elzbieta Trzop, Yang Chen, Jiji Tang, Laura J. Allen, Robert H. Crabtree, Jason B. Benedict, and Philip Coppens. J. Am. Chem. Soc.: June 19, 2012
  • Dinuclear Cu(II) Complexes of Isomeric Bis-(3-acetylacetonate)benzene Ligands: Synthesis, Structure, and Magnetic Properties. Marzio Rancan, Alessandro Dolmella, Roberta Seraglia, Simonetta Orlandi, Silvio Quici, Lorenzo Sorace, Dante Gatteschi, and Lidia Armelao. Inorg. Chem.: April 19, 2012
  • Bis(acetylacetonate) Tungsten(IV) Complexes Containing a Basic Diazoalkane or Oxo Ligand. Chetna Khosla, Andrew B. Jackson, Peter S. White, and Joseph L. Templeton. Organometallics: January 17, 2012
  • Visible-Light-Driven Copper Acetylacetonate Decomposition by BiVO4. Shin-ichi Naya, Masanori Tanaka, Keisuke Kimura, and Hiroaki Tada. Langmuir: July 7, 2011
  • Metal-Acetylacetonate Synthesis Experiments: Which Is Greener?. M. Gabriela T. C. Ribeiro and Adélio A. S. C. Machado. J. Chem. Educ.: April 11, 2011