5,10,15,20-Tetrakis(4-sulfonatophenyl)-21H,23H-porphine Manganese(III) Chloride is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions.
5,10,15,20-Tetrakis(4-sulfonatophenyl)-21H,23H-porphine Manganese(III) Chloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available.
Manganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminumalloys. Manganese oxide is used in dry cell batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural amethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Citric acid production from Aspergillus niger MT-4 using hydrolysate extract of the insect Locusta migratoria.
Taskin M, Tasar GE, Incekara U.
Toxicol Ind Health. 2012 Feb 9. [Epub ahead of print]
PMID:
22323475
[PubMed - as supplied by publisher]
Seminal Plasma Metals Concentration with Respect to Semen Quality.
Li P, Zhong Y, Jiang X, Wang C, Zuo Z, Sha A.
Biol Trace Elem Res. 2012 Feb 10. [Epub ahead of print]
PMID:
22322880
[PubMed - as supplied by publisher]
Fermentable Carbohydrate Alters Hypothalamic Neuronal Activity and Protects Against the Obesogenic Environment.
Anastasovska J, Arora T, Sanchez Canon GJ, Parkinson JR, Touhy K, R Gibson G, Nadkarni NA, So PW, Goldstone AP, Thomas EL, K Hankir M, Van Loo J, Modi N, Bell JD, Frost G.
Obesity (Silver Spring). 2012 Jan 17. doi: 10.1038/oby.2012.6. [Epub ahead of print]
PMID:
22322344
[PubMed - as supplied by publisher]
Tremor, olfactory and motor changes in Italian adolescents exposed to historical ferro-manganese emission.
Lucchini RG, Guazzetti S, Zoni S, Donna F, Peter S, Zacco A, Salmistraro M, Bontempi E, Zimmerman NJ, Smith DR.
Neurotoxicology. 2012 Jan 31. [Epub ahead of print]
PMID:
22322213
[PubMed - as supplied by publisher]
Measuring hypoxia induced metal release from highly contaminated estuarine sediments during a 40day laboratory incubation experiment.
Banks JL, Ross DJ, Keough MJ, Eyre BD, Macleod CK.
Sci Total Environ. 2012 Feb 8. [Epub ahead of print]
PMID:
22321900
[PubMed - as supplied by publisher]
Catalytic remediation of 2-propanol on Pt-Mn/?-Al(2)O(3) bimetallic catalyst during catalytic combustion-Experimental study and response surface methodology (RSM) modeling.
Salari D, Niaei A, Aghazadeh F, Hosseini SA, Seyednajafi F.
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012 Feb;47(3):351-7.
PMID:
22320686
[PubMed - in process]
A healthy volunteer study to investigate trace element contamination of blood samples by stainless steel venepuncture needles.
Hodnett D, Wood DM, Raja K, Dargan PI, Shah AD.
Clin Toxicol (Phila). 2012 Feb;50(2):99-107.
PMID:
22320210
[PubMed - in process]
Homogeneity and stability studies during the preparation of a laboratory reference material of soy leaves for the determination of metals.
dos Santos AM, Lima DC, de Jesus RM, Ferreira SL.
J AOAC Int. 2011 Nov-Dec;94(6):1906-10.
PMID:
22320099
[PubMed - in process]
Initial Steps of Photosystem II de Novo Assembly and Preloading with Manganese Take Place in Biogenesis Centers in Synechocystis.
Stengel A, Gügel IL, Hilger D, Rengstl B, Jung H, Nickelsen J.
Plant Cell. 2012 Feb 7. [Epub ahead of print]
PMID:
22319052
[PubMed - as supplied by publisher]
Physiologic implications of metal-ion transport by ZIP14 and ZIP8.
Jenkitkasemwong S, Wang CY, Mackenzie B, Knutson MD.
Biometals. 2012 Feb 9. [Epub ahead of print]
PMID:
22318508
[PubMed - as supplied by publisher]
The Association of Manganese Superoxide Dismutase Expression in Barrett's Esophageal Progression With MnTBAP and Curcumin Oil Therapy.
Schiffman SC, Li Y, Martin RC.
J Surg Res. 2011 Dec 13. [Epub ahead of print]
PMID:
22316666
[PubMed - as supplied by publisher]
Monte-Carlo simulations of the new LNHB manganese bath facility.
Ogheard F, Chartier JL, Cassette P.
Appl Radiat Isot. 2012 Jan 25. [Epub ahead of print]
PMID:
22316586
[PubMed - as supplied by publisher]
Proteomic analysis of proteins associated with cellular senescence by calorie restriction in mesenchymal stem cells.
Kim HJ, Ji BR, Kim JS, Lee HN, Ha DH, Kim CW.
In Vitro Cell Dev Biol Anim. 2012 Feb 8. [Epub ahead of print]
PMID:
22314686
[PubMed - as supplied by publisher]
Metal concentrations in the soils and native plants surrounding the old flotation tailings pond of the Copper Mining and Smelting Complex Bor (Serbia).
Antonijevic MM, Dimitrijevic MD, Milic SM, Nujkic MM.
J Environ Monit. 2012 Feb 8. [Epub ahead of print]
PMID:
22314513
[PubMed - as supplied by publisher]
Research capacity development in South African manganese mines to bridge exposure and neuropathologic outcomes.
Nelson G, Criswell SR, Zhang J, Murray J, Racette BA.
Neurotoxicology. 2012 Jan 31. [Epub ahead of print]
PMID:
22313906
[PubMed - as supplied by publisher]
Manganese toxicity with ephedrone abuse manifesting as parkinsonism: a case report.
Iqbal M, Monaghan T, Redmond J.
J Med Case Reports. 2012 Feb 7;6(1):52. [Epub ahead of print]
PMID:
22313512
[PubMed - as supplied by publisher]
Occurrence and biodegradation of nonylphenol in the environment.
Mao Z, Zheng XF, Zhang YQ, Tao XX, Li Y, Wang W.
Int J Mol Sci. 2012;13(1):491-505. Epub 2012 Jan 4.
PMID:
22312266
[PubMed - in process]
Influencing the Symmetry of High-Nuclearity and High-Spin Manganese Oxo-Clusters: Supramolecular Approaches to Manganese-Based Keplerates and Chiral Solids.
Zhang L, Clérac R, Heijboer P, Schmitt W.
Angew Chem Int Ed Engl. 2012 Feb 6. doi: 10.1002/anie.201107358. [Epub ahead of print]
PMID:
22311623
[PubMed - as supplied by publisher]
Biodegradation of organic compounds of molasses melanoidin (MM) from biomethanated distillery spent wash (BMDS) during the decolourisation by a potential bacterial consortium.
Yadav S, Chandra R.
Biodegradation. 2012 Feb 5. [Epub ahead of print]
PMID:
22311589
[PubMed - as supplied by publisher]
Metals in Fish along the Southeast Coast of India.
Thiyagarajan D, Dhaneesh KV, Ajith Kumar TT, Kumaresan S, Balasubramanian T.
Bull Environ Contam Toxicol. 2012 Feb 5. [Epub ahead of print]
PMID:
22310845
[PubMed - as supplied by publisher]
Self-assembly of a sulphur-terminated graphene nanoribbon within a single-walled carbon nanotube.
Chuvilin A, Bichoutskaia E, Gimenez-Lopez MC, Chamberlain TW, Rance GA, Kuganathan N, Biskupek J, Kaiser U, Khlobystov AN.
Nat Mater. 2011 Aug 7. doi: 10.1038/nmat3082. [Epub ahead of print]
PMID:
21822259
[PubMed - as supplied by publisher]
Crystallization and preliminary X-ray analysis of the yeast tRNA-thiouridine modification protein 1 (Tum1p).
Qiu R, Wang F, Liu M, Yang Z, Wu T, Ji C.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Aug 1;67(Pt 8):953-5. Epub 2011 Jul 27.
PMID:
21821903
[PubMed - in process]
Characterization of Bacillus thuringiensis L-isoleucine dioxygenase toward the production of useful amino acids.
Hibi M, Kawashima T, Kodera T, Smirnov SV, Sokolov PM, Sugiyama M, Shimizu S, Yokozeki K, Ogawa J.
Appl Environ Microbiol. 2011 Aug 5. [Epub ahead of print]
PMID:
21821743
[PubMed - as supplied by publisher]
Characterization of the sulfurtransferase family from Oryza sativa L.
Guretzki S, Papenbrock J.
Plant Physiol Biochem. 2011 Jul 23. [Epub ahead of print]
PMID:
21821426
[PubMed - as supplied by publisher]
Development of a small-scale bioreactor method to monitor the molecular diversity and environmental impacts of bacterial biofilm communities from an acid mine drainage impacted creek.
Cole M, Wrubel J, Henegan P, Janzen C, Holt J, Tobin T.
J Microbiol Methods. 2011 Jul 28. [Epub ahead of print]
PMID:
21821067
[PubMed - as supplied by publisher]
In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent-solute interaction and its activity toward adsorptive desulfurization of gas oil.
Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A.
J Hazard Mater. 2011 Jul 6. [Epub ahead of print]
PMID:
21820806
[PubMed - as supplied by publisher]
Stearoyl-CoA desaturase is an essential enzyme for the parasitic protist Trypanosoma brucei.
Alloatti A, Gupta S, Gualdrón-López M, Nguewa PA, Altabe SG, Deumer G, Wallemacq P, Michels PA, Uttaro AD.
Biochem Biophys Res Commun. 2011 Jul 28. [Epub ahead of print]
PMID:
21820408
[PubMed - as supplied by publisher]
The use of multi-element stable isotope analysis to monitor the origin of chondroitin sulfates.
Thomas F, Jamin E, Shimoo K, Nagao J, Osaki Y, Granier C.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2533-7. doi: 10.1002/rcm.5159.
PMID:
21818814
[PubMed - in process]
Sulphur isotopes in animal hair track distance to sea.
Zazzo A, Monahan FJ, Moloney AP, Green S, Schmidt O.
Rapid Commun Mass Spectrom. 2011 Sep 15;25(17):2371-8. doi: 10.1002/rcm.5131.
PMID:
21818798
[PubMed - in process]
Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-Like Molecules with Metal-Metal Multiple Bonds.
Fang W, He Q, Tan ZF, Liu CY, Lu X, Murillo CA.
Chemistry. 2011 Aug 4. doi: 10.1002/chem.201003693. [Epub ahead of print]
PMID:
21818792
[PubMed - as supplied by publisher]
Rhodovulum phaeolacus sp. nov. a phototrophic alphaproteobacterium isolated from a brown pond.
Venkata Naga Satya Lakshmi K, Sasikala C, Venkata Ramana V, Veera Venkata Ramaprasad E, Venkata Ramana C.
J Gen Appl Microbiol. 2011;57(3):145-51.
PMID:
21817826
[PubMed - in process]
Comparative data on effects of leading pretreatments and enzyme loadings and formulations on sugar yields from different switchgrass sources.
Wyman CE, Balan V, Dale BE, Elander RT, Falls M, Hames B, Holtzapple MT, Ladisch MR, Lee YY, Mosier N, Pallapolu VR, Shi J, Thomas SR, Warner RE.
Bioresour Technol. 2011 Jun 21. [Epub ahead of print]
PMID:
21816612
[PubMed - as supplied by publisher]
Target loads of atmospheric sulfur deposition for the protection and recovery of acid-sensitive streams in the Southern Blue Ridge Province.
Sullivan TJ, Cosby BJ, Jackson WA.
J Environ Manage. 2011 Aug 2. [Epub ahead of print]
PMID:
21816535
[PubMed - as supplied by publisher]
Differential effects of a post-anthesis fertilizer regimen on the wheat flour proteome determined by quantitative 2-DE.
Altenbach SB, Tanaka CK, Hurkman WJ, Whitehand LC, Vensel WH, Dupont FM.
Proteome Sci. 2011 Aug 4;9(1):46. [Epub ahead of print]
PMID:
21816081
[PubMed - as supplied by publisher]
Comparative toxicity of arsenic metabolites in human bladder cancer EJ-1 cells.
Naranmandura H, Michael CW, Xu S, Lee J, Leslie E, Weinfeld M, Le XC.
Chem Res Toxicol. 2011 Aug 4. [Epub ahead of print]
PMID:
21815631
[PubMed - as supplied by publisher]
The Effects of Different Garlic-derived Allyl Sulfides on Peroxidative Processes and Anaerobic Sulfur Metabolism in Mouse Liver.
Iciek MB, Kowalczyk-Pachel D, Kwiecien I, Dudek MB.
Phytother Res. 2011 Aug 4. doi: 10.1002/ptr.3572. [Epub ahead of print]
PMID:
21815229
[PubMed - as supplied by publisher]
A combined model of hepatic polyamine and sulfur amino acid metabolism to analyze S-adenosyl methionine availability.
Reyes-Palomares A, Montañez R, Sánchez-Jiménez F, Medina MA.
Amino Acids. 2011 Aug 4. [Epub ahead of print]
PMID:
21814788
[PubMed - as supplied by publisher]
Microbial gene functions enriched in the Deepwater Horizon deep-sea oil plume.
Lu Z, Deng Y, Van Nostrand JD, He Z, Voordeckers J, Zhou A, Lee YJ, Mason OU, Dubinsky EA, Chavarria KL, Tom LM, Fortney JL, Lamendella R, Jansson JK, D'haeseleer P, Hazen TC, Zhou J.
ISME J. 2011 Aug 4. doi: 10.1038/ismej.2011.91. [Epub ahead of print]
PMID:
21814288
[PubMed - as supplied by publisher]
1,1'-(3-Methyl-4-phenylthieno[2,3-b]thiophene-2,5-diyl)diethanone as a Building Block in Heterocyclic Synthesis. Novel Synthesis of Some Pyrazole and Pyrimidine Derivatives.
Mabkhot YN, Al-Majid AM, Barakat A, Alshahrani S, Siddiqui Y.
Molecules. 2011 Aug 3;16(8):6502-11.
PMID:
21814162
[PubMed - in process]
Towards the Growth of an Aligned Single-Layer MoS2 Film.
Kim D, Sun D, Lu W, Cheng Z, Zhu Y, Le D, Rahman TS, Bartels L.
Langmuir. 2011 Aug 3. [Epub ahead of print]
PMID:
21812475
[PubMed - as supplied by publisher]
5,10,15,20-Tetrakis(4-sulfonatophenyl)-21H,23H-porphine Manganese(III) Chloride is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions.
5,10,15,20-Tetrakis(4-sulfonatophenyl)-21H,23H-porphine Manganese(III) Chloride is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. Additional technical, research and safety information is available. 
Manganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminum alloys. Manganese oxide is used in dry cell
batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural 
amethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.
Sulfur is a Block P, Group 16, Period 3 element. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electronic configuration is [Ne]3s2 3p4. In its elemental form sulfur's CAS number is 7704-34-9. The sulfur atom has a radius of 100pm and it's Van der Waals radius is 180pm. Sulfur is a crucial element for all life and serves as both fuels and respiratory (oxygen-replacing) materials for simple organisms. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, Epsom salts, and barite. Sulfur, when organically bonded, is a component of all proteins, as the amino acids methionine 
and cysteine. In organic form, Sulfur is present in the vitamins thiamine and biotin. Sulfur is also a vital part of many enzymes and also in antioxidant molecules like glutathione and thioredoxin.Sulfur is available as compounds with purities from 99% to 99.9999% (ACS grade to ultra-high purity). Sulfur has been known since ancient times but was not accepted as an element until 1777. Antoine Lavoisier helped to convince the scientific commuity that sulfus is an element and not a compound. See Sulfur research below.
