American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. See See safety data and research below and pricing/lead time above. American Elements specializes in producing Lithium Boards in various thicknesses and sizes. Most Boards are produced from cast Ingots for use in coating and thin film Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Organometallic and Chemical Vapor Deposition (MOCVD) for specific applications such as fuel cells and solar energy. Thickness can range from 0.04" to 0.25" for all metals. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and in the form of solutions and organometallics. We also produce Lithium as rods, powder and plates. Other shapes are available by request.
Lithium is a Block S, Group 1, Period 2 element. The number of electrons in each of Lithium's shells is 2, 1 and its electronic configuration is [He] 2s1. In its elemental form lithium's CAS number is 7439-93-2. The lithium atom has a radius of 152.pm and it's Van der Waals radius is 182.pm. Lithium is a member of the alkali group of metals. It has the highest specific heat of any material and the highest electrochemical potential. This makes it important in applications involving heat transfer and as the anode in batteries. Lithium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Lithium is a dopant in advanced optical glass. It is used as an alloy in light weight metals. Lithium stearate is a common high temperature lubricant. Lithium was first discovered by Johann Arvedson in 1817. The origin of the name Lithium comes from the Greek word lithose which means "stone". See Lithium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Bullion and bar forms are best if purchasing solely for physical possession and risk exposure.
Do men with prostate abnormalities (prostatitis/benign prostatic hyperplasia/prostate cancer) develop immunity to spermatozoa or seminal plasma?
Hoover P, Naz RK.
Int J Androl. 2012 Feb 9. doi: 10.1111/j.1365-2605.2011.01246.x. [Epub ahead of print]
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Determination of absorbed dose to water around a clinical HDR (192)Ir source using LiF:Mg,Ti TLDs demonstrates an LET dependence of detector response.
Carlsson Tedgren A, Elia R, Hedtja¨rn H, Olsson S, Alm Carlsson G.
Med Phys. 2012 Feb;39(2):1133.
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Synthesis of Triptycene-Derived Macrotricyclic Host Containing Two Dibenzo-[18]-crown-6 Moieties and Its Complexation with Paraquat Derivatives: Li(+)-Ion-Controlled Binding and Release of the Guests in the Complexes.
Han Y, Lu HY, Zong QS, Guo JB, Chen CF.
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Synthesis and Characterization of ß-Diketiminate Germanium(II) Compounds.
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Inorg Chem. 2012 Feb 9. [Epub ahead of print]
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GSK-3 and Wnt Signaling in Neurogenesis and Bipolar Disorder.
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Front Mol Neurosci. 2012;5:1. Epub 2012 Jan 30.
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Anisotropic Ionic Mobility of Lithium Salts in Lamellar Liquid Crystalline Polymer Networks.
Ramón-Gimenez L, Storz R, Haberl J, Finkelmann H, Hoffmann A.
Macromol Rapid Commun. 2012 Feb 8. doi: 10.1002/marc.201100792. [Epub ahead of print]
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Ab initio and density functional theoretical design and screening of model crown ether based ligand (host) for extraction of lithium metal ion (guest): effect of donor and electronic induction.
Boda A, Ali SM, Rao H, Ghosh SK.
J Mol Model. 2012 Feb 10. [Epub ahead of print]
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In situ TEM observation of lithium nanoparticle growth and morphological cycling.
Ghatak J, Guan W, Möbus G.
Nanoscale. 2012 Feb 8. [Epub ahead of print]
PMID:
22318611
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Psychotropic drug-induced weight gain and other metabolic complications in a Swiss psychiatric population.
Choong E, Bondolfi G, Etter M, Jermann F, Aubry JM, Bartolomei J, Gholam-Rezaee M, Eap CB.
J Psychiatr Res. 2012 Feb 6. [Epub ahead of print]
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Using adjunctive treatments when first-line antidepressants fail.
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J Clin Psychiatry. 2012 Jan;73(1):e01.
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What Can We Learn from Ionic Conductivity Measurements in Polymer Electrolytes? - A Case Study on PEO-NaI and PEO-LiTFSI.
Stolwijk NA, Wiencierz M, Heddier C, Kösters J.
J Phys Chem B. 2012 Feb 8. [Epub ahead of print]
PMID:
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Exfoliation and Reassembly of Cobalt Oxide Nanosheets into a Reversible Lithium-Ion Battery Cathode.
Compton OC, Abouimrane A, An Z, Palmeri MJ, Brinson LC, Amine K, Nguyen ST.
Small. 2012 Feb 8. doi: 10.1002/smll.201101131. [Epub ahead of print]
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Tanshinone IIA protects PC12 cells from ß-amyloid(25-35)-induced apoptosis via PI3K/Akt signaling pathway.
Dong H, Mao S, Wei J, Liu B, Zhang Z, Zhang Q, Yan M.
Mol Biol Rep. 2012 Feb 8. [Epub ahead of print]
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A facile titanium glycolate precursor route to mesoporous Au/Li4Ti5O12 spheres for high-rate lithium ion batteries.
Li C, Li Q, Chen L, Wang T.
ACS Appl Mater Interfaces. 2012 Feb 7. [Epub ahead of print]
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Enhanced Performance of Solution-Processed Amorphous LiYInZnO Thin-Film Transistors.
Koo CY, Song K, Jung Y, Yang W, Kim SH, Jeong S, Moon J.
ACS Appl Mater Interfaces. 2012 Feb 6. [Epub ahead of print]
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TiO(2) Nanocages: Fast Synthesis, Interior Functionalization and Improved Lithium Storage Properties.
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Adv Mater. 2012 Feb 7. doi: 10.1002/adma.201104546. [Epub ahead of print]
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Enhanced electrochemical properties of LiFePO(4) by Mo-substitution and graphitic carbon-coating via a facile and fast microwave-assisted solid-state reaction.
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Phys Chem Chem Phys. 2012 Feb 7. [Epub ahead of print]
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Penetration of alkali atoms throughout a graphene membrane: theoretical modeling.
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Nanoscale. 2012 Feb 7. [Epub ahead of print]
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Bifurcated Hydrogen-Bond in Lithium Nitrate Trihydrate Probed by Ab Initio Molecular Dynamics.
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Material Safety Data Sheet
1 Identification of substance
Product details
Trade name Lithium metal
2 Composition/Data on components:
Chemical characterization: Designation: (CAS#)
Lithium (CAS# 7439-93-2), 100%
Identification number(s):
EINECS Number: 231-102-5
EC Number: 003-001-00-4
Additonal information: Packaged under mineral oil (CAS# 8012-95-1)
3 Hazards identification
Hazard designation:
C Corrosive
F Highly flammable
Information pertaining to particular dangers for man and environment
R 14/15 Reacts violently with water, liberating extremely flammable gases.
R 34 Causes burns.
4 First aid measures
General information
Instantly remove any clothing soiled by the product.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
Seek immediate medical advice.
After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowing Seek immediate medical advice.
5 Fire fighting measures
Suitable extinguishing agents Extinguishing powder. Do not use water.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Do not flush with water or aqueous cleansing agents
Keep away from ignition sources.
Additional information:
See Section 7 for information on safe handling
See section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
Handling
Information for safe handling:
Handle under dry argon.
Keep containers tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Protect from humidity and keep away from water.
Keep ignition sources away - Do not smoke.
Storage
Requirements to be met by storerooms and containers:
No special requirements.
Information about storage in one common storage facility:
Store away from water.
Store away from air.
Do not store together with acids.
Store away from oxidizing agents.
Store away from halogens.
Further information about storage conditions:
Store under dry argon.
Protect from humidity and keep away from water.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Store in a locked cabinet or with access restricted to technical experts or their assistants.
8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with critical values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from foodstuffs, beverages and food.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Breathing equipment: Use breathing protection with high concentrations.
Protection of hands: Impervious gloves
Eye protection:
Safety glasses
Tightly sealed safety glasses.
Full face protection
Face protection
Body protection: Protective work clothing.
9 Physical and chemical properties:
General Information
Form: Solid.
Colour: Silver grey
Smell: Odourless
Value/Range Unit Method
Change in condition
Melting point/Melting range: 180.5 ° C
Boiling point/Boiling range: 1336 ° C
Sublimation temperature / start: Not determined
Flash point: Not applicable
Inflammability (solid, gaseous)
Contact with water liberates extremely flammable gases.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Critical values for explosion:
Lower: Not determined
Upper: Not determined
Steam pressure: Not determined
Density at 20 ° C 0.531 g/cm³
Solubility in / Miscibility with
Water: Reacts violently
Not determined
10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
Materials to be avoided:
Water/moisture
Air
Acids
Oxidizing agents
Halogens
Heavy metal powders
Sulfur
Halocarbons
Carbon dioxide
Dangerous reactions:
Contact with water releases flammable gases
Reacts with heavy metals
Contact with acids releases flammable gases
Dangerous products of decomposition:
Hydrogen
Metal oxide
11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin:
Caustic effect on skin and mucous membranes.
Irritant for skin and mucous membranes.
on the eye:
Strong caustic effect.
Irritant effect.
Sensitization: No sensitizing effect known.
Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations for proper disposal.
Hand over to disposers of hazardous waste.
Must be specially treated under adherence to official regulations.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
14 Transport information
Land transport ADR/RID and GGVS/GGVE (cross-border/domestic)
ADR/RID-GGVS/E Class: 4.3 (W2) Substances which, in contact with
water, emit flammable gases.
Kemler Number: X423
UN-Number: 1415
Packaging group: I
Label 4.3
Designation of goods: 1415 LITHIUM
Maritime transport IMDG/GGVSea:
IMDG/GGVSea Class: 4.3
UN Number: 1415
Label 4.3
Packaging group: I
Correct technical name: LITHIUM
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 4.3
UN/ID Number: 1415
Label 4.3
Packaging group: I
Correct technical name: LITHIUM
15 Regulatory information
Designation according to EC guidelines:
Code letter and hazard designation of product:
C Corrosive F Highly flammable
Safety phrases:
8 Keep container dry.
43 In case of fire, use powdered extinguishing agent. Never use water.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
National regulations
Information about limitation of use:
For use only by technically qualified individuals.
Employment restrictions concerning young persons must be observed.
Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Proud sponsors of Aeromat 2012. Please join us and our customers & co-sponsors Boeing and ATI on
June 18-20, 2012
in Charlotte, North Carolina
American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. See See safety data and research below and pricing/lead time above. American Elements specializes in producing Lithium Boards in various thicknesses and sizes. Most Boards are produced from cast Ingots for use in coating and thin film Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Organometallic and Chemical Vapor Deposition (MOCVD) for specific applications such as fuel cells and solar energy. Thickness can range from 0.04" to 0.25" for all metals. Materials are produced using crystallization, solid state and other ultra high purification processes such as sublimation. American Elements specializes in producing custom compositions for commercial and research applications and for new proprietary technologies. American Elements also casts any of the rare earth metals and most other advanced materials into rod, bar or plate form, as well as other machined shapes and through other processes such as nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and in the form of solutions and organometallics. We also produce Lithium as rods, powder and plates. Other shapes are available by request.
Lithium is a Block S, Group 1, Period 2 element. The number of electrons in each of Lithium's shells is 2, 1 and its electronic configuration is [He] 2s1. In its elemental form lithium's CAS number is 7439-93-2. The lithium atom has a radius of 152.pm and it's Van der Waals radius is 182.pm. Lithium is a member of the alkali group of metals. It has the highest specific heat of any material and the highest electrochemical
potential. This makes it important in applications involving heat transfer and as the anode in batteries. Lithium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Lithium is a dopant in advanced optical glass. It is used as an alloy in light weight metals. Lithium stearate is a common high temperature lubricant. Lithium was first discovered by Johann Arvedson in 1817. The origin of the name Lithium comes from the Greek word lithose which means "stone". See Lithium research below.
