Lithium Deuteride

LiD
CAS 13587-16-1


Product Product Code Order or Specifications
(2N) 99% Lithium Deuteride LI-HD-02 Contact American Elements
(3N) 99.9% Lithium Deuteride LI-HD-03 Contact American Elements
(4N) 99.99% Lithium Deuteride LI-HD-04 Contact American Elements
(5N) 99.999% Lithium Deuteride LI-HD-05 Contact American Elements

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
LiD 13587-16-1 24879454 6914554 MFCD00011091 237-018-5 lithium deuteride N/A [Li+].[2H-] InChI=1S/Li.H/q+1;-1/i;1+1 SRTHRWZAMDZJOS-IEOVAKBOSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
DLi 8.96 g/mol Yellow, gray, purple, or brown powder and/or chunks N/A 9.030106 9.030106 0 Safety Data Sheet

Lithium Deuteride is generally immediately available in most volumes. American Elements offers a broad range of products for hydrogen storage research, advanced fuel cells and battery applications. Hydrogen can easily be generated from renewable energy sources and is the most abundant element in the universe. Hydrogen is produced from various sources such as fossil fuels, water and renewables. Hydrogen is nonpolluting and forms water as a harmless byproduct during use. The challenges associated with the use of hydrogen as a form of energy include developing safe, compact, reliable, and cost-effective hydrogen storage and delivery technologies. Currently, hydrogen can be stored in these three forms: Compressed Hydrogen, Liquid Hydrogen and Chemical Storage. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lithium Bohr ModelLithium (Li) atomic and molecular weight, atomic number and elemental symbolLithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek word "lithose" which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife; its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics. For more information on lithium, including properties, safety data, research, and American Elements' catalog of lithium products, visit the Lithium Information Center.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H260-H314
Hazard Codes F,C
Risk Codes 11-14-34
Safety Precautions 16-26-36/37/39-45-7/9
RTECS Number N/A
Transport Information UN 1414 4.3/PG 1
WGK Germany 2
Globally Harmonized System of
Classification and Labelling (GHS)
Flame-Flammables Corrosion-Corrosive to metals      

LITHIIUM DEUTERIDE SYNONYMS
Lithium hydride-d

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


Have a Question? Ask a Chemical Engineer or Material Scientist
Request an MSDS or Certificate of Analysis





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Production Catalog Available in 36 Countries & Languages


Recent Research & Development for Lithium

  • Development of a selective culture medium for bifidobacteria, Raffinose-Propionate Lithium Mupirocin (RP-MUP) and assessment of its usage with Petrifilm™ Aerobic Count plates. Miranda RO, Carvalho AF, Nero LA. Food Microbiol. 2014 May.
  • Layer structured a-FeSe: A potential anode material for lithium storage - D Wei, J Liang, Y Zhu, L Hu, K Zhang, J Zhang - Electrochemistry 2014 - Elsevier
  • Facile and fast synthesis of porous TiO2 spheres for use in lithium ion batteries. Wang HE, Jin J, Cai Y, Xu JM, Chen DS, Zheng XF, Deng Z, Li Y, Bello I, Su BL. J Colloid Interface Sci. 2014 Mar.
  • Novel sodium intercalated (NH4)2V6O16 platelets: High performance cathode materials for lithium-ion battery. J Colloid Interface Sci. 2014 create date:2013/11/26 | first author:Fei H
  • Isomeric thiophene-fused benzocarborane molecules-different lithium doping effect on the nonlinear optical property. Li Y, Xu HL, Wu HQ, Zhong RL, Sun SL, Su ZM. Dalton Trans. 2014 Feb.
  • Voltage changes in the lithium dilution cardiac output sensor after exposure to blood from horses given xylazine. Ambrisko TD, Moens Y. Br J Anaesth. 2014 Feb.
  • Self-stopping effects of lithium penetration into silicon nanowires. Nanoscale. 2013 date:2013/10/29 | first author:Lang L
  • Lithium chloride attenuates root resorption during orthodontic tooth movement in rats. Wang Y, Gao S, Jiang H, Lin P, Bao X, Zhang Z, Hu M. Exp Ther Med. 2014 Feb.
  • Ethylcellulose-coated polyolefin separators for lithium-ion batteries with improved safety performance. Carbohydr Polym. 2014 create date:2013/12/05 | first author:Xiong M
  • Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties. Chem Soc Rev. 2014 create date:2013/11/10 | first author:Islam MS
  • Lithium Chloride Induces TNFα in Mouse Macrophages Via MEK-ERK-Dependent Pathway. J Cell Biochem. 2014 create date:2013/08/02 | first author:Hull M
  • Lithium Chloride Alleviates Neurodegeneration Partly by Inhibiting Activity of GSK3β in a SCA3 Drosophila Model. Cerebellum. 2013 create date:2013/07/03 | first author:Jia DD
  • No association of endocannabinoid genes with bipolar disorder or lithium response in a Sardinian sample. Psychiatry Res. 2013 | first author:Pisanu C
  • Electrochemical performance of a graphene nanosheets anode in a high voltage lithium-ion cell. Phys Chem Chem Phys. 2013 create date:2013/11/05 | first author:Vargas O
  • LixFeF6 (x = 2, 3, 4) battery materials: structural, electronic and lithium diffusion properties. Phys Chem Chem Phys. 2013 | first author:Schroeder M
  • Facile fabrication of Si mesoporous nanowires for high-capacity and long-life lithium storage. Nanoscale. 2013 create date:2013/09/24 | first author:Chen J
  • Inhibition of glycogen synthase kinase 3beta activity with lithium prevents and attenuates paclitaxel-induced neuropathic pain. Neuroscience. 2013 create date:2013/09/28 | first author:Gao M
  • Effects of lithium on magnetic resonance imaging signal might not preclude increases in brain volume after chronic lithium treatment. Biol Psychiatry. 2013 create date:2013/09/04 | first author:Vernon AC
  • Assembling metal oxide nanocrystals into dense, hollow, porous nanoparticles for lithium-ion and lithium-oxygen battery application. Nanoscale. 2013 | first author:Ming J
  • Single-crystalline metal germanate nanowire-carbon textiles as binder-free, self-supported anodes for high-performance lithium storage. Nanoscale. 2013 | first author:Li W

Recent Research & Development for Hydrides

  • Surface hydride on titanium by cathodic polarization promotes human gingival fibroblast growth. Xing R, Salou L, Taxt-Lamolle S, Reseland JE, Lyngstadaas SP, Haugen HJ. J Biomed Mater Res A. 2014
  • Dual-mode chemical vapor generation for simultaneous determination of hydride-forming and non-hydride-forming elements by atomic fluorescence spectrometry. Wang Y, Xu K, Jiang X, Hou X, Zheng C. Analyst. 2014.
  • Reactivity and catalytic activity of tert-butoxy-aluminium hydride reagents. Less RJ, Simmonds HR, Wright DS. Dalton Trans. 2014.
  • CH Bond Activation during and after the Reactions of a Metallacyclic Amide with Silanes: Formation of a μ-Alkylidene Hydride Complex, Its H-D Exchange, and β-H Abstraction by a Hydride Ligand. Wang L, Hunter SC, Song Z, Steren CA, Chen T, Wei Z, Cai H, Xue ZL. Chemistry. 2014
  • Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride. Tan G, Wang W, Blom B, Driess M. Dalton Trans. 2014
  • Kinetics and Thermodynamics of H(-)/H•/H(+) Transfer from a Rhodium(III) Hydride. Hu Y, Norton JR. J Am Chem Soc. 2014
  • Synthesis, Characterization, and Reactivity of Ruthenium Hydride Complexes of N-Centered Triphosphine Ligands. Phanopoulos A, Brown NJ, White AJ, Long NJ, Miller PW. Inorg Chem. 2014.
  • A mechanical-force-driven physical vapour deposition approach to fabricating complex hydride nanostructures. Pang Y, Liu Y, Gao M, Ouyang L, Liu J, Wang H, Zhu M, Pan H. Nat Commun. 2014.
  • Yttrium hydride nanoantennas for active plasmonics. Strohfeldt N, Tittl A, Schäferling M, Neubrech F, Kreibig U, Griessen R, Giessen H. Nano Lett. 2014 Mar.
  • Hydride ions in oxide hosts hidden by hydroxide ions. Hayashi K, Sushko PV, Hashimoto Y, Shluger AL, Hosono H. Nat Commun. 2014.
  • Correlations between the zeta potentials of silica hydride-based stationary phases, analyte retention behaviour and their ionic interaction descriptors. Kulsing C, Yang Y, Munera C, Tse C, Matyska MT, Pesek JJ, Boysen RI, Hearn MT. Anal Chim Acta. 2014.
  • Synthesis, Spectroscopy, and Hydrogen/Deuterium Exchange in High-Spin Iron(II) Hydride Complexes. Dugan TR, Bill E, Macleod KC, Brennessel WW, Holland PL. Inorg Chem. 2014.
  • Deuterium studies reveal a new mechanism for the formose reaction involving hydride shifts. Appayee C, Breslow R. J Am Chem Soc. 2014 Mar.
  • Double C(sp(3))-H Bond Functionalization Mediated by Sequential Hydride Shift/Cyclization Process: Diastereoselective Construction of Polyheterocycles. Mori K, Kurihara K, Yabe S, Yamanaka M, Akiyama T. J Am Chem Soc. 2014.
  • Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds. Hadlington TJ, Hermann M, Frenking G, Jones C. J Am Chem Soc. 2014.
  • Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp(3))-H bond functionalization. Mori K, Kurihara K, Akiyama T. Chem Commun (Camb). 2014.
  • Effect of Sodium Cation on Metallacycle ß-Hydride Elimination in CO2 -Ethylene Coupling to Acrylates. Jin D, Williard PG, Hazari N, Bernskoetter WH. Chemistry. 2014.
  • Study of hydration process on silica hydride surfaces by microcalorimetry and water adsorption. Bocian S, Rychlicki G, Matyska M, Pesek J, Buszewski B. J Colloid Interface Sci. 2014 Feb.
  • Computational replication of the abnormal secondary kinetic isotope effects in a hydride transfer reaction in solution with a motion assisted h-tunneling model. Kashefolgheta S, Razzaghi M, Hammann B, Eilers J, Roston D, Lu Y. J Org Chem. 2014.
  • Mechanistic Insights into the Pd-Catalyzed Direct Amination of Allyl Alcohols: Evidence for an Outer-sphere Mechanism Involving a Palladium Hydride Intermediate. Sawadjoon S, Sjöberg PJ, Orthaber A, Matsson O, Samec JS. Chemistry. 2014.