Lutetium
Nitrate is a highly water soluble Lutetium source for uses compatible with nitrates. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Lutetium is used for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG). Lutetium Nitrate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Lutetium Nitrate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Lutetium is a Block F, Group 3, Period 6 element. The number of electrons in each of Lutetium's shells is 2, 8, 18, 32, 9, 2 and its electronic configuration is [Xe] 4f15 5d1 6s2. In its elemental form lutetium's CAS number is 7439-94-3. The lutetium atom has a radius of 171.8.pm and it's Van der Waals radius is unknown. Lutetium is not toxic. Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. It also has the smallest metallic radius of any rare earth. It is perhaps the least naturally abundant of the lanthanides. It is the ideal host for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG) crystals due its lack of a magnetic moment.Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. Lutetium was first discovered by George Urbain in 1907. The name Lutetium originates from the Latin word Lutetia meaning Paris. See Lutetium research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Use of internal scintillator radioactivity to calibrate DOI function of a PET detector with a dual-ended-scintillator readout.
Bircher C, Shao Y.
Med Phys. 2012 Feb;39(2):777.
PMID:
22320787
[PubMed - in process]
Phthalocyanine with a giant dielectric constant.
Yazici A, Unüs N, Altindal A, Salih B, Bekaroglu O.
Dalton Trans. 2012 Feb 7. [Epub ahead of print]
PMID:
22310939
[PubMed - as supplied by publisher]
Towards the Real Octupolar Cube: ABAB Bis(phthalocyaninato)lutetium(III) Complex exhibiting Out-standing Quadratic Hyperpolarizability.
Ayhan MM, Singh A, Hirel C, Gürek AG, Ahsen V, Jeanneau E, Ledoux-Rak I, Zyss J, Andraud C, Bretonničre Y.
J Am Chem Soc. 2012 Feb 6. [Epub ahead of print]
PMID:
22308960
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Rare-Earth-Metal-Hydrocarbyl Complexes Bearing Linked Cyclopentadienyl or Fluorenyl Ligands: Synthesis, Catalyzed Styrene Polymerization, and Structure-Reactivity Relationship.
Jian Z, Cui D, Hou Z.
Chemistry. 2012 Jan 26. doi: 10.1002/chem.201102682. [Epub ahead of print]
PMID:
22282393
[PubMed - as supplied by publisher]
Outpatient therapeutic nuclear oncology.
Turner JH.
Ann Nucl Med. 2012 Jan 7. [Epub ahead of print]
PMID:
22222779
[PubMed - as supplied by publisher]
Poly[tetra-aquadi-?(4)-oxalato-lutetium(III)potassium].
Zhang FM, Sun TZ, Hou GF, Yan PF, Li GM.
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov 1;67(Pt 11):m1591. Epub 2011 Oct 22.
PMID:
22219822
[PubMed - in process]
Selected Trace Elements in the Sacramento River, California: Occurrence and Distribution.
Taylor HE, Antweiler RC, Roth DA, Alpers CN, Dileanis P.
Arch Environ Contam Toxicol. 2011 Dec 23. [Epub ahead of print]
PMID:
22193863
[PubMed - as supplied by publisher]
Nuclear chemical transformations of ytterbium and lutetium radionuclides following (n,?) and beta decay reactions in Tris(2,2,6,6-tetramethyle-3,5-heptanedionato)Yb(III).
Nassan L, Achkar B, Yassine T.
Appl Radiat Isot. 2011 Dec 6. [Epub ahead of print]
PMID:
22189373
[PubMed - as supplied by publisher]
Influence of cations on the complexation yield of DOTATATE with yttrium and lutetium: a perspective study for enhancing the (90)Y and (177)Lu labeling conditions.
Asti M, Tegoni M, Farioli D, Iori M, Guidotti C, Cutler CS, Mayer P, Versari A, Salvo D.
Nucl Med Biol. 2011 Dec 13. [Epub ahead of print]
PMID:
22172388
[PubMed - as supplied by publisher]
A novel compensation method for the anode gain non-uniformity of multi-anode photomultiplier tubes.
Lee CM, Il Kwon S, Ko GB, Ito M, Yoon HS, Lee DS, Hong SJ, Lee JS.
Phys Med Biol. 2012 Jan 7;57(1):191-207.
PMID:
22156011
[PubMed - in process]
Automated Module Radiolabeling of Peptides and Antibodies with Gallium-68, Lutetium-177 and Iodine-131.
De Decker M, Turner JH.
Cancer Biother Radiopharm. 2011 Dec 7. [Epub ahead of print]
PMID:
22149590
[PubMed - as supplied by publisher]
An unusual organoyttrium alkyl complex containing a [C5HMe3(?(3)-CH2)-C5H4N-?]- ligand and an elusive cyclopentadienide-based scandium tuck-over zwitterion obtained by C-H bond activation.
Jian Z, Cui D.
Chemistry. 2011 Dec 16;17(51):14578-85. doi: 10.1002/chem.201102378. Epub 2011 Nov 14.
PMID:
22083978
[PubMed - in process]
Evaluation of 177Lu-DOTA-sst2 antagonist versus 177Lu-DOTA-sst2 agonist binding in human cancers in vitro.
Cescato R, Waser B, Fani M, Reubi JC.
J Nucl Med. 2011 Dec;52(12):1886-90. Epub 2011 Nov 8.
PMID:
22068898
[PubMed - indexed for MEDLINE]
Reactions of late lanthanide metal atoms and methanol in solid argon: a matrix isolation infrared spectroscopic and theoretical study.
Gong Y, Andrews L, Chen M, Dixon DA.
J Phys Chem A. 2011 Dec 29;115(51):14581-92. Epub 2011 Dec 5.
PMID:
22054215
[PubMed - in process]
Nuclear medicine techniques for the imaging and treatment of neuroendocrine tumours.
Teunissen JJ, Kwekkeboom DJ, Valkema R, Krenning EP.
Endocr Relat Cancer. 2011 Oct 17;18 Suppl 1:S27-51. Print 2011 Oct. Review.
PMID:
22005114
[PubMed - indexed for MEDLINE]
A Positron Emission Tomograph Based on LSO-APD Modules with a Sampling ADC Read-out System for a Students' Advanced Laboratory Course.
Schneider FR, Mann AB, Konorov I, Delso G, Paul S, Ziegler SI.
Z Med Phys. 2011 Oct 20. [Epub ahead of print]
PMID:
22019183
[PubMed - as supplied by publisher]
Preparation and scintillating properties of sol-gel eu, tb co-doped lu(2)o(3) nanopowders.
de Jesús Morales Ramírez A, Murillo AG, de Jesús Carrillo Romo F, Hernández MG, Palmerin JM, Guerrero RR.
Int J Mol Sci. 2011;12(9):6240-54. Epub 2011 Sep 23.
PMID:
22016655
[PubMed - in process]
Timing and optimized acquisition parameters for the whole-body imaging of š??Lu-EDTMP toward performing bone pain palliation treatment.
Liu C, Brasic JR, Liu X, Li H, Xiang X, Luo Z, Wang Y, Kuai D, Zhang G, Zaknun JJ.
Nucl Med Commun. 2012 Jan;33(1):90-6.
PMID:
22001721
[PubMed - in process]
Physical performance of the new hybrid PET?CT Discovery-690.
Bettinardi V, Presotto L, Rapisarda E, Picchio M, Gianolli L, Gilardi MC.
Med Phys. 2011 Oct;38(10):5394-411.
PMID:
21992359
[PubMed - indexed for MEDLINE]
Dihydrogen addition in a dinuclear rare-earth metal hydride complex supported by a metalated TREN ligand.
Venugopal A, Fegler W, Spaniol TP, Maron L, Okuda J.
J Am Chem Soc. 2011 Nov 9;133(44):17574-7. Epub 2011 Oct 18.
Material Safety Data Sheet
· 1 Identification of substance:
Product details:
Trade name Lutetium nitrate
· 2 Composition/Data on components:
Chemical characterization: Description: (CAS#)
Lutetium nitrate, hydrate (CAS# 100641-16-5); 100%
Identification number(s):
EINECS Number: 233-241-7
· 3 Hazards identification
Hazard description:
Xi Irritant
O Oxidizing
Information pertaining to particular dangers for man and environment
R 8 Contact with combustible material may cause fire.
R 36/37/38 Irritating to eyes, respiratory system and skin.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Seek immediate medical advice.
· 5 Fire fighting measures
Suitable extinguishing agents
Product is not flammable. Use fire fighting measures that suit the surrounding fire.
Special hazards caused by the material, its products of combustion or resulting gases:
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Measures for environmental protection:
Do not allow material to be released to the environment without proper governmental permits.
Measures for cleaning/collecting: Ensure adequate ventilation.
Additional information:
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· 7 Handling and storage
Handling
Information for safe handling:
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Substance/product can reduce the ignition temperature of flammable substances.
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from flammable substances.
Store away from reducing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
· 8 Exposure controls and personal protection
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Components with limit values that require monitoring at the workplace:
Not required.
Additional information: No data
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands: Impervious gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.
· 9 Physical and chemical properties:
General Information
Form: Crystalline aggregrates
Color: White
Odor: Odorless
Value/Range Unit Method
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicable
Flammability (solid, gaseous)
Contact with combustible material may cause fire.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not determined
Density: Not determined
Solubility in / Miscibility with
Water: Soluble
· 10 Stability and reactivity
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Materials to be avoided: Reducing agents, easily oxidized materials
Dangerous reactions
Reacts with reducing agents
Reacts with flammable substances
Dangerous products of decomposition: Nitrogen oxides
· 11 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
Subacute to chronic toxicity:
Lanthanons can cause delayed blood clotting leading to hemorrhages. Exposure may also lead to sensitivity to heat, itching, increased awareness of odor and taste, and liver damage.
Small doses of nitrates may cause weakness, general depression, headache and mental impairment. Larger doses may cause dizziness, abdominal cramps, vomiting, bloody diarrhea, convulsions and collapse.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
· 12 Ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
· 13 Disposal considerations
Product:
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.
· 14 Transport information
DOT regulations:
Hazard class: 5.1
Identification number: UN1477
Packing group: III
Proper shipping name (technical name):
Nitrates, inorganic, n.o.s., lutetium nitrate
Land transport ADR/RID (cross-border)
ADR/RID class: 5.1 Oxidizing substances
Item: 22c
Danger code (Kemler): 50
UN-Number: 1477
Description of goods: Nitrates, inorganic, n.o.s., lutetium nitrate
Risk phrases:
8 Contact with combustible material may cause fire.
36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases:
17 Keep away from combustible material.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
Information about limitation of use:
For use only by technically qualified individuals.
· 16 Other information:
Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees. This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.
Lutetium
Nitrate is a highly water soluble Lutetium source for uses compatible with nitrates. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Lutetium is used for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG). Lutetium Nitrate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Lutetium Nitrate Solution.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Lutetium is a Block F, Group 3, Period 6 element. The number of electrons in each of Lutetium's shells is 2, 8, 18, 32, 9, 2 and its electronic configuration is [Xe] 4f15 5d1 6s2. In its elemental form lutetium's CAS number is 7439-94-3. The lutetium atom has a radius of 171.8.pm and it's Van der Waals radius is unknown. Lutetium is not toxic. Lutetium is the last member of the rare earth series. Lutetium is available as metal and 
compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic 
moment. It also has the smallest metallic radius of any rare earth. It also has the smallest metallic radius of any rare earth. It is perhaps the least naturally abundant of the lanthanides. It is the ideal host for x-ray phosphors because it produces the densest known white material, lutetium tantalate (LuTaO4). It is utilized as a dopant in matching lattice parameters of certain substrate garnet crystals, such as indium-gallium-garnet (IGG) crystals due its lack of a magnetic moment.Lutetium is the last member of the rare earth series. Lutetium is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. Unlike most rare earths it lacks a magnetic moment. It also has the smallest metallic radius of any rare earth. Lutetium was first discovered by George Urbain in 1907. The name Lutetium originates from the Latin word Lutetia meaning Paris. See Lutetium research below. 
