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Hafnium Sulfate
Hf(SO4)2
Product Product Code Order or Specifications
(2N) 99% Hafnium Sulfate HF-SAT-02 Contact American Elements
(2N5) 99.5% Hafnium Sulfate HF-SAT-025 Contact American Elements
(3N) 99.9% Hafnium Sulfate HF-SAT-03 Contact American Elements
(3N5) 99.95% Hafnium Sulfate HF-SAT-035 Contact American Elements
(4N) 99.99% Hafnium Sulfate HF-S-04 Contact American Elements
(5N) 99.999% Hafnium Sulfate HF-SAT-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Hf(SO4)2 15823-43-5 24853295 3014906 MFCD00168081   hafnium: sulfuric acid   [Hf].OS(O)(=O)=O InChI=1S/Hf.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4) KOELDGKLEFTHGN-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
H2HfO4S 276.57 White g/cm3 277.914 277.914 0 Safety Data Sheet


Sulfate IonHafnium Sulfate is a moderately water and acid soluble Hafnium source for uses compatible with sulfates. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells.

Hafnium Sulfate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Hafnium Sulfate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Hafnium(Hf) atomic and molecular weight, atomic number and elemental symbol Hafnium is a Block D, Group 4, Period 6 element. The number of electrons in each of Hafnium's shells is 2, 8, 18, 32, 10, 2 and its electronic configuration is [Xe] 4f14 5d2 6s2. In its elemental form hafnium's CAS number is 7440-58-6.The hafnium atom has a radius of 156.4.pm and it's Van der Waals radius is 200.pm. Hafnium is not toxic. Hafnium is one of the Group IV transition elements that is refined from various zirconic mineral deposits. Hafnium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It's primary uses are due to its ability as a nuclear "getter" or absorber of neutrons. It is a primary component in nuclear control rods for this purpose. It also finds uses as a dopant in the alloy of steel and Hafnium Bohr Modeltitanium. It is also used in the production of mantles for high intensity incandescent lamps. Hafnium is replacing polysilicon as the principle gate or electrode material in metal oxide semiconductor field effect transistors (MOSFETs) which are the basis for all modern semiconductors. As semiconductors have gotten smaller, the limiting factor in further size reduction has been the ability of the silicon oxide gate to perform below 10 angstroms where leakage occurs. Recent research has been devoted to the development of High-k materials which can function as a di-electric barrier or gate with lower leakage. Using hafnium based alloys as this di-electric gate has allowed for the development of MOSFET gates smaller than 10 angstroms. This allows for further size reduction, reduced switching power requirements and improved performance. Hafnium was first discovered by Dirk Coster in 1923. See Hafnium research below.

Sulfur(S) Aluminum(Al) atomic and molecular weight, atomic number and elemental symbolSulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms.  In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine Sulfur Bohr Modeland cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.

Have a Question? Ask a Chemical Engineer or Material Scientist   Request an MSDS or Certificate of Analysis

 
Safety &
Handling
 
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
N/A N/A N/A N/A N/A N/A N/A 3

 

Synonyms for Hafnium Sulfate Include:


Hafnium(IV) sulfate
Hafnium; sulfuric acid

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 


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Recent Research & Development for Hafnium

  • Fluorescence Signaling of Zr(4+) by Hydrogen Peroxide Assisted Selective Desulfurization of Thioamide. Hwang J, Choi MG, Eor S, Chang SK. Inorg Chem. 2012 Jan 19. [Epub ahead of print] PMID: 22260347 [PubMed - as supplied by publisher]

  • Hafnium metallocene compounds used as cathode interfacial layers for enhanced electron transfer in organic solar cells. Park K, Oh S, Jung D, Chae H, Kim H, Boo JH. Nanoscale Res Lett. 2012 Jan 9;7(1):74. [Epub ahead of print] PMID: 22230259 [PubMed - as supplied by publisher]

  • Synthesis of hafnium oxide-gold core-shell nanoparticles. Dahal N, Chikan V. Inorg Chem. 2012 Jan 2;51(1):518-22. Epub 2011 Dec 16. PMID: 22221284 [PubMed - in process]

  • Di-?-hydroxido-bis-[tris-(4,4,4-trifluoro-1-phenyl-acetyl-acetonato-?O,O')hafnium(IV)] dimethyl-formamide disolvate. Viljoen JA, Visser HG, Roodt A. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1822-3. Epub 2011 Nov 25. PMID: 22199601 [PubMed - in process]

  • Potential of high-Z contrast agents in clinical contrast-enhanced computed tomography. Nowak T, Hupfer M, Brauweiler R, Eisa F, Kalender WA. Med Phys. 2011 Dec;38(12):6469. PMID: 22149830 [PubMed - in process]

  • Ni ion release, osteoblast-material interactions, and hemocompatibility of hafnium-implanted NiTi alloy. Zhao T, Li Y, Zhao X, Chen H, Zhang T. J Biomed Mater Res B Appl Biomater. 2011 Nov 28. doi: 10.1002/jbm.b.31989. [Epub ahead of print] PMID: 22121018 [PubMed - as supplied by publisher]

  • Electrochemical oxide nanotube formation on the Ti-35Ta-xHf alloys for dental materials. Moon BH, Jeong YH, Choe HC. J Nanosci Nanotechnol. 2011 Aug;11(8):7428-32. PMID: 22103212 [PubMed - indexed for MEDLINE]

  • Environmentally stable flexible metal-insulator-metal capacitors using zirconium-silicate and hafnium-silicate thin film composite materials as gate dielectrics. Meena JS, Chu MC, Wu CS, Ravipati S, Ko FH. J Nanosci Nanotechnol. 2011 Aug;11(8):6858-67. PMID: 22103091 [PubMed]

  • In situ gas phase measurements during metal alkylamide atomic layer deposition. Maslar JE, Kimes WA, Sperling BA. J Nanosci Nanotechnol. 2011 Sep;11(9):8226-32. PMID: 22097559 [PubMed]

  • Tetra-kis(5,7-dimethyl-quinolin-8-olato-?N,O)hafnium(IV) dimethyl-formamide disolvate. Viljoen JA, Visser HG, Roodt A. Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1428-9. Epub 2011 Sep 30. PMID: 22058710 [PubMed]

  • Synthesis, characterization, and materials chemistry of Group 4 silylimides. Cosham SD, Johnson AL, Molloy KC, Kingsley AJ. Inorg Chem. 2011 Dec 5;50(23):12053-63. Epub 2011 Nov 4. PMID: 22053704 [PubMed - in process]

  • Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). Curley JJ, Bergman RG, Tilley TD. Dalton Trans. 2012 Jan 7;41(1):192-200. Epub 2011 Oct 21. PMID: 22020701 [PubMed - in process]

  • New stable aryl-substituted acyclic imino-N-heterocyclic carbene: synthesis, characterisation and coordination to early transition metals. Larocque TG, Badaj AC, Dastgir S, Lavoie GG. Dalton Trans. 2011 Dec 21;40(47):12705-12. Epub 2011 Oct 18. PMID: 22006062 [PubMed - in process]

  • Sterically demanding hetero-substituted [2]borametallocenophanes of group IV metals: synthesis, structure and reactivity. Braunschweig H, Dörfler R, Mies J, Oechsner A. Chemistry. 2011 Oct 17;17(43):12101-7. doi: 10.1002/chem.201101774. Epub 2011 Sep 9. PMID: 21905138 [PubMed]

  • The role of electron localization in the atomic structure of transition-metal 13-atom clusters: the example of Co13, Rh13, and Hf13. Piotrowski MJ, Piquini P, Cândido L, Da Silva JL. Phys Chem Chem Phys. 2011 Oct 14;13(38):17242-8. Epub 2011 Aug 30. PMID: 21879054 [PubMed - indexed for MEDLINE]

  • Monte Carlo dose enhancement studies in microbeam radiation therapy. Martínez-Rovira I, Prezadoa Y. Med Phys. 2011 Jul;38(7):4430-9. PMID: 21859044 [PubMed - indexed for MEDLINE]

  • Electronic structure characterization of La incorporated Hf-based high-k gate dielectrics by NEXAFS. Yamamoto T, Ogawa S, Kunisu M, Tsuji J, Kita K, Saeki M, Oku Y, Arimura H, Kitano N, Hosoi T, Shimura T, Watanabe H. J Nanosci Nanotechnol. 2011 Apr;11(4):2823-8. PMID: 21776638 [PubMed - indexed for MEDLINE]

  • Oxygen-containing gas-phase diatomic trications and tetracations: ReO(z+), NbO(z+) and HfO(z+) (z=3, 4). Brites V, Franzreb K, Harvey JN, Sayres SG, Ross MW, Blumling DE, Castleman AW Jr, Hochlaf M. Phys Chem Chem Phys. 2011 Sep 7;13(33):15233-43. Epub 2011 Jul 15. PMID: 21761073 [PubMed]

  • Tris(?-cyclo-penta-dien-yl)hafnium(III). Burlakov VV, Arndt P, Spannenberg A, Rosenthal U. Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m629. Epub 2011 Apr 22. PMID: 21754338 [PubMed]

  • Synthesis of freestanding HfO2 nanostructures. Kidd T, O'Shea A, Boyle K, Wallace J, Strauss L. Nanoscale Res Lett. 2011 Apr 5;6(1):294. PMID: 21711786 [PubMed - in process]

 

Recent Research & Development for Sulfur

  • Self-assembly of a sulphur-terminated graphene nanoribbon within a single-walled carbon nanotube. Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN. Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print] PMID: 21822259 [PubMed - as supplied by publisher]

  • Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p). Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C. Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27. PMID: 21821903 [PubMed - in process]

  • Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids. Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J. Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print] PMID: 21821743 [PubMed - as supplied by publisher]

  • Characterization of the sulfurtransferase family from Oryza sativa L. Guretzki S, Papenbrock J. Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print] PMID: 21821426 [PubMed - as supplied by publisher]

  • Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek. Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T. J Microbiol Methods. 2011 Jul 28. [Epub ahead of print] PMID: 21821067 [PubMed - as supplied by publisher]

  • In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent-solute interaction and its activity toward adsorptive desulfurization of gas oil. Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A. J Hazard Mater. 2011 Jul 6. [Epub ahead of print] PMID: 21820806 [PubMed - as supplied by publisher]

  • Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei. Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD. Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print] PMID: 21820408 [PubMed - as supplied by publisher]

  • The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates. Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C. Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159. PMID: 21818814 [PubMed - in process]

  • Sulphur isotopes in animal hair track distance to sea. Zazzo A, Monahan FJ, Moloney AP, Green S, Schmidt O. Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2371-8. doi: 10.1002/rcm.5131. PMID: 21818798 [PubMed - in process]

  • Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds. Fang W, He Q, Tan ZF, Liu CY, Lu X, Murillo CA. Chemistry. 2011 Aug 4. doi: 10.1002/chem.201003693. [Epub ahead of print] PMID: 21818792 [PubMed - as supplied by publisher]

  • Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond. Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C. J Gen Appl Microbiol. 2011;57(3):145-51. PMID: 21817826 [PubMed - in process]

  • Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources. Wyman CE, Balan V, Dale BE, Elander RT, Falls M, Hames B, Holtzapple MT, Ladisch MR, Lee YY, Mosier N, Pallapolu VR, Shi J, Thomas SR, Warner RE. Bioresour Technol. 2011 Jun 21. [Epub ahead of print] PMID: 21816612 [PubMed - as supplied by publisher]

  • Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province. Sullivan TJ, Cosby BJ, Jackson WA. J Environ Manage. 2011 Aug 2. [Epub ahead of print] PMID: 21816535 [PubMed - as supplied by publisher]

  • Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE. Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM. Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print] PMID: 21816081 [PubMed - as supplied by publisher]

  • Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells. Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC. Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print] PMID: 21815631 [PubMed - as supplied by publisher]

  • The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver. Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB. Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print] PMID: 21815229 [PubMed - as supplied by publisher]

  • A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability. Reyes-Palomares A, Montañez R, Sánchez-Jiménez F, Medina MA. Amino Acids. 2011 Aug 4. [Epub ahead of print] PMID: 21814788 [PubMed - as supplied by publisher]

  • Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume. Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J. ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print] PMID: 21814288 [PubMed - as supplied by publisher]

  • 1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives. Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y. Molecules. 2011 Aug 3;16(8):6502-11. PMID: 21814162 [PubMed - in process]

  • Towards the Growth of an Aligned Single-Layer MoS2 Film. Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L. Langmuir. 2011 Aug 3. [Epub ahead of print] PMID: 21812475 [PubMed - as supplied by publisher]

     

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