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Manganese Acetylacetonate
Mn(CH3COCHCOCH3)2
14024-58-9

Product Product Code Order or Specifications
(2N) 99% Manganese Acetylacetonate MN-ACAC-02 Contact American Elements
(3N) 99.9% Manganese Acetylacetonate MN-ACAC-03 Contact American Elements
(4N) 99.99% Manganese Acetylacetonate MN-ACAC-04 Contact American Elements
(5N) 99.999% Manganese Acetylacetonate MN-ACAC-05 Contact American Elements

 

CHEMICAL
IDENTIFICATION
Formula CAS No. PubChem
SID
PubChem CID MDL No. EC No IUPAC Name Beilstein
Re. No.
SMILES
Identifier
InChI
Identifier
InChI
Key
Mn(CH3COCHCOCH3)2 14024-58-9 24854756 407386 MFCD00000022 237-858-2 4-hydroxypent-3-en-2-one: manganese 4157965 [Mn+2].O=C(/C=C(\[O-])C)C.[O-]\C(=C/C(=O)C)C InChI=1S/2C5H8O2.Mn/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-; ZQZQURFYFJBOCE-FDGPNNRMSA-L

Compound Formula Mol. Wt. Appearance Density

Exact Mass

Monoisotopic Mass Charge MSDS
Mn(CH3COCHCOCH3)2 253.15 Tan g/cm3 255.043 255.043 0 Safety Data Sheet


Acetylaceton Formula Diagram (C5H8O2)Manganese Acetylacetonate is a Manganese source that is soluble in organic solvents as an organometallic compound (also known as metalorganic, organo-inorganic and Acetylacetonate Packaging, Lab Quantitymetallo-organic compounds). The high purity acetylacetonate anion complexes by bonding each oxygen atom to the metallic cation to form a chelate ring.Because of this property, Manganese Acetylacetonate is commonly used in various catalysts and catalytic reagents for organic synthesis. It is generally immediately available in most volumes. Ultra high purity and high purity forms may be considered. Manganese Acetylacetonate is one of numerous organo-metallic compounds (also known as metalorganic, organo-inorganic and metallo-organic compounds) sold by American Elements under the tradename AE Organo-Metallics™ for uses requiring non-aqueous solubility such as recent solar energy and water treatment applications. Similar results can sometimes also be achieved with Nanoparticles (also see Nanotechnology and Quantum Dots) and by thin film deposition. Note American Elements additionally supplies many materials as solutions. The numerous commercial applications for Manganese include steel production to remove sulfur and oxygen, the colorant in natural amethyst stones and is used in glass and ceramics to also create the amethyst color.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.

Manganese(Mn) atomic and molecular weight, atomic number and elemental symbolManganese is a Block D, Group 7, Period 4 element. The number of electrons in each of Manganese's shells is 2, 8, 13, 2 and its electronic configuration is [Ar] 3d5 4s2. In its elemental form manganese's CAS number is 7439-96-5. The manganese atom has a radius of 136.7.pm and it's Van der Waals radius is 200.pm. Manganese in excess is toxic, in particular the inhalation of manganese in powder or dust form. Manganese metal is a key component of aluminum alloys. Manganese oxide is used in dry cellManganese Bohr Model batteries. Manganese is used in steel production to remove sulfur and oxygen. Manganese is the colorant in natural Elemental Manganeseamethyst stones and is used in glass and ceramics to also create the amethyst color. It is used like the element cerium to "decolorize" glass by offsetting the green from impurities of ferric ions. Permanganate is a powerful oxidizing agent and is used in medicine. It is added as a nutritional supplement for both human and animal consumption. Recently, the oxide in the form of various perovskite structures have demonstrated applications in oxygen generation and solid oxide fuel cells. Manganese was first discovered by Johann Gahn in 1774. The name Manganese originates from the Latin word mangnes meaning magnet. See Manganese research below.

Have a Question? Ask a Chemical Engineer or Material Scientist   Request an MSDS or Certificate of Analysis

 
Safety &
Handling
  Exclamation Mark-Acute Toxicity Health Hazard
Signal Word Hazard Statements Hazard Codes Risk Codes Safety Precautions RTECS No. Transport Information WGK Germany
Warning H302-H312-H315-H319-H332-H335-H351 Xn 20/21/22-36/37/38-40 26-36 OO9350000 N/A 3

 

Synonyms for Manganese Acetylacetonate Include:


Mn(acac)2
Manganous acetylacetonate
2,4-Pentanedione manganese(II) derivative
Bis(acetylacetonato)manganese
Manganese; pentane-2,4-dione

 

PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES


Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.


 


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Recent Research & Development for Manganese

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  • Tremor, olfactory and motor changes in Italian adolescents exposed to historical ferro-manganese emission. Lucchini RG, Guazzetti S, Zoni S, Donna F, Peter S, Zacco A, Salmistraro M, Bontempi E, Zimmerman NJ, Smith DR. Neurotoxicology. 2012 Jan 31. [Epub ahead of print] PMID: 22322213 [PubMed - as supplied by publisher]

  • Measuring hypoxia induced metal release from highly contaminated estuarine sediments during a 40day laboratory incubation experiment. Banks JL, Ross DJ, Keough MJ, Eyre BD, Macleod CK. Sci Total Environ. 2012 Feb 8. [Epub ahead of print] PMID: 22321900 [PubMed - as supplied by publisher]

  • Catalytic remediation of 2-propanol on Pt-Mn/?-Al(2)O(3) bimetallic catalyst during catalytic combustion-Experimental study and response surface methodology (RSM) modeling. Salari D, Niaei A, Aghazadeh F, Hosseini SA, Seyednajafi F. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2012 Feb;47(3):351-7. PMID: 22320686 [PubMed - in process]

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  • The Association of Manganese Superoxide Dismutase Expression in Barrett's Esophageal Progression With MnTBAP and Curcumin Oil Therapy. Schiffman SC, Li Y, Martin RC. J Surg Res. 2011 Dec 13. [Epub ahead of print] PMID: 22316666 [PubMed - as supplied by publisher]

  • Monte-Carlo simulations of the new LNHB manganese bath facility. Ogheard F, Chartier JL, Cassette P. Appl Radiat Isot. 2012 Jan 25. [Epub ahead of print] PMID: 22316586 [PubMed - as supplied by publisher]

  • Proteomic analysis of proteins associated with cellular senescence by calorie restriction in mesenchymal stem cells. Kim HJ, Ji BR, Kim JS, Lee HN, Ha DH, Kim CW. In Vitro Cell Dev Biol Anim. 2012 Feb 8. [Epub ahead of print] PMID: 22314686 [PubMed - as supplied by publisher]

  • Metal concentrations in the soils and native plants surrounding the old flotation tailings pond of the Copper Mining and Smelting Complex Bor (Serbia). Antonijevic MM, Dimitrijevic MD, Milic SM, Nujkic MM. J Environ Monit. 2012 Feb 8. [Epub ahead of print] PMID: 22314513 [PubMed - as supplied by publisher]

  • Research capacity development in South African manganese mines to bridge exposure and neuropathologic outcomes. Nelson G, Criswell SR, Zhang J, Murray J, Racette BA. Neurotoxicology. 2012 Jan 31. [Epub ahead of print] PMID: 22313906 [PubMed - as supplied by publisher]

  • Manganese toxicity with ephedrone abuse manifesting as parkinsonism: a case report. Iqbal M, Monaghan T, Redmond J. J Med Case Reports. 2012 Feb 7;6(1):52. [Epub ahead of print] PMID: 22313512 [PubMed - as supplied by publisher]

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  • Influencing the Symmetry of High-Nuclearity and High-Spin Manganese Oxo-Clusters: Supramolecular Approaches to Manganese-Based Keplerates and Chiral Solids. Zhang L, Clérac R, Heijboer P, Schmitt W. Angew Chem Int Ed Engl. 2012 Feb 6. doi: 10.1002/anie.201107358. [Epub ahead of print] PMID: 22311623 [PubMed - as supplied by publisher]

  • Biodegradation of organic compounds of molasses melanoidin (MM) from biomethanated distillery spent wash (BMDS) during the decolourisation by a potential bacterial consortium. Yadav S, Chandra R. Biodegradation. 2012 Feb 5. [Epub ahead of print] PMID: 22311589 [PubMed - as supplied by publisher]

  • Metals in Fish along the Southeast Coast of India. Thiyagarajan D, Dhaneesh KV, Ajith Kumar TT, Kumaresan S, Balasubramanian T. Bull Environ Contam Toxicol. 2012 Feb 5. [Epub ahead of print] PMID: 22310845 [PubMed - as supplied by publisher]
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