Manganese(II) Nitrate Hexahydrate

CAS #:

Linear Formula:

Mn(NO3)2 • 6H2O

MDL Number:

MFCD00149790

EC No.:

N/A

ORDER

PRODUCT Product Code ORDER SAFETY DATA TECHNICAL DATA
(2N) 99% Manganese(II) Nitrate Hexahydrate
MN-NAT-02-C.6HYD
Pricing > SDS > Data Sheet >
(3N) 99.9% Manganese(II) Nitrate Hexahydrate
MN-NAT-03-C.6HYD
Pricing > SDS > Data Sheet >
(4N) 99.99% Manganese(II) Nitrate Hexahydrate
MN-NAT-04-C.6HYD
Pricing > SDS > Data Sheet >
(5N) 99.999% Manganese(II) Nitrate Hexahydrate
MN-NAT-05-C.6HYD
Pricing > SDS > Data Sheet >

Manganese(II) Nitrate Hexahydrate Properties (Theoretical)

Compound Formula H12MnN2O12
Molecular Weight 287.04
Appearance Pink crystals or lump
Melting Point 26 °C
Boiling Point 129.4℃
Density 1.82 g/cm3
Solubility in H2O N/A
Exact Mass 286.977069
Monoisotopic Mass 286.977069

Manganese(II) Nitrate Hexahydrate Health & Safety Information

Signal Word Danger
Hazard Statements H272-H301-H332-H315-H319-H335
Hazard Codes Xn, Xi, O, C
Risk Codes 8-20/22-36/37/38
Safety Statements 9-17-26-36/37-60
RTECS Number QU9780000
Transport Information UN2724 5.1/PG III
WGK Germany N/A
GHS Pictograms

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 03/28/2024
Date Revised:01/15/2022

SECTION 1. IDENTIFICATION

Product Name: Manganese(II) Nitrate Hexahydrate

Product Number: All applicable American Elements product codes, e.g. MN-NAT-02-C.6HYD , MN-NAT-03-C.6HYD , MN-NAT-04-C.6HYD , MN-NAT-05-C.6HYD

CAS #: 17141-63-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Oxidizing solids Category 2
Acute oral toxicity Category 4
Skin Corrosion/Irritation Category 1 B
Serious Eye Damage/Eye Irritation Category 1
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system. Specific target organ toxicity - (repeated exposure) Category 2
Target Organs - Brain.
Signal Word
Danger
Hazard Statements
May intensify fire; oxidize
Harmful if swallowed
Causes severe skin burns and eye damage
May cause respiratory irritation
May cause damage to organs through prolonged or repeated exposure

Flame Over Circle - GHS03 Corrosion - GHS05 Exclamation Mark - GHS07 Health Hazard - GHS08

Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dust/fume/gas/mist/vapors/spray
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
Rinse mouth
Do NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Harmful to aquatic life with long lasting effects


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component / CAS-No / Weight %:
Manganese(II) nitrate hexahydrate / 17141-63-8 / <=100


SECTION 4. FIRST AID MEASURES

General Advice
Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Keep eye wide open while rinsing.
Skin Contact
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Call a physician immediately.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison
control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled
the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Ingestion
Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person.
Most important symptoms and effects
Causes burns by all exposure routes. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation
Notes to Physician
Treat symptomatically


SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media Not combustible. CO 2, dry chemical, dry sand, alcohol-resistant foam. Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Oxidizing Properties Oxidizer
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause fire. May ignite combustibles (wood paper, oil, clothing, etc.).
Hazardous Combustion Products
Nitrogen oxides (NOx). Manganese oxides.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health
3
Flammability
0
Instability
1
Physical hazards
- OX


SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions
Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing.
Environmental Precautions
Should not be released into the environment. Do not allow material to contaminate ground water system. See Section 12 for additional Ecological Information. Avoid release to the environment. Collect spillage. Do not flush into surface water or sanitary sewer system.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Sweep up and shovel into suitable containers for disposal


SECTION 7. HANDLING AND STORAGE

Handling
Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials.
Storage
Store under an inert atmosphere. Protect from moisture. Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store near combustible materials


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures
Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid
Appearance Pink
Odor Odorless
Odor Threshold No information available
pH No information available
Melting Point/Range ~ 26 °C / 78.8 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula MnN2 O6.6H2 O
Molecular Weight 287.04 (178.95anhy)


SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard Yes
Stability Hygroscopic. Oxidizer: Contact with combustible/organic material may cause fire.
Conditions to Avoid Exposure to moist air or water. Incompatible products. Excess heat.
Combustible material.
Incompatible Materials Strong reducing agents, Combustible material
Hazardous Decomposition Products Nitrogen oxides (NOx), Manganese oxides
Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing.


SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available. Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure Brain
Aspiration hazard No information available
Symptoms / effects,both acute and delayed
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.


SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
May cause long-term adverse effects in the environment. Do not allow material to contaminate ground water system. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment.
Persistence and Degradability based on information available. May persist
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility


SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.


SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
TDG
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
IATA
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III
IMDG/IMO
UN-No UN2724
Proper Shipping Name MANGANESE NITRATE
Hazard Class 5.1
Packing Group III


SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
OSHA - Occupational Safety and
Health Administration
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals. Other International Regulations
Mexico - Grade No information available


SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

About Manganese(II) Nitrate Hexahydrate

High purity Manganese(II) Nitrate Hexahydrate Nitrate IonManganese(II) Nitrate Hexahydrate is a highly water soluble crystalline Manganese source for uses compatible with nitrates and lower (acidic) pH. Nitrate compounds are generally soluble in water. Nitrate materials are also oxidizing agents. When mixed with hydrocarbons, nitrate compounds can form a flammable mixture. Nitrates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale (nanoparticles and nanopowders) materials. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms (Symbol: NO3) for a total formula weight of 62.05. Manganese Nitrate is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. We also produce Manganese Nitrate Solution. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards. Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Manganese(II) Nitrate Hexahydrate Synonyms

Manganous nitrate hexahydrate; manganese dinitrate hexahydrate; manganese(2+) dinitrate hexahydrate; Mananese(2+) nitrate hexahydrate; Manganous nitrate hexahydrate; nitric acid, manganese(2+) salt, hexahydrate

Chemical Identifiers

Linear Formula Mn(NO3)2 • 6H2O
MDL Number MFCD00149790
EC No. N/A
Beilstein/Reaxys No. N/A
Pubchem CID 17814495
IUPAC Name Manganese(2+); dinitrate; hexahydrate
SMILES O.[Mn+2].O.O.O.O.O.[O-]N(=O)=O.[O-]N(=O)=O
InchI Identifier InChI=1S/Mn.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;
InchI Key YMKHJSXMVZVZNU-UHFFFAOYSA-N

Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Manganese

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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