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Lithium Bromide Hydrate
LiBr • xH2O
Product Product Code Order or Specifications
(2N) 99% Lithium Bromide Hydrate LI-BR-02-HYD Contact American Elements
(3N) 99.9% Lithium Bromide Hydrate LI-BR-03-HYD Contact American Elements
(4N) 99.99% Lithium Bromide Hydrate LI-BR-04-HYD Contact American Elements
(5N) 99.999% Lithium Bromide Hydrate LI-BR-05-HYD Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
LiBr • xH2O 85017-82-9 24868650 23702478 MFCD00149763 231-439-8 lithium bromide hydrate N/A [Li+].[Br-].O InChI=1S/BrH.Li.H2O/h1H;;1H2/q;+1;/p-1 IPLONMMJNGTUAI-UHFFFAOYSA-M

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
BrH2LiO 104.86 N/A N/A 103.944906 103.944906 0 Safety Data Sheet


Bromide IonLithium Bromide Hydrate is a moderately water soluble crystalline Lithium source that decomposes to Lithium oxide on heating. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bromide in an aqueous solution can be detected by adding carbon disulfide (CS2) and chlorine. Lithium Bromide Hydrate is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lithium(Li) atomic and molecular weight, atomic number and elemental symbol Lithium is a Block S, Group 1, Period 2 element. The number of electrons in each of Lithium's shells is 2, 1 and its electronic configuration is [He] 2s1. In its elemental form lithium's CAS number is 7439-93-2. The lithium atom has a radius of 152.pm and it's Van der Waals radius is 182.pm. Lithium is toxic and corrosive. Lithium is a member of the alkali group of metals. It has the highest specific heat of any material and the highest electrochemicalLithium Bohr Model potential. This makes it important in applications involving heat transfer and as the anode in batteries. Lithium is available as metal and compounds with purities from 99% to 99.999% Elemental Lithium(ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Lithium is a dopant in advanced optical glass. It is used as an alloy in light weight metals. Lithium stearate is a common high temperature lubricant. Lithium was first discovered by Johann Arvedson in 1817. The origin of the name Lithium comes from the Greek word lithose which means "stone". See Lithium research below.

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Toxicity
Safety & Handling
  Exclamation Mark-Acute Toxicity
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Warning H302-H315-H319-H335 Xn 22-36/37/38 26-36 N/A N/A 3

 

Synonyms for Lithium Bromide Hydrate Include:


LITHIUM BROMIDE, HYDROUS
LITHIUM BROMIDE MONOHYDRATE

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 

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Production Catalog Available in 36 Countries & Languages

Recent Research & Development for Lithium

  • Do men with prostate abnormalities (prostatitis/benign prostatic hyperplasia/prostate cancer) develop immunity to spermatozoa or seminal plasma? Hoover P, Naz RK. Int J Androl. 2012 Feb 9. doi: 10.1111/j.1365-2605.2011.01246.x. [Epub ahead of print] PMID: 22321000 [PubMed - as supplied by publisher]

  • Determination of absorbed dose to water around a clinical HDR (192)Ir source using LiF:Mg,Ti TLDs demonstrates an LET dependence of detector response. Carlsson Tedgren A, Elia R, Hedtja¨rn H, Olsson S, Alm Carlsson G. Med Phys. 2012 Feb;39(2):1133. PMID: 22320824 [PubMed - as supplied by publisher]

  • Synthesis of Triptycene-Derived Macrotricyclic Host Containing Two Dibenzo-[18]-crown-6 Moieties and Its Complexation with Paraquat Derivatives: Li(+)-Ion-Controlled Binding and Release of the Guests in the Complexes. Han Y, Lu HY, Zong QS, Guo JB, Chen CF. J Org Chem. 2012 Feb 9. [Epub ahead of print] PMID: 22320661 [PubMed - as supplied by publisher]

  • Synthesis and Characterization of ß-Diketiminate Germanium(II) Compounds. Yang Y, Zhao N, Wu Y, Zhu H, Roesky HW. Inorg Chem. 2012 Feb 9. [Epub ahead of print] PMID: 22320161 [PubMed - as supplied by publisher]

  • GSK-3 and Wnt Signaling in Neurogenesis and Bipolar Disorder. Valvezan AJ, Klein PS. Front Mol Neurosci. 2012;5:1. Epub 2012 Jan 30. PMID: 22319467 [PubMed - in process]

  • Anisotropic Ionic Mobility of Lithium Salts in Lamellar Liquid Crystalline Polymer Networks. Ramón-Gimenez L, Storz R, Haberl J, Finkelmann H, Hoffmann A. Macromol Rapid Commun. 2012 Feb 8. doi: 10.1002/marc.201100792. [Epub ahead of print] PMID: 22318912 [PubMed - as supplied by publisher]

  • Ab initio and density functional theoretical design and screening of model crown ether based ligand (host) for extraction of lithium metal ion (guest): effect of donor and electronic induction. Boda A, Ali SM, Rao H, Ghosh SK. J Mol Model. 2012 Feb 10. [Epub ahead of print] PMID: 22318713 [PubMed - as supplied by publisher]

  • In situ TEM observation of lithium nanoparticle growth and morphological cycling. Ghatak J, Guan W, Möbus G. Nanoscale. 2012 Feb 8. [Epub ahead of print] PMID: 22318611 [PubMed - as supplied by publisher]

  • Psychotropic drug-induced weight gain and other metabolic complications in a Swiss psychiatric population. Choong E, Bondolfi G, Etter M, Jermann F, Aubry JM, Bartolomei J, Gholam-Rezaee M, Eap CB. J Psychiatr Res. 2012 Feb 6. [Epub ahead of print] PMID: 22316639 [PubMed - as supplied by publisher]

  • Using adjunctive treatments when first-line antidepressants fail. Thase ME. J Clin Psychiatry. 2012 Jan;73(1):e01. PMID: 22316580 [PubMed - in process]

  • What Can We Learn from Ionic Conductivity Measurements in Polymer Electrolytes? - A Case Study on PEO-NaI and PEO-LiTFSI. Stolwijk NA, Wiencierz M, Heddier C, Kösters J. J Phys Chem B. 2012 Feb 8. [Epub ahead of print] PMID: 22316082 [PubMed - as supplied by publisher]

  • Exfoliation and Reassembly of Cobalt Oxide Nanosheets into a Reversible Lithium-Ion Battery Cathode. Compton OC, Abouimrane A, An Z, Palmeri MJ, Brinson LC, Amine K, Nguyen ST. Small. 2012 Feb 8. doi: 10.1002/smll.201101131. [Epub ahead of print] PMID: 22315165 [PubMed - as supplied by publisher]

  • Tanshinone IIA protects PC12 cells from ß-amyloid(25-35)-induced apoptosis via PI3K/Akt signaling pathway. Dong H, Mao S, Wei J, Liu B, Zhang Z, Zhang Q, Yan M. Mol Biol Rep. 2012 Feb 8. [Epub ahead of print] PMID: 22314911 [PubMed - as supplied by publisher]

  • A facile titanium glycolate precursor route to mesoporous Au/Li4Ti5O12 spheres for high-rate lithium ion batteries. Li C, Li Q, Chen L, Wang T. ACS Appl Mater Interfaces. 2012 Feb 7. [Epub ahead of print] PMID: 22313873 [PubMed - as supplied by publisher]

  • Enhanced Performance of Solution-Processed Amorphous LiYInZnO Thin-Film Transistors. Koo CY, Song K, Jung Y, Yang W, Kim SH, Jeong S, Moon J. ACS Appl Mater Interfaces. 2012 Feb 6. [Epub ahead of print] PMID: 22311703 [PubMed - as supplied by publisher]

  • TiO(2) Nanocages: Fast Synthesis, Interior Functionalization and Improved Lithium Storage Properties. Wang Z, Lou XW. Adv Mater. 2012 Feb 7. doi: 10.1002/adma.201104546. [Epub ahead of print] PMID: 22311574 [PubMed - as supplied by publisher]

  • Enhanced electrochemical properties of LiFePO(4) by Mo-substitution and graphitic carbon-coating via a facile and fast microwave-assisted solid-state reaction. Li D, Huang Y, Sharma N, Chen Z, Jia D, Guo Z. Phys Chem Chem Phys. 2012 Feb 7. [Epub ahead of print] PMID: 22311165 [PubMed - as supplied by publisher]

  • Penetration of alkali atoms throughout a graphene membrane: theoretical modeling. Boukhvalov DW, Virojanadara C. Nanoscale. 2012 Feb 7. [Epub ahead of print] PMID: 22310963 [PubMed - as supplied by publisher]

  • Proteasome inhibition-induced p38 MAPK/ERK signaling regulates autophagy and apoptosis through the dual phosphorylation of glycogen synthase kinase 3ß Choi CH, Lee BH, Ahn SG, Oh SH. Biochem Biophys Res Commun. 2012 Jan 28. [Epub ahead of print] PMID: 22310719 [PubMed - as supplied by publisher]

  • Bifurcated Hydrogen-Bond in Lithium Nitrate Trihydrate Probed by Ab Initio Molecular Dynamics. Muniz-Miranda F, Pagliai M, Cardini G, Righini R. J Phys Chem A. 2012 Feb 6. [Epub ahead of print] PMID: 22309150 [PubMed - as supplied by publisher]

 

Recent Research & Development for Bromides

  • Palladium(ii) thiocarboxamide complexes: synthesis, characterisation and application to catalytic Suzuki coupling reactions. Sindhuja E, Ramesh R, Liu Y. Dalton Trans. 2012 Mar 8. [Epub ahead of print] PMID: 22399145 [PubMed - as supplied by publisher]

  • Direct Arylation of Benzene with Aryl Bromides using High-Temperature/High-Pressure Process Windows: Expanding the Scope of C?H Activation Chemistry. Pieber B, Cantillo D, Kappe CO. Chemistry. 2012 Mar 7. doi: 10.1002/chem.201103748. [Epub ahead of print] PMID: 22396386 [PubMed - as supplied by publisher]

  • Copper-Free Asymmetric Allylic Alkylation Using Grignard Reagents on Bifunctional Allylic Bromides. Grassi D, Alexakis A. Org Lett. 2012 Mar 6. [Epub ahead of print] PMID: 22394218 [PubMed - as supplied by publisher]

  • Palladium-Catalyzed N-Arylation of 2-Aminothiazoles. McGowan MA, Henderson JL, Buchwald SL. Org Lett. 2012 Mar 6. [Epub ahead of print] PMID: 22394197 [PubMed - as supplied by publisher]

  • A Guide to Sonogashira Cross-Coupling Reactions: The Influence of Substituents in Aryl Bromides, Acetylenes, and Phosphines. Schilz M, Plenio H. J Org Chem. 2012 Mar 6. [Epub ahead of print] PMID: 22390837 [PubMed - as supplied by publisher]

  • Stereoselective C-Glycosylation Reactions with Arylzinc Reagents. Lemaire S, Houpis IN, Xiao T, Li J, Digard E, Gozlan C, Liu R, Gavryushin A, Dične C, Wang Y, Farina V, Knochel P. Org Lett. 2012 Mar 2. [Epub ahead of print] PMID: 22385274 [PubMed - as supplied by publisher]

  • Nickel-Catalyzed Heck-Type Alkenylation of Secondary and Tertiary ?-Carbonyl Alkyl Bromides. Liu C, Tang S, Liu D, Yuan J, Zheng L, Meng L, Lei A. Angew Chem Int Ed Engl. 2012 Mar 1. doi: 10.1002/anie.201108350. [Epub ahead of print] PMID: 22383291 [PubMed - as supplied by publisher]

  • Theoretical Study on the Mechanism of Ni-Catalyzed Alkyl-Alkyl Suzuki Cross-Coupling. Li Z, Jiang YY, Fu Y. Chemistry. 2012 Feb 28. doi: 10.1002/chem.201103882. [Epub ahead of print] PMID: 22374716 [PubMed - as supplied by publisher]

  • Regioselective synthesis and antimicrobial activities of some novel aryloxyacetic acid derivatives. Abdel-Wahab BF, Khidre RE, Awad GE. Eur J Med Chem. 2012 Jan 20. [Epub ahead of print] PMID: 22373733 [PubMed - as supplied by publisher]

  • Hydrazone as the Directing Group for Ir-Catalyzed Arene Diborylations and Sequential Functionalizations. Ros A, López-Rodríguez R, Estepa B, Alvarez E, Fernández R, Lassaletta JM. J Am Chem Soc. 2012 Mar 2. [Epub ahead of print] PMID: 22369472 [PubMed - as supplied by publisher]

  • Erratum: "Theoretical predictions of properties and gas-phase chromatography behaviour of bromides of group-5 elements Nb, Ta, and element 105, Db" [J. Chem. Phys. 136, 034308 (2012)]. Pershina V, Anton J. J Chem Phys. 2012 Feb 14;136(6):069901. No abstract available. PMID: 22360227 [PubMed - in process]

  • Recent advances in the stereoselective synthesis of carbohydrate 2-C-analogs. Yin J, Linker T. Org Biomol Chem. 2012 Mar 28;10(12):2351-62. Epub 2012 Feb 7. PMID: 22311080 [PubMed - in process]

  • An expedient Pd/DBU mediated cyanation of aryl/heteroaryl bromides with K(4)[Fe(CN)(6)]. Zhang D, Sun H, Zhang L, Zhou Y, Li C, Jiang H, Chen K, Liu H. Chem Commun (Camb). 2012 Mar 18;48(23):2909-11. Epub 2012 Feb 3. PMID: 22307456 [PubMed - in process]

  • Functionalization of magnetic nanoparticles with amphiphilic block copolymers: self-assembled thermoresponsive submicrometer particles. Budgin AM, Kabachii YA, Shifrina ZB, Valetsky PM, Kochev SS, Stein BD, Malyutin A, Bronstein LM. Langmuir. 2012 Mar 6;28(9):4142-51. Epub 2012 Feb 22. PMID: 22303838 [PubMed - in process]

  • Synthesis and biological evaluation of some thiazole derivatives as new cholinesterase inhibitors. Turan-Zitouni G, Ozdemir A, Kaplancikli ZA, Altintop MD, Temel HE, Ciftçi GA. J Enzyme Inhib Med Chem. 2012 Feb 3. [Epub ahead of print] PMID: 22299580 [PubMed - as supplied by publisher]

  • Cyanation of Aryl Bromides with K(4) [Fe(CN)(6) ] Catalyzed by Dichloro[bis{1-(dicyclohexylphosphanyl)piperidine}]palladium, a Molecular Source of Nanoparticles, and the Reactions Involved in the Catalyst-Deactivation Processes. Gerber R, Oberholzer M, Frech CM. Chemistry. 2012 Mar 5;18(10):2978-86. doi: 10.1002/chem.201102936. Epub 2012 Feb 1. PMID: 22298440 [PubMed - in process]

  • A convenient and practical synthesis of anisoles and deuterated anisoles by palladium-catalyzed coupling reactions of aryl bromides and chlorides. Gowrisankar S, Neumann H, Beller M. Chemistry. 2012 Feb 27;18(9):2498-502. doi: 10.1002/chem.201103347. Epub 2012 Feb 1. PMID: 22298324 [PubMed - in process]

  • An Alternative Approach to para-C-H Arylation of Phenol: Palladium-Catalyzed Tandem ?-Arylation/Aromatization of 2-Cyclohexen-1-one Derivatives. Imahori T, Tokuda T, Taguchi T, Takahata H. Org Lett. 2012 Feb 17;14(4):1172-5. Epub 2012 Feb 1. PMID: 22296212 [PubMed - in process]

  • Theoretical predictions of properties and gas-phase chromatography behaviour of bromides of group-5 elements Nb, Ta, and element 105, Db. Pershina V, Anton J. J Chem Phys. 2012 Jan 21;136(3):034308. PMID: 22280761 [PubMed - in process]

  • Size-selective phase-transfer catalysis with interfacially cross-linked reverse micelles. Lee LC, Zhao Y. Org Lett. 2012 Feb 3;14(3):784-7. Epub 2012 Jan 24. PMID: 22273173 [PubMed - in process]

     

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