Germanium(II) Selenide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Germanium is a Block P, Group 14, Period 4 element. The number of electrons in each of Germanium's shells is 2, 8, 18, 4 and its electronic configuration is [Ar] 3d10 4s2 4p2. In its elemental form germanium's CAS number is 7440-56-4. The germanium atom has a radius of 122.5.pm and it's Van der Waals radius is 200.pm. Germanium is not toxic. Germanium is a very important semiconductor. Zone-refining techniques have led to production of crystalline germanium for semiconductor use with extremely high purities. When germanium is doped with arsenic, gallium, or other elements, it is used as a transistor element in thousands of electronic applications. The most common use of germanium is as a semiconductor. Germanium is also finding many other applications including use as an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst. Germanium and germanium oxide are transparent to the infrared and are used in infrared spectroscopes and other optical equipment, including extremely sensitive infrared detectors. The high refractive index and dispersion properties of its oxide's have made germanium useful as a component of wide-angle camera lenses and microscope objectives. The field of organo-germanium chemistry is becoming increasingly important. Germanium was first discovered by Clemens Winkler in 1886. See Germanium research below.
Selenium is a Block P, Group 16, Period 4 element. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electronic configuration is [Ar] 3d10 4s2 4p4. In its elemental form selenium's CAS number is 7782-49-2. The selenium atom has a radius of 116.pm and it's Van der Waals radius is 190.pm. The EPA does not classify selenium as carcinogenic, although selenium sulfide is a probable carcinogen. Selenates and selenites which are compounds of selenium, are highly toxic. Hydrogen selenide gas (SeH2) is the most acutely toxic compound of selenium. Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. of photocells and exposure meters for photographic use, as well as solar cells. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications. Selenium is available as metal and compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Selenium was first discovered by Jons Berzelius in 1817. The origin of the name Selenium comes from the Greek word "Selênê" meaning moon. See selenium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Synthesis of Mixed Tin-Ruthenium and Tin-Germanium-Ruthenium Carbonyl Clusters from [Ru(3)(CO)(12)] and Diaminometalenes (M = Sn, Ge).
Cabeza JA, García-Álvarez P, Polo D.
Inorg Chem. 2012 Jan 11. [Epub ahead of print]
PMID:
22235838
[PubMed - as supplied by publisher]
RADIOACTIVITY RISK ASSOCIATED WITH THE HANDLING OF COMPACT FLUORESCENT LAMPS.
Medhat ME, Eissa HS, Elmaghraby EK, Abu Khadra SA.
Radiat Prot Dosimetry. 2012 Jan 9. [Epub ahead of print]
PMID:
22232775
[PubMed - as supplied by publisher]
Synthesis of Nanoamorphous Germanium and Its Transformation to Nanocrystalline Germanium.
Dag O, Henderson EJ, Ozin GA.
Small. 2012 Jan 9. doi: 10.1002/smll.201101993. [Epub ahead of print]
PMID:
22228493
[PubMed - as supplied by publisher]
Synthesis and structural characterization of two-coordinate low-valent 14-group metal complexes bearing bulky bis(amido)silane ligands.
Yang D, Guo J, Wu H, Ding Y, Zheng W.
Dalton Trans. 2012 Jan 5. [Epub ahead of print]
PMID:
22218706
[PubMed - as supplied by publisher]
Compositional Differences between Size Classes of Dissolved Organic Matter from Freshwater and Seawater Revealed by an HPLC-FTIR System.
Tremblay L, Landry C.
Environ Sci Technol. 2012 Jan 4. [Epub ahead of print]
PMID:
22216934
[PubMed - as supplied by publisher]
Soft Lithographic Functionalization and Patterning Oxide-free Silicon and Germanium.
Bowers CM, Toone EJ, Clark RL, Shestopalov AA.
J Vis Exp. 2011 Dec 16;(58). pii: 3478. doi: 10.3791/3478.
PMID:
22214997
[PubMed - in process]
The ARRONAX Project.
Haddad F, Barbet J, Chatal JF.
Curr Radiopharm. 2011 Jul 1;4(3):186-96.
PMID:
22201708
[PubMed - in process]
Metastable Ge1-xCx Alloy Nanowires.
Kim BS, Lee JH, Son K, Hwang SW, Choi BL, Lee EK, Kim JM, Whang D.
ACS Appl Mater Interfaces. 2011 Dec 27. [Epub ahead of print]
PMID:
22201458
[PubMed - as supplied by publisher]
Reactivity of Digermylenes toward Potassium Graphite: Synthesis and Characterization of Germylidenide Anions.
Chia SP, Yeong HX, So CW.
Inorg Chem. 2012 Jan 16;51(2):1002-10. Epub 2011 Dec 21.
PMID:
22188525
[PubMed - in process]
Optics of semiconductors from meta-generalized-gradient-approximation-based time-dependent density-functional theory.
Nazarov VU, Vignale G.
Phys Rev Lett. 2011 Nov 18;107(21):216402. Epub 2011 Nov 15.
PMID:
22181900
[PubMed - in process]
Active microwave negative-index metamaterial transmission line with gain.
Jiang T, Chang K, Si LM, Ran L, Xin H.
Phys Rev Lett. 2011 Nov 11;107(20):205503. Epub 2011 Nov 11.
PMID:
22181744
[PubMed - in process]
Mesoporous zinc germanium oxynitride for CO(2) photoreduction under visible light.
Zhang N, Ouyang S, Kako T, Ye J.
Chem Commun (Camb). 2012 Jan 9;48(9):1269-71. Epub 2011 Dec 16.
PMID:
22179125
[PubMed - in process]
In Situ X-ray Absorption Spectroscopy Study of Si(1-x)Ge(x)O(2) Dissolution and Germanium Aqueous Speciation under Hydrothermal Conditions.
Ranieri V, Haines J, Cambon O, Levelut C, Le Parc R, Cambon M, Hazemann JL.
Inorg Chem. 2012 Jan 2;51(1):414-9. Epub 2011 Dec 16.
PMID:
22175278
[PubMed - in process]
Open-shell complexes containing metal-germanium triple bonds.
Filippou AC, Barandov A, Schnakenburg G, Lewall B, van Gastel M, Marchanka A.
Angew Chem Int Ed Engl. 2012 Jan 16;51(3):789-93. doi: 10.1002/anie.201107120. Epub 2011 Dec 15.
PMID:
22173926
[PubMed - in process]
A review of recent developments in the speciation and location of arsenic and selenium in rice grain.
Carey AM, Lombi E, Donner E, de Jonge MD, Punshon T, Jackson BP, Guerinot ML, Price AH, Meharg AA.
Anal Bioanal Chem. 2011 Dec 8. [Epub ahead of print]
PMID:
22159463
[PubMed - as supplied by publisher]
Electrodeposition of germanium from supercritical fluids.
Ke J, Bartlett PN, Cook D, Easun TL, George MW, Levason W, Reid G, Smith D, Su W, Zhang W.
Phys Chem Chem Phys. 2012 Jan 4;14(4):1517-28. Epub 2011 Dec 12.
PMID:
22158943
[PubMed - in process]
Gamma-ray fast-timing coincidence measurements from the (18)O+(18)O fusion-evaporation reaction using a mixed LaBr(3)-HPGe array.
Alharbi T, Mason PJ, Regan PH, Podolyák Z, Marginean N, Nakhostin M, Bowry M, Bucurescu D, Cata-Danil G, Cata-Danil I, Deleanu D, Filipescu D, Glodariu T, Ghita D, Marginean R, Mihai C, Negret A, Pascu S, Sava T, Stroe L, Suliman G, Zamfir NV, Bruce AM, Rodriguez Triguero C, Bender PC, Garg U, Erduran MN, Kusoglu A, Bostan M, Detistov P, Alkhomashi N, Sinha AK, Chakrabarti R, Ghugre SS.
Appl Radiat Isot. 2011 Dec 3. [Epub ahead of print]
PMID:
22154387
[PubMed - as supplied by publisher]
Mesoporous Nitrogen-Doped Carbon-Glass Ceramic Cathodes for Solid-State Lithium-Oxygen Batteries.
Kichambare P, Rodrigues S, Kumar J.
ACS Appl Mater Interfaces. 2011 Dec 14. [Epub ahead of print]
PMID:
22148159
[PubMed - as supplied by publisher]
Synthesis, Structure, Chemical Bonding, and Magnetism of the Series RELiGe(2) (RE = La-Nd, Sm, Eu).
Bobev S, You TS, Suen NT, Saha S, Greene R, Paglione J.
Inorg Chem. 2012 Jan 2;51(1):620-8. Epub 2011 Dec 6.
PMID:
22145852
[PubMed - in process]
Inducing novel electronic properties in <112> Ge nanowires by means of variations in their size, shape and strain: a first-principles computational study.
Zhang C, De Sarkar A, Zhang RQ.
J Phys Condens Matter. 2012 Jan 11;24(1):015301. Epub 2011 Dec 2.
PMID:
22133518
[PubMed - in process]
Toenail selenium status and the risk of Barrett's esophagus: the Netherlands Cohort Study.
Steevens J, Schouten LJ, Driessen AL, Huysentruyt CJ, Keulemans YC, Goldbohm RA, van den Brandt PA.
Cancer Causes Control. 2010 Oct 10. [Epub ahead of print]PMID: 20936529 [PubMed - as supplied by publisher]Related citations
Promotion of Growth in Mungbean (Phaseolus aureus Roxb.) by Selenium is Associated with Stimulation of Carbohydrate Metabolism.
Malik JA, Kumar S, Thakur P, Sharma S, Kaur N, Kaur R, Pathania D, Bhandhari K, Kaushal N, Singh K, Srivastava A, Nayyar H.
Biol Trace Elem Res. 2010 Oct 9. [Epub ahead of print]PMID: 20936436 [PubMed - as supplied by publisher]Related citations
Transition metal chemistry of cyclodiphosphanes containing phosphine and amide-phosphine functionalities: Formation of a stable dipalladium(II) complex containing a Pd-P s-bond.
Balakrishna MS, Venkateswaran R, Mague JT.
Dalton Trans. 2010 Oct 8. [Epub ahead of print]PMID: 20936211 [PubMed - as supplied by publisher]Related citations
Associations between blood metals and fecundity among women residing in New York State.
Bloom MS, Louis GM, Sundaram R, Kostyniak PJ, Jain J.
Reprod Toxicol. 2010 Oct 6. [Epub ahead of print]PMID: 20933593 [PubMed - as supplied by publisher]Related citations
The protective role of selenium in recalcitrant Acer saccharium L. seeds subjected to desiccation.
Pukacka S, Ratajczak E, Kalemba E.
J Plant Physiol. 2010 Oct 6. [Epub ahead of print]PMID: 20933296 [PubMed - as supplied by publisher]Related citations
Trace element concentrations in nesting flatback turtles (Natator depressus) from Curtis Island, Queensland, Australia.
Ikonomopoulou MP, Olszowy H, Limpus C, Francis R, Whittier J.
Mar Environ Res. 2010 Sep 25. [Epub ahead of print]PMID: 20933265 [PubMed - as supplied by publisher]Related citations
Correlation between serum selenium level and febrile seizures.
Mahyar A, Ayazi P, Fallahi M, Javadi A.
Pediatr Neurol. 2010 Nov;43(5):331-4.PMID: 20933176 [PubMed - in process]Related citations
Anti-Tumor Activity of Aloe vera Against DMBA/Croton Oil-Induced Skin Papillomagenesis in Swiss Albino Mice.
Saini M, Goyal PK, Chaudhary G.
J Environ Pathol Toxicol Oncol. 2010;29(2):127-35.PMID: 20932247 [PubMed - in process]Related citations
Aluminosilicate Relatives: Chalcogenoaluminogermanates Rb(3)(AlQ(2))(3)(GeQ(2))(7) (Q = S, Se).
Rothenberger A, Shafaei-Fallah M, Kanatzidis MG.
Inorg Chem. 2010 Oct 8. [Epub ahead of print]PMID: 20932019 [PubMed - as supplied by publisher]Related citations
A Nutrient Approach to Prostate Cancer Prevention: The Selenium and Vitamin E Cancer Prevention Trial (SELECT).
Dunn BK, Richmond ES, Minasian LM, Ryan AM, Ford LG.
Nutr Cancer. 2010 Oct;62(7):896-918.PMID: 20924966 [PubMed - in process]Related citations
Serum levels of selenium in patients with breast cancer before and after treatment of external beam radiotherapy.
Franca CA, Nogueira CR, Ramalho A, Carvalho AC, Vieira SL, Penna AB.
Ann Oncol. 2010 Oct 5. [Epub ahead of print]PMID: 20924074 [PubMed - as supplied by publisher]Related citations
Kenji Soda--researching enzymes with the spirit of an alpinist.
Yoshimura T, Mihara H, Ohshima T, Tanizawa K.
J Biochem. 2010 Oct;148(4):371-9.PMID: 20924059 [PubMed - in process]Related citations
Inhibitory effect of arsenic on aerobic gut flora in rat.
Choudhry ZK, Misbahuddin M, Hosain AK, Saleh AA.
Bangladesh Med Res Counc Bull. 2009 Dec;35(3):79-83.PMID: 20922909 [PubMed - in process]Related citations
[Endemic and biogeochemical features of the territory of Chuvash Republic]
[No authors listed]
Vestn Ross Akad Med Nauk. 2010;(8):40-6. Russian. PMID: 20922843 [PubMed - in process]Related citations
Interaction of uranyl with Se(IV) and Se(VI) in aqueous acid solutions by means of capillary electrophoresis.
Sladkov V.
Electrophoresis. 2010 Oct 4. [Epub ahead of print]PMID: 20922762 [PubMed - as supplied by publisher]Related citations
Ensemble Modeling Coupled with Six Element Concentrations in Human Blood for Cancer Diagnosis.
Chen H, Tan C, Wu T.
Biol Trace Elem Res. 2010 Oct 5. [Epub ahead of print]PMID: 20922500 [PubMed - as supplied by publisher]Related citations
Use of dietary vitamin E and selenium (Se) to increase the shelf life of modified atmosphere packaged light lamb meat.
Ripoll G, Joy M, Muñoz F.
Meat Sci. 2010 Sep 18. [Epub ahead of print]PMID: 20920835 [PubMed - as supplied by publisher]Related citations
Impacts of maternal selenium and nutritional level on growth, adiposity, and glucose tolerance in female offspring in sheep.
Vonnahme KA, Luther JS, Reynolds LP, Hammer CJ, Carlson DB, Redmer DA, Caton JS.
Domest Anim Endocrinol. 2010 Nov;39(4):240-8. Epub 2010 Jul 25.PMID: 20920781 [PubMed - in process]Related citations
Mutations disrupting selenocysteine formation cause progressive cerebello-cerebral atrophy.
Agamy O, Ben Zeev B, Lev D, Marcus B, Fine D, Su D, Narkis G, Ofir R, Hoffmann C, Leshinsky-Silver E, Flusser H, Sivan S, Söll D, Lerman-Sagie T, Birk OS.
Am J Hum Genet. 2010 Oct 8;87(4):538-44.PMID: 20920667 [PubMed - in process]Related citations
Developmental toxicity of selenium to Dolly Varden char (Salvelinus malma).
McDonald BG, Debruyn AM, Elphick JR, Davies M, Bustard D, Chapman PM.
Environ Toxicol Chem. 2010 Aug 3. [Epub ahead of print]PMID: 20891017 [PubMed - as supplied by publisher]Related citations