Potassium Hexabromoiridate(IV) is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Potassium is a Block S, Group 1, Period 4 element. The number of electrons in each of Potassium's shells is 2, 8, 8, 1 and its electronic configuration is [Ar] 4s1. In its elemental form potassium's CAS number is 7440-09-7. The potassium atom has a radius of 227.2 .pm and it's Van der Waals radius is 275.pm. Potassium is not toxic. Potassium is the seventh most abundant element on earth. In its metallic form it is one of the most reactive and electropositive of all metals and rapidly oxidizes. As with other metals of the alkali group, the metal decomposes in water with the evolution of hydrogen. It catches fire spontaneously in water. In high purity, potassium compounds have numerous pharmacological, medical, and electronics applications. Important compounds include the hydroxide, nitrate, carbonate, chloride, bromide, iodide, and sulfate. Lower purity compounds are used in pyrotechnics for its violet color on ignition and in glass and ceramic glazes to produce this color. Potassium also used as a nutrient in plant growth. Potassium was first discovered by Sir Humphrey Davy in 1807. The origin of the element name comes from the English word 'potash' meaning pot ashes and the Arabic word 'qali' which means alkali. The symbol K originates from the Latin word 'kalium'. See Potassium research below.
Iridium is a Block D, Group 9, Period 6 element. The number of electrons in each of Iridium's shells is 2, 8, 18, 32, 15, 2 and its electronic configuration is [Xe] 4f14 5d7 6s2. In its elemental form iridium's CAS number is 7439-88-5. The iridium atom has a radius of 135.7.pm and it's Van der Waals radius is 200.pm. Iridium is only slightly toxic. Iridium is a member of the platinum group of metals. It is the most corrosion resistant metal known. It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. It is alloyed with platinum to produce highly corrosive resistant electrical contacts for spark plugs. Iridium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iridium information, including Technical Data, Safety Data and its high purityproperties, research, applications and other useful facts are discussed here. Iridium was first discovered by Smithson Tennant in 1804. See Iridium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Kv7 Channels Can Function without Constitutive Calmodulin Tethering.
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Hydrogen Sulfide as Endothelium-Derived Hyperpolarizing Factor Sulfhydrates Potassium Channels.
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Effects of pH on Potassium: New Explanations for Old Observations.
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J Am Soc Nephrol. 2011 Oct 6. [Epub ahead of print]
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J Smooth Muscle Res. 2011;47(3-4):89-110.
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J Exp Bot. 2011 Oct 5. [Epub ahead of print]
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J Clin Endocrinol Metab. 2011 Oct 5. [Epub ahead of print]
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Mutation of the gastric hydrogen-potassium ATPase alpha subunit causes iron-deficiency anemia in mice.
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Blood. 2011 Oct 5. [Epub ahead of print]
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J Cell Biochem. 2011 Oct 4. doi: 10.1002/jcb.23393. [Epub ahead of print]
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The effects of cannabidiolic acid and cannabidiol on contractility of the gastrointestinal tract of Suncus murinus.
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Arch Pharm Res. 2011 Sep;34(9):1509-17. Epub 2011 Oct 6.
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J Neurophysiol. 2011 Oct 5. [Epub ahead of print]
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Prognostic significance of biochemical markers in African Burkitt's lymphoma.
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21975335
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Formulating a new basis for the treatment against botulinum neurotoxin intoxication: 3,4-Diaminopyridine prodrug design and characterization.
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Bioorg Med Chem. 2011 Sep 14. [Epub ahead of print]
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Shape-tailoring and catalytic function of anisotropic gold nanostructures.
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In-Water Dehydrative Alkylation of Ammonia and Amines with Alcohols by a Polymeric Bimetallic Catalyst.
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Green chemiluminescence from a bis-cyclometalated iridium(iii) complex with an ancillary bathophenanthroline disulfonate ligand.
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Analyst. 2011 Jun 27. [Epub ahead of print]
PMID:
21709858
[PubMed - as supplied by publisher]
Evaluation of cuprimine® and syprine® for decorporation of radioisotopes of cesium, cobalt, iridium and strontium.
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PMID:
21709497
[PubMed - in process]
The Role of Coordination Geometry in Dictating the Barrier to Hydride Migration in d6 Square Pyramidal Iridium and Rhodium Pincer Complexes.
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J Am Chem Soc. 2011 Jun 24. [Epub ahead of print]
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Net oxidative addition of C(sp3)-F bonds to iridium via initial C-H bond activation.
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Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H(3)B·NMeHBH(2)·NMeH(2) Bound to Iridium.
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J Am Chem Soc. 2011 Jul 1. [Epub ahead of print]
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21699193
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Ir-catalysed formation of C-F bonds. From allylic alcohols to a-fluoroketones.
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Chem Commun (Camb). 2011 Jun 22. [Epub ahead of print]
PMID:
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Rhodium and iridium complexes of an asymmetric bicyclic NHC bearing secondary pyridyl donors.
Newman PD, Cavell KJ, Hallett AJ, Kariuki BM.
Dalton Trans. 2011 Jun 20. [Epub ahead of print]
PMID:
21687899
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Atomic layer-deposited tunnel oxide stabilizes silicon photoanodes for water oxidation.
Chen YW, Prange JD, Dühnen S, Park Y, Gunji M, Chidsey CE, McIntyre PC.
Nat Mater. 2011 Jun 19;10(7):539-44. doi: 10.1038/nmat3047.
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21685904
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A Nonemissive Iridium(III) Complex That Specifically Lights-Up the Nuclei of Living Cells.
Li C, Yu M, Sun Y, Wu Y, Huang C, Li F.
J Am Chem Soc. 2011 Jul 1. [Epub ahead of print]
PMID:
21682270
[PubMed - as supplied by publisher]
Synthesis, Structure, and Reactivity of Hydridoiridium Complexes Bearing a Pincer-Type PSiP Ligand.
Fang H, Choe YK, Li Y, Shimada S.
Chem Asian J. 2011 Jun 15. doi: 10.1002/asia.201100085. [Epub ahead of print]
PMID:
21678557
[PubMed - as supplied by publisher]
Anodic Deposition of Colloidal Iridium Oxide Thin Films from Hexahydroxyiridate(IV) Solutions.
Zhao Y, Vargas-Barbosa NM, Hernandez-Pagan EA, Mallouk TE.
Small. 2011 Jun 16. doi: 10.1002/smll.201100485. [Epub ahead of print]
PMID:
21678551
[PubMed - as supplied by publisher]
Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes.
Schley ND, Blakemore JD, Subbaiyan NK, Incarvito CD, D'Souza F, Crabtree RH, Brudvig GW.
J Am Chem Soc. 2011 Jun 15. [Epub ahead of print]
PMID:
21671679
[PubMed - as supplied by publisher]
Fine tuning of emission color of iridium(iii) complexes from yellow to red via substituent effect on 2-phenylbenzothiazole ligands: synthesis, photophysical, electrochemical and DFT study.
Li M, Zeng H, Meng Y, Sun H, Liu S, Lu Z, Huang Y, Pu X.
Dalton Trans. 2011 Jul 21;40(27):7153-64. Epub 2011 Jun 10.
PMID:
21666891
[PubMed - in process]
A 50-Year Record of Platinum, Iridium, and Rhodium in Antarctic Snow: Volcanic and Anthropogenic Sources.
Soyol-Erdene TO, Huh Y, Hong S, Hur SD.
Environ Sci Technol. 2011 Jun 21. [Epub ahead of print]
PMID:
21662990
[PubMed - as supplied by publisher]
Iridium-catalysed condensation of alcohols and amines as a method for aminosugar synthesis.
Cumpstey I, Agrawal S, Borbas KE, Martín-Matute B.
Chem Commun (Camb). 2011 Jul 21;47(27):7827-9. Epub 2011 Jun 8.
PMID:
21655585
[PubMed - in process]
Catalytic-adsorptive stripping voltammetric determination of ultra-trace iridium(III). Application to fresh- and sea-water.
Locatelli C.
Talanta. 2011 Jul 15;85(1):546-50. Epub 2011 Apr 16.
PMID:
21645739
[PubMed - in process]
Synthesis and hydroamination catalysis with 3-aryl substituted pyrrolyl and dipyrrolylmethane titanium(iv) complexes.
Swartz Ii DL, Staples RJ, Odom AL.
Dalton Trans. 2011 Jun 6. [Epub ahead of print]
PMID:
21643608
[PubMed - as supplied by publisher]
Flow injection analysis combined with a hydrothermal flow reactor: Application to kinetic determination of trace amounts of iridium using a water-soluble porphyrin.
Kawamura K, Ikoma K, Igarashi S, Hisamoto H, Yao T.
Talanta. 2011 Jun 15;84(5):1318-22. Epub 2011 Mar 4.
PMID:
21641445
[PubMed - in process]
Iridium Complexes of the Doubly Cyclometalated NHC Ligand IMes''
Navarro J, Torres O, Marti´n M, Sola E.
J Am Chem Soc. 2011 Jun 29;133(25):9738-9740. Epub 2011 Jun 8.
PMID:
21639135
[PubMed - as supplied by publisher]