Gallium Antimonide is a crystal grown gallium source used to produce sputtering targets and deposition sources and as a starting material for various semiconductor and photo optic materials.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Gallium is a Block P, Group 13, Period 4 element. The number of electrons in each of Gallium's shells is 2, 8, 18, 3 and its electronic configuration is [Ar] 3d10 4s2 4p1. In its elemental form gallium's CAS number is 7440-55-3. The gallium atom has a radius of 122.1.pm and it's Van der Waals radius is 187.pm. Gallium is not toxic. Gallium is one of three elements that naturally occur as a liquid at room temperature. The other two are mercury and cesium. The application of gallium that has received the most attention is the production of semiconducting compounds. Of these, the most important are the compounds of gallium with antimony, arsenic or phosphor. Nowadays gallium arsenide (Ga-As) is undoubtedly the most used. This compound is used in the production of several electronic parts such as diodes and transistors, made for voltage rectification, signal amplification, etc. Other gallium arsenide applications are the semiconductor "lasing" and microwave generation and also in sensors to measure temperature, light or magnetic field. Gallium was first discovered by Hans Christian Oersted in 1825. See Gallium research below.
Antimony is a Block P, Group 15, Period 5 element. The number of electrons in each of Antimony's shells is 2, 8, 18, 18, 5 and its electronic configuration is [Kr] 4d10 5s2 5p3. In its elemental form antimony's CAS number is 7440-36-0. The antimony atom has a radius of 145.pm and it's Van der Waals radius is 200.pm. The chemical state of antimony affects the toxicity of the element and its compounds. Antimony is finding use in semiconductor technology for making infrared detectors, diodes and Hall-effect devices in crystalline structures, such as antimony telluride and gallium antimonide. Antimony is however a poor conductor of heat and electricity. It greatly increases the hardness and mechanical strength of lead. This has found applications in batteries, antifriction alloys, small arms and tracer bullets and cable sheathing. Antimony compounds are used in manufacturing flame-proofing compounds, paints, ceramic enamels, glass, and pottery glazes. Antimony is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. See Antimony research below.
American Elements semi conducting materials are crystal structures produced from ultra high purity starting materials synthesized by our high purity production facility which includes several large electric muffle furnaces, a tube furnace for hydrogen reduction, 50 gallon glass-lined Pfaudler reactors supported by our analytical laboratory containing X-ray diffraction, SEM, AA, BET surface area, and ICP Spectrometry for trace metals analysis. See a discussion of American Elements Ultra High Purity and Analytical capabilities. See Crystal Growth for processes used to fabricate semiconductor materials, which include:
Crystal "pulling" by the Czochaiski method for production of semiconductor materials
Flux growth and gradient freeze
Directional solidification of fluorites using both the Bridgman-Stockbarger and float zoning techniques
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Synthesis of fluoranthenes by hydroarylation of alkynes catalyzed by gold(I) or gallium trichloride.
Pascual S, Bour C, de Mendoza P, Echavarren AM.
Beilstein J Org Chem. 2011;7:1520-5. Epub 2011 Nov 14.
PMID:
22238527
[PubMed - in process]
Radioguided surgery in neuroendocrine tumors using ga-68-labeled somatostatin analogs: a pilot study.
Kaemmerer D, Prasad V, Daffner W, Haugvik SP, Senftleben S, Baum RP, Hommann M.
Clin Nucl Med. 2012 Feb;37(2):142-7.
PMID:
22228336
[PubMed - in process]
Complexation of Metal Ions with TRAP (1,4,7-Triazacyclononane Phosphinic Acid) Ligands and 1,4,7-Triazacyclononane-1,4,7-triacetic Acid: Phosphinate-Containing Ligands as Unique Chelators for Trivalent Gallium.
Simecek J, Schulz M, Notni J, Plutnar J, Kubícek V, Havlícková J, Hermann P.
Inorg Chem. 2012 Jan 2;51(1):577-90. Epub 2011 Dec 20.
PMID:
22221285
[PubMed - in process]
A Sterically Demanding Iminopyridine Ligand Affords Redox-Active Complexes of Aluminum(III) and Gallium(III).
Myers TW, Berben LA.
Inorg Chem. 2012 Jan 5. [Epub ahead of print]
PMID:
22220939
[PubMed - as supplied by publisher]
Report from the 1(st )World Congress on Gallium-68 and Peptide Receptor Radio Nuclide Therapy (PRRNT), Bad Berka (Germany), June 23-26, 2011.
Jurgilewicz D.
Nucl Med Rev Cent East Eur. 2011;14(2):125-6. No abstract available.
PMID:
22219158
[PubMed - in process]
Molecular effects of gallium on osteoclastic differentiation of mouse and human monocytes.
Verron E, Loubat A, Carle GF, Vignes-Colombeix C, Strazic I, Guicheux J, Rochet N, Bouler JM, Scimeca JC.
Biochem Pharmacol. 2011 Dec 19. [Epub ahead of print]
PMID:
22202439
[PubMed - as supplied by publisher]
The ARRONAX Project.
Haddad F, Barbet J, Chatal JF.
Curr Radiopharm. 2011 Jul 1;4(3):186-96.
PMID:
22201708
[PubMed - in process]
Differential Cytostatic and Cytotoxic Action of Metallocorroles against Human Cancer Cells: Potential Platforms for Anticancer Drug Development.
Lim P, Mahammed A, Okun Z, Saltsman I, Gross Z, Gray HB, Termini J.
Chem Res Toxicol. 2012 Jan 10. [Epub ahead of print]
PMID:
22185566
[PubMed - as supplied by publisher]
Autonomic Restoration of Electrical Conductivity.
Blaiszik BJ, Kramer SL, Grady ME, McIlroy DA, Moore JS, Sottos NR, White SR.
Adv Mater. 2011 Dec 20. doi: 10.1002/adma.201102888. [Epub ahead of print]
PMID:
22183927
[PubMed - as supplied by publisher]
Dependence of the Redshifted and Blueshifted Photoluminescence Spectra of Single In_{x}Ga_{1-x}As/GaAs Quantum Dots on the Applied Uniaxial Stress.
Jöns KD, Hafenbrak R, Singh R, Ding F, Plumhof JD, Rastelli A, Schmidt OG, Bester G, Michler P.
Phys Rev Lett. 2011 Nov 18;107(21):217402. Epub 2011 Nov 15.
PMID:
22181923
[PubMed - in process]
Second line salvage chemotherapy for transplant-eligible patients with Hodgkin lymphoma resistant to platinum-containing first-line salvage chemotherapy.
Villa D, Seshadri T, Puig N, Massey C, Tsang R, Keating A, Crump M, Kuruvilla J.
Haematologica. 2011 Dec 16. [Epub ahead of print]
PMID:
22180434
[PubMed - as supplied by publisher]
Hole spin relaxation in Ge-Si core-shell nanowire qubits.
Hu Y, Kuemmeth F, Lieber CM, Marcus CM.
Nat Nanotechnol. 2011 Dec 18;7(1):47-50. doi: 10.1038/nnano.2011.234.
PMID:
22179569
[PubMed - in process]
Synthesis, radiometal labeling and in vitro evaluation of a targeted PPIX derivative.
Behnam Azad B, Cho CF, Lewis JD, Luyt LG.
Appl Radiat Isot. 2012 Mar;70(3):505-11. Epub 2011 Dec 6.
PMID:
22178308
[PubMed - in process]
Leukemia, thyroiditis and gallium-67 scan.
Wiwanitkit V.
Indian J Med Paediatr Oncol. 2011 Apr;32(2):122. No abstract available.
PMID:
22174505
[PubMed - in process]
Unusual presentation of mycosis fungoides as a lump in the scalp.
Imran MB, Othman S, Shahid A.
Singapore Med J. 2011 Nov;52(11):e226-8.
PMID:
22173261
[PubMed - in process]
(68)Ga-labeling and in vivo evaluation of a uPAR binding DOTA- and NODAGA-conjugated peptide for PET imaging of invasive cancers.
Persson M, Madsen J, Ostergaard S, Ploug M, Kjaer A.
Nucl Med Biol. 2011 Dec 13. [Epub ahead of print]
PMID:
22172391
[PubMed - as supplied by publisher]
Cathodoluminescence spectra of gallium nitride nanorods.
Tsai CC, Li GH, Lin YT, Chang CW, Wadekar P, Chen QY, Rigutti L, Tchernycheva M, Julien FH, Tu LW.
Nanoscale Res Lett. 2011 Dec 14;6(1):631. [Epub ahead of print]
PMID:
22168896
[PubMed - as supplied by publisher]
Design of neutral lewis superacids of group 13 elements.
Mück LA, Timoshkin AY, Frenking G.
Inorg Chem. 2012 Jan 2;51(1):640-6. Epub 2011 Dec 14.
PMID:
22168307
[PubMed - in process]
Role of Gallium-67 scintigraphy in the evaluation of occult sepsis in the medical ICU.
Chen WC, Tsai KD, Chen CH, Lin MS, Chen CM, Shih CM, Chen W.
Intern Emerg Med. 2011 Dec 14. [Epub ahead of print]
PMID:
22167445
[PubMed - as supplied by publisher]
Susceptibility of Candida albicans to photodynamic therapy using methylene blue and toluidine blue as photosensitizing dyes.
Pupo YM, Gomes GM, Santos EB, Chaves L, Michel MD, Kozlowski VA Jr, Gomes OM, Gomes JC.
Acta Odontol Latinoam. 2011;24(2):188-92.
PMID:
22165318
[PubMed - in process]
Synthesis of four different antimony(III) O,O'-dialkyldithiophosphates: Characterization by (31)P CP/MAS NMR, single-crystal X-ray diffraction, and adsorption at a stibnite surface (Sb(2)S(3)).
Larsson AC, Ivanov MA, Gerasimenko AV, Ivanov AV.
J Colloid Interface Sci. 2011 Nov 6. [Epub ahead of print]
PMID:
22115160
[PubMed - as supplied by publisher]
Sensing of Aqueous Fluoride Anions by Cationic Stibine-Palladium Complexes.
Wade CR, Ke IS, Gabbaï FP.
Angew Chem Int Ed Engl. 2011 Nov 24. doi: 10.1002/anie.201106242. [Epub ahead of print]
PMID:
22113959
[PubMed - as supplied by publisher]
Electrical characterization of n/p-type nickel silicide/silicon junctions by Sb segregation.
Jun M, Park Y, Hyun Y, Choi SJ, Zyung T, Jang M.
J Nanosci Nanotechnol. 2011 Aug;11(8):7339-42.
PMID:
22103191
[PubMed - in process]
Hydride generation in-atomizer collection atomic absorption spectrometry for the determination of antimony in acetic acid leachates from pewter cups.
Dessuy MB, Kratzer J, Vale MG, Welz B, Dedina J.
Talanta. 2011 Dec 15;87:255-61. Epub 2011 Oct 17.
PMID:
22099676
[PubMed - in process]
Electrical and optical performance of transparent conducting oxide films deposited by electrostatic spray assisted vapour deposition.
Hou X, Choy KL, Liu JP.
J Nanosci Nanotechnol. 2011 Sep;11(9):8114-9.
PMID:
22097539
[PubMed - in process]
Biomolecule-assisted green route to Sb2S3 crystals with three-dimensional dandelionlike patterns.
Xiang W, Ji G, Wei J, Yang Y, Yuan H, Liu X.
J Nanosci Nanotechnol. 2011 Sep;11(9):7820-32.
PMID:
22097493
[PubMed - in process]
Use of antimony in the treatment of leishmaniasis: current status and future directions.
Haldar AK, Sen P, Roy S.
Mol Biol Int. 2011;2011:571242. Epub 2011 Jun 8.
PMID:
22091408
[PubMed - in process]
Comparison between one day and two days protocols for sentinel node mapping of breast cancer patients.
Ali J, Alireza R, Mostafa M, Naser FM, Bahram M, Ramin S.
Hell J Nucl Med. 2011 Sep;14(3):313-5.
PMID:
22087458
[PubMed - in process]
Identification of Gunshot Residues in Fabric Targets Using Sector Field Inductively Coupled Plasma Mass Spectrometry Technique and Ternary Graphs*
Freitas JC, Sarkis JE, Neto ON, Viebig SB.
J Forensic Sci. 2011 Nov 10. doi: 10.1111/j.1556-4029.2011.01956.x. [Epub ahead of print]
PMID:
22074259
[PubMed - as supplied by publisher]
MAP Kinase1 of Leishmania Donovani: Down Regulation Associates With Antimony Resistance in Field Isolates.
Ashutosh, Garg M, Sundar S, Duncan R, Nakhasi HL, Goyal N.
Antimicrob Agents Chemother. 2011 Nov 7. [Epub ahead of print]
PMID:
22064540
[PubMed - as supplied by publisher]
Use of carbon nanotubes and electrothermal atomic absorption spectrometry for the speciation of very low amounts of arsenic and antimony in waters.
López-García I, Rivas RE, Hernández-Córdoba M.
Talanta. 2011 Oct 30;86:52-7. Epub 2011 Aug 27.
PMID:
22063510
[PubMed - in process]
Frequency of use controls chemical leaching from drinking-water containers subject to disinfection.
Andra SS, Makris KC, Shine JP.
Water Res. 2011 Dec 15;45(20):6677-87. Epub 2011 Oct 12.
PMID:
22040714
[PubMed - in process]
Antimony leaching from MSWI bottom ash: Modelling of the effect of pH and carbonation.
Cornelis G, Gerven TV, Vandecasteele C.
Waste Manag. 2011 Oct 27. [Epub ahead of print]
PMID:
22035902
[PubMed - as supplied by publisher]
Discovery of Safe and Orally Effective 4-Aminoquinaldine Analogues as Apoptotic Inducers with Activity against Experimental Visceral Leishmaniasis.
Palit P, Hazra A, Maity A, Vijayan RS, Manoharan P, Banerjee S, Mondal NB, Ghoshal N, Ali N.
Antimicrob Agents Chemother. 2011 Oct 24. [Epub ahead of print]
PMID:
22024817
[PubMed - as supplied by publisher]
Bone marrow leishmaniasis: a review of situation in Thailand.
Wiwanitkit V.
Asian Pac J Trop Med. 2011 Oct;4(10):757-9.
PMID:
22014727
[PubMed - in process]
Spectroelectrochemistry of cytochrome c and azurin immobilized in nanoporous antimony-doped tin oxide.
Kwan P, Schmitt D, Volosin AM, McIntosh CL, Seo DK, Jones AK.
Chem Commun (Camb). 2011 Dec 7;47(45):12367-9. Epub 2011 Oct 20.
PMID:
22011849
[PubMed - in process]
Structural diversity for phosphine complexes of stibenium and stibinidenium cations.
Chitnis SS, Peters B, Conrad E, Burford N, McDonald R, Ferguson MJ.
Chem Commun (Camb). 2011 Nov 8;47(45):12331-3. Epub 2011 Oct 20.
PMID:
22011846
[PubMed - in process]
Pressure-induced disordered substitution alloy in sb(2)te(3).
Zhao J, Liu H, Ehm L, Chen Z, Sinogeikin S, Zhao Y, Gu G.
Inorg Chem. 2011 Nov 21;50(22):11291-3. Epub 2011 Oct 18.
PMID:
22007692
[PubMed - in process]
Electrospun antimony doped tin oxide (ATO) nanofibers as a versatile conducting matrix.
Ostermann R, Zieba R, Rudolph M, Schlettwein D, Smarsly BM.
Chem Commun (Camb). 2011 Nov 28;47(44):12119-21. Epub 2011 Oct 14.
PMID:
22003493
[PubMed - in process]
Multi-metal(loid) methylation in methanoarchaea is linked to central intermediates of methanogenesis.
Thomas F, Diaz-Bone RA, Wuerfel O, Huber B, Weidenbach K, Schmitz RA, Hensel R.
Appl Environ Microbiol. 2011 Oct 14. [Epub ahead of print]
PMID:
22003009
[PubMed - as supplied by publisher]