Gallium Oxide

Ga2O3
CAS 12024-21-4


Product Product Code Order or Specifications
(3N) 99.9% Gallium Oxide GA-OX-03 Contact American Elements
(4N) 99.99% Gallium Oxide GA-OX-04 Contact American Elements
(5N) 99.999% Gallium Oxide GA-OX-05 Contact American Elements
(6N) 99.9999% Gallium Oxide GA-OX-06 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Ga2O3 12024-21-4 24852864 5139834 MFCD00011020 234-691-7 Digallium oxygen(2-) N/A O=[Ga]O[Ga]=O InChI=1S/2Ga.3O QZQVBEXLDFYHSR-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Melting Point Boiling Point Density

Exact Mass

Monoisotopic Mass Charge MSDS
Ga2O3 187.44 White Powder 1,900° C
(3,452° F)
N/A 5.88 g/cm3 187.835 g/mol 185.835906 Da 0 Safety Data Sheet

Oxide IonGallium Oxide is a highly insoluble thermally stable Gallium source suitable for glass, optic and ceramic applications. The precipitation of the hydrated form of gallium oxide is caused by the neutralization of acidic or basic gallium salt solution. Oxide compounds are not conductive to electricity. However, certain perovskite structured oxides are electronically conductive findingHigh Purity (99.999%) Gallium Oxide (Ga2O3) Powder application in the cathode of solid oxide fuel cells and oxygen generation systems. They are compounds containing at least one oxygen anion and one metallic cation. They are typically insoluble in aqueous solutions (water) and extremely stable making them useful in ceramic structures as simple as producing clay bowls to advanced electronics and in light weight structural components in aerospace and electrochemical applications such as fuel cells in which they exhibit ionic conductivity. Metal oxide compounds are basicanhydrides and can therefore react with acids and with strong reducing agents in redox reactions. Gallium Oxide is also available in pellets, pieces, powder sputtering targets, tablets, and nanopowder (from American Elements' nanoscale production facilities). See Nanotechnology for more nanotechnology applications information. Gallium Oxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety (MSDS) information is available.

Gallium (Ga) atomic and molecular weight, atomic number and elemental symbolGallium (atomic symbol: Ga, atomic number: 31) is a Block P, Group 13, Period 4 element with an atomic weight of 69.723. Gallium Bohr ModelThe number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electron configuration is [Ar] 3d10 4s2 4p1. The gallium atom has a radius of 122.1 pm and a Van der Waals radius of 187 pm. Gallium was predicted by Dmitri Mendeleev in 1871. It was first discovered and isoalted by Hans Christian Oersted in 1825. Elemental Gallium In its elemental form, gallium has a silvery appearance. Gallium is one of three elements that occur naturally as a liquid at room temperature, the other two being mercury and cesium. Gallium does not exist as a free element in nature and is sourced commercially from bauxite and sphalerite. Currently, gallium is used in semiconductor materials for microelectronics and optics. The element name originates from the Latin word 'Gallia', the old name of France, and the word 'Gallus,' meaning rooster. For more information on gallium, including properties, safety data, research, and American Elements' catalog of gallium products, visit the Gallium Information Center.

HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany 2
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

GALLIUM OXIDE SYNONYMS
Digallium oxygen(2-), Digallium trioxide, Gallium sesquioxide, Gallia, Oxo-oxogallanyloxy-gallane, Gallium(III) oxide, Gallium trioxide

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Gallium

  • Ultrasonic cavitation of molten gallium: formation of micro- and nano-spheres. Kumar VB, Gedanken A, Kimmel G, Porat Z. Ultrason Sonochem. 2014
  • Retardation Mechanism of Ultrathin Al(2)O(3) Interlayer on Y(2)O(3) Passivated Gallium Nitride Surface. Quah HJ, Cheong KY. ACS Appl Mater Interfaces. 2014
  • Efficacy of gallium maltolate against Lawsonia intracellularis infection in a rabbit model. Sampieri F, Allen AL, Alcorn J, Clark CR, Vannucci FA, Pusterla N, Mapes SM, Ball KR, Dowling PM, Thompson J, Bernstein LR, Gebhart CJ, Hamilton DL. J Vet Pharmacol Ther. 2014
  • Colloidal nickel/gallium nanoalloys obtained from organometallic precursors in conventional organic solvents and in ionic liquids: noble-metal-free alkyne semihydrogenation catalysts. Schütte K, Doddi A, Kroll C, Meyer H, Wiktor C, Gemel C, van Tendeloo G, Fischer RA, Janiak C. Nanoscale. 2014
  • Measuring systolic ankle and toe pressure using the strain gauge technique - a comparison study between mercury and indium-gallium strain gauges. Broholm R, Wiinberg N, Simonsen L. Scand J Clin Lab Invest. 2014
  • Main group bismuth(III), gallium(III) and diorganotin(IV) complexes derived from bis(2-acetylpyrazine)thiocarbonohydrazone: synthesis, crystal structures and biological evaluation. Zhang N, Tai Y, Li M, Ma P, Zhao J, Niu J. Dalton Trans. 2014
  • Slow and Fast Singlet Energy Transfers in BODIPY-gallium(III)corrole Dyads Linked by Flexible Chains. Brizet B, Desbois N, Bonnot A, Langlois A, Dubois A, Barbe JM, Gros CP, Goze C, Denat F, Harvey PD. Inorg Chem. 2014
  • Benefits of NOPO As Chelator in Gallium-68 Peptides, Exemplified by Preclinical Characterization of (68)Ga-NOPO-c(RGDfK). Simeček J, Notni J, Kapp TG, Kessler H, Wester HJ. Mol Pharm. 2014
  • Gallium-68 DOTATOC PET/CT In Vivo Characterization of Somatostatin Receptor Expression in the Prostate. Todorović-Tirnanić MV, Gajić MM, Obradović VB, Baum RP. Cancer Biother Radiopharm. 2014
  • Photodeposition of copper and chromia on gallium oxide: the role of co-catalysts in photocatalytic water splitting. Busser GW, Mei B, Pougin A, Strunk J, Gutkowski R, Schuhmann W, Willinger MG, SchlÃgl R, Muhler M. ChemSusChem. 2014
  • Synthesis and characterization of functional multicomponent nanosized gallium chelated gold crystals. Zambre A, Silva F, Upendran A, Afrasiabi Z, Xin Y, Paulo A, Kannan R. Chem Commun (Camb). 2014
  • Gallium phosphinoarylbisthiolato complexes counteract drug resistance of cancer cells. Fischer-Fodor E, Vălean AM, Virag P, Ilea P, Tatomir C, Imre-Lucaci F, Schrepler MP, Krausz LT, Tudoran LB, Precup CG, Lupan I, Hey-Hawkins E, Silaghi-Dumitrescu L. Metallomics. 2014
  • Demonstrating the capability of the high-performance plasmonic gallium-graphene couple. Losurdo M, Yi C, Suvorova A, Rubanov S, Kim TH, Giangregorio MM, Jiao W, Bergmair I, Bruno G, Brown AS. ACS Nano. 2014
  • Gallium nitrate ameliorates type II collagen-induced arthritis in mice. Choi JH, Lee JH, Roh KH, Seo SK, Choi IW, Park SG, Lim JG, Lee WJ, Kim MH, Cho KR, Kim YJ. Int Immunopharmacol. 2014
  • Electrochemically deposited gallium oxide nanostructures on silicon substrates. Ghazali NM, Mahmood MR, Yasui K, Hashim AM. Nanoscale Res Lett. 2014
  • Bulk mixed ion electron conduction in amorphous gallium oxide causes memristive behaviour. Aoki Y, Wiemann C, Feyer V, Kim HS, Schneider CM, Ill-Yoo H, Martin M. Nat Commun. 2014
  • Masking of Lewis acidity trends in the solid-state structures of trichlorido- and tribromido(2,2':6',2''-terpyridine-κ(3)N,N',N'')gallium(III). Kazakov IV, Bodensteiner M, Timoshkin AY. Acta Crystallogr C Struct Chem. 2014
  • Pharmacokinetics of gallium maltolate in Lawsonia intracellularis-infected and uninfected rabbits. Sampieri F, Alcorn J, Allen AL, Clark CR, Vannucci FA, Pusterla N, Mapes S, Ball KR, Dowling PM, Thompson J, Bernstein LR, Gebhart CJ, Hamilton DL. J Vet Pharmacol Ther. 2014
  • Efficient eye-safe neodymium doped composite yttrium gallium garnet crystal laser. Yu H, Wang S, Han S, Wu K, Su L, Zhang H, Wang Z, Xu J, Wang J. Opt Lett. 2014
  • Indium-chlorine and gallium-chlorine tetrasubstituted phthalocyanines in a bulk system, Langmuir monolayers and Langmuir-Blodgett nanolayers - Spectroscopic investigations. Bursa B, Wróbel D, Biadasz A, Kędzierski K, Lewandowska K, Graja A, Szybowicz M, Durmuş M. Spectrochim Acta A Mol Biomol Spectrosc. 2014

 

  • Doubly TEMPO-coordinated gadolinium(iii), lanthanum(iii), and yttrium(iii) complexes. Strong superexchange coupling across rare earth ions. Murakami R, Nakamura T, Ishida T. Dalton Trans. 2014.
  • Nuclear magnetization in gallium arsenide quantum dots at zero magnetic field. Sallen G, Kunz S, Amand T, Bouet L, Kuroda T, Mano T, Paget D, Krebs O, Marie X, Sakoda K, Urbaszek B. Nat Commun. 2014.
  • Clinical significance of late gadolinium enhancement in patients <20 years of age with hypertrophic cardiomyopathy. Smith BM, Dorfman AL, Yu S, Russell MW, Agarwal PP, Mahani MG, Lu JC. Am J Cardiol. 2014
  • Gallium oxide nanorods: novel, template-free synthesis and high catalytic activity in epoxidation reactions. Lueangchaichaweng W, Brooks NR, Fiorilli S, Gobechiya E, Lin K, Li L, Parres-Esclapez S, Javon E, Bals S, Van Tendeloo G, Martens JA, Kirschhock CE, Jacobs PA, Pescarmona PP. Angew Chem Int Ed Engl. 2014.
  • Ultrasonic cavitation of molten gallium: Formation of micro- and nano-spheres. Kumar VB, Gedanken A, Kimmel G, Porat Z. Ultrason Sonochem. 2014.
  • Synthesis and characterization of functional multicomponent nanosized gallium chelated gold crystals. Zambre A, Silva F, Upendran A, Afrasiabi Z, Xin Y, Paulo A, Kannan R. Chem Commun (Camb). 2014 Jan.
  • Gallium SPECT/CT for Permanent Catheter Infection. Chuang TL, Wang YF. Clin Nucl Med. 2014.
  • Acute gangrenous cholecystitis diagnosed on gallium scan. Ma HY, Freeman LM. Clin Nucl Med. 2014 Mar.
  • Microencapsulation of gallium-indium (Ga-In) liquid metal for self-healing applications. Blaiszik BJ, Jones AR, Sottos NR, White SR. J Microencapsul. 2014.
  • The structure of hyperalkaline aqueous solutions containing high concentrations of gallium - a solution X-ray diffraction and computational study. Radnai T, Bálint S, Bakó I, Megyes T, Grósz T, Pallagi A, Peintler G, Pálinkó I, Sipos P. Phys Chem Chem Phys. 2014.
  • Lacrimal Gland Uptake of (67)Ga-gallium Citrate Correlates with Biopsy Results in Patients with Suspected Sarcoidosis. Tannen BL, Kolomeyer AM, Turbin RE, Frohman L, Langer PD, Oh C, Ghesani NV, Zuckier LS, Chu DS. Ocul Immunol Inflamm. 2014.
  • Organo-gallium/indium chalcogenide complexes of copper(i): molecular structures and thermal decomposition to ternary semiconductors. Kluge O, Biedermann R, Holldorf J, Krautscheid H. Chemistry. 2014 Jan.
  • Gallium-mediated siderophore quenching as an evolutionarily robust antibacterial treatment. Ross-Gillespie A, Weigert M, Brown SP, Kümmerli R. Evol Med Public Health. 2014 Jan.
  • Effect of Microtextured Surface Topography on the Wetting Behavior of Eutectic Gallium-Indium Alloys. Kramer RK, Boley JW, Stone HA, Weaver JC, Wood RJ. Langmuir. 2014 Jan.
  • Gallium-68 DOTATOC PET/CT In Vivo Characterization of Somatostatin Receptor Expression in the Prostate. Todorovic-Tirnanic MV, Gajic MM, Obradovic VB, Baum RP. Cancer Biother Radiopharm. 2014 Jan.
  • A hybrid density functional view of native vacancies in gallium nitride. Gillen R, Robertson J. J Phys Condens Matter.
  • Effect of microtextured surface topography on the wetting behavior of eutectic gallium-indium alloys. Kramer RK, Boley JW, Stone HA, Weaver JC, Wood RJ. Langmuir. 2014.
  • Total neutron scattering investigation of the structure of a cobalt gallium oxide spinel prepared by solvothermal oxidation of gallium metal. Playford HY, Hannon AC, Tucker MG, Lees MR, Walton RI. J Phys Condens Matter.
  • Copper Indium Gallium Selenide (CIGS) Photovoltaic Devices Made Using Multistep Selenization of Nanocrystal Films. Harvey TB, Mori I, Stolle CJ, Bogart TD, Ostrowski DP, Glaz MS, Du J, Pernik DR, Akhavan VA, Kesrouani H, Vanden Bout DA, Korgel BA. ACS Appl Mater Interfaces.