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Lithium Deuteride

LiD
CAS 13587-16-1


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(2N) 99% Lithium Deuteride LI-HD-02 Request Quote
(3N) 99.9% Lithium Deuteride LI-HD-03 Request Quote
(4N) 99.99% Lithium Deuteride LI-HD-04 Request Quote
(5N) 99.999% Lithium Deuteride LI-HD-05 Request Quote

CHEMICAL
IDENTIFIER
Formula CAS No. PubChem SID PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
LiD 13587-16-1 24879454 6914554 MFCD00011091 237-018-5 lithium deuteride N/A [Li+].[2H-] InChI=1S/Li.H/q+1;-1/i;1+1 SRTHRWZAMDZJOS-IEOVAKBOSA-N

PROPERTIES Compound Formula Mol. Wt. Appearance Density Exact Mass Monoisotopic Mass Charge MSDS
DLi 8.96 g/mol Yellow, gray, purple, or brown powder and/or chunks N/A 9.030106 9.030106 0 Safety Data Sheet

Lithium Deuteride is generally immediately available in most volumes. American Elements offers a broad range of products for hydrogen storage research, advanced fuel cells and battery applications. Hydrogen can easily be generated from renewable energy sources and is the most abundant element in the universe. Hydrogen is produced from various sources such as fossil fuels, water and renewables. Hydrogen is nonpolluting and forms water as a harmless byproduct during use. The challenges associated with the use of hydrogen as a form of energy include developing safe, compact, reliable, and cost-effective hydrogen storage and delivery technologies. Currently, hydrogen can be stored in these three forms: Compressed Hydrogen, Liquid Hydrogen and Chemical Storage. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Lithium Bohr ModelLithium (Li) atomic and molecular weight, atomic number and elemental symbolLithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife; its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics. For more information on lithium, including properties, safety data, research, and American Elements' catalog of lithium products, visit the Lithium element page.


HEALTH, SAFETY & TRANSPORTATION INFORMATION
Material Safety Data Sheet MSDS
Signal Word Danger
Hazard Statements H260-H314
Hazard Codes F,C
Risk Codes 11-14-34
Safety Precautions 16-26-36/37/39-45-7/9
RTECS Number N/A
Transport Information UN 1414 4.3/PG 1
WGK Germany 2
Globally Harmonized System of
Classification and Labelling (GHS)
Flame-Flammables Corrosion-Corrosive to metals      

LITHIIUM DEUTERIDE SYNONYMS
Lithium hydride-d

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


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Recent Research & Development for Lithium

  • Permselective Graphene Oxide Membrane for High-Stable and Anti-Self-Discharge Lithium-Sulfur Batteries. Jia-Qi Huang, Ting-Zhou Zhuang, Qiang Zhang, Hong-Jie Peng, Cheng-Meng Chen, and Fei Wei. ACS Nano: February 16, 2015
  • Recent achievements on inorganic electrode materials for lithium ion batteries. Laurence Croguennec and M. Rosa Palacin. J. Am. Chem. Soc.: 42048
  • Ion Transport in Separator Membranes of Lithium Secondary Batteries. Yuria Saito, Wataru Morimura, Rika Kuratani, and Satoshi Nishikawa. J. Phys. Chem. C: February 12, 2015
  • Computational identification and experimental realisation of lithium vacancy introduction into the olivine LiMgPO4. Leopoldo Enciso-Maldonado, Matthew S. Dyer, Michael D. Jones, Ming Li, Julia L. Payne, Michael J. Pitcher, Mona K. Omir, John B. Claridge, Frédéric Blanc, and Matthew J. Rosseinsky. Chem. Mater.: February 12, 2015
  • First-Principles Study of Redox End-Members in Lithium-Sulfur Batteries. Haesun Park, Hyun Seung Koh, and Donald J. Siegel. J. Phys. Chem. C: February 9, 2015
  • Recovery of lithium from wastewater using development of Li ion-imprinted polymers. Xubiao Luo, Bin Guo, Jinming Luo, Feng Deng, Siyu Zhang, Shenglian Luo, and John Charles Crittenden. ACS Sustainable Chem. Eng.: February 9, 2015
  • Impedance Spectroscopy Characterization of Porous Electrodes under Different Electrode Thickness Using a Symmetric Cell for High-Performance Lithium-Ion Batteries. Nobuhiro Ogihara, Yuichi Itou, Tsuyoshi Sasaki, and Yoji Takeuchi. J. Phys. Chem. C: February 9, 2015
  • Charge Relaxation and Stokes–Einstein Relation in Diluted Electrolyte Solution of Propylene Carbonate and Lithium Perchlorate. Jolanta wiergiel, Iwona Powa, and Jan Jadyn. Ind. Eng. Chem. Res.: February 6, 2015
  • Mesoporous Carbon Interlayers with Tailored Pore Volume as Polysulfide Reservoir for High-Energy Lithium–Sulfur Batteries. Juan Balach, Tony Jaumann, Markus Klose, Steffen Oswald, Jürgen Eckert, and Lars Giebeler. J. Phys. Chem. C: February 5, 2015
  • Size-Tunable Single-Crystalline Anatase TiO2 Cubes as Anode Materials for Lithium Ion Batteries. Xuming Yang, Yingchang Yang, Hongshuai Hou, Yan Zhang, Laibing Fang, Jun Chen, and Xiaobo Ji. J. Phys. Chem. C: February 4, 2015

Recent Research & Development for Hydrides

  • Insights into the Origin of the Separation Selectivity with Silica Hydride Adsorbents. Chadin Kulsing, Yada Nolvachai, Philip J. Marriott, Reinhard I. Boysen, Maria T. Matyska, Joseph J. Pesek, and Milton T. W. Hearn. J. Phys. Chem. B: February 6, 2015
  • An Antiferro-to-Ferromagnetic Transition in EuTiO3–xHx Induced by Hydride Substitution. Takafumi Yamamoto, Ryuta Yoshii, Guillaume Bouilly, Yoji Kobayashi, Koji Fujita, Yoshiro Kususe, Yoshitaka Matsushita, Katsuhisa Tanaka, and Hiroshi Kageyama. Inorg. Chem.: January 16, 2015
  • The Activating Oxydianion Binding Domain for Enzyme-Catalyzed Proton Transfer, Hydride Transfer, and Decarboxylation: Specificity and Enzyme Architecture. Archie C. Reyes, Xiang Zhai, Kelsey T. Morgan, Christopher J. Reinhardt, Tina L. Amyes, and John P. Richard. J. Am. Chem. Soc.: January 2, 2015
  • C–H Bond Functionalization via [1,5]-Hydride Shift/Cyclization Sequence: Approach to Spiroindolenines. Peng-Fei Wang, Chun-Huan Jiang, Xiaoan Wen, Qing-Long Xu, and Hongbin Sun. J. Org. Chem.: December 28, 2014
  • In Situ Embedding of Mg2NiH4 and YH3 Nanoparticles into Bimetallic Hydride NaMgH3 to Inhibit Phase Segregation for Enhanced Hydrogen Storage. Yongtao Li, Luxing Zhang, Qingan Zhang, Fang Fang, Dalin Sun, Kongzhai Li, Hua Wang, Liuzhang Ouyang, and Min Zhu. J. Phys. Chem. C: September 26, 2014
  • Mechanistic Study and Ligand Design for the Formation of Zinc Formate Complexes from Zinc Hydride Complexes and Carbon Dioxide. Chunhua Dong, Xinzheng Yang, Jiannian Yao, and Hui Chen. Organometallics: December 18, 2014
  • Determination of Nanoparticle Size by Measuring the Metal–Metal Bond Length: The Case of Palladium Hydride. Jianqiang Wang, Qi Wang, Xinghua Jiang, Zhongneng Liu, Weimin Yang, and Anatoly I. Frenkel. J. Phys. Chem. C: December 10, 2014
  • Calculation of Ionization Energy, Electron Affinity, and Hydride Affinity Trends in Pincer-Ligated d8-Ir(tBu4PXCXP) Complexes: Implications for the Thermodynamics of Oxidative H2 Addition. Abdulkader Baroudi, Ahmad El-Hellani, Ashfaq A. Bengali, Alan S. Goldman, and Faraj Hasanayn. Inorg. Chem.: November 18, 2014
  • Reactivity of TpMe2-Containing Hydride–Iridafurans with Alkenes, Alkynes, and H2. Ángela Vivancos, Cristina M. Posadas, Yohar A. Hernández, et. al. Organometallics: November 12, 2014
  • Facile Synthesis of Ba1–xKxFe2As2 Superconductors via Hydride Route. Julia V. Zaikina, Maria Batuk, Artem M. Abakumov, Alexandra Navrotsky, and Susan M. Kauzlarich. J. Am. Chem. Soc.: November 11, 2014