|Formula||CAS No.||PubChem SID||PubChem CID||MDL No.||EC No||IUPAC Name||Beilstein
|PROPERTIES||Compound Formula||Mol. Wt.||Appearance||Melting Point||Boiling Point||Density||Monoisotopic Mass||Charge||MSDS|
|MoS2||160.07||black solid||1,185° C
|N/A||5.06 g/cm3||161.849549||161.849549||0||Safety Data Sheet|
Molybdenum Sulfide or Molybdenum Disulfide is a moderately water and acid soluble Molybdenum source for uses compatible with sulfates. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Most metal sulfate compounds are readily soluble in water for uses such as water treatment, unlike fluorides and oxides which tend to be insoluble. Organometallic forms are soluble in organic solutions and sometimes in both aqueous and organic solutions. Metallic ions can also be dispersed utilizing suspended or coated nanoparticles (See also application discussion at Nanotechnology Information and at Quantum Dots) and deposited utilizing sputtering targets and evaporation materials for uses such as solar energy materials and fuel cells. Molybdenum Sulfide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale (See also Nanotechnology Information and Quantum Dots) elemental powders and suspensions, as alternative high surface area forms, may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopeia/British Pharmacopeia) and follows applicable ASTM testing standards. Additional technical, research and safety (MSDS) information is available as is a Reference Calculator for converting relevant units of measurement.
Molybdenum (atomic symbol: Mo, atomic number: 42) is a Block D, Group 6, Period 5 element with an atomic weight of 95.96. The number of electrons in each of molybdenum's shells is [2, 8, 18, 13, 1] and its electron configuration is [Kr] 4d5 5s1. The molybdenum atom has a radius of 139 pm and a Van der Waals radius of 209 pm. In its elemental form, molybdenum has a gray metallic appearance. Molybdenum was discovered by Carl Wilhelm in 1778 and first isolated by Peter Jacob Hjelm in 1781. Molybdenum is the 54th most abundant element in the earth's crust. It has the third highest melting point of any element, exceeded only by tungsten and tantalum. Molybdenum does not occur naturally as a free metal, it is found in various oxidation states in minerals. The primary commercial source of molybdenum is molybdenite, although it is also recovered as a byproduct of copper and tungsten mining. The origin of the name Molybdenum comes from the Greek word molubdos meaning lead. For more information on molybdenum, including properties, safety data, research, and American Elements' catalog of molybdenum products, visit the Molybdenum Information Center.
Sulfur or Sulphur (atomic symbol: S, atomic number: 16) is a Block P, Group 16, Period 3 element with an atomic radius of 32.066. The number of electrons in each of Sulfur's shells is 2, 8, 6 and its electron configuration is [Ne]3s2 3p4. In its elemental form, sulfur has a light yellow appearance. The sulfur atom has a covalent radius of 105 pm and a Van der Waals radius of 180 pm. In nature, sulfur can be found in hot springs, meteorites, volcanoes, and as galena, gypsum, and epsom salts. Sulfur has been known since ancient times but was not accepted as an element until 1777 when Antoine Lavoisier helped to convince the scientific community that it was an element and not a compound. For more information on sulfur, including properties, safety data, research, and American Elements' catalog of sulfur products, visit the Sulfur Information Center.
|HEALTH, SAFETY & TRANSPORTATION INFORMATION|
|Material Safety Data Sheet||MSDS|
|Globally Harmonized System of
Classification and Labelling (GHS)
|MOLYBDENUM SULFIDE SYNONYMS|
|Molybdenum(IV) sulfide, Molybdenite, Molykote, hydrogen sulfide; molybdenum, Molybdenum disulphide, Molykote, bis(sulfanylidene)molybdenum, Molysulfide, Nichimoly C, Sumipowder PA, Molykote Z, disulfanylidene molybdenum, dithioxomolybdenum, molybdenum disulfide|
PACKAGING SPECIFICATIONS FOR BULK & RESEARCH QUANTITIES
|Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Material Safety Data Sheet (MSDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes.|
Recent Research & Development for Molybdenum
- Sub-femtomolar DNA detection based on layered molybdenum disulfide/multi-walled carbon nanotube composites, Au nanoparticle and enzyme multiple signal amplification. Huang KJ, Liu YJ, Wang HB, Wang YY, Liu YM. Biosens Bioelectron. 2014 May
- Electro-reduction of nitrogen on molybdenum nitride: structure, energetics, and vibrational spectra from DFT. Matanovic I, Garzon FH, Henson NJ. Phys Chem Chem Phys. 2014 Feb.
- Automated in-chip kinetic-catalytic method for molybdenum determination. Phansi P, Henríquez C, Palacio E, Nacapricha D, Cerdà V. Talanta. 2014 Feb.
- Nano-molybdenum carbide/carbon nanotubes composite as bifunctional anode catalyst for high-performance Escherichia coli-based microbial fuel cell. Biosens Bioelectron. 2014 create date:2013/09/03 | first author:Wang Y.
- Molybdenum cofactor: A key component of Mycobacterium tuberculosis pathogenesis? Williams M, Mizrahi V, Kana BD. Crit Rev Microbiol. 2014 Feb.
- Method validation for simultaneous determination of chromium, molybdenum and selenium in infant formulas by ICP-OES and ICP-MS. Food Chem. 2013 create date:2013/09/03 | first author:Khan N.
- The reactivity of molybdenum pentachloride with ethers: routes to the synthesis of Mo(IV)Cl4 adducts, Mo(v) chlorido-alkoxides and Mo(v) oxydo-chlorides. Dalton Trans. 2013 create date:2013/09/06 | first author:Marchetti F
- Tungsten and molybdenum incomplete cuboidal clusters; kinetico-mechanistic studies and association in dimers. Dalton Trans. 2013 create date:2013/09/03 | first author:Hernandez-Molina R
- Elastic bending modulus of single-layer molybdenum disulfide (MoS2): finite thickness effect. Nanotechnology. 2013 | first author:Jiang JW
- Iron-molybdenum-oxo complexes as initiators for olefin autoxidation with O(2.) Dalton Trans. 2013 | first author:Falkenhagen JP
- Hopping transport through defect-induced localized states in molybdenum disulphide. Nat Commun. 2013 | first author:Qiu H
- Effect of exchange of the cysteine molybdenum ligand by selenocysteine on structure and function of the active site in human sulfite oxidase. Biochemistry. 2013 | first author:Reschke S
- Tris(3,5-di-tert-butylcatecholato)molybdenum(VI): Lewis Acidity and Nonclassical Oxygen Atom Transfer Reactions. Inorg Chem. 2013 | first author:Randolph AH
- Graphene-molybdenum oxynitride porous material with improved cyclic stability and rate capability for rechargeable lithium ion batteries. Phys Chem Chem Phys. 2013 | first author:Zhou D
- Alkene to carbyne: tandem lewis Acid activation and dehydrogenation of a molybdenum ethylene complex. Angew Chem Int Ed Engl. 2013 | first author:Stennett TE
- The interaction of molybdenum pentachloride with O- and S-heterocycles. Dalton Trans. 2013 create date:2013/10/15 | first author:Favero L
- Highly Active, Low-Valence Molybdenum- and Tungsten-Amide Catalysts for Bifunctional Imine-Hydrogenation Reactions. Chem Asian J. 2013 | first author:Chakraborty S
- Revealing and accelerating slow electron transport in amorphous molybdenum sulphide particles for hydrogen evolution reaction. Chem Commun (Camb). 2013 | first author:Vrubel H
- Gypsum addition to soils contaminated by red mud: implications for aluminium, arsenic, molybdenum and vanadium solubility. Environ Geochem Health. 2013 | first author:Lehoux AP
- Trace elements (copper, zinc, selenium and molybdenum) as markers in oral sub mucous fibrosis and oral squamous cell carcinoma. J Trace Elem Med Biol. 2013 create date:2013/05/15 | first author:Khanna S
Recent Research & Development for Sulfides
- Hydrogen sulfide and cell signaling: Team player or referee? Hancock JT, Whiteman M. Plant Physiol Biochem. 2014.
- Reactive iron sulfide (FeS)-supported ultrafiltration for removal of mercury (Hg(II)) from water. Han DS, Orillano M, Khodary A, Duan Y, Batchelor B, Abdel-Wahab A. Water Res. 2014.
- Kinetic and stoichiometric characterization of anoxic sulfide oxidation by SO-NR mixed cultures from anoxic biotrickling filters. Mora M, Fernández M, Gómez JM, Cantero D, Lafuente J, Gamisans X, Gabriel D. Appl Microbiol Biotechnol. 2014.
- Synthesis of nickel sulfide nanoparticles loaded on activated carbon as a novel adsorbent for the competitive removal of Methylene blue and Safranin-O. Ghaedi M, Pakniat M, Mahmoudi Z, Hajati S, Sahraei R, Daneshfar A. Spectrochim Acta A Mol Biomol Spectrosc. 2014
- Disturbance of endogenous hydrogen sulfide generation and endoplasmic reticulum stress in hippocampus are involved in homocysteine-induced defect in learning and memory of rats. Li MH, Tang JP, Zhang P, Li X, Wang CY, Wei HJ, Yang XF, Zou W, Tang XQ. Behav Brain Res. 2014
- Biochemical and behavioural responses of the marine polychaete Hediste diversicolor to cadmium sulfide quantum dots (CdS QDs): Waterborne and dietary exposure. Buffet PE, Poirier L, Zalouk-Vergnoux A, Lopes C, Amiard JC, Gaudin P, Risso-de Faverney C, Guibbolini M, Gilliland D, Perrein-Ettajani H, Valsami-Jones E, Mouneyrac C. Chemosphere. 2014
- GYY4137, a hydrogen sulfide (H2S) donor, shows potent anti-hepatocellular carcinoma activity through blocking the STAT3 pathway. Lu S, Gao Y, Huang X, Wang X. Int J Oncol. 2014
- Manipulating surface ligands of Copper Sulfide nanocrystals: Synthesis, characterization, and application to organic solar cells. Li J, Jiu T, Tao GH, Wang G, Sun C, Li P, Fang J, He L. J Colloid Interface Sci. 2014
- Recolonization of macrozoobenthos on defaunated sediments in a hypertrophic brackish lagoon: Effects of sulfide removal and sediment grain size. Kanaya G. Mar Environ Res. 2014
- Experimental design based response surface methodology optimization of ultrasonic assisted adsorption of safaranin O by tin sulfide nanoparticle loaded on activated carbon. Roosta M, Ghaedi M, Daneshfar A, Sahraei R. Spectrochim Acta A Mol Biomol Spectrosc. 2014
- Metal sulfide-functionalized DNA concatamer for ultrasensitive electronic monitoring of ATP using a programmable capillary-based aptasensor. Liu B, Zhang B, Chen G, Yang H, Tang D. Biosens Bioelectron. 2014 Mar.
- Self-assembly of manganese doped zinc sulfide quantum dots/CTAB nanohybrids for detection of rutin. Biosens Bioelectron. 2014 | first author:Miao Y
- Silver sulfide nanoparticles sensitized titanium dioxide nanotube arrays synthesized by in situ sulfurization for photocatalytic hydrogen production. J Colloid Interface Sci. 2014 | first author:Liu X
- A sensitive method for the sulfur isotope analysis of dimethyl sulfide and dimethylsulfoniopropionate in seawater. Rapid Commun Mass Spectrom. 2013 | first author:Said-Ahmad W
- Target-stimulated metallic HgS nanostructures on a DNA-based polyion complex membrane for highly efficient impedimetric detection of dissolved hydrogen sulfide. Chem Commun (Camb). 2013 | first author:Zhuang J
- A fatal work-related poisoning by hydrogen sulfide: report on a case. Am J Forensic Med Pathol. 2013 create date:2013/11/08 | first author:Lancia M
- Highly enantioselective oxidation of phenyl methyl sulfide and its derivatives into optically pure (S)-sulfoxides with Rhodococcus sp. CCZU10-1 in an n-octane-water biphasic system. Appl Microbiol Biotechnol. 2013 create date:2013/10/05 | first author:He YC
- Biochemical properties of nematode O-acetylserine(thiol)lyase paralogs imply their distinct roles in hydrogen sulfide homeostasis. Biochim Biophys Acta. 2013 | first author:Vozdek R
- Involvement of hydrogen sulfide and homocysteine transsulfuration pathway in the progression of kidney fibrosis after ureteral obstruction. Biochim Biophys Acta. 2013 | first author:Jung KJ
- High electrocatalytic activity of self-standing hollow NiCo2S4 single crystalline nanorod arrays towards sulfide redox shuttles in quantum dot-sensitized solar cells. Chem Commun (Camb). | first author:Xiao J