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Lanthanum Acetylacetonate
La(CH3COCHCOCH3)3 • xH2O
64424-12-0

Product Product Code Order or Specifications
(2N) 99% Lanthanum Acetylacetonate LA-ACAC-02 Contact American Elements
(3N) 99.9% Lanthanum Acetylacetonate LA-ACAC-03 Contact American Elements
(4N) 99.99% Lanthanum Acetylacetonate LA-ACAC-04 Contact American Elements
(5N) 99.999% Lanthanum Acetylacetonate LA-ACAC-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
La(CH3COCHCOCH3)3 • xH2O 64424-12-0 24859531 1621059 MFCD00149057 238-187-8 4-hydroxypent-3-en-2-one: lanthanum N/A CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[La] 1/3C5H8O2.La.H2O/c3*1-4(6)3-5(2)7;/h3*3H2,1-2H3;1H2 YLJWVIYLZXDNHZ-UHFFFAOYSA-N

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
C15H24LaO6 436.23 White g/cm3 439.064 439.064 0 Safety Data Sheet


Acetylaceton Formula Diagram (C5H8O2)Lanthanum Acetylacetonate is a Lanthanum source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and Acetylacetonate Packaging, Lab Quantitymetallo-organic compounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Lanthanum Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Lanthanum Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Lanthanum include cracking reactions in FCC catalysts, especially to manufacture low-octane fuel for heavy crude oil. It is utilized in green phosphors based on the aluminate (La0.4Ce0.45Tb0.15)PO4..American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lanthanum(La) atomic and molecular weight, atomic number and elemental symbol Lanthanum is a Block F, Group 3, Period 6 element. The number of electrons in each of Lanthanum's shells is 2, 8, 18, 18, 9, 2 and its electronic configuration is [Xe] 5d1 6s2. In its elemental form lanthanum 's CAS number is 7439-91-0. The lanthanum atom has a radius of 187.pm and it's Van der Waals radius is 200.pm. Lanthanum and compounds of Elemental LanthanumLanthanum are somewhat toxic. Lanthanum is one of the products manufactured and distributed under the tradename AE Rare EarthsLanthanum Bohr Model. Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths. After cerium, it is the second most abundant of the rare earths. Lanthanum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.Lanthanum-rich lanthanide compositions have been used extensively for cracking reactions in FCC catalysts, especially to manufacture low-octane fuel for heavy crude oil. The name Lanthanum originates from the Greek word Lanthaneia which means 'To lie hidden'. See Lanthanum research below.

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Safety &
Handling
  Exclamation Mark-Acute Toxicity Health Hazard
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Warning H302-H312-H315-H319-H332-H335-H351 Xn 20/21/22-36/37/38-40 26-36/37/39-45 N/A N/A 3

 

Synonyms for Lanthanum Acetylacetonate Include:


2,4-Pentanedione lanthanum derivative
La(acac)3
Lanthanum(III) 2,4-pentanedionate
Lanthanum ; pentane-2,4-dione;hydrate

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 


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Recent Research & Development for Lanthanum

  • Intestinal pseudo-obstruction secondary to persistent constipation due to lanthanum carbonate. Camarero-Temiño V, Mercado-Valdivia V, Hijazi-Prieto B, Abaigar-Luquin P. Nefrologia. 2012 Jan 27;32(1):129. doi: 10.3265/Nefrologia.pre2011.Nov.11191. English, Spanish. No abstract available. PMID: 22294019 [PubMed - as supplied by publisher]

  • Chlorination of Lanthanum Oxide. Gaviría JP, Navarro LG, Bohé AE. J Phys Chem A. 2012 Jan 25. [Epub ahead of print] PMID: 22280490 [PubMed - as supplied by publisher]

  • Dipyridyl ?-diketonate complexes and their use as metalloligands in the formation of mixed-metal coordination networks. Burrows AD, Mahon MF, Renouf CL, Richardson C, Warren AJ, Warren JE. Dalton Trans. 2012 Jan 26. [Epub ahead of print] PMID: 22278306 [PubMed - as supplied by publisher]

  • Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks. Colodrero RM, Olivera-Pastor P, Losilla ER, Aranda MA, Leon-Reina L, Papadaki M, McKinlay AC, Morris RE, Demadis KD, Cabeza A. Dalton Trans. 2012 Jan 25. [Epub ahead of print] PMID: 22278089 [PubMed - as supplied by publisher]

  • Biosorption and desorption of lanthanum(III) and neodymium(III) in fixed-bed columns with Sargassum sp.: Perspectives for separation of rare earth metals. Oliveira RC, Guibal E, Garcia O. Biotechnol Prog. 2012 Jan 24. doi: 10.1002/btpr.1525. [Epub ahead of print] PMID: 22275117 [PubMed - as supplied by publisher]

  • Mid-infrared spectral broadening in an ultrafast laser inscribed gallium lanthanum sulphide waveguide. McCarthy JE, Bookey HT, Psaila ND, Thomson RR, Kar AK. Opt Express. 2012 Jan 16;20(2):1545-51. doi: 10.1364/OE.20.001545. PMID: 22274497 [PubMed - in process]

  • Redetermination of LaZn(5) based on single crystal X-ray diffraction data. Oshchapovsky I, Zelinska O, Rozdzynska-Kielbik B, Pavlyuk V. Acta Crystallogr Sect E Struct Rep Online. 2012 Jan 1;68(Pt 1):i1. Epub 2011 Dec 3. PMID: 22259311 [PubMed - in process]

  • Novel LaBO(3) hollow nanospheres of size 34±2nm templated by polymeric micelles. Sasidharan M, Gunawardhana N, Luitel HN, Yokoi T, Inoue M, Yusa SI, Watari T, Yoshio M, Tatsumi T, Nakashima K. J Colloid Interface Sci. 2011 Dec 28. [Epub ahead of print] PMID: 22257959 [PubMed - as supplied by publisher]

  • Lanthanum Carbonate Reduces Urine Phosphorus Excretion: Evidence of High-Capacity Phosphate Binding. Pennick M, Poole L, Dennis K, Smyth M. Ren Fail. 2012 Jan 17. [Epub ahead of print] PMID: 22250993 [PubMed - as supplied by publisher]

  • Effect of Lanthanum on Rooting of In Vitro Regenerated Shoots of Saussurea involucrata Kar. et Kir. Guo B, Xu LL, Guan ZJ, Wei YH. Biol Trace Elem Res. 2012 Jan 13. [Epub ahead of print] PMID: 22246792 [PubMed - as supplied by publisher]

  • Fabrication, Characterization, and Application of a Composite Adsorbent for Simultaneous Removal of Arsenic and Fluoride. Jing C, Cui J, Huang Y, Li A. ACS Appl Mater Interfaces. 2012 Jan 25. [Epub ahead of print] PMID: 22235839 [PubMed - as supplied by publisher]

  • Gas-phase lanthanide chloride clusters: relationships among ESI abundances and DFT structures and energetics. Rutkowski PX, Michelini MC, Gibson JK. Phys Chem Chem Phys. 2012 Feb 14;14(6):1965-77. Epub 2012 Jan 6. PMID: 22227857 [PubMed - in process]

  • Enhanced electrochemical properties of fluoride-coated LiCoO2 thin films. Lee HJ, Kim SB, Park YJ. Nanoscale Res Lett. 2012 Jan 5;7(1):16. [Epub ahead of print] PMID: 22221488 [PubMed - as supplied by publisher]

  • La(5)Zn(2)Sn. Oshchapovsky I, Pavlyuk V, Dmytriv G, Chumak I, Ehrenberg H. Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):i65. Epub 2011 Oct 22. PMID: 22219730 [PubMed - in process]

  • Lanthanum chloride bidirectionally influences calcification in bovine vascular muscle smooth cells. Zhao WH, Gou BD, Zhang TL, Wang K. J Cell Biochem. 2011 Dec 28. doi: 10.1002/jcb.24049. [Epub ahead of print] PMID: 22213182 [PubMed - as supplied by publisher]

  • The Intramolecular Rearrangement of Phosphinohydrazides [R'(2)P-NR-NR-M] ? [RN?PR'(2)-NR-M]: General Rules and Exceptions. Transformations of Bulky Phosphinohydrazines (R-NH-N(PPh(2))(2), R = tBu, Ph(2)P). Kornev AN, Sushev VV, Panova YS, Belina NV, Lukoyanova OV, Fukin GK, Ketkov SY, Abakumov GA, Lönnecke P, Hey-Hawkins E. Inorg Chem. 2012 Jan 16;51(2):874-81. Epub 2011 Dec 30. PMID: 22208524 [PubMed - in process]

  • Medicare Part D: challenges for dialysis patients. Part 1. Smith S, Witten B, Paykin C, Weiner S, Chianchiano D, St Peter WL. Nephrol News Issues. 2011 Nov;25(12):38-40, 42, 44-5. PMID: 22204167 [PubMed - indexed for MEDLINE]

  • Nanocrystalline Brookite with Enhanced Stability and Photocatalytic Activity: Influence of Lanthanum(III) Doping. Perego C, Wang YH, Durupthy O, Cassaignon S, Revel R, Jolivet JP. ACS Appl Mater Interfaces. 2012 Jan 17. [Epub ahead of print] PMID: 22201282 [PubMed - as supplied by publisher]

  • The light-sensitive conductance of melanopsin-expressing Joseph and Hesse cells in amphioxus. Pulido C, Malagón G, Ferrer C, Chen JK, Angueyra JM, Nasi E, Gomez Mdel P. J Gen Physiol. 2012 Jan;139(1):19-30. PMID: 22200946 [PubMed - in process]

  • Preparation and characterization of La(III) encapsulated silica gel/chitosan composite and its metal uptake studies. Gandhi MR, Meenakshi S. J Hazard Mater. 2012 Feb 15;203-204:29-37. Epub 2011 Nov 28. PMID: 22197561 [PubMed - in process]

     

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