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Iridium Bromide
IrBr3
Product Product Code Order or Specifications
(2N) 99% Iridium Bromide IR-BR-02 Contact American Elements
(3N) 99.9% Iridium Bromide IR-BR-03 Contact American Elements
(4N) 99.99% Iridium Bromide IR-BR-04 Contact American Elements
(5N) 99.999% Iridium Bromide IR-BR-05 Contact American Elements
Bromide Ionridium Bromide is a highly water soluble crystalline Iridium source for uses compatible with Bromides and lower (acidic) pH. Metallic Bromides are marketed under the trade name AE Bromides™. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine. Iridium Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Iridium(Ir) atomic and molecular weight, atomic number and elemental symbolIridium is a Block D, Group 9, Period 6 element. The number of electrons in each of Iridium's shells is 2, 8, 18, 32, 15, 2 and its electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm. Iridium is only slightly toxic. Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react Iridium Bohr Modelwith any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical Elemental Iridiumcontacts for spark plugs. Iridium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iridium information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed here. Iridium was first discovered by Smithson Tennant in 1804. See Iridium research below.

Formula CAS No. Appearance Molecular Weight
IrBr3
10049-24-8 Red-Brown or Mustard-Grey Crystalline Solid 431.929
PRODUCT CATALOG Bromide Products Foil Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Home

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Iridium

  • A bifunctional nonprecious metal catalyst for oxygen reduction and water oxidation. Gorlin Y, Jaramillo TF. J Am Chem Soc. 2010 Oct 6;132(39):13612-4. PubMed PMID: 20839797.

  • MRI may be sufficient for noninvasive assessment of great vessel stents: an in vitro comparison of MRI, CT, and conventional angiography. Nordmeyer J, Gaudin R, Tann OR, Lurz PC, Bonhoeffer P, Taylor AM, Muthurangu V. AJR Am J Roentgenol. 2010 Oct;195(4):865-71. PubMed PMID: 20858811.

  • High-efficiency red phosphorescent electroluminescence devices based on mixed p / n host matrices. Duan Y, Mazzeo M, Cheng G, Mariano F, Gigli G. Opt Lett. 2010 Oct 1;35(19):3174-6. doi: 10.1364/OL.35.003174. PubMed PMID: 20890324.

  • An Ir-Pt Catalyst for the Multistep Preparation of Functionalized Indoles from the Reaction of Amino Alcohols and Alkynyl Alcohols. Zanardi A, Mata JA, Peris E. Chemistry. 2010 Sep 30. [Epub ahead of print] PubMed PMID: 20886472.

  • Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution. Hartwig JF, Stanley LM. Acc Chem Res. 2010 Sep 28. [Epub ahead of print] PubMed PMID: 20873839.

  • Gold vs. platinum-iridium tip catheter for cavotricuspid isthmus ablation: the AURUM 8 study. Lewalter T, Weiss C, Spencker S, Jung W, Haverkamp W, Willems S, Deneke T, Kautzner J, Wiedemann M, Siebels J, Pitschner HF, Hoffmann E, Hindricks G, Zabel M, Vester E, Schwacke H, Mittmann-Braun E, Lickfett L, Hoffmeister S, Proff J, Mewis C, Bauer W; for the AURUM 8 Study Investigators. Europace. 2010 Sep 28. [Epub ahead of print] PubMed PMID: 20876601.

  • Modulation of iridium(iii) phosphorescence via photochromic ligands: a density functional theory study. Li X, Zhang Q, Tu Y, Agren H, Tian H. Phys Chem Chem Phys. 2010 Sep 28. [Epub ahead of print] PubMed PMID: 20877839.

  • Simultaneous iridium catalysed oxidation and enzymatic reduction employing orthogonal reagents. Mutti FG, Orthaber A, Schrittwieser JH, Vries JG, Pietschnig R, Kroutil W.Chem Commun (Camb). 2010 Sep 27. [Epub ahead of print] PubMed PMID: 20871888.

  • Regio- and Enantioselective Iridium-Catalyzed Allylation of Thiophenol: Synthesis of Enantiopure Allyl Phenyl Sulfides. Zheng S, Gao N, Liu W, Liu D, Zhao X, Cohen T. Org Lett. 2010 Sep 23. [Epub ahead of print] PubMed PMID: 20863112.

  • Enantioselective and Z/E-Selective Conjugate Addition of ?-Substituted Cyanoacetates to Acetylenic Esters Catalyzed by Bifunctional Ruthenium and Iridium Complexes. Hasegawa Y, Gridnev ID, Ikariya T. Angew Chem Int Ed Engl. 2010 Sep 20. [Epub ahead of print] PubMed PMID: 20857471.

  • Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents. Vanchura Ii BA, Preshlock SM, Roosen PC, Kallepalli VA, Staples RJ, Maleczka Jr RE, Singleton DA, Smith Iii MR. Chem Commun (Camb). 2010 Sep 20. [Epub ahead of print] PubMed PMID: 20852803.

  • The Triplet State of fac-Ir(ppy)(3). Hofbeck T, Yersin H. Inorg Chem. 2010 Sep 20. [Epub ahead of print] PubMed PMID: 20853860.

  • Mechanistic Studies of the Reaction of Ir(III) Porphyrin Hydride with 2,2,6,6-Tetramethylpiperidine-1-oxyl to an Unsupported Ir-Ir Porphyrin Dimer. Lee SY, Cheung CW, Hsu IJ, Chan KS. Inorg Chem. 2010 Sep 17. [Epub ahead of print] PubMed PMID: 20849073.

  • Improved Catalysts for the Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Based on Charton Analysis. Mantilli L, Gérard D, Torche S, Besnard C, Mazet C. Chemistry. 2010 Sep 15. [Epub ahead of print] PubMed PMID: 20845413.

  • Simple Conjugated Polymers with On-Chain Phosphorescent Iridium(III) Complexes: Toward Ratiometric Chemodosimeters for Detecting Trace Amounts of Mercury(II). Shi HF, Liu SJ, Sun HB, Xu WJ, An ZF, Chen J, Sun S, Lu XM, Zhao Q, Huang W. Chemistry. 2010 Sep 14. [Epub ahead of print] PubMed PMID: 20839372.

  • Photophysical Properties of the Series fac- and mer-(1-Phenylisoquinolinato-N(?)C(2'))(x)(2-phenylpyridinato-N(?)C(2'))(3-x)Iridi um(III) (x = 1-3) (61?). Deaton JC, Young RH, Lenhard JR, Rajeswaran M, Huo S. Inorg Chem. 2010 Sep 14. [Epub ahead of print] PubMed PMID: 20839842.

  • Coating of tips for electrochemical scanning tunneling microscopy by means of silicon, magnesium, and tungsten oxides. Salerno M. Rev Sci Instrum. 2010 Sep;81(9):093703. PubMed PMID: 20886983.

  • High Dose Rate Brachytherapy in the Treatment of cervical cancer: preliminary experience with cobalt 60 Radionuclide source-A Prospective Study. Ntekim A, Adenipekun A, Akinlade B, Campbell O. Clin Med Insights Oncol. 2010 Aug 19;4:89-94. PubMed PMID: 20838638; PubMed Central PMCID: PMC2934612.

  • Kitaev-Heisenberg model on a honeycomb lattice: possible exotic phases in iridium oxides A2IrO3. Chaloupka J, Jackeli G, Khaliullin G. Phys Rev Lett. 2010 Jul 9;105(2):027204. Epub 2010 Jul 9. PubMed PMID: 20867736.

  • Italian network for human biomonitoring of metals: preliminary results from two Regions. Bocca B, Mattei D, Pino A, Alimonti A. Ann Ist Super Sanita. 2010;46(3):259-65. PubMed PMID: 20847458.

 

Recent Research & Development for Bromides

  • Synthesis of Enol Lactones via Cu(I)-Catalyzed Intramolecular O-Vinylation of Carboxylic Acids. Sun C, Fang Y, Li S, Zhang Y, Zhao Q, Zhu S, Li C. Org Lett. 2010 Jan 5. [Epub ahead of print] PMID: 19689116 [PubMed - as supplied by publisher]

  • Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides. Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Science. 2009 Aug 13. [Epub ahead of print] PMID: 19679769 [PubMed - as supplied by publisher]

  • (2-Pyridyl)acetone-Promoted Cu-Catalyzed O-Arylation of Phenols with Aryl Iodides, Bromides, and Chlorides. Zhang Q, Wang D, Wang X, Ding K. J Org Chem. 2009 Aug 12. [Epub ahead of print] PMID: 19673481 [PubMed - as supplied by publisher]

  • Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides. Vechorkin O, Barmaz D, Proust V, Hu X. J Am Chem Soc. 2009 Aug 11. [Epub ahead of print] PMID: 19670863 [PubMed - as supplied by publisher]

  • Zn-mediated electrochemical allylation of aldehydes in aqueous ammonia. Huang JM, Dong Y. Chem Commun (Camb). 2009 Jul 14;(26):3943-5. Epub 2009 May 28. PMID: 19662260 [PubMed - in process]

  • Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols. Salvi L, Kim JG, Walsh PJ. J Am Chem Soc. 2009 Aug 4. [Epub ahead of print] PMID: 19653691 [PubMed - as supplied by publisher]

  • Direct Palladium-Catalyzed Arylations of Aryl Bromides with 2/9-Substituted Pyrimido[5,4-b]indolizines. Jiang M, Li T, Meng L, Yang C, Xie Y, Ding J. J Comb Chem. 2009 Jul 31. [Epub ahead of print] PMID: 19645499 [PubMed - as supplied by publisher]

  • Versatile chemoselectivity in Ni-catalyzed multiple bond carbonylations and cyclocarbonylations in CO(2)-expanded liquids. del Moral D, Banet Osuna AM, Córdoba A, Moretó JM, Veciana J, Ricart S, Ventosa N. Chem Commun (Camb). 2009 Aug 21;(31):4723-5. Epub 2009 Jun 29. PMID: 19641822 [PubMed - in process]

  • Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination of N-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides. Hatakeyama T, Hashimoto S, Ishizuka K, Nakamura M. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639999 [PubMed - as supplied by publisher]

  • Hexacationic Dendriphos Ligands in the Pd-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: Scope and Mechanistic Studies. Snelders DJ, van Koten G, Klein Gebbink RJ. J Am Chem Soc. 2009 Jul 29. [Epub ahead of print] PMID: 19639941 [PubMed - as supplied by publisher]

  • Can One Predict Changes from S(N)1 to S(N)2 Mechanisms? Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. J Am Chem Soc. 2009 Jul 27. [Epub ahead of print] PMID: 19634906 [PubMed - as supplied by publisher]

  • A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides. Liao Q, Wang Y, Zhang L, Xi C. J Org Chem. 2009 Jul 15. [Epub ahead of print] PMID: 19603753 [PubMed - as supplied by publisher]

  • Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides. Shi L, Chu Y, Knochel P, Mayr H. Org Lett. 2009 Jul 14. [Epub ahead of print] PMID: 19601592 [PubMed - as supplied by publisher]

  • C5-Modified nucleosides exhibiting anticancer activity. Lee YS, Park SM, Kim HM, Park SK, Lee K, Lee CW, Kim BH. Bioorg Med Chem Lett. 2009 Aug 15;19(16):4688-91. Epub 2009 Jun 21. PMID: 19596579 [PubMed - in process]

  • Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. Vo GD, Hartwig JF. J Am Chem Soc. 2009 Jul 10. [Epub ahead of print] PMID: 19591470 [PubMed - as supplied by publisher]

  • New One-Pot Synthesis of (E)-beta-Aryl Vinyl Halides from Styrenes. Pawluc´ P, Hreczycho G, Szudkowska J, Kubicki M, Marciniec B. Org Lett. 2009 Jul 2. [Epub ahead of print] PMID: 19572730 [PubMed - as supplied by publisher]

  • The Scope and Limitation of Nickel-Catalyzed Aminocarbonylation of Aryl Bromides from Formamide Derivatives. Jo Y, Ju J, Choe J, Song KH, Lee S. J Org Chem. 2009 Jul 2. [Epub ahead of print] PMID: 19572571 [PubMed - as supplied by publisher]

  • Electroencephalographic and behavioral convulsant effects of hydrobromide and hydrochloride salts of bupropion in conscious rodents. Henshall DC, Dürmüller N, White HS, Williams R, Moser P, Dunleavy M, Silverstone PH. Neuropsychiatr Dis Treat. 2009;5:189-206. Epub 2009 Apr 8. PMID: 19557114 [PubMed - in process]

  • A facile route to C2-substituted imidazolium ionic liquids. Ennis E, Handy ST. Molecules. 2009 Jun 19;14(6):2235-45. PMID: 19553895 [PubMed - in process]

  • Synthesis of 1,3-amino alcohol derivatives via a silicon-mediated ring-opening of substituted piperidines. McCall WS, Comins DL. Org Lett. 2009 Jul 2;11(13):2940-2. PMID: 19552467 [PubMed - indexed for MEDLINE]

     

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