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Hafnium Nitrate

Hf(NO3)4
CAS 15509-05-4


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(2N) 99% Hafnium Nitrate HF-NAT-02 Request Quote
(3N) 99.9% Hafnium Nitrate HF-NAT-03 Request Quote
(4N) 99.99% Hafnium Nitrate HF-NAT-04 Request Quote
(5N) 99.999% Hafnium Nitrate HF-NAT-05 Request Quote

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name SMILES
Identifier
InChI
Identifier
InChI
Key
Hf(NO 3)4 15509-05-4 113460343 167292 MFCD00792273 N/A hafnium(4+) tetranitrate [Hf].O=[N+]([O-])[
O-].[O-][N+]([O-])=
O.[O-][N+]([O-])=O
.[O-][N+]([O-])=O
InChI=1S/Hf
.4NO3/c;4*2
-1(3)4/q;4*-1
RRXYXXKGMLRGCG-UHFFFAOYSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Density Exact Mass Monoisotopic Mass Charge MSDS
HfN 4O12 426.51 N/A N/A 427.898 427.898 0 Safety Data Sheet

Nitrate IonHafnium Nitrate is a moderately water soluble crystalline Hafnium source that decomposes to Hafnium oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. Ultra high purity, high purity, submicron and nanopowder forms may be considered. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Hafnium (Hf) atomic and molecular weight, atomic number and elemental symbol Hafnium (atomic symbol: Hf, atomic number: 72) is a Block D, Group 4, Period 6 element with an atomic weight of 178.49. Hafnium Bohr ModelThe number of electrons in each of Hafnium's shells is 2, 8, 18, 32, 10, 2 and its electron configuration is [Xe] 4f14 5d2 6s2. The hafnium atom has a radius of 159 pm and a Van der Waals radius of 212 pm. Hafnium was predicted by Dmitri Mendeleev in 1869 but it was not until 1922 that it was first isolated Dirk Coster and George de Hevesy.Elemental Hafnium In its elemental form, hafnium has a lustrous silvery-gray appearance. Hafnium does not exist as a free element in nature. It is found in zirconium compounds such as zircon. Hafnium is often a component of superalloys and circuits used in semiconductor device fabrication. Its name is derived from the Latin word Hafnia, meaning Copenhagen, where it was discovered. For more information on hafnium, including properties, safety data, research, and American Elements' catalog of hafnium products, visit the Hafnium element page.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word N/A
Hazard Statements N/A
Hazard Codes N/A
Risk Codes N/A
Safety Precautions N/A
RTECS Number N/A
Transport Information N/A
WGK Germany N/A
Globally Harmonized System of
Classification and Labelling (GHS)
N/A        

HAFNIUM NITRATE SYNONYMS
Hafnium tetranitrate, Nitric acid, hafnium(4+) salt, Hafnium (+4) cation tetranitrate

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Hafnium

  • Direct Macrolactonization of Seco Acids via Hafnium(IV) Catalysis. Mylène de Léséleuc and Shawn K. Collins. ACS Catal.: February 2, 2015
  • Electric Field Cycling Behavior of Ferroelectric Hafnium Oxide. Tony Schenk, Uwe Schroeder, Milan Peši?, Mihaela Popovici, Yuriy V. Pershin, and Thomas Mikolajick. ACS Appl. Mater. Interfaces: November 3, 2014
  • Application of the Zr/Hf Ratio in the Determination of Hafnium in Geochemical Samples by High-Resolution Inductively Coupled Plasma Mass Spectrometry. Ya Xuan Liu, Qing Xia Li, Na Ma, Xiao Ling Sun, Jin Feng Bai, and Qin Zhang. Anal. Chem.: October 24, 2014
  • Aqueous Hafnium Sulfate Chemistry: Structures of Crystalline Precipitates. Ali Kalaji and L. Soderholm. Inorg. Chem.: October 9, 2014
  • Single-Source-Precursor Synthesis of Hafnium-Containing Ultrahigh-Temperature Ceramic Nanocomposites (UHTC-NCs). Jia Yuan, Stefania Hapis, Hergen Breitzke, Yeping Xu, Claudia Fasel, Hans-Joachim Kleebe, Gerd Buntkowsky, Ralf Riedel, and Emanuel Ionescu. Inorg. Chem.: September 18, 2014
  • Nature of Tunable Optical Reflectivity of Rocksalt Hafnium Nitride Films. Chaoquan Hu, Zhiqing Gu, Jianbo Wang, Kan Zhang, Xiaobo Zhang, Mingming Li, Sam Zhang, Xiaofeng Fan, and Weitao Zheng. J. Phys. Chem. C: August 18, 2014
  • Changing Hafnium Speciation in Aqueous Sulfate Solutions: A High-Energy X-ray Scattering Study. Ali Kalaji, S. Skanthakumar, Mercouri G. Kanatzidis, John F. Mitchell, and L. Soderholm. Inorg. Chem.: May 28, 2014
  • Ferroelastic Domain Organization and Precursor Control of Size in Solution-Grown Hafnium Dioxide Nanorods. Sean W. Depner, Nicholas D. Cultrara, Katie E. Farley, Yueling Qin, and Sarbajit Banerjee. ACS Nano: April 17, 2014
  • Hafnium Sulfate Prenucleation Clusters and the Hf18 PolyoxoMetalate Red Herring. Rose E. Ruther, Brenna M. Baker, Jung-Ho Son, William H. Casey, and May Nyman. Inorg. Chem.: April 2, 2014
  • Zirconium and Hafnium Hydrazinediido Half-Sandwich Complexes: Synthesis and Reactivity. Peter D. Schweizer, Hubert Wadepohl, and Lutz H. Gade. Organometallics: March 18, 2014

Recent Research & Development for Nitrates

  • Surface-Enhanced Nitrate Photolysis on Ice. Guillaume Marcotte, Patrick Marchand, Stéphanie Pronovost, Patrick Ayotte, Carine Laffon, and Philippe Parent. J. Phys. Chem. A: February 11, 2015
  • Enhancement of Nitrite and Nitrate Electrocatalytic Reduction through the Employment of Self-Assembled Layers of Nickel- and Copper-Substituted Crown-Type Heteropolyanions. Shahzad Imar, Chiara Maccato, Calum Dickinson, Fathima Laffir, Mikhail Vagin, and Timothy McCormac. Langmuir: February 2, 2015
  • Facultative Nitrate Reduction by Electrode-Respiring Geobacter Metallireducens Biofilms as a Competitive Reaction to Electrode Reduction in a Bioelectrochemical System. Hiroyuki Kashima and John M. Regan. Environ. Sci. Technol.: January 27, 2015
  • Reactions of Rare Earth Hydrated Nitrates and oxides with Formamide: Relevant to Recycling Rare Earth Metals. Pradeep Samarasekere, Xiqu Wang, Watchareeya Kaveevivitchai, and Allan J. Jacobson. Crystal Growth & Design: January 20, 2015
  • Thermodynamic Modeling of Apparent Molal Volumes of Metal Nitrate Salts with Pitzer Model. Mouad Arrad, Mohammed Kaddami, Hannu Sippola, and Pekka Taskinen. J. Chem. Eng. Data: January 16, 2015
  • Fast Diffusion Reaction in the Composition and Morphology of Coprecipitated Carbonates and Nitrates of Copper(II), Magnesium(II), and Zinc(II). J. Michael Davidson, Khellil Sefiane, and Tiffany Wood. Ind. Eng. Chem. Res.: January 14, 2015
  • Novel Approach for the Preparation of Hydroxylammonium Nitrate from the Acid-Catalyzed Hydrolysis of Cyclohexanone Oxime. Fangfang Zhao, Kuiyi You, Ruige Li, Shan Tan, Pingle Liu, Jian Wu, Qiuhong Ai, and He’an Luo. Ind. Eng. Chem. Res.: January 6, 2015
  • Comparative Lipidomic Profiling of Two Dunaliella tertiolecta Strains with Different Growth Temperatures under Nitrate-Deficient Conditions. So-Hyun Kim, Hye Min Ahn, Sa Rang Lim, Seong-Joo Hong, Byung-Kwan Cho, Hookeun Lee, Choul-Gyun Lee, and Hyung-Kyoon Choi. J. Agric. Food Chem.: December 30, 2014
  • Independence of Nitrate and Nitrite Inhibition of Desulfovibrio vulgaris Hildenborough and Use of Nitrite as a Substrate for Growth. Hannah L. Korte, Avneesh Saini, Valentine V. Trotter, Gareth P. Butland, Adam P. Arkin, and Judy D. Wall. Environ. Sci. Technol.: December 22, 2014
  • Nitrate Concentration near the Surface of Frozen Aqueous Solutions. Harley A. Marrocco and Rebecca R. H. Michelsen. J. Phys. Chem. B: December 15, 2014