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Gadolinia doped Ceria (GDC)
Cerium Oxide stabilized with Gadolinium Oxide |
CeO2/Gd2O3 |
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Gadolinia doped Ceria (Gd = 10%) Powder |
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Gadolinia doped Ceria (Gd = 10%) Ink |
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Gadolinia doped Ceria (Gd = 20%) Powder |
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Gadolinia doped Ceria (Gd = 20%) Ink |
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American Elements specializes in producing gadolinia doped ceria (GDC), cerium oxide stabilized by various doping levels of gadolinium oxide, a material that upon firing forms a highly ionically conductive thin film electrolyte layer for use in solid oxide fuel cell electrochemistry structures. Gadolinium Oxide doped Ceria belongs to a class of doped Ceria compounds with ionic conductivity exceeding Yttria Stabilized Zirconia (YSZ) electrolytes. These include Samarium doped Ceria (SDC) and Yttria doped Ceria (YDC). Even higher conductivity can be achieved with American Elements Scandia doped Zirconia (SCZ) and Yttria doped Bismuth Oxide. Gadolinium Oxide doped Cerium Oxide is available in a powder for tape casting, air spray, extrusion and sputtering fuel cell applications and as an ink for screen printing. Gadolinia doping levels are available at 10% and 20% and as specified by customer. American Elements provides guidance on firing parameters, doping levels, and thermal expansion matching with American Elements' cathode and anode cell layers.
Cerium is a Block F, Group 3, Period 6 element. The electronic configuration is [Xe]4f26s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. It is, therefore, strongly acidic. It is also a strong oxidizer. The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors.
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Recent Research & Development for Gadolinium
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Combined SPIO-gadolinium magnetic resonance imaging in cirrhotic patients: negative predictive value and role in screening for hepatocellular carcinoma.
Abdom Imaging. 2007 Oct 3; [Epub ahead of print]
- In vivo Imaging of the Systemic Recruitment of Fibroblasts to the Angiogenic Rim of Ovarian Carcinoma Tumors.
Cancer Res. 2007 Oct 1;67(19):9180-9.
- Evidence for a different anatomic basis for joint disease localization in polymyalgia rheumatica in comparison with rheumatoid arthritis.
Arthritis Rheum. 2007 Sep 28;56(10):3496-3501 [Epub ahead of print]
- Nephrogenic systemic fibrosis and gadolinium exposure: Association and lessons for idiopathic fibrosing disorders.
Arthritis Rheum. 2007 Sep 28;56(10):3173-3175 [Epub ahead of print] No abstract available.
- Cutaneous changes of nephrogenic systemic fibrosis: Predictor of early mortality and association with gadolinium exposure.
Arthritis Rheum. 2007 Sep 28;56(10):3433-3441 [Epub ahead of print]
- Gadolinium:Nonionic Contrast Media (1:1) Coronary Angiography in Patients With Impaired Renal Function.
Angiology. 2007 Sep 28; [Epub ahead of print]
- Nephrogenic systemic fibrosis (NSF): a late adverse reaction to some of the gadolinium based contrast agents.
Cancer Imaging. 2007 Sep 24;7(1):130-137.
- 3-Dimensional magnetic resonance genitography: a different look at cloacal malformations.
J Urol. 2007 Oct;178(4 Pt 2):1675-8; discussion 1678-9. Epub 2007 Aug 17.
- Spontaneous intracranial hypotension: a cause of severe acute headache.
Emerg Med J. 2007 Oct;24(10):739-41.
- Influence of Kupffer cell inactivation on cycloheximide-induced hepatic injury.
Toxicology. 2007 Aug 25; [Epub ahead of print]
- Intraosseous pilomatricoma: a possible rare skeletal manifestation of Gardner syndrome.
Skeletal Radiol. 2007 Jan 18; [Epub ahead of print]
- Cavernous hemangioma of the internal auditory canal.
Eur Arch Otorhinolaryngol. 2007 Jan 18; [Epub ahead of print]
- Nanosuspensions of alendronate with gallium or gadolinium attenuate neointimal hyperplasia in rats.
J Control Release. 2006 Nov 11; [Epub ahead of print]
- Receptor-mediated internalization of chelator-PNA-peptide hybridization probes for radioimaging or magnetic resonance imaging of oncogene mRNAs in tumours.
Biochem Soc Trans. 2007 Feb;35(Pt 1):72-6.
- Gadolinium periconceptional exposure: pregnancy and neonatal outcome.
Acta Obstet Gynecol Scand. 2007;86(1):99-101.
- MRI contrast agents may pose risk for patients with kidney disease.
JAMA. 2007 Jan 17;297(3):252-3. No abstract available.
- Clear Cell Sarcoma of Tendons and Aponeuroses: A Review.
Arch Pathol Lab Med. 2007 Jan 1;131(1):152 [Epub ahead of print]
- On the role of the counter-ion in defining water structure and dynamics: order, structure and dynamics in hydrophilic and hydrophobic gadolinium salt complexes.
Dalton Trans. 2006 Dec 21;(47):5605-16. Epub 2006 Aug 25.
- Magnetic resonance imaging findings associated with surgically proven rotator interval lesions.
Skeletal Radiol. 2007 Jan 16; [Epub ahead of print]
- Inflammatory synovitis due to underlying lipoma arborescens (gadolinium-enhanced MRI features): report of two cases.
Clin Rheumatol. 2007 Jan 16; [Epub ahead of print]
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