Molybdenum Acetate is a moderately water soluble crystalline Molybdenum source that decomposes to Molybdenum oxide on heating. It is generally immediately available in most volumes. Acetates are excellent precursors for production of ultra high purity compounds and certain catalyst and nanoscale(nanoparticles and nanopowders) materials. All metallic acetates are inorganic salts of a metal cation and the acetate anion. The acetate anion is a univalent (-1 charge) polyatomic ion composed of two carbon atoms ionically bound to three hydrogen and two oxygen atoms (Symbol: CH3COO) for a total formula weight of 59.05. High purity, submicron and nanopowder forms may be considered.American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia)and follows applicable ASTM testing standards.Typical and custom packaging is available. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Molybdenum is a Block D, Group 6, Period 5 element. The number of electrons in each of Molybdenum's shells is 2, 8, 18, 13, 1 and its electronic configuration is [Kr] 4d5 5s1. In its elemental form molybdenum's CAS number is 7439-98-7. The molybdenum atom has a radius of 136.3.pm and it's Van der Waals radius is 200.pm. Molybdenum is toxic unless it is in small quantities. Molybdenum has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum is a catalyst in the oil refining. It has many other applications, including in catalysts, pigments, corrosion inhibitors and lubricants. It has a very high elastic modulus. Molybdenum is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder. It is used in steel alloys to add hardness and raise melting points. It is a component in Hastelloys brand steel. Molybdenum is used in nuclear reactors and aerospace components. Molybdenum was first discovered by Carl Wilhelm in 1778. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead. See Molybdenum research below.
Acetate is an anion used as a ligand in metal complexes. The formula is CH3CO2-, C2H3O2-, or CH3COO-. Metal acetates are used in biology, printing, vinyl acetate in plastic production, volatile organic esters as solvents and cellulose acetate in photographic films and textiles. Cellulose acetate, one of the first synthetic fibers, is often called acetate.
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.
Process development for the separation and recovery of Mo and Co from chloride leach liquors of petroleum refining catalyst by solvent extraction.
Banda R, Sohn SH, Lee MS.
J Hazard Mater. 2012 Jan 9. [Epub ahead of print]
PMID:
22336581
[PubMed - as supplied by publisher]
Selective cleavage of pepsin by molybdenum metallopeptidase.
Yenjai S, Malaikaew P, Liwporncharoenvong T, Buranaprapuk A.
Biochem Biophys Res Commun. 2012 Feb 5. [Epub ahead of print]
PMID:
22330807
[PubMed - as supplied by publisher]
Iminopyridine Complexes of Manganese, Rhenium, and Molybdenum Derived from Amino Ester Methylserine and Peptides Gly-Gly, Gly-Val, and Gly-Gly-Gly: Self-Assembly of the Peptide Chains.
Alvarez CM, García-Rodríguez R, Miguel D.
Inorg Chem. 2012 Feb 13. [Epub ahead of print]
PMID:
22329711
[PubMed - as supplied by publisher]
Low-Temperature, Solution-Processed MoO(x) for Efficient and Stable Organic Solar Cells.
Zilberberg K, Gharbi H, Behrendt A, Trost S, Riedl T.
ACS Appl Mater Interfaces. 2012 Feb 15. [Epub ahead of print]
PMID:
22324481
[PubMed - as supplied by publisher]
A molecular MoS? edge site mimic for catalytic hydrogen generation.
Karunadasa HI, Montalvo E, Sun Y, Majda M, Long JR, Chang CJ.
Science. 2012 Feb 10;335(6069):698-702.
PMID:
22323816
[PubMed - in process]
The use of total reflectance X-ray fluorescence (TXRF) for the determination of metals in the pharmaceutical industry.
Antosz FJ, Xiang Y, Diaz AR, Jensen AJ.
J Pharm Biomed Anal. 2012 Jan 16. [Epub ahead of print]
PMID:
22316622
[PubMed - as supplied by publisher]
Kinetic Resolution of Planar-Chiral (?(6) -Arene)Chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis.
Ogasawara M, Wu WY, Arae S, Watanabe S, Morita T, Takahashi T, Kamikawa K.
Angew Chem Int Ed Engl. 2012 Feb 3. doi: 10.1002/anie.201108292. [Epub ahead of print]
PMID:
22308166
[PubMed - as supplied by publisher]
Measurement of mass attenuation coefficients of Rhizophora spp. binderless particleboards in the 16.59-25.26keV photon energy range and their density profile using x-ray computed tomography.
Marashdeh MW, Bauk S, Tajuddin AA, Hashim R.
Appl Radiat Isot. 2012 Jan 20. [Epub ahead of print]
PMID:
22304963
[PubMed - as supplied by publisher]
Nitrite and Nitrite Reductases: From Molecular Mechanisms to Significance in Human Health and Disease.
Castiglione N, Rinaldo S, Giardina G, Stelitano V, Cutruzzolà F.
Antioxid Redox Signal. 2012 Feb 5. [Epub ahead of print]
PMID:
22304560
[PubMed - as supplied by publisher]
Molybdenum(vi) catalysts obtained from ?(3)-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation.
Gamelas CA, Gomes AC, Bruno SM, Almeida Paz FA, Valente AA, Pillinger M, Romão CC, Gonçalves IS.
Dalton Trans. 2012 Feb 2. [Epub ahead of print]
PMID:
22302175
[PubMed - as supplied by publisher]
Field-Effect Tunneling Transistor Based on Vertical Graphene Heterostructures.
Britnell L, Gorbachev RV, Jalil R, Belle BD, Schedin F, Mishchenko A, Georgiou T, Katsnelson MI, Eaves L, Morozov SV, Peres NM, Leist J, Geim AK, Novoselov KS, Ponomarenko LA.
Science. 2012 Feb 2. [Epub ahead of print]
PMID:
22300848
[PubMed - as supplied by publisher]
Spectroscopic reflectometry of mirror surfaces during plasma exposure.
Wisse M, Eren B, Marot L, Steiner R, Meyer E.
Rev Sci Instrum. 2012 Jan;83(1):013509.
PMID:
22299953
[PubMed - in process]
[Absorption characteristics of molybdenum by reed and cattail].
Lian JJ, Xu SG, Han CW.
Huan Jing Ke Xue. 2011 Nov;32(11):3335-40. Chinese.
PMID:
22295632
[PubMed - in process]
Conserved Signal Peptide Recognition Systems across the Prokaryotic Domains.
Coulthurst SJ, Dawson A, Hunter WN, Sargent F.
Biochemistry. 2012 Feb 13. [Epub ahead of print]
PMID:
22289056
[PubMed - as supplied by publisher]
Two methods can simultaneously display both intramuscular nerves and blood vessels.
Yu DZ, Liu AT, Zhang JL, Dang RS, Chen G, Liu BL, Han T, Yi J, Nagasao T, Jiang H.
Plast Reconstr Surg. 2012 Feb;129(2):401-11.
PMID:
22286423
[PubMed - in process]
Synthesis, characterization and biological activities of some new chromium molybdenum and tungsten complexes with 2,6-diaminopyridine.
Soliman AA, Ali SA, Marei AH, Nassar DH.
Spectrochim Acta A Mol Biomol Spectrosc. 2012 Apr;89:329-32. Epub 2011 Dec 30.
PMID:
22286054
[PubMed - in process]
Tuning the Photochromic Properties of Molybdenum Bisphosphonate Polyoxometalates.
El Moll H, Dolbecq A, Mbomekalle IM, Marrot J, Deniard P, Dessapt R, Mialane P.
Inorg Chem. 2012 Jan 27. [Epub ahead of print]
PMID:
22283587
[PubMed - as supplied by publisher]
In vivo evaluation of defined polished titanium surfaces to prevent soft tissue adhesion.
Hayes JS, Welton JL, Wieling R, Richards RG.
J Biomed Mater Res B Appl Biomater. 2012 Jan 27. doi: 10.1002/jbm.b.31967. [Epub ahead of print]
PMID:
22282225
[PubMed - as supplied by publisher]
Reaction dynamics of Mo + O(2) ? MoO + O studied by a crossed-beam velocity map imaging technique.
Honma K, Matsumoto Y.
J Chem Phys. 2012 Jan 21;136(3):034301.
PMID:
22280754
[PubMed - in process]
A new class of electrocatalysts for hydrogen production from water electrolysis: metal monolayers supported on low-cost transition metal carbides.
Esposito DV, Hunt ST, Kimmel YC, Chen JG.
J Am Chem Soc. 2012 Feb 15;134(6):3025-33. Epub 2012 Feb 1.
PMID:
22280370
[PubMed - in process]
Recent Research & Development for Acetates
Effect of different solvent extracts of Benincasa hispida T. on experimental hypochlorhydria in rat.
Mandal U, De D, Ali KM, Biswas A, Ghosh D.
J Adv Pharm Technol Res. 2012 Jan;3(1):41-6.
PMID:
22470892
[PubMed - in process]
The effect of nitrogen enrichment on c(1)-cycling microorganisms and methane flux in salt marsh sediments.
Irvine IC, Vivanco L, Bentley PN, Martiny JB.
Front Microbiol. 2012;3:90. Epub 2012 Mar 19.
PMID:
22470369
[PubMed - in process]
PKCα phosphorylation of RhoGDI2 at Ser31 disrupts interactions with Rac1 and decreases GDI activity.
Griner EM, Churchill ME, Brautigan DL, Theodorescu D.
Oncogene. 2012 Apr 2. doi: 10.1038/onc.2012.124. [Epub ahead of print]
PMID:
22469974
[PubMed - as supplied by publisher]
Influence of precursor solvent properties on drug release rates from nanoparticle aerosol lipid matrices.
Pawar AA, Chen DR, Venkataraman C.
Int J Pharm. 2012 Mar 23. [Epub ahead of print]
PMID:
22469694
[PubMed - as supplied by publisher]
Sex hormone-binding globulin as a marker for the thrombotic risk of hormonal contraceptives.
Raps M, Helmerhorst F, Fleischer K, Thomassen S, Rosendaal F, Rosing J, Ballieux B, van Vliet H.
J Thromb Haemost. 2012 Mar 31. doi: 10.1111/j.1538-7836.2012.04720.x. [Epub ahead of print]
PMID:
22469296
[PubMed - as supplied by publisher]
Protective role of chrysin against oxidative stress in d-galactose-induced aging in an experimental rat model.
Anand KV, Mohamed Jaabir MS, Thomas PA, Geraldine P.
Geriatr Gerontol Int. 2012 Apr 2. doi: 10.1111/j.1447-0594.2012.00843.x. [Epub ahead of print]
PMID:
22469068
[PubMed - as supplied by publisher]
Modulation of Metallophilic Bonds: Solvent-Induced Isomerization and Luminescence Vapochromism of a Polymorphic Au-Cu Cluster.
Koshevoy IO, Chang YC, Karttunen AJ, Haukka M, Pakkanen TA, Chou PT.
J Am Chem Soc. 2012 Apr 2. [Epub ahead of print]
PMID:
22469012
[PubMed - as supplied by publisher]
Experiment on formulation and drug release behavior of porosity asymmetric membrane capsules in vitro.
Fu HX, Li H, Zhang FZ, Zhao YZ, Wan CW, Chen MT, Jia XC, Yan L, Sun CC, Xu YY.
Drug Dev Ind Pharm. 2012 Apr 3. [Epub ahead of print]
PMID:
22469006
[PubMed - as supplied by publisher]
An overview of the development of combined oral contraceptives containing estradiol: focus on estradiol valerate/dienogest.
Fruzzetti F, Trémollieres F, Bitzer J.
Gynecol Endocrinol. 2012 Apr 2. [Epub ahead of print]
PMID:
22468839
[PubMed - as supplied by publisher]
A novel approach to test the relative recovery of liquid-phase standard in sorbent-tube analysis of gaseous VOCs.
Kim YH, Kim KH.
Anal Chem. 2012 Apr 2. [Epub ahead of print]
PMID:
22468653
[PubMed - as supplied by publisher]
[Purification of complicated industrial organic waste gas by complex absorption].
Chen DS, Cen CP, Tang ZX, Fang P, Chen ZH.
Huan Jing Ke Xue. 2011 Dec;32(12):3680-4. Chinese.
PMID:
22468539
[PubMed - in process]
Determination of natural pesticides in fresh fruits using liquid chromatography/mass spectrometry.
Ruiz I, Morales A, Barba A, Oliva J.
J AOAC Int. 2012 Jan-Feb;95(1):238-43.
PMID:
22468366
[PubMed - in process]
Bacteria, colonic fermentation, and gastrointestinal health.
Macfarlane GT, Macfarlane S.
J AOAC Int. 2012 Jan-Feb;95(1):50-60.
PMID:
22468341
[PubMed - in process]
Effect of Vitamin E on sP-Selectin Levels in Pre-Eclampsia.
Wangkheimayum S, Kumar S, Suri V.
Indian J Clin Biochem. 2011 Apr;26(2):169-71. Epub 2011 Jan 13.
PMID:
22468044
[PubMed - in process]
Serum cystatin C levels in renal transplant recipients.
Krishnamurthy N, Arumugasamy K, Anand U, Anand CV, Aruna V, Venu G.
Indian J Clin Biochem. 2011 Apr;26(2):120-4. Epub 2010 Nov 19.
PMID:
22468036
[PubMed - in process]
Intravaginal ring delivery of tenofovir disoproxil fumarate for prevention of HIV and herpes simplex virus infection.
Mesquita PM, Rastogi R, Segarra TJ, Teller RS, Torres NM, Huber AM, Kiser PF, Herold BC.
J Antimicrob Chemother. 2012 Mar 30. [Epub ahead of print]
PMID:
22467632
[PubMed - as supplied by publisher]
Identification of pesticide transformation products in agricultural soils using liquid chromatography/quadrupole-time-of-flight mass spectrometry.
Padilla-Sánchez JA, Michael Thurman E, Plaza-Bolaños P, Ferrer I.
Rapid Commun Mass Spectrom. 2012 May 15;26(9):1091-9. doi: 10.1002/rcm.6206.
PMID:
22467459
[PubMed - in process]
Determination of organophosphorus pesticide residues in vegetables by an enzyme inhibition method using α-naphthyl acetate esterase extracted from wheat flour.
Wang JL, Xia Q, Zhang AP, Hu XY, Lin CM.
J Zhejiang Univ Sci B. 2012 Apr;13(4):267-73.
PMID:
22467368
[PubMed - in process]
MICE LACKING MACROPHAGE 12/15-LIPOXYGENASE ARE RESISTANT TO EXPERIMENTAL HYPERTENSION.
Kriska T, Cepura C, Magier D, Siangjong L, Gauthier KM, Campbell WB.
Am J Physiol Heart Circ Physiol. 2012 Mar 30. [Epub ahead of print]
PMID:
22467300
[PubMed - as supplied by publisher]
Development and validation of a UPLC-ESI-MS/MS method for the determination of N-butylscopolamine in human plasma: Application to a bioequivalence study.
Favreto WA, Pugens Pinto AM, Manfio JL, Fiametti KG, Percio MF, Santos MB.
Drug Test Anal. 2012 Mar;4(3-4):215-21. doi: 10.1002/dta.403.
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