Manganese Acetylacetonate is a Manganese source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and metallo-organic compounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Manganese Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Manganese Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Manganese include steel production to remove sulfur and oxygen, the colorant in natural amethyst stones and is used in glass and ceramics to also create the amethyst color.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Manganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminumalloys. Manganese oxide is used in dry cell batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural amethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Citric acid production from Aspergillus niger MT-4 using hydrolysate extract of the insect Locusta migratoria.
Taskin M, Tasar GE, Incekara U.
Toxicol Ind Health. 2012 Feb 9. [Epub ahead of print]
PMID:
22323475
[PubMed - as supplied by publisher]
Seminal Plasma Metals Concentration with Respect to Semen Quality.
Li P, Zhong Y, Jiang X, Wang C, Zuo Z, Sha A.
Biol Trace Elem Res. 2012 Feb 10. [Epub ahead of print]
PMID:
22322880
[PubMed - as supplied by publisher]
Fermentable Carbohydrate Alters Hypothalamic Neuronal Activity and Protects Against the Obesogenic Environment.
Anastasovska J, Arora T, Sanchez Canon GJ, Parkinson JR, Touhy K, R Gibson G, Nadkarni NA, So PW, Goldstone AP, Thomas EL, K Hankir M, Van Loo J, Modi N, Bell JD, Frost G.
Obesity (Silver Spring). 2012 Jan 17. doi: 10.1038/oby.2012.6. [Epub ahead of print]
PMID:
22322344
[PubMed - as supplied by publisher]
Tremor, olfactory and motor changes in Italian adolescents exposed to historical ferro-manganese emission.
Lucchini RG, Guazzetti S, Zoni S, Donna F, Peter S, Zacco A, Salmistraro M, Bontempi E, Zimmerman NJ, Smith DR.
Neurotoxicology. 2012 Jan 31. [Epub ahead of print]
PMID:
22322213
[PubMed - as supplied by publisher]
Measuring hypoxia induced metal release from highly contaminated estuarine sediments during a 40day laboratory incubation experiment.
Banks JL, Ross DJ, Keough MJ, Eyre BD, Macleod CK.
Sci Total Environ. 2012 Feb 8. [Epub ahead of print]
PMID:
22321900
[PubMed - as supplied by publisher]
Catalytic remediation of 2-propanol on Pt-Mn/?-Al(2)O(3) bimetallic catalyst during catalytic combustion-Experimental study and response surface methodology (RSM) modeling.
Salari D, Niaei A, Aghazadeh F, Hosseini SA, Seyednajafi F.
J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012 Feb;47(3):351-7.
PMID:
22320686
[PubMed - in process]
A healthy volunteer study to investigate trace element contamination of blood samples by stainless steel venepuncture needles.
Hodnett D, Wood DM, Raja K, Dargan PI, Shah AD.
Clin Toxicol (Phila). 2012 Feb;50(2):99-107.
PMID:
22320210
[PubMed - in process]
Homogeneity and stability studies during the preparation of a laboratory reference material of soy leaves for the determination of metals.
dos Santos AM, Lima DC, de Jesus RM, Ferreira SL.
J AOAC Int. 2011 Nov-Dec;94(6):1906-10.
PMID:
22320099
[PubMed - in process]
Initial Steps of Photosystem II de Novo Assembly and Preloading with Manganese Take Place in Biogenesis Centers in Synechocystis.
Stengel A, Gügel IL, Hilger D, Rengstl B, Jung H, Nickelsen J.
Plant Cell. 2012 Feb 7. [Epub ahead of print]
PMID:
22319052
[PubMed - as supplied by publisher]
Physiologic implications of metal-ion transport by ZIP14 and ZIP8.
Jenkitkasemwong S, Wang CY, Mackenzie B, Knutson MD.
Biometals. 2012 Feb 9. [Epub ahead of print]
PMID:
22318508
[PubMed - as supplied by publisher]
The Association of Manganese Superoxide Dismutase Expression in Barrett's Esophageal Progression With MnTBAP and Curcumin Oil Therapy.
Schiffman SC, Li Y, Martin RC.
J Surg Res. 2011 Dec 13. [Epub ahead of print]
PMID:
22316666
[PubMed - as supplied by publisher]
Monte-Carlo simulations of the new LNHB manganese bath facility.
Ogheard F, Chartier JL, Cassette P.
Appl Radiat Isot. 2012 Jan 25. [Epub ahead of print]
PMID:
22316586
[PubMed - as supplied by publisher]
Proteomic analysis of proteins associated with cellular senescence by calorie restriction in mesenchymal stem cells.
Kim HJ, Ji BR, Kim JS, Lee HN, Ha DH, Kim CW.
In Vitro Cell Dev Biol Anim. 2012 Feb 8. [Epub ahead of print]
PMID:
22314686
[PubMed - as supplied by publisher]
Metal concentrations in the soils and native plants surrounding the old flotation tailings pond of the Copper Mining and Smelting Complex Bor (Serbia).
Antonijevic MM, Dimitrijevic MD, Milic SM, Nujkic MM.
J Environ Monit. 2012 Feb 8. [Epub ahead of print]
PMID:
22314513
[PubMed - as supplied by publisher]
Research capacity development in South African manganese mines to bridge exposure and neuropathologic outcomes.
Nelson G, Criswell SR, Zhang J, Murray J, Racette BA.
Neurotoxicology. 2012 Jan 31. [Epub ahead of print]
PMID:
22313906
[PubMed - as supplied by publisher]
Manganese toxicity with ephedrone abuse manifesting as parkinsonism: a case report.
Iqbal M, Monaghan T, Redmond J.
J Med Case Reports. 2012 Feb 7;6(1):52. [Epub ahead of print]
PMID:
22313512
[PubMed - as supplied by publisher]
Occurrence and biodegradation of nonylphenol in the environment.
Mao Z, Zheng XF, Zhang YQ, Tao XX, Li Y, Wang W.
Int J Mol Sci. 2012;13(1):491-505. Epub 2012 Jan 4.
PMID:
22312266
[PubMed - in process]
Influencing the Symmetry of High-Nuclearity and High-Spin Manganese Oxo-Clusters: Supramolecular Approaches to Manganese-Based Keplerates and Chiral Solids.
Zhang L, Clérac R, Heijboer P, Schmitt W.
Angew Chem Int Ed Engl. 2012 Feb 6. doi: 10.1002/anie.201107358. [Epub ahead of print]
PMID:
22311623
[PubMed - as supplied by publisher]
Biodegradation of organic compounds of molasses melanoidin (MM) from biomethanated distillery spent wash (BMDS) during the decolourisation by a potential bacterial consortium.
Yadav S, Chandra R.
Biodegradation. 2012 Feb 5. [Epub ahead of print]
PMID:
22311589
[PubMed - as supplied by publisher]
Metals in Fish along the Southeast Coast of India.
Thiyagarajan D, Dhaneesh KV, Ajith Kumar TT, Kumaresan S, Balasubramanian T.
Bull Environ Contam Toxicol. 2012 Feb 5. [Epub ahead of print]
PMID:
22310845
[PubMed - as supplied by publisher]
Arsenic trioxide treatment decreases the oxygen consumption rate of tumor cells and radiosensitizes solid tumors.
Diepart C, Karroum O, Magat J, Feron O, Verrax J, Buc Calderon P, Grégoire V, Leveque P, Stockis J, Dauguet N, Jordan BF, Gallez B.
Cancer Res. 2011 Dec 2. [Epub ahead of print]
PMID:
22139377
[PubMed - as supplied by publisher]
Arsenic-Induced Straighthead: An Impending Threat to Sustainable Rice Production in South and South-East Asia!
Azizur Rahman M, Mamunur Rahman M, Hasegawa H.
Bull Environ Contam Toxicol. 2011 Dec 4. [Epub ahead of print]
PMID:
22139332
[PubMed - as supplied by publisher]
Comparative Soil Metal Analyses in Sudbury (Ontario, Canada) and Lubumbashi (Katanga, DR-Congo).
Narendrula R, Nkongolo KK, Beckett P.
Bull Environ Contam Toxicol. 2011 Dec 4. [Epub ahead of print]
PMID:
22139330
[PubMed - as supplied by publisher]
Purification, crystallization and preliminary X-ray diffraction studies of the arsenic repressor ArsR from Corynebacterium glutamicum.
Santha S, Pandaranayaka EP, Rosen BP, Thiyagarajan S.
Acta Crystallogr Sect F Struct Biol Cryst Commun. 2011 Dec 1;67(Pt 12):1616-8. Epub 2011 Nov 26.
PMID:
22139180
[PubMed - in process]
Arsenic contamination and speciation in surrounding waters of three old cinnabar mines.
Larios R, Fernández-Martínez R, Silva V, Loredo J, Rucandio I.
J Environ Monit. 2011 Dec 5. [Epub ahead of print]
PMID:
22139034
[PubMed - as supplied by publisher]
Arsenic Exposure and Hypertension: A Systematic Review.
Abhyankar LN, Jones MR, Guallar E, Navas-Acien A.
Environ Health Perspect. 2011 Dec 2. [Epub ahead of print]
PMID:
22138666
[PubMed - as supplied by publisher]
Metals in biology: defining metalloproteomes.
Yannone SM, Hartung S, Menon AL, Adams MW, Tainer JA.
Curr Opin Biotechnol. 2011 Dec 2. [Epub ahead of print]
PMID:
22138493
[PubMed - as supplied by publisher]
Total and inorganic arsenic concentrations in different species of economically important algae harvested from coastal zones of Chile.
Díaz O, Tapia Y, Muñoz O, Montoro R, Velez D, Almela C.
Food Chem Toxicol. 2011 Nov 25. [Epub ahead of print]
PMID:
22138359
[PubMed - as supplied by publisher]
Zamzam water: Concentration of trace elements and other characteristics.
Shomar B.
Chemosphere. 2011 Dec 2. [Epub ahead of print]
PMID:
22138338
[PubMed - as supplied by publisher]
Removal of methylated arsenic using a nanostructured zirconia-based sorbent: Process performance and adsorption chemistry.
Zheng YM, Yu L, Chen JP.
J Colloid Interface Sci. 2011 Oct 12. [Epub ahead of print]
PMID:
22137855
[PubMed - as supplied by publisher]
Humans seem to produce arsenobetaine and dimethylarsinate after a bolus dose of seafood.
Molin M, Ulven SM, Dahl L, Telle-Hansen VH, Holck M, Skjegstad G, Ledsaak O, Sloth JJ, Goessler W, Oshaug A, Alexander J, Fliegel D, Ydersbond TA, Meltzer HM.
Environ Res. 2011 Dec 1. [Epub ahead of print]
PMID:
22137101
[PubMed - as supplied by publisher]
A modified batch reactor system to study equilibrium-reactive transport problems.
Jeppu GP, Clement TP, Barnett MO, Lee KK.
J Contam Hydrol. 2011 Oct 20. [Epub ahead of print]
PMID:
22136983
[PubMed - as supplied by publisher]
Identification of the GST-T1 and GST-M1 Null Genotypes using High Resolution Melting Analysis.
Drobna Z, Del Razo LM, Garcia-Vargas G, Sanchez-Ramirez B, Gonzalez-Horta C, Ballinas ML, Loomis D, Styblo M.
Chem Res Toxicol. 2011 Dec 2. [Epub ahead of print]
PMID:
22136492
[PubMed - as supplied by publisher]
Uranium and trace elements in phosphate fertilizers-saudi arabia.
Khater AE.
Health Phys. 2012 Jan;102(1):63-70.
PMID:
22134079
[PubMed - in process]
Natural attenuation of arsenic in soils near a highly contaminated historical mine waste dump.
Drahota P, Filippi M, Ettler V, Rohovec J, Mihaljevic M, Sebek O.
Sci Total Environ. 2011 Nov 29. [Epub ahead of print]
PMID:
22134035
[PubMed - as supplied by publisher]
Removing arsenic from synthetic groundwater with iron electrocoagulation: An Fe and As K-edge EXAFS study.
van Genuchten CM, Addy SE, Pena J, Gadgil A.
Environ Sci Technol. 2011 Dec 1. [Epub ahead of print]
PMID:
22132945
[PubMed - as supplied by publisher]
Embryotoxicity assessment of developmental neurotoxicants using a neuronal endpoint in the embryonic stem cell test.
Baek DH, Kim TG, Lim HK, Kang JW, Seong SK, Choi SE, Lim SY, Park SH, Nam BH, Kim EH, Kim MS, Park KL.
J Appl Toxicol. 2011 Dec 1. doi: 10.1002/jat.1747. [Epub ahead of print]
PMID:
22131109
[PubMed - as supplied by publisher]
Comparing different means of signal treatment for improving the detection power in HPLC-ICP-MS.
Prikler S, Pick D, Einax JW.
Anal Bioanal Chem. 2011 Dec 1. [Epub ahead of print]
PMID:
22130722
[PubMed - as supplied by publisher]
Biological monitoring versus air monitoring strategies in assessing environmental-occupational exposure.
Jakubowski M.
J Environ Monit. 2011 Dec 1. [Epub ahead of print]
PMID:
22130625
[PubMed - as supplied by publisher]
Overexpression of alfalfa mitochondrial HSP23 in prokaryotic and eukaryotic model systems confers enhanced tolerance to salinity and arsenic stress.
Lee KW, Cha JY, Kim KH, Kim YG, Lee BH, Lee SH.
Biotechnol Lett. 2011 Nov 30. [Epub ahead of print]
PMID:
22127759
[PubMed - as supplied by publisher]