American Elements specializes in producing lanthanum strontium cobaltite ferrite for fuel cell cathode applications utilizing solid state processing to produce single phase perovskite structures with various doping levels and surface areas (SSA) for use in thin film layers. Upon firing, American Elements' Lanthanum Strontium Cobaltite Ferrite will partially sinter to form well-defined necks and open gas paths to permit simultaneous gas and electrical transfer. Lanthanum Strontium Cobaltite Ferrite has an excellent thermal expansion match with Yttria Stabilized Zirconia (YSZ) electrolytes. It is highly electronically conductive and has proven long term stability. Lanthanum Strontium Cobaltite Ferrite belongs to a class of "A" site and "B" site doped perovskite structures with these properties. These include Lanthanum Strontium Manganite (LSM), Lanthanum Strontium Ferrite (LSF), Lanthanum Calcium Manganite (LCM), Lanthanum Strontium Chromite (LSC), and Lanthanum Strontium Gallate Magnesite (LSGM). Lanthanum Strontium Cobaltite Ferrite is available as a powder for tape casting, air spray/thermal spray/plasma spray, extrusion and sputtering fuel cell applications and as an ink for screen printing. Strontium doping levels are available at 10% and 20% and as specified by customer. Oxygen starved compositions are available. American Elements provides guidance on firing parameters, doping levels, and thermal expansion matching with American Elements' electrolyte and interconnect fuel cell layers. Gadolinia doped ceria (GDC), cerium oxide stabilized by various doping levels of gadolinium oxide, a material that upon firing forms a highly ionically conductive thin film electrolyte layer for use in solid oxide fuel cell electrochemistry structures. Gadolinium Oxide doped Ceria belongs to a class of doped Ceria compounds with ionic conductivity exceeding Yttria Stabilized Zirconia (YSZ) electrolytes. These include Samarium doped Ceria (SDC) and Yttria doped Ceria (YDC). Even higher conductivity can be achieved with American Elements Scandia doped Zirconia (SCZ) and Yttria doped Bismuth Oxide. Gadolinium Oxide doped Cerium Oxide is available in a powder for tape casting, air spray, extrusion and sputtering fuel cell applications and as an ink for screen printing. Gadolinia doping levels are available at 10% and 20% and as specified by customer. American Elements provides guidance on firing parameters, doping levels, and thermal expansion matching with American Elements' cathode and anode cell layers.
Lanthanum is a Block F, Group 3, Period 6 element. The number of electrons in each of Lanthanum's shells is 2, 8, 18, 18, 9, 2 and its electronic configuration is [Xe] 5d1 6s2. In its elemental form lanthanum 's CAS number is 7439-91-0. The lanthanum atom has a radius of 187.pm and it's Van der Waals radius is 200.pm. Lanthanum and compounds of Lanthanum are somewhat toxic. Lanthanum is one of the products manufactured and distributed under the tradename AE Rare Earths. Lanthanum is the first element in the rare earth or lanthanide series. It is the model for all the other trivalent rare earths. After cerium, it is the second most abundant of the rare earths. Lanthanum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.
Strontium is a Block S, Group 2, Period 5 element. The number of electrons in each of Strontium's shells is 2, 8, 18, 8, 2 and its electronic configuration is [Kr] 5s2. In its elemental form strontium's CAS number is 7440-24-6. The strontium atom has a radius of 215.1.pm and it's Van der Waals radius is 200.pm. The non-radioactive isotopes of Strontium are not toxic. Strontium has low tech applications as an additive to flares and pyrotechnics because of the bright crimson flame produced by its salts. Strontium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It also has many high technology applications because of its high refractive index as a titanate in glass, as a "getter" in electron tubes and as a dopant for numerous perovskite formulations to produce cathodes for oxygen generation or solid oxide fuel cells. Historically the primary use of strontium was to produce CRT glass for color television and computer tubes. Strontium was first discovered by A. Crawford in 1790. Strontium was named after the Scottish town it was discovered in, Strontian. See Strontium research below.
Cobalt is a Block D, Group 9, Period 4 element. The number of electrons in each of Cobalt's shells is 2, 8, 15, 2 and its electronic configuration is [Ar] 3d7 4s2. In its elemental form cobalt's CAS number is 7440-48-4. Thecobalt atom has a radius of 125.3.pm and it's Van der Waals radius is 200.pm. Cobalt has a metallic permeability two thirds that of iron. It exists as a mixture of two allotropes over a wide temperature range. The transformation is slow and accounts in part for the wide variation in the physical properties of cobalt. It is alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many important uses. Samarium-cobalt is one of the highest strength magnet alloys known. Cobalt compounds produce a brilliant and permanent blue color in ceramic glazes, glass, pottery, tiles, and enamels. Co-60 is useful as a gamma ray source. Toxicity of cobalt and its compounds are mild by skin contact and moderate by ingestion. Cobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Cobalt was first discovered by George Brandt in 1737.
Iron is a Block D, Group 8, Period 4 element. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electronic configuration is [Ar] 3d6 4s2. In its elemental form iron's CAS number is 7439-89-6. The iron atom has a radius of 124.1.pm and it's Van der Waals radius is 200.pm. Iron is not toxic. Iron is the most commonly used metal for commercial applications due to its hardness, historical availability and low cost. Once used on its own, it is now alloyed with nickel and other elements to produce steel and other high strength, non-corrosive structural metals. Iron as a metal and as its many compounds has numerous uses. It is a primary colorant in glass and ceramics. It is a catalyst. It is the basis for low grade magnets and because of its magnetic properties is used extensively in memory tape. Recent applications for Iron nanoparticles include in water treatment of carbon tetrachloride in contaminated groundwater, magnetic data storage and resonance imaging (MRI) and in certain alloy and catalyst applications. Iron can also be introduced into processes using iron foil, pellets, rod and wire by thin film Chemical Vapor Deposition (CVD) and Physical Vapor Deposition (PVD) processes including Thermal and Electron Beam (E-Beam) Evaporation, Low Temperature Organic Evaporation, Atomic Layer Deposition (ALD), Organometallic and Chemical Vapor Deposition (MOCVD) for specific applications such as fuel cells and solar energy. Iron is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Iron was first discovered by Early Man.See Iron research below.
Cerium is a Block F, Group 3, Period 6 element. The number of electrons in each of Cerium's shells is 2, 8, 18, 19, 9, 2 and its electronic configuration is [Xe]4f2 6s2. In its elemental form cerium's CAS number is 7440-45-1. The cerium atom has a radius of 182.5.pm and it's Van der Waals radius is 181.pm. Cerium is one of the products manufactured and distributed under the tradename AE Rare Earths. Cerium is the most abundant of the rare earths metals. It is characterized chemically by having two valence states , the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueoussolutions.It is, therefore, strongly acidic and moderately toxic. It is also a strong oxidizer.The cerous state closely resembles the other trivalent rare earths. The numerous commercial applications for cerium include metallurgy, glass and glass polishing, ceramics, catalysts, as the electrolyte for solid oxide fuel cells when doped with yttrium, gadolinium or samarium and in phosphors. In steel manufacturing it is used to remove free oxygen and sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony. It is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolor glass by keeping iron in its ferrous state. The ability of cerium-doped glass to block out ultra violet light is utilized in the manufacturing of medical glassware and aerospace windows. It is also used to prevent polymers from darkening in sunlight and to suppress discoloration of television glass.
Cerium was first discovered by W. von Hisinger in 1903. The element was named after the asteroid Ceres. See Cerium research below.
Gadolinium is a Block F, Group 3, Period 6 element. The number of electrons in each of Gadolinium's shells is 2, 8, 18, 25, 9, 2 and its electronic configuration is [Xe] 4f7 5d1 6s2. In its elemental form gadolinium's CAS number is 7440-54-2. The gadolinium atom has a radius of 178.7.pm and it's Van der Waals radius is unknown. Gadolinium is very toxic. Gadolinium is utilized for both its high magnetic moment (7.94µB) and in phosphors and scintillator material. When complexed with EDTA ligands, it is used as an injectable contrast agent for patients undergoing magnetic resonance imaging. With its high magnetic moment, gadolinium can reduce relaxation times and thereby enhance signal intensity. The extra stable half-full 4f electron shell with no low lying energy levels creates applications as an inert phosphor host. Gadolinium can therefore act as hosts for x-ray cassettes and in scintillator materials for computer tomography. Gadolinium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Gadolinium was first discovered by Jean de Marignac in 1880. The element is named after the Finnish chemist and geologist Johan Gadolin. See Gadolinium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
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