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Manganese Borohydride
Mn(BH4)2
Product Product Code Order or Specifications
(2N) 99% Manganese Borohydride MN-BH-02 Contact American Elements
(3N) 99.9% Manganese Borohydride MN-BH-03 Contact American Elements
(4N) 99.99% Manganese Borohydride MN-BH-04 Contact American Elements
(5N) 99.999% Manganese Borohydride MN-BH-05 Contact American Elements

Hydride IonManganese Borohydride is generally immediately available in most volumes. American Elements offers a broad range of products for hydrogen storage research, advanced fuel cells and battery applications. Hydrogen can easily be generated from renewable energy sources and is the most abundant element in the universe. Hydrogen is produced from various sources such as fossil fuels, water and renewables. Hydrogen is nonpolluting and forms water as a harmless byproduct during use. The challenges associated with the use of hydrogen as a form of energy include developing safe, compact, reliable, and cost-effective hydrogen storage and delivery technologies. Currently, hydrogen can be stored in these three forms: Compressed Hydrogen, Liquid Hydrogen and Chemical Storage. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Manganese(Mn) atomic and molecular weight, atomic number and elemental symbolManganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminum alloys. Manganese oxide is used in dry cellManganese Bohr Model batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural Elemental Manganeseamethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.

Boron(B) atomic and molecular weight, atomic number and elemental symbolBoron is a Block P, Group 13, Period 2 element. The number of electrons in each of Boron's shells is 2, 3 and its electronic configuration is [He] 2s2 2p1. In its elemental form boron's CAS number is 7440-42-8. The boron atom has a radius of 79.5.pm and it's Van der Waals radius is 200.pm. Boron is not toxic. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. Optical characteristics include transmitting portions of the infrared. Boron is a poor conductor of electricity at room temperature but a good conductor at high temperature. Boron in its elemental form is not toxic. Amorphous Elemental Boronboron is used in pyrotechnic flares to provide a distinctive green color, and in rockets as an igniter Boric acid is also an important boron compound with major markets in textile products. Boron compounds are also extensively used in the manufacture of borosilicate Boron Bohr Modelglasses. The isotope Boron-10 is used as a control for nuclear reactors, as a shield for nuclear radiation, and in instruments used for detecting neutrons. Boron nitride has remarkable properties and can be used to make a material as hard as diamond. The nitride also behaves like an electrical insulator but conducts heat like a metal. Boron also has lubricating properties similar to graphite. Boron was first discovered by Sir Humphry Davy and J.L Gay-Lussac in 1808. The name Boron originates from a combination of carbon and the Arabic word 'buraqu meaning borax. See Boron research below.

Formula CAS No. Appearance Molecular Weight
Mn(BH4)2      

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PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.

 

 

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Recent Research & Development for Manganese

  • Citric acid production from Aspergillus niger MT-4 using hydrolysate extract of the insect Locusta migratoria. Taskin M, Tasar GE, Incekara U. Toxicol Ind Health. 2012 Feb 9. [Epub ahead of print] PMID: 22323475 [PubMed - as supplied by publisher]

  • Seminal Plasma Metals Concentration with Respect to Semen Quality. Li P, Zhong Y, Jiang X, Wang C, Zuo Z, Sha A. Biol Trace Elem Res. 2012 Feb 10. [Epub ahead of print] PMID: 22322880 [PubMed - as supplied by publisher]

  • Fermentable Carbohydrate Alters Hypothalamic Neuronal Activity and Protects Against the Obesogenic Environment. Anastasovska J, Arora T, Sanchez Canon GJ, Parkinson JR, Touhy K, R Gibson G, Nadkarni NA, So PW, Goldstone AP, Thomas EL, K Hankir M, Van Loo J, Modi N, Bell JD, Frost G. Obesity (Silver Spring). 2012 Jan 17. doi: 10.1038/oby.2012.6. [Epub ahead of print] PMID: 22322344 [PubMed - as supplied by publisher]

  • Tremor, olfactory and motor changes in Italian adolescents exposed to historical ferro-manganese emission. Lucchini RG, Guazzetti S, Zoni S, Donna F, Peter S, Zacco A, Salmistraro M, Bontempi E, Zimmerman NJ, Smith DR. Neurotoxicology. 2012 Jan 31. [Epub ahead of print] PMID: 22322213 [PubMed - as supplied by publisher]

  • Measuring hypoxia induced metal release from highly contaminated estuarine sediments during a 40day laboratory incubation experiment. Banks JL, Ross DJ, Keough MJ, Eyre BD, Macleod CK. Sci Total Environ. 2012 Feb 8. [Epub ahead of print] PMID: 22321900 [PubMed - as supplied by publisher]

  • Catalytic remediation of 2-propanol on Pt-Mn/?-Al(2)O(3) bimetallic catalyst during catalytic combustion-Experimental study and response surface methodology (RSM) modeling. Salari D, Niaei A, Aghazadeh F, Hosseini SA, Seyednajafi F. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012 Feb;47(3):351-7. PMID: 22320686 [PubMed - in process]

  • A healthy volunteer study to investigate trace element contamination of blood samples by stainless steel venepuncture needles. Hodnett D, Wood DM, Raja K, Dargan PI, Shah AD. Clin Toxicol (Phila). 2012 Feb;50(2):99-107. PMID: 22320210 [PubMed - in process]

  • Homogeneity and stability studies during the preparation of a laboratory reference material of soy leaves for the determination of metals. dos Santos AM, Lima DC, de Jesus RM, Ferreira SL. J AOAC Int. 2011 Nov-Dec;94(6):1906-10. PMID: 22320099 [PubMed - in process]

  • Initial Steps of Photosystem II de Novo Assembly and Preloading with Manganese Take Place in Biogenesis Centers in Synechocystis. Stengel A, Gügel IL, Hilger D, Rengstl B, Jung H, Nickelsen J. Plant Cell. 2012 Feb 7. [Epub ahead of print] PMID: 22319052 [PubMed - as supplied by publisher]

  • Physiologic implications of metal-ion transport by ZIP14 and ZIP8. Jenkitkasemwong S, Wang CY, Mackenzie B, Knutson MD. Biometals. 2012 Feb 9. [Epub ahead of print] PMID: 22318508 [PubMed - as supplied by publisher]

  • The Association of Manganese Superoxide Dismutase Expression in Barrett's Esophageal Progression With MnTBAP and Curcumin Oil Therapy. Schiffman SC, Li Y, Martin RC. J Surg Res. 2011 Dec 13. [Epub ahead of print] PMID: 22316666 [PubMed - as supplied by publisher]

  • Monte-Carlo simulations of the new LNHB manganese bath facility. Ogheard F, Chartier JL, Cassette P. Appl Radiat Isot. 2012 Jan 25. [Epub ahead of print] PMID: 22316586 [PubMed - as supplied by publisher]

  • Proteomic analysis of proteins associated with cellular senescence by calorie restriction in mesenchymal stem cells. Kim HJ, Ji BR, Kim JS, Lee HN, Ha DH, Kim CW. In Vitro Cell Dev Biol Anim. 2012 Feb 8. [Epub ahead of print] PMID: 22314686 [PubMed - as supplied by publisher]

  • Metal concentrations in the soils and native plants surrounding the old flotation tailings pond of the Copper Mining and Smelting Complex Bor (Serbia). Antonijevic MM, Dimitrijevic MD, Milic SM, Nujkic MM. J Environ Monit. 2012 Feb 8. [Epub ahead of print] PMID: 22314513 [PubMed - as supplied by publisher]

  • Research capacity development in South African manganese mines to bridge exposure and neuropathologic outcomes. Nelson G, Criswell SR, Zhang J, Murray J, Racette BA. Neurotoxicology. 2012 Jan 31. [Epub ahead of print] PMID: 22313906 [PubMed - as supplied by publisher]

  • Manganese toxicity with ephedrone abuse manifesting as parkinsonism: a case report. Iqbal M, Monaghan T, Redmond J. J Med Case Reports. 2012 Feb 7;6(1):52. [Epub ahead of print] PMID: 22313512 [PubMed - as supplied by publisher]

  • Occurrence and biodegradation of nonylphenol in the environment. Mao Z, Zheng XF, Zhang YQ, Tao XX, Li Y, Wang W. Int J Mol Sci. 2012;13(1):491-505. Epub 2012 Jan 4. PMID: 22312266 [PubMed - in process]

  • Influencing the Symmetry of High-Nuclearity and High-Spin Manganese Oxo-Clusters: Supramolecular Approaches to Manganese-Based Keplerates and Chiral Solids. Zhang L, Clérac R, Heijboer P, Schmitt W. Angew Chem Int Ed Engl. 2012 Feb 6. doi: 10.1002/anie.201107358. [Epub ahead of print] PMID: 22311623 [PubMed - as supplied by publisher]

  • Biodegradation of organic compounds of molasses melanoidin (MM) from biomethanated distillery spent wash (BMDS) during the decolourisation by a potential bacterial consortium. Yadav S, Chandra R. Biodegradation. 2012 Feb 5. [Epub ahead of print] PMID: 22311589 [PubMed - as supplied by publisher]

  • Metals in Fish along the Southeast Coast of India. Thiyagarajan D, Dhaneesh KV, Ajith Kumar TT, Kumaresan S, Balasubramanian T. Bull Environ Contam Toxicol. 2012 Feb 5. [Epub ahead of print] PMID: 22310845 [PubMed - as supplied by publisher]

Recent Research & Development for Boride

  • Planar four-coordinate boron: a single, flat boron atom as a ligand for four metals. Braunschweig H, Dewhurst RD, Kraft K, Ostreicher S, Radacki K. Angew Chem Int Ed Engl. 2012 Feb 27;51(9):2183-6. doi: 10.1002/anie.201107248. Epub 2012 Jan 17. PMID: 22253194 [PubMed - in process]

  • Boron oxynitride nanoclusters on tungsten trioxide as a metal-free cocatalyst for photocatalytic oxygen evolution from water splitting. Xie YP, Liu G, Lu GQ, Cheng HM. Nanoscale. 2012 Feb 2;4(4):1267-70. Epub 2012 Jan 13. PMID: 22241455 [PubMed - in process]

  • Effect of the disinfection agents chlorine, UV irradiation, silver ions, and TiO2 nanoparticles/near-UV on DNA molecules. Van Aken B, Lin LS. Water Sci Technol. 2011;64(6):1226-32. PMID: 22214074 [PubMed - indexed for MEDLINE]

  • Crystal structure refinement and bonding patterns of CrB4: a boron-rich boride with a framework of tetrahedrally coordinated B atoms. Knappschneider A, Litterscheid C, Kurzman J, Seshadri R, Albert B. Inorg Chem. 2011 Nov 7;50(21):10540-2. Epub 2011 Oct 10. PMID: 21985336 [PubMed]

  • Tailored materials for high-performance MgB(2) wire. Kim JH, Oh S, Kumakura H, Matsumoto A, Heo YU, Song KS, Kang YM, Maeda M, Rindfleisch M, Tomsic M, Choi S, Dou SX. Adv Mater. 2011 Nov 9;23(42):4942-6. doi: 10.1002/adma.201101243. Epub 2011 Sep 28. No abstract available. PMID: 21956864 [PubMed - indexed for MEDLINE]

  • Synthesis, characterization, and electronic structure of new type of heterometallic boride clusters. Bose SK, Geetharani K, Sahoo S, Reddy KH, Varghese B, Jemmis ED, Ghosh S. Inorg Chem. 2011 Oct 3;50(19):9414-22. Epub 2011 Aug 29. PMID: 21875060 [PubMed - in process]

  • Scaffolding, ladders, chains, and rare ferrimagnetism in intermetallic borides: synthesis, crystal chemistry and magnetism. Goerens C, Brgoch J, Miller GJ, Fokwa BP. Inorg Chem. 2011 Jul 4;50(13):6289-96. Epub 2011 Jun 2. PMID: 21634389 [PubMed]

  • Wet-chemical synthesis of nanoscale iron boride, XAFS analysis and crystallisation to a-FeB. Rades S, Kornowski A, Weller H, Albert B. Chemphyschem. 2011 Jun 20;12(9):1756-60. doi: 10.1002/cphc.201001072. Epub 2011 May 12. PMID: 21567704 [PubMed]

  • Nickel bis-muth boride, Ni(23-x)Bi(x)B(6) [x = 2.44 (1)]. Berthebaud D, Sato A, Mori T. Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):i17. PMID: 21522814 [PubMed]

  • Thermal and stress studies of normal incidence Mo/B4C multilayers for a 6.7 nm wavelength. Barthelmess M, Bajt S. Appl Opt. 2011 Apr 10;50(11):1610-9. doi: 10.1364/AO.50.001610. PMID: 21478937 [PubMed]

  • New nickel gallium boride, B14Ga3Ni27: synthesis and crystal structure. Tillard M, Belin C. Inorg Chem. 2011 May 2;50(9):3907-12. Epub 2011 Apr 6. PMID: 21469649 [PubMed]

  • A general solution route toward metal boride nanocrystals. Portehault D, Devi S, Beaunier P, Gervais C, Giordano C, Sanchez C, Antonietti M. Angew Chem Int Ed Engl. 2011 Mar 28;50(14):3262-5. doi: 10.1002/anie.201006810. Epub 2011 Feb 25. No abstract available. PMID: 21432954 [PubMed]

  • Complete titanium substitution by boron in a tetragonal prism: exploring the complex boride series Ti(3-x)Ru(5-y)Ir(y)B(2+x) (0 = x = 1 and 1 < y < 3) by experiment and theory. Fokwa BP, Hermus M. Inorg Chem. 2011 Apr 18;50(8):3332-41. Epub 2011 Mar 23. PMID: 21428308 [PubMed - in process]

  • Two-dimensional intrinsic ferromagnetism at nitride-boride interfaces. Gohda Y, Tsuneyuki S. Phys Rev Lett. 2011 Jan 28;106(4):047201. Epub 2011 Jan 25. PMID: 21405354 [PubMed]

  • A General Solution Route toward Metal Boride Nanocrystals. Portehault D, Devi S, Beaunier P, Gervais C, Giordano C, Sanchez C, Antonietti M. Angew Chem Int Ed Engl. 2011 Mar 7. doi: 10.1002/anie.201101207. [Epub ahead of print] No abstract available. PMID: 21384481 [PubMed - as supplied by publisher]

  • LiB(12) PC, the First Boron-Rich Metal Boride with Phosphorus-Synthesis, Crystal Structure, Hardness, Spectroscopic Investigations. Vojteer N, Sagawe V, Stauffer J, Schroeder M, Hillebrecht H. Chemistry. 2011 Feb 9. doi: 10.1002/chem.201002968. [Epub ahead of print] PMID: 21308812 [PubMed - as supplied by publisher]

  • Effects of laser pulsing on analysis of steels by atom probe tomography. Liu F, Andrén HO. Ultramicroscopy. 2011 May;111(6):633-41. Epub 2010 Dec 19. PMID: 21239116 [PubMed]

  • Binary boron-rich borides of magnesium: single-crystal investigations and properties of MgB(7) and the new boride Mg(~5)B(44). Pediaditakis A, Schroeder M, Sagawe V, Ludwig T, Hillebrecht H. Inorg Chem. 2010 Dec 6;49(23):10882-93. Epub 2010 Nov 2. PMID: 21043472 [PubMed]

  • A photoelectrochemical immunosensor based on Au-doped TiO2 nanotube arrays for the detection of a-synuclein. An Y, Tang L, Jiang X, Chen H, Yang M, Jin L, Zhang S, Wang C, Zhang W. Chemistry. 2010 Dec 27;16(48):14439-46. PMID: 21038326 [PubMed - indexed for MEDLINE]

  • Study on boron-film thermal neutron converter prepared by pulsed laser deposition. Song ZF, Ye SZ, Chen ZY, Song L, Shen J. Appl Radiat Isot. 2011 Feb;69(2):443-7. Epub 2010 Sep 25. PMID: 20951052 [PubMed]

     


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